Selective conversion of allyl alcohol to oxygenates and hydrocarbons using ion exchanged zeolite Y
Abstract The reaction of allyl alcohol using zeolite Y as catalyst has been investigated and it is shown that it can be converted into a range of products, including hydrocarbons, acrolein and diallyl ether. Control of product selectivity can be achieved by careful selection and manipulation of the...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Hutchings, Graham J. [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1995 |
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| Schlagwörter: |
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| Systematik: |
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| Anmerkung: |
© J.C. Baltzer AG, Science Publishers 1995 |
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| Übergeordnetes Werk: |
Enthalten in: Catalysis letters - Baltzer Science Publishers, Baarn/Kluwer Academic Publishers, 1988, 34(1995), 1-2 vom: März, Seite 115-127 |
|---|---|
| Übergeordnetes Werk: |
volume:34 ; year:1995 ; number:1-2 ; month:03 ; pages:115-127 |
| Links: |
|---|
| DOI / URN: |
10.1007/BF00808328 |
|---|
| Katalog-ID: |
OLC2040134298 |
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| 520 | |a Abstract The reaction of allyl alcohol using zeolite Y as catalyst has been investigated and it is shown that it can be converted into a range of products, including hydrocarbons, acrolein and diallyl ether. Control of product selectivity can be achieved by careful selection and manipulation of the charge balancing cation, a series of catalysts can be prepared which, for the conversion of allyl alcohol, lead almost exclusively to the initial formation of either (a) $ C_{2} $-$ C_{6} $ hydrocarbons and coke (H-NaY), (b) acrolein (H-CsY), (c) propene (Li-NaY) or (d) diallyl ether (Cs-NaY). The effects of addition of $ H_{2} $ and $ H_{2} $O to the reactant are described and discussed with respect to the reaction mechanism and the reaction of potential intermediates (2-propanol and propene oxide) is also described. Mechanisms of formation of the major products are proposed that involve the concerted action of Brønsted acid and basic sites within the zeolite. In particular, since the addition of $ H_{2} $O does not affect the product distribution, it is considered that the mechanism of hydrocarbon formation does not involve the allyl cation as an intermediate. | ||
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10.1007/BF00808328 doi (DE-627)OLC2040134298 (DE-He213)BF00808328-p DE-627 ger DE-627 rakwb eng 540 660 VZ VA 2890 VZ rvk Hutchings, Graham J. verfasserin aut Selective conversion of allyl alcohol to oxygenates and hydrocarbons using ion exchanged zeolite Y 1995 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © J.C. Baltzer AG, Science Publishers 1995 Abstract The reaction of allyl alcohol using zeolite Y as catalyst has been investigated and it is shown that it can be converted into a range of products, including hydrocarbons, acrolein and diallyl ether. Control of product selectivity can be achieved by careful selection and manipulation of the charge balancing cation, a series of catalysts can be prepared which, for the conversion of allyl alcohol, lead almost exclusively to the initial formation of either (a) $ C_{2} $-$ C_{6} $ hydrocarbons and coke (H-NaY), (b) acrolein (H-CsY), (c) propene (Li-NaY) or (d) diallyl ether (Cs-NaY). The effects of addition of $ H_{2} $ and $ H_{2} $O to the reactant are described and discussed with respect to the reaction mechanism and the reaction of potential intermediates (2-propanol and propene oxide) is also described. Mechanisms of formation of the major products are proposed that involve the concerted action of Brønsted acid and basic sites within the zeolite. In particular, since the addition of $ H_{2} $O does not affect the product distribution, it is considered that the mechanism of hydrocarbon formation does not involve the allyl cation as an intermediate. zeolite Y allyl alcohol conversion acrolein acetone propene oxide Lee, Darren F. aut Enthalten in Catalysis letters Baltzer Science Publishers, Baarn/Kluwer Academic Publishers, 1988 34(1995), 1-2 vom: März, Seite 115-127 (DE-627)130436550 (DE-600)644234-1 (DE-576)025720724 1011-372X nnns volume:34 year:1995 number:1-2 month:03 pages:115-127 https://doi.org/10.1007/BF00808328 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2006 GBV_ILN_2016 GBV_ILN_4012 GBV_ILN_4305 GBV_ILN_4314 VA 2890 AR 34 1995 1-2 03 115-127 |
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10.1007/BF00808328 doi (DE-627)OLC2040134298 (DE-He213)BF00808328-p DE-627 ger DE-627 rakwb eng 540 660 VZ VA 2890 VZ rvk Hutchings, Graham J. verfasserin aut Selective conversion of allyl alcohol to oxygenates and hydrocarbons using ion exchanged zeolite Y 1995 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © J.C. Baltzer AG, Science Publishers 1995 Abstract The reaction of allyl alcohol using zeolite Y as catalyst has been investigated and it is shown that it can be converted into a range of products, including hydrocarbons, acrolein and diallyl ether. Control of product selectivity can be achieved by careful selection and manipulation of the charge balancing cation, a series of catalysts can be prepared which, for the conversion of allyl alcohol, lead almost exclusively to the initial formation of either (a) $ C_{2} $-$ C_{6} $ hydrocarbons and coke (H-NaY), (b) acrolein (H-CsY), (c) propene (Li-NaY) or (d) diallyl ether (Cs-NaY). The effects of addition of $ H_{2} $ and $ H_{2} $O to the reactant are described and discussed with respect to the reaction mechanism and the reaction of potential intermediates (2-propanol and propene oxide) is also described. Mechanisms of formation of the major products are proposed that involve the concerted action of Brønsted acid and basic sites within the zeolite. In particular, since the addition of $ H_{2} $O does not affect the product distribution, it is considered that the mechanism of hydrocarbon formation does not involve the allyl cation as an intermediate. zeolite Y allyl alcohol conversion acrolein acetone propene oxide Lee, Darren F. aut Enthalten in Catalysis letters Baltzer Science Publishers, Baarn/Kluwer Academic Publishers, 1988 34(1995), 1-2 vom: März, Seite 115-127 (DE-627)130436550 (DE-600)644234-1 (DE-576)025720724 1011-372X nnns volume:34 year:1995 number:1-2 month:03 pages:115-127 https://doi.org/10.1007/BF00808328 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2006 GBV_ILN_2016 GBV_ILN_4012 GBV_ILN_4305 GBV_ILN_4314 VA 2890 AR 34 1995 1-2 03 115-127 |
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10.1007/BF00808328 doi (DE-627)OLC2040134298 (DE-He213)BF00808328-p DE-627 ger DE-627 rakwb eng 540 660 VZ VA 2890 VZ rvk Hutchings, Graham J. verfasserin aut Selective conversion of allyl alcohol to oxygenates and hydrocarbons using ion exchanged zeolite Y 1995 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © J.C. Baltzer AG, Science Publishers 1995 Abstract The reaction of allyl alcohol using zeolite Y as catalyst has been investigated and it is shown that it can be converted into a range of products, including hydrocarbons, acrolein and diallyl ether. Control of product selectivity can be achieved by careful selection and manipulation of the charge balancing cation, a series of catalysts can be prepared which, for the conversion of allyl alcohol, lead almost exclusively to the initial formation of either (a) $ C_{2} $-$ C_{6} $ hydrocarbons and coke (H-NaY), (b) acrolein (H-CsY), (c) propene (Li-NaY) or (d) diallyl ether (Cs-NaY). The effects of addition of $ H_{2} $ and $ H_{2} $O to the reactant are described and discussed with respect to the reaction mechanism and the reaction of potential intermediates (2-propanol and propene oxide) is also described. Mechanisms of formation of the major products are proposed that involve the concerted action of Brønsted acid and basic sites within the zeolite. In particular, since the addition of $ H_{2} $O does not affect the product distribution, it is considered that the mechanism of hydrocarbon formation does not involve the allyl cation as an intermediate. zeolite Y allyl alcohol conversion acrolein acetone propene oxide Lee, Darren F. aut Enthalten in Catalysis letters Baltzer Science Publishers, Baarn/Kluwer Academic Publishers, 1988 34(1995), 1-2 vom: März, Seite 115-127 (DE-627)130436550 (DE-600)644234-1 (DE-576)025720724 1011-372X nnns volume:34 year:1995 number:1-2 month:03 pages:115-127 https://doi.org/10.1007/BF00808328 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2006 GBV_ILN_2016 GBV_ILN_4012 GBV_ILN_4305 GBV_ILN_4314 VA 2890 AR 34 1995 1-2 03 115-127 |
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10.1007/BF00808328 doi (DE-627)OLC2040134298 (DE-He213)BF00808328-p DE-627 ger DE-627 rakwb eng 540 660 VZ VA 2890 VZ rvk Hutchings, Graham J. verfasserin aut Selective conversion of allyl alcohol to oxygenates and hydrocarbons using ion exchanged zeolite Y 1995 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © J.C. Baltzer AG, Science Publishers 1995 Abstract The reaction of allyl alcohol using zeolite Y as catalyst has been investigated and it is shown that it can be converted into a range of products, including hydrocarbons, acrolein and diallyl ether. Control of product selectivity can be achieved by careful selection and manipulation of the charge balancing cation, a series of catalysts can be prepared which, for the conversion of allyl alcohol, lead almost exclusively to the initial formation of either (a) $ C_{2} $-$ C_{6} $ hydrocarbons and coke (H-NaY), (b) acrolein (H-CsY), (c) propene (Li-NaY) or (d) diallyl ether (Cs-NaY). The effects of addition of $ H_{2} $ and $ H_{2} $O to the reactant are described and discussed with respect to the reaction mechanism and the reaction of potential intermediates (2-propanol and propene oxide) is also described. Mechanisms of formation of the major products are proposed that involve the concerted action of Brønsted acid and basic sites within the zeolite. In particular, since the addition of $ H_{2} $O does not affect the product distribution, it is considered that the mechanism of hydrocarbon formation does not involve the allyl cation as an intermediate. zeolite Y allyl alcohol conversion acrolein acetone propene oxide Lee, Darren F. aut Enthalten in Catalysis letters Baltzer Science Publishers, Baarn/Kluwer Academic Publishers, 1988 34(1995), 1-2 vom: März, Seite 115-127 (DE-627)130436550 (DE-600)644234-1 (DE-576)025720724 1011-372X nnns volume:34 year:1995 number:1-2 month:03 pages:115-127 https://doi.org/10.1007/BF00808328 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2006 GBV_ILN_2016 GBV_ILN_4012 GBV_ILN_4305 GBV_ILN_4314 VA 2890 AR 34 1995 1-2 03 115-127 |
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10.1007/BF00808328 doi (DE-627)OLC2040134298 (DE-He213)BF00808328-p DE-627 ger DE-627 rakwb eng 540 660 VZ VA 2890 VZ rvk Hutchings, Graham J. verfasserin aut Selective conversion of allyl alcohol to oxygenates and hydrocarbons using ion exchanged zeolite Y 1995 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © J.C. Baltzer AG, Science Publishers 1995 Abstract The reaction of allyl alcohol using zeolite Y as catalyst has been investigated and it is shown that it can be converted into a range of products, including hydrocarbons, acrolein and diallyl ether. Control of product selectivity can be achieved by careful selection and manipulation of the charge balancing cation, a series of catalysts can be prepared which, for the conversion of allyl alcohol, lead almost exclusively to the initial formation of either (a) $ C_{2} $-$ C_{6} $ hydrocarbons and coke (H-NaY), (b) acrolein (H-CsY), (c) propene (Li-NaY) or (d) diallyl ether (Cs-NaY). The effects of addition of $ H_{2} $ and $ H_{2} $O to the reactant are described and discussed with respect to the reaction mechanism and the reaction of potential intermediates (2-propanol and propene oxide) is also described. Mechanisms of formation of the major products are proposed that involve the concerted action of Brønsted acid and basic sites within the zeolite. In particular, since the addition of $ H_{2} $O does not affect the product distribution, it is considered that the mechanism of hydrocarbon formation does not involve the allyl cation as an intermediate. zeolite Y allyl alcohol conversion acrolein acetone propene oxide Lee, Darren F. aut Enthalten in Catalysis letters Baltzer Science Publishers, Baarn/Kluwer Academic Publishers, 1988 34(1995), 1-2 vom: März, Seite 115-127 (DE-627)130436550 (DE-600)644234-1 (DE-576)025720724 1011-372X nnns volume:34 year:1995 number:1-2 month:03 pages:115-127 https://doi.org/10.1007/BF00808328 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2006 GBV_ILN_2016 GBV_ILN_4012 GBV_ILN_4305 GBV_ILN_4314 VA 2890 AR 34 1995 1-2 03 115-127 |
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Selective conversion of allyl alcohol to oxygenates and hydrocarbons using ion exchanged zeolite Y |
| author_sort |
Hutchings, Graham J. |
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Catalysis letters |
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Catalysis letters |
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eng |
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500 - Science 600 - Technology |
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marc |
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1995 |
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115 |
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Hutchings, Graham J. Lee, Darren F. |
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34 |
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540 660 VZ VA 2890 VZ rvk |
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Aufsätze |
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Hutchings, Graham J. |
| doi_str_mv |
10.1007/BF00808328 |
| dewey-full |
540 660 |
| title_sort |
selective conversion of allyl alcohol to oxygenates and hydrocarbons using ion exchanged zeolite y |
| title_auth |
Selective conversion of allyl alcohol to oxygenates and hydrocarbons using ion exchanged zeolite Y |
| abstract |
Abstract The reaction of allyl alcohol using zeolite Y as catalyst has been investigated and it is shown that it can be converted into a range of products, including hydrocarbons, acrolein and diallyl ether. Control of product selectivity can be achieved by careful selection and manipulation of the charge balancing cation, a series of catalysts can be prepared which, for the conversion of allyl alcohol, lead almost exclusively to the initial formation of either (a) $ C_{2} $-$ C_{6} $ hydrocarbons and coke (H-NaY), (b) acrolein (H-CsY), (c) propene (Li-NaY) or (d) diallyl ether (Cs-NaY). The effects of addition of $ H_{2} $ and $ H_{2} $O to the reactant are described and discussed with respect to the reaction mechanism and the reaction of potential intermediates (2-propanol and propene oxide) is also described. Mechanisms of formation of the major products are proposed that involve the concerted action of Brønsted acid and basic sites within the zeolite. In particular, since the addition of $ H_{2} $O does not affect the product distribution, it is considered that the mechanism of hydrocarbon formation does not involve the allyl cation as an intermediate. © J.C. Baltzer AG, Science Publishers 1995 |
| abstractGer |
Abstract The reaction of allyl alcohol using zeolite Y as catalyst has been investigated and it is shown that it can be converted into a range of products, including hydrocarbons, acrolein and diallyl ether. Control of product selectivity can be achieved by careful selection and manipulation of the charge balancing cation, a series of catalysts can be prepared which, for the conversion of allyl alcohol, lead almost exclusively to the initial formation of either (a) $ C_{2} $-$ C_{6} $ hydrocarbons and coke (H-NaY), (b) acrolein (H-CsY), (c) propene (Li-NaY) or (d) diallyl ether (Cs-NaY). The effects of addition of $ H_{2} $ and $ H_{2} $O to the reactant are described and discussed with respect to the reaction mechanism and the reaction of potential intermediates (2-propanol and propene oxide) is also described. Mechanisms of formation of the major products are proposed that involve the concerted action of Brønsted acid and basic sites within the zeolite. In particular, since the addition of $ H_{2} $O does not affect the product distribution, it is considered that the mechanism of hydrocarbon formation does not involve the allyl cation as an intermediate. © J.C. Baltzer AG, Science Publishers 1995 |
| abstract_unstemmed |
Abstract The reaction of allyl alcohol using zeolite Y as catalyst has been investigated and it is shown that it can be converted into a range of products, including hydrocarbons, acrolein and diallyl ether. Control of product selectivity can be achieved by careful selection and manipulation of the charge balancing cation, a series of catalysts can be prepared which, for the conversion of allyl alcohol, lead almost exclusively to the initial formation of either (a) $ C_{2} $-$ C_{6} $ hydrocarbons and coke (H-NaY), (b) acrolein (H-CsY), (c) propene (Li-NaY) or (d) diallyl ether (Cs-NaY). The effects of addition of $ H_{2} $ and $ H_{2} $O to the reactant are described and discussed with respect to the reaction mechanism and the reaction of potential intermediates (2-propanol and propene oxide) is also described. Mechanisms of formation of the major products are proposed that involve the concerted action of Brønsted acid and basic sites within the zeolite. In particular, since the addition of $ H_{2} $O does not affect the product distribution, it is considered that the mechanism of hydrocarbon formation does not involve the allyl cation as an intermediate. © J.C. Baltzer AG, Science Publishers 1995 |
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| title_short |
Selective conversion of allyl alcohol to oxygenates and hydrocarbons using ion exchanged zeolite Y |
| url |
https://doi.org/10.1007/BF00808328 |
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2024-07-04T01:20:09.024Z |
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