Amination of alcohols, using Cu/Ni-based colloidal catalyst, for consecutive reaction system
Abstract Animation of dodecyl alcohol and monomethylamine (MMA, di-functional) using Cu/Ni-based colloidal catalyst stabilized by barium stearate, and its kinetic study were performed to effectively synthesize didodecylmethylamine (DDMA). For the initial 3–4 h when MMA/dodecyl alcohol mole ratio was...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Kimura, Hiroshi [verfasserIn] |
|---|
| Format: |
Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
2005 |
|---|
| Schlagwörter: |
|---|
| Systematik: |
|
|---|
| Anmerkung: |
© Springer Science+Business Media, Inc. 2005 |
|---|
| Übergeordnetes Werk: |
Enthalten in: Catalysis letters - Kluwer Academic Publishers-Plenum Publishers, 1988, 99(2005), 3-4 vom: Feb., Seite 133-140 |
|---|---|
| Übergeordnetes Werk: |
volume:99 ; year:2005 ; number:3-4 ; month:02 ; pages:133-140 |
| Links: |
|---|
| DOI / URN: |
10.1007/s10562-005-2105-9 |
|---|
| Katalog-ID: |
OLC2040160310 |
|---|
| LEADER | 01000caa a22002652 4500 | ||
|---|---|---|---|
| 001 | OLC2040160310 | ||
| 003 | DE-627 | ||
| 005 | 20230503020240.0 | ||
| 007 | tu | ||
| 008 | 200819s2005 xx ||||| 00| ||eng c | ||
| 024 | 7 | |a 10.1007/s10562-005-2105-9 |2 doi | |
| 035 | |a (DE-627)OLC2040160310 | ||
| 035 | |a (DE-He213)s10562-005-2105-9-p | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
| 041 | |a eng | ||
| 082 | 0 | 4 | |a 540 |a 660 |q VZ |
| 084 | |a VA 2890 |q VZ |2 rvk | ||
| 100 | 1 | |a Kimura, Hiroshi |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Amination of alcohols, using Cu/Ni-based colloidal catalyst, for consecutive reaction system |
| 264 | 1 | |c 2005 | |
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a ohne Hilfsmittel zu benutzen |b n |2 rdamedia | ||
| 338 | |a Band |b nc |2 rdacarrier | ||
| 500 | |a © Springer Science+Business Media, Inc. 2005 | ||
| 520 | |a Abstract Animation of dodecyl alcohol and monomethylamine (MMA, di-functional) using Cu/Ni-based colloidal catalyst stabilized by barium stearate, and its kinetic study were performed to effectively synthesize didodecylmethylamine (DDMA). For the initial 3–4 h when MMA/dodecyl alcohol mole ratio was less than 1, the amination reaction proceeded very fast (72 mole-alcohol $ h^{-1} $ mole-Cu at 200 °) by zero-order kinetics to directly produce DDMA (85%), with complete consumption of MMA, without liberation of the intermediate, momomethyldodecylamine (MMDA) at all. Then, immediately after the mole ratio exceeded 1, the amination proceeded very slowly (3.4 mole-alcohol $ h^{-1} $ mole-Cu) by consecutive mechanism (second order) with liberation of MMDA. Aldolization of dodecyl aldehyde, formed by dehydrogenation of dodecyl alcohol, was found to be catalyzed by methylamines. Maintaining the zero-order kinetics by continuous control of MMA/alcohol mole ratio at less than 1 through out the amination is essential to obtain a highest DDMA yield by preventing the unwanted aldolization and transalkylation of MMA leading to various byproducts. Catalytic activity of the colloidal catalyst was sevenfold active than that of corresponding solid ones. Amination of 1,6-hexanediol and dimethylamine, using the colloidal catalyst and liquid paraffin as a solvent, was proceeded by consecutive mechanism to form N,N,N′,N′-tetramethyl-l,6-hexamethylenediamine with an yield of 80%. | ||
| 650 | 4 | |a synergism | |
| 650 | 4 | |a Cu/Ni/Ba | |
| 650 | 4 | |a Cu/Ni/Ca/Ba | |
| 650 | 4 | |a amination | |
| 650 | 4 | |a metal colloid | |
| 650 | 4 | |a nanoparticles | |
| 700 | 1 | |a Yokota, Yukinaga |4 aut | |
| 700 | 1 | |a Sawamoto, Yuji |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Catalysis letters |d Kluwer Academic Publishers-Plenum Publishers, 1988 |g 99(2005), 3-4 vom: Feb., Seite 133-140 |w (DE-627)130436550 |w (DE-600)644234-1 |w (DE-576)025720724 |x 1011-372X |7 nnns |
| 773 | 1 | 8 | |g volume:99 |g year:2005 |g number:3-4 |g month:02 |g pages:133-140 |
| 856 | 4 | 1 | |u https://doi.org/10.1007/s10562-005-2105-9 |z lizenzpflichtig |3 Volltext |
| 912 | |a GBV_USEFLAG_A | ||
| 912 | |a SYSFLAG_A | ||
| 912 | |a GBV_OLC | ||
| 912 | |a SSG-OLC-TEC | ||
| 912 | |a SSG-OLC-CHE | ||
| 912 | |a GBV_ILN_21 | ||
| 912 | |a GBV_ILN_65 | ||
| 912 | |a GBV_ILN_70 | ||
| 912 | |a GBV_ILN_2010 | ||
| 912 | |a GBV_ILN_2016 | ||
| 912 | |a GBV_ILN_4012 | ||
| 912 | |a GBV_ILN_4305 | ||
| 912 | |a GBV_ILN_4307 | ||
| 936 | r | v | |a VA 2890 |
| 951 | |a AR | ||
| 952 | |d 99 |j 2005 |e 3-4 |c 02 |h 133-140 | ||
| author_variant |
h k hk y y yy y s ys |
|---|---|
| matchkey_str |
article:1011372X:2005----::mntooachluiguiaeclodlaaytocn |
| hierarchy_sort_str |
2005 |
| publishDate |
2005 |
| allfields |
10.1007/s10562-005-2105-9 doi (DE-627)OLC2040160310 (DE-He213)s10562-005-2105-9-p DE-627 ger DE-627 rakwb eng 540 660 VZ VA 2890 VZ rvk Kimura, Hiroshi verfasserin aut Amination of alcohols, using Cu/Ni-based colloidal catalyst, for consecutive reaction system 2005 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, Inc. 2005 Abstract Animation of dodecyl alcohol and monomethylamine (MMA, di-functional) using Cu/Ni-based colloidal catalyst stabilized by barium stearate, and its kinetic study were performed to effectively synthesize didodecylmethylamine (DDMA). For the initial 3–4 h when MMA/dodecyl alcohol mole ratio was less than 1, the amination reaction proceeded very fast (72 mole-alcohol $ h^{-1} $ mole-Cu at 200 °) by zero-order kinetics to directly produce DDMA (85%), with complete consumption of MMA, without liberation of the intermediate, momomethyldodecylamine (MMDA) at all. Then, immediately after the mole ratio exceeded 1, the amination proceeded very slowly (3.4 mole-alcohol $ h^{-1} $ mole-Cu) by consecutive mechanism (second order) with liberation of MMDA. Aldolization of dodecyl aldehyde, formed by dehydrogenation of dodecyl alcohol, was found to be catalyzed by methylamines. Maintaining the zero-order kinetics by continuous control of MMA/alcohol mole ratio at less than 1 through out the amination is essential to obtain a highest DDMA yield by preventing the unwanted aldolization and transalkylation of MMA leading to various byproducts. Catalytic activity of the colloidal catalyst was sevenfold active than that of corresponding solid ones. Amination of 1,6-hexanediol and dimethylamine, using the colloidal catalyst and liquid paraffin as a solvent, was proceeded by consecutive mechanism to form N,N,N′,N′-tetramethyl-l,6-hexamethylenediamine with an yield of 80%. synergism Cu/Ni/Ba Cu/Ni/Ca/Ba amination metal colloid nanoparticles Yokota, Yukinaga aut Sawamoto, Yuji aut Enthalten in Catalysis letters Kluwer Academic Publishers-Plenum Publishers, 1988 99(2005), 3-4 vom: Feb., Seite 133-140 (DE-627)130436550 (DE-600)644234-1 (DE-576)025720724 1011-372X nnns volume:99 year:2005 number:3-4 month:02 pages:133-140 https://doi.org/10.1007/s10562-005-2105-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2010 GBV_ILN_2016 GBV_ILN_4012 GBV_ILN_4305 GBV_ILN_4307 VA 2890 AR 99 2005 3-4 02 133-140 |
| spelling |
10.1007/s10562-005-2105-9 doi (DE-627)OLC2040160310 (DE-He213)s10562-005-2105-9-p DE-627 ger DE-627 rakwb eng 540 660 VZ VA 2890 VZ rvk Kimura, Hiroshi verfasserin aut Amination of alcohols, using Cu/Ni-based colloidal catalyst, for consecutive reaction system 2005 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, Inc. 2005 Abstract Animation of dodecyl alcohol and monomethylamine (MMA, di-functional) using Cu/Ni-based colloidal catalyst stabilized by barium stearate, and its kinetic study were performed to effectively synthesize didodecylmethylamine (DDMA). For the initial 3–4 h when MMA/dodecyl alcohol mole ratio was less than 1, the amination reaction proceeded very fast (72 mole-alcohol $ h^{-1} $ mole-Cu at 200 °) by zero-order kinetics to directly produce DDMA (85%), with complete consumption of MMA, without liberation of the intermediate, momomethyldodecylamine (MMDA) at all. Then, immediately after the mole ratio exceeded 1, the amination proceeded very slowly (3.4 mole-alcohol $ h^{-1} $ mole-Cu) by consecutive mechanism (second order) with liberation of MMDA. Aldolization of dodecyl aldehyde, formed by dehydrogenation of dodecyl alcohol, was found to be catalyzed by methylamines. Maintaining the zero-order kinetics by continuous control of MMA/alcohol mole ratio at less than 1 through out the amination is essential to obtain a highest DDMA yield by preventing the unwanted aldolization and transalkylation of MMA leading to various byproducts. Catalytic activity of the colloidal catalyst was sevenfold active than that of corresponding solid ones. Amination of 1,6-hexanediol and dimethylamine, using the colloidal catalyst and liquid paraffin as a solvent, was proceeded by consecutive mechanism to form N,N,N′,N′-tetramethyl-l,6-hexamethylenediamine with an yield of 80%. synergism Cu/Ni/Ba Cu/Ni/Ca/Ba amination metal colloid nanoparticles Yokota, Yukinaga aut Sawamoto, Yuji aut Enthalten in Catalysis letters Kluwer Academic Publishers-Plenum Publishers, 1988 99(2005), 3-4 vom: Feb., Seite 133-140 (DE-627)130436550 (DE-600)644234-1 (DE-576)025720724 1011-372X nnns volume:99 year:2005 number:3-4 month:02 pages:133-140 https://doi.org/10.1007/s10562-005-2105-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2010 GBV_ILN_2016 GBV_ILN_4012 GBV_ILN_4305 GBV_ILN_4307 VA 2890 AR 99 2005 3-4 02 133-140 |
| allfields_unstemmed |
10.1007/s10562-005-2105-9 doi (DE-627)OLC2040160310 (DE-He213)s10562-005-2105-9-p DE-627 ger DE-627 rakwb eng 540 660 VZ VA 2890 VZ rvk Kimura, Hiroshi verfasserin aut Amination of alcohols, using Cu/Ni-based colloidal catalyst, for consecutive reaction system 2005 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, Inc. 2005 Abstract Animation of dodecyl alcohol and monomethylamine (MMA, di-functional) using Cu/Ni-based colloidal catalyst stabilized by barium stearate, and its kinetic study were performed to effectively synthesize didodecylmethylamine (DDMA). For the initial 3–4 h when MMA/dodecyl alcohol mole ratio was less than 1, the amination reaction proceeded very fast (72 mole-alcohol $ h^{-1} $ mole-Cu at 200 °) by zero-order kinetics to directly produce DDMA (85%), with complete consumption of MMA, without liberation of the intermediate, momomethyldodecylamine (MMDA) at all. Then, immediately after the mole ratio exceeded 1, the amination proceeded very slowly (3.4 mole-alcohol $ h^{-1} $ mole-Cu) by consecutive mechanism (second order) with liberation of MMDA. Aldolization of dodecyl aldehyde, formed by dehydrogenation of dodecyl alcohol, was found to be catalyzed by methylamines. Maintaining the zero-order kinetics by continuous control of MMA/alcohol mole ratio at less than 1 through out the amination is essential to obtain a highest DDMA yield by preventing the unwanted aldolization and transalkylation of MMA leading to various byproducts. Catalytic activity of the colloidal catalyst was sevenfold active than that of corresponding solid ones. Amination of 1,6-hexanediol and dimethylamine, using the colloidal catalyst and liquid paraffin as a solvent, was proceeded by consecutive mechanism to form N,N,N′,N′-tetramethyl-l,6-hexamethylenediamine with an yield of 80%. synergism Cu/Ni/Ba Cu/Ni/Ca/Ba amination metal colloid nanoparticles Yokota, Yukinaga aut Sawamoto, Yuji aut Enthalten in Catalysis letters Kluwer Academic Publishers-Plenum Publishers, 1988 99(2005), 3-4 vom: Feb., Seite 133-140 (DE-627)130436550 (DE-600)644234-1 (DE-576)025720724 1011-372X nnns volume:99 year:2005 number:3-4 month:02 pages:133-140 https://doi.org/10.1007/s10562-005-2105-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2010 GBV_ILN_2016 GBV_ILN_4012 GBV_ILN_4305 GBV_ILN_4307 VA 2890 AR 99 2005 3-4 02 133-140 |
| allfieldsGer |
10.1007/s10562-005-2105-9 doi (DE-627)OLC2040160310 (DE-He213)s10562-005-2105-9-p DE-627 ger DE-627 rakwb eng 540 660 VZ VA 2890 VZ rvk Kimura, Hiroshi verfasserin aut Amination of alcohols, using Cu/Ni-based colloidal catalyst, for consecutive reaction system 2005 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, Inc. 2005 Abstract Animation of dodecyl alcohol and monomethylamine (MMA, di-functional) using Cu/Ni-based colloidal catalyst stabilized by barium stearate, and its kinetic study were performed to effectively synthesize didodecylmethylamine (DDMA). For the initial 3–4 h when MMA/dodecyl alcohol mole ratio was less than 1, the amination reaction proceeded very fast (72 mole-alcohol $ h^{-1} $ mole-Cu at 200 °) by zero-order kinetics to directly produce DDMA (85%), with complete consumption of MMA, without liberation of the intermediate, momomethyldodecylamine (MMDA) at all. Then, immediately after the mole ratio exceeded 1, the amination proceeded very slowly (3.4 mole-alcohol $ h^{-1} $ mole-Cu) by consecutive mechanism (second order) with liberation of MMDA. Aldolization of dodecyl aldehyde, formed by dehydrogenation of dodecyl alcohol, was found to be catalyzed by methylamines. Maintaining the zero-order kinetics by continuous control of MMA/alcohol mole ratio at less than 1 through out the amination is essential to obtain a highest DDMA yield by preventing the unwanted aldolization and transalkylation of MMA leading to various byproducts. Catalytic activity of the colloidal catalyst was sevenfold active than that of corresponding solid ones. Amination of 1,6-hexanediol and dimethylamine, using the colloidal catalyst and liquid paraffin as a solvent, was proceeded by consecutive mechanism to form N,N,N′,N′-tetramethyl-l,6-hexamethylenediamine with an yield of 80%. synergism Cu/Ni/Ba Cu/Ni/Ca/Ba amination metal colloid nanoparticles Yokota, Yukinaga aut Sawamoto, Yuji aut Enthalten in Catalysis letters Kluwer Academic Publishers-Plenum Publishers, 1988 99(2005), 3-4 vom: Feb., Seite 133-140 (DE-627)130436550 (DE-600)644234-1 (DE-576)025720724 1011-372X nnns volume:99 year:2005 number:3-4 month:02 pages:133-140 https://doi.org/10.1007/s10562-005-2105-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2010 GBV_ILN_2016 GBV_ILN_4012 GBV_ILN_4305 GBV_ILN_4307 VA 2890 AR 99 2005 3-4 02 133-140 |
| allfieldsSound |
10.1007/s10562-005-2105-9 doi (DE-627)OLC2040160310 (DE-He213)s10562-005-2105-9-p DE-627 ger DE-627 rakwb eng 540 660 VZ VA 2890 VZ rvk Kimura, Hiroshi verfasserin aut Amination of alcohols, using Cu/Ni-based colloidal catalyst, for consecutive reaction system 2005 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, Inc. 2005 Abstract Animation of dodecyl alcohol and monomethylamine (MMA, di-functional) using Cu/Ni-based colloidal catalyst stabilized by barium stearate, and its kinetic study were performed to effectively synthesize didodecylmethylamine (DDMA). For the initial 3–4 h when MMA/dodecyl alcohol mole ratio was less than 1, the amination reaction proceeded very fast (72 mole-alcohol $ h^{-1} $ mole-Cu at 200 °) by zero-order kinetics to directly produce DDMA (85%), with complete consumption of MMA, without liberation of the intermediate, momomethyldodecylamine (MMDA) at all. Then, immediately after the mole ratio exceeded 1, the amination proceeded very slowly (3.4 mole-alcohol $ h^{-1} $ mole-Cu) by consecutive mechanism (second order) with liberation of MMDA. Aldolization of dodecyl aldehyde, formed by dehydrogenation of dodecyl alcohol, was found to be catalyzed by methylamines. Maintaining the zero-order kinetics by continuous control of MMA/alcohol mole ratio at less than 1 through out the amination is essential to obtain a highest DDMA yield by preventing the unwanted aldolization and transalkylation of MMA leading to various byproducts. Catalytic activity of the colloidal catalyst was sevenfold active than that of corresponding solid ones. Amination of 1,6-hexanediol and dimethylamine, using the colloidal catalyst and liquid paraffin as a solvent, was proceeded by consecutive mechanism to form N,N,N′,N′-tetramethyl-l,6-hexamethylenediamine with an yield of 80%. synergism Cu/Ni/Ba Cu/Ni/Ca/Ba amination metal colloid nanoparticles Yokota, Yukinaga aut Sawamoto, Yuji aut Enthalten in Catalysis letters Kluwer Academic Publishers-Plenum Publishers, 1988 99(2005), 3-4 vom: Feb., Seite 133-140 (DE-627)130436550 (DE-600)644234-1 (DE-576)025720724 1011-372X nnns volume:99 year:2005 number:3-4 month:02 pages:133-140 https://doi.org/10.1007/s10562-005-2105-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2010 GBV_ILN_2016 GBV_ILN_4012 GBV_ILN_4305 GBV_ILN_4307 VA 2890 AR 99 2005 3-4 02 133-140 |
| language |
English |
| source |
Enthalten in Catalysis letters 99(2005), 3-4 vom: Feb., Seite 133-140 volume:99 year:2005 number:3-4 month:02 pages:133-140 |
| sourceStr |
Enthalten in Catalysis letters 99(2005), 3-4 vom: Feb., Seite 133-140 volume:99 year:2005 number:3-4 month:02 pages:133-140 |
| format_phy_str_mv |
Article |
| institution |
findex.gbv.de |
| topic_facet |
synergism Cu/Ni/Ba Cu/Ni/Ca/Ba amination metal colloid nanoparticles |
| dewey-raw |
540 |
| isfreeaccess_bool |
false |
| container_title |
Catalysis letters |
| authorswithroles_txt_mv |
Kimura, Hiroshi @@aut@@ Yokota, Yukinaga @@aut@@ Sawamoto, Yuji @@aut@@ |
| publishDateDaySort_date |
2005-02-01T00:00:00Z |
| hierarchy_top_id |
130436550 |
| dewey-sort |
3540 |
| id |
OLC2040160310 |
| language_de |
englisch |
| fullrecord |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">OLC2040160310</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230503020240.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">200819s2005 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10562-005-2105-9</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC2040160310</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-He213)s10562-005-2105-9-p</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">540</subfield><subfield code="a">660</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">VA 2890</subfield><subfield code="q">VZ</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Kimura, Hiroshi</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Amination of alcohols, using Cu/Ni-based colloidal catalyst, for consecutive reaction system</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2005</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Springer Science+Business Media, Inc. 2005</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Animation of dodecyl alcohol and monomethylamine (MMA, di-functional) using Cu/Ni-based colloidal catalyst stabilized by barium stearate, and its kinetic study were performed to effectively synthesize didodecylmethylamine (DDMA). For the initial 3–4 h when MMA/dodecyl alcohol mole ratio was less than 1, the amination reaction proceeded very fast (72 mole-alcohol $ h^{-1} $ mole-Cu at 200 °) by zero-order kinetics to directly produce DDMA (85%), with complete consumption of MMA, without liberation of the intermediate, momomethyldodecylamine (MMDA) at all. Then, immediately after the mole ratio exceeded 1, the amination proceeded very slowly (3.4 mole-alcohol $ h^{-1} $ mole-Cu) by consecutive mechanism (second order) with liberation of MMDA. Aldolization of dodecyl aldehyde, formed by dehydrogenation of dodecyl alcohol, was found to be catalyzed by methylamines. Maintaining the zero-order kinetics by continuous control of MMA/alcohol mole ratio at less than 1 through out the amination is essential to obtain a highest DDMA yield by preventing the unwanted aldolization and transalkylation of MMA leading to various byproducts. Catalytic activity of the colloidal catalyst was sevenfold active than that of corresponding solid ones. Amination of 1,6-hexanediol and dimethylamine, using the colloidal catalyst and liquid paraffin as a solvent, was proceeded by consecutive mechanism to form N,N,N′,N′-tetramethyl-l,6-hexamethylenediamine with an yield of 80%.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">synergism</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Cu/Ni/Ba</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Cu/Ni/Ca/Ba</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">amination</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">metal colloid</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">nanoparticles</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Yokota, Yukinaga</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Sawamoto, Yuji</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Catalysis letters</subfield><subfield code="d">Kluwer Academic Publishers-Plenum Publishers, 1988</subfield><subfield code="g">99(2005), 3-4 vom: Feb., Seite 133-140</subfield><subfield code="w">(DE-627)130436550</subfield><subfield code="w">(DE-600)644234-1</subfield><subfield code="w">(DE-576)025720724</subfield><subfield code="x">1011-372X</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:99</subfield><subfield code="g">year:2005</subfield><subfield code="g">number:3-4</subfield><subfield code="g">month:02</subfield><subfield code="g">pages:133-140</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1007/s10562-005-2105-9</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-CHE</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_21</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2010</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2016</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4012</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4307</subfield></datafield><datafield tag="936" ind1="r" ind2="v"><subfield code="a">VA 2890</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">99</subfield><subfield code="j">2005</subfield><subfield code="e">3-4</subfield><subfield code="c">02</subfield><subfield code="h">133-140</subfield></datafield></record></collection>
|
| author |
Kimura, Hiroshi |
| spellingShingle |
Kimura, Hiroshi ddc 540 rvk VA 2890 misc synergism misc Cu/Ni/Ba misc Cu/Ni/Ca/Ba misc amination misc metal colloid misc nanoparticles Amination of alcohols, using Cu/Ni-based colloidal catalyst, for consecutive reaction system |
| authorStr |
Kimura, Hiroshi |
| ppnlink_with_tag_str_mv |
@@773@@(DE-627)130436550 |
| format |
Article |
| dewey-ones |
540 - Chemistry & allied sciences 660 - Chemical engineering |
| delete_txt_mv |
keep |
| author_role |
aut aut aut |
| collection |
OLC |
| remote_str |
false |
| illustrated |
Not Illustrated |
| issn |
1011-372X |
| topic_title |
540 660 VZ VA 2890 VZ rvk Amination of alcohols, using Cu/Ni-based colloidal catalyst, for consecutive reaction system synergism Cu/Ni/Ba Cu/Ni/Ca/Ba amination metal colloid nanoparticles |
| topic |
ddc 540 rvk VA 2890 misc synergism misc Cu/Ni/Ba misc Cu/Ni/Ca/Ba misc amination misc metal colloid misc nanoparticles |
| topic_unstemmed |
ddc 540 rvk VA 2890 misc synergism misc Cu/Ni/Ba misc Cu/Ni/Ca/Ba misc amination misc metal colloid misc nanoparticles |
| topic_browse |
ddc 540 rvk VA 2890 misc synergism misc Cu/Ni/Ba misc Cu/Ni/Ca/Ba misc amination misc metal colloid misc nanoparticles |
| format_facet |
Aufsätze Gedruckte Aufsätze |
| format_main_str_mv |
Text Zeitschrift/Artikel |
| carriertype_str_mv |
nc |
| hierarchy_parent_title |
Catalysis letters |
| hierarchy_parent_id |
130436550 |
| dewey-tens |
540 - Chemistry 660 - Chemical engineering |
| hierarchy_top_title |
Catalysis letters |
| isfreeaccess_txt |
false |
| familylinks_str_mv |
(DE-627)130436550 (DE-600)644234-1 (DE-576)025720724 |
| title |
Amination of alcohols, using Cu/Ni-based colloidal catalyst, for consecutive reaction system |
| ctrlnum |
(DE-627)OLC2040160310 (DE-He213)s10562-005-2105-9-p |
| title_full |
Amination of alcohols, using Cu/Ni-based colloidal catalyst, for consecutive reaction system |
| author_sort |
Kimura, Hiroshi |
| journal |
Catalysis letters |
| journalStr |
Catalysis letters |
| lang_code |
eng |
| isOA_bool |
false |
| dewey-hundreds |
500 - Science 600 - Technology |
| recordtype |
marc |
| publishDateSort |
2005 |
| contenttype_str_mv |
txt |
| container_start_page |
133 |
| author_browse |
Kimura, Hiroshi Yokota, Yukinaga Sawamoto, Yuji |
| container_volume |
99 |
| class |
540 660 VZ VA 2890 VZ rvk |
| format_se |
Aufsätze |
| author-letter |
Kimura, Hiroshi |
| doi_str_mv |
10.1007/s10562-005-2105-9 |
| dewey-full |
540 660 |
| title_sort |
amination of alcohols, using cu/ni-based colloidal catalyst, for consecutive reaction system |
| title_auth |
Amination of alcohols, using Cu/Ni-based colloidal catalyst, for consecutive reaction system |
| abstract |
Abstract Animation of dodecyl alcohol and monomethylamine (MMA, di-functional) using Cu/Ni-based colloidal catalyst stabilized by barium stearate, and its kinetic study were performed to effectively synthesize didodecylmethylamine (DDMA). For the initial 3–4 h when MMA/dodecyl alcohol mole ratio was less than 1, the amination reaction proceeded very fast (72 mole-alcohol $ h^{-1} $ mole-Cu at 200 °) by zero-order kinetics to directly produce DDMA (85%), with complete consumption of MMA, without liberation of the intermediate, momomethyldodecylamine (MMDA) at all. Then, immediately after the mole ratio exceeded 1, the amination proceeded very slowly (3.4 mole-alcohol $ h^{-1} $ mole-Cu) by consecutive mechanism (second order) with liberation of MMDA. Aldolization of dodecyl aldehyde, formed by dehydrogenation of dodecyl alcohol, was found to be catalyzed by methylamines. Maintaining the zero-order kinetics by continuous control of MMA/alcohol mole ratio at less than 1 through out the amination is essential to obtain a highest DDMA yield by preventing the unwanted aldolization and transalkylation of MMA leading to various byproducts. Catalytic activity of the colloidal catalyst was sevenfold active than that of corresponding solid ones. Amination of 1,6-hexanediol and dimethylamine, using the colloidal catalyst and liquid paraffin as a solvent, was proceeded by consecutive mechanism to form N,N,N′,N′-tetramethyl-l,6-hexamethylenediamine with an yield of 80%. © Springer Science+Business Media, Inc. 2005 |
| abstractGer |
Abstract Animation of dodecyl alcohol and monomethylamine (MMA, di-functional) using Cu/Ni-based colloidal catalyst stabilized by barium stearate, and its kinetic study were performed to effectively synthesize didodecylmethylamine (DDMA). For the initial 3–4 h when MMA/dodecyl alcohol mole ratio was less than 1, the amination reaction proceeded very fast (72 mole-alcohol $ h^{-1} $ mole-Cu at 200 °) by zero-order kinetics to directly produce DDMA (85%), with complete consumption of MMA, without liberation of the intermediate, momomethyldodecylamine (MMDA) at all. Then, immediately after the mole ratio exceeded 1, the amination proceeded very slowly (3.4 mole-alcohol $ h^{-1} $ mole-Cu) by consecutive mechanism (second order) with liberation of MMDA. Aldolization of dodecyl aldehyde, formed by dehydrogenation of dodecyl alcohol, was found to be catalyzed by methylamines. Maintaining the zero-order kinetics by continuous control of MMA/alcohol mole ratio at less than 1 through out the amination is essential to obtain a highest DDMA yield by preventing the unwanted aldolization and transalkylation of MMA leading to various byproducts. Catalytic activity of the colloidal catalyst was sevenfold active than that of corresponding solid ones. Amination of 1,6-hexanediol and dimethylamine, using the colloidal catalyst and liquid paraffin as a solvent, was proceeded by consecutive mechanism to form N,N,N′,N′-tetramethyl-l,6-hexamethylenediamine with an yield of 80%. © Springer Science+Business Media, Inc. 2005 |
| abstract_unstemmed |
Abstract Animation of dodecyl alcohol and monomethylamine (MMA, di-functional) using Cu/Ni-based colloidal catalyst stabilized by barium stearate, and its kinetic study were performed to effectively synthesize didodecylmethylamine (DDMA). For the initial 3–4 h when MMA/dodecyl alcohol mole ratio was less than 1, the amination reaction proceeded very fast (72 mole-alcohol $ h^{-1} $ mole-Cu at 200 °) by zero-order kinetics to directly produce DDMA (85%), with complete consumption of MMA, without liberation of the intermediate, momomethyldodecylamine (MMDA) at all. Then, immediately after the mole ratio exceeded 1, the amination proceeded very slowly (3.4 mole-alcohol $ h^{-1} $ mole-Cu) by consecutive mechanism (second order) with liberation of MMDA. Aldolization of dodecyl aldehyde, formed by dehydrogenation of dodecyl alcohol, was found to be catalyzed by methylamines. Maintaining the zero-order kinetics by continuous control of MMA/alcohol mole ratio at less than 1 through out the amination is essential to obtain a highest DDMA yield by preventing the unwanted aldolization and transalkylation of MMA leading to various byproducts. Catalytic activity of the colloidal catalyst was sevenfold active than that of corresponding solid ones. Amination of 1,6-hexanediol and dimethylamine, using the colloidal catalyst and liquid paraffin as a solvent, was proceeded by consecutive mechanism to form N,N,N′,N′-tetramethyl-l,6-hexamethylenediamine with an yield of 80%. © Springer Science+Business Media, Inc. 2005 |
| collection_details |
GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2010 GBV_ILN_2016 GBV_ILN_4012 GBV_ILN_4305 GBV_ILN_4307 |
| container_issue |
3-4 |
| title_short |
Amination of alcohols, using Cu/Ni-based colloidal catalyst, for consecutive reaction system |
| url |
https://doi.org/10.1007/s10562-005-2105-9 |
| remote_bool |
false |
| author2 |
Yokota, Yukinaga Sawamoto, Yuji |
| author2Str |
Yokota, Yukinaga Sawamoto, Yuji |
| ppnlink |
130436550 |
| mediatype_str_mv |
n |
| isOA_txt |
false |
| hochschulschrift_bool |
false |
| doi_str |
10.1007/s10562-005-2105-9 |
| up_date |
2024-07-04T01:24:59.636Z |
| _version_ |
1803609754448166912 |
| fullrecord_marcxml |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">OLC2040160310</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230503020240.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">200819s2005 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10562-005-2105-9</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC2040160310</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-He213)s10562-005-2105-9-p</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">540</subfield><subfield code="a">660</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">VA 2890</subfield><subfield code="q">VZ</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Kimura, Hiroshi</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Amination of alcohols, using Cu/Ni-based colloidal catalyst, for consecutive reaction system</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2005</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Springer Science+Business Media, Inc. 2005</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Animation of dodecyl alcohol and monomethylamine (MMA, di-functional) using Cu/Ni-based colloidal catalyst stabilized by barium stearate, and its kinetic study were performed to effectively synthesize didodecylmethylamine (DDMA). For the initial 3–4 h when MMA/dodecyl alcohol mole ratio was less than 1, the amination reaction proceeded very fast (72 mole-alcohol $ h^{-1} $ mole-Cu at 200 °) by zero-order kinetics to directly produce DDMA (85%), with complete consumption of MMA, without liberation of the intermediate, momomethyldodecylamine (MMDA) at all. Then, immediately after the mole ratio exceeded 1, the amination proceeded very slowly (3.4 mole-alcohol $ h^{-1} $ mole-Cu) by consecutive mechanism (second order) with liberation of MMDA. Aldolization of dodecyl aldehyde, formed by dehydrogenation of dodecyl alcohol, was found to be catalyzed by methylamines. Maintaining the zero-order kinetics by continuous control of MMA/alcohol mole ratio at less than 1 through out the amination is essential to obtain a highest DDMA yield by preventing the unwanted aldolization and transalkylation of MMA leading to various byproducts. Catalytic activity of the colloidal catalyst was sevenfold active than that of corresponding solid ones. Amination of 1,6-hexanediol and dimethylamine, using the colloidal catalyst and liquid paraffin as a solvent, was proceeded by consecutive mechanism to form N,N,N′,N′-tetramethyl-l,6-hexamethylenediamine with an yield of 80%.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">synergism</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Cu/Ni/Ba</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Cu/Ni/Ca/Ba</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">amination</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">metal colloid</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">nanoparticles</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Yokota, Yukinaga</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Sawamoto, Yuji</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Catalysis letters</subfield><subfield code="d">Kluwer Academic Publishers-Plenum Publishers, 1988</subfield><subfield code="g">99(2005), 3-4 vom: Feb., Seite 133-140</subfield><subfield code="w">(DE-627)130436550</subfield><subfield code="w">(DE-600)644234-1</subfield><subfield code="w">(DE-576)025720724</subfield><subfield code="x">1011-372X</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:99</subfield><subfield code="g">year:2005</subfield><subfield code="g">number:3-4</subfield><subfield code="g">month:02</subfield><subfield code="g">pages:133-140</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1007/s10562-005-2105-9</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-CHE</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_21</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2010</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2016</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4012</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4307</subfield></datafield><datafield tag="936" ind1="r" ind2="v"><subfield code="a">VA 2890</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">99</subfield><subfield code="j">2005</subfield><subfield code="e">3-4</subfield><subfield code="c">02</subfield><subfield code="h">133-140</subfield></datafield></record></collection>
|
| score |
7.401079 |