A new catalytic transesterification for the synthesis of N, N-dimethylaminoethyl acrylate with organotin catalyst
Abstract A new transesterification method for preparing N, N-dimethylaminoethyl acrylate (DMAEA) from methyl acrylate (MA) and dimethylaminoethanol (DMAE) was carried out in the presence of organotin catalyst. Among the catalysts examined, ($ C_{8} $$ H_{17} $)2Sn($ OCOC_{11} $$ H_{23} $)2(TD) is th...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Jiang, Pingping [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2006 |
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| Schlagwörter: |
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| Systematik: |
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| Anmerkung: |
© Springer Science+Business Media, Inc. 2006 |
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| Übergeordnetes Werk: |
Enthalten in: Catalysis letters - Kluwer Academic Publishers-Plenum Publishers, 1988, 110(2006), 1-2 vom: Aug., Seite 101-106 |
|---|---|
| Übergeordnetes Werk: |
volume:110 ; year:2006 ; number:1-2 ; month:08 ; pages:101-106 |
| Links: |
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| DOI / URN: |
10.1007/s10562-006-0091-1 |
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OLC2040164154 |
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| 520 | |a Abstract A new transesterification method for preparing N, N-dimethylaminoethyl acrylate (DMAEA) from methyl acrylate (MA) and dimethylaminoethanol (DMAE) was carried out in the presence of organotin catalyst. Among the catalysts examined, ($ C_{8} $$ H_{17} $)2Sn($ OCOC_{11} $$ H_{23} $)2(TD) is the most active one for the reaction. The products were characterized by gas chromatography, IR spectroscopy, NMR spectroscopy and Mass spectroscopy. The effects of various reaction conditions such as the different catalysts, the reactants ratio, the amount of catalyst, the reaction time on the DMAE conversion, the selectivity to DMAEA and the DMAEA yield were investigated. Experimental results indicated that the sort of catalyst is vital to improving DMAEA yield. The reactants ratio could effect on the DMAE conversion, the selectivity to DMAEA and the DMAEA yield. The 96.28% conversion of DMAE was obtained over catalyst TD, the yield of DMAEA could reach 94.65%, the selectivity is 98.68%. A possible catalytic mechanism of transesterification of DMAE and MA with organotin catalysts was also presumed. | ||
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10.1007/s10562-006-0091-1 doi (DE-627)OLC2040164154 (DE-He213)s10562-006-0091-1-p DE-627 ger DE-627 rakwb eng 540 660 VZ VA 2890 VZ rvk Jiang, Pingping verfasserin aut A new catalytic transesterification for the synthesis of N, N-dimethylaminoethyl acrylate with organotin catalyst 2006 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, Inc. 2006 Abstract A new transesterification method for preparing N, N-dimethylaminoethyl acrylate (DMAEA) from methyl acrylate (MA) and dimethylaminoethanol (DMAE) was carried out in the presence of organotin catalyst. Among the catalysts examined, ($ C_{8} $$ H_{17} $)2Sn($ OCOC_{11} $$ H_{23} $)2(TD) is the most active one for the reaction. The products were characterized by gas chromatography, IR spectroscopy, NMR spectroscopy and Mass spectroscopy. The effects of various reaction conditions such as the different catalysts, the reactants ratio, the amount of catalyst, the reaction time on the DMAE conversion, the selectivity to DMAEA and the DMAEA yield were investigated. Experimental results indicated that the sort of catalyst is vital to improving DMAEA yield. The reactants ratio could effect on the DMAE conversion, the selectivity to DMAEA and the DMAEA yield. The 96.28% conversion of DMAE was obtained over catalyst TD, the yield of DMAEA could reach 94.65%, the selectivity is 98.68%. A possible catalytic mechanism of transesterification of DMAE and MA with organotin catalysts was also presumed. catalytic transesterification , -dimethylaminoethylacrylate organotin catalysts Zhang, Dianpeng aut Li, Qi aut Lu, Yun aut Enthalten in Catalysis letters Kluwer Academic Publishers-Plenum Publishers, 1988 110(2006), 1-2 vom: Aug., Seite 101-106 (DE-627)130436550 (DE-600)644234-1 (DE-576)025720724 1011-372X nnns volume:110 year:2006 number:1-2 month:08 pages:101-106 https://doi.org/10.1007/s10562-006-0091-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2010 GBV_ILN_2016 GBV_ILN_4012 GBV_ILN_4305 GBV_ILN_4307 VA 2890 AR 110 2006 1-2 08 101-106 |
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10.1007/s10562-006-0091-1 doi (DE-627)OLC2040164154 (DE-He213)s10562-006-0091-1-p DE-627 ger DE-627 rakwb eng 540 660 VZ VA 2890 VZ rvk Jiang, Pingping verfasserin aut A new catalytic transesterification for the synthesis of N, N-dimethylaminoethyl acrylate with organotin catalyst 2006 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, Inc. 2006 Abstract A new transesterification method for preparing N, N-dimethylaminoethyl acrylate (DMAEA) from methyl acrylate (MA) and dimethylaminoethanol (DMAE) was carried out in the presence of organotin catalyst. Among the catalysts examined, ($ C_{8} $$ H_{17} $)2Sn($ OCOC_{11} $$ H_{23} $)2(TD) is the most active one for the reaction. The products were characterized by gas chromatography, IR spectroscopy, NMR spectroscopy and Mass spectroscopy. The effects of various reaction conditions such as the different catalysts, the reactants ratio, the amount of catalyst, the reaction time on the DMAE conversion, the selectivity to DMAEA and the DMAEA yield were investigated. Experimental results indicated that the sort of catalyst is vital to improving DMAEA yield. The reactants ratio could effect on the DMAE conversion, the selectivity to DMAEA and the DMAEA yield. The 96.28% conversion of DMAE was obtained over catalyst TD, the yield of DMAEA could reach 94.65%, the selectivity is 98.68%. A possible catalytic mechanism of transesterification of DMAE and MA with organotin catalysts was also presumed. catalytic transesterification , -dimethylaminoethylacrylate organotin catalysts Zhang, Dianpeng aut Li, Qi aut Lu, Yun aut Enthalten in Catalysis letters Kluwer Academic Publishers-Plenum Publishers, 1988 110(2006), 1-2 vom: Aug., Seite 101-106 (DE-627)130436550 (DE-600)644234-1 (DE-576)025720724 1011-372X nnns volume:110 year:2006 number:1-2 month:08 pages:101-106 https://doi.org/10.1007/s10562-006-0091-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2010 GBV_ILN_2016 GBV_ILN_4012 GBV_ILN_4305 GBV_ILN_4307 VA 2890 AR 110 2006 1-2 08 101-106 |
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10.1007/s10562-006-0091-1 doi (DE-627)OLC2040164154 (DE-He213)s10562-006-0091-1-p DE-627 ger DE-627 rakwb eng 540 660 VZ VA 2890 VZ rvk Jiang, Pingping verfasserin aut A new catalytic transesterification for the synthesis of N, N-dimethylaminoethyl acrylate with organotin catalyst 2006 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, Inc. 2006 Abstract A new transesterification method for preparing N, N-dimethylaminoethyl acrylate (DMAEA) from methyl acrylate (MA) and dimethylaminoethanol (DMAE) was carried out in the presence of organotin catalyst. Among the catalysts examined, ($ C_{8} $$ H_{17} $)2Sn($ OCOC_{11} $$ H_{23} $)2(TD) is the most active one for the reaction. The products were characterized by gas chromatography, IR spectroscopy, NMR spectroscopy and Mass spectroscopy. The effects of various reaction conditions such as the different catalysts, the reactants ratio, the amount of catalyst, the reaction time on the DMAE conversion, the selectivity to DMAEA and the DMAEA yield were investigated. Experimental results indicated that the sort of catalyst is vital to improving DMAEA yield. The reactants ratio could effect on the DMAE conversion, the selectivity to DMAEA and the DMAEA yield. The 96.28% conversion of DMAE was obtained over catalyst TD, the yield of DMAEA could reach 94.65%, the selectivity is 98.68%. A possible catalytic mechanism of transesterification of DMAE and MA with organotin catalysts was also presumed. catalytic transesterification , -dimethylaminoethylacrylate organotin catalysts Zhang, Dianpeng aut Li, Qi aut Lu, Yun aut Enthalten in Catalysis letters Kluwer Academic Publishers-Plenum Publishers, 1988 110(2006), 1-2 vom: Aug., Seite 101-106 (DE-627)130436550 (DE-600)644234-1 (DE-576)025720724 1011-372X nnns volume:110 year:2006 number:1-2 month:08 pages:101-106 https://doi.org/10.1007/s10562-006-0091-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2010 GBV_ILN_2016 GBV_ILN_4012 GBV_ILN_4305 GBV_ILN_4307 VA 2890 AR 110 2006 1-2 08 101-106 |
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10.1007/s10562-006-0091-1 doi (DE-627)OLC2040164154 (DE-He213)s10562-006-0091-1-p DE-627 ger DE-627 rakwb eng 540 660 VZ VA 2890 VZ rvk Jiang, Pingping verfasserin aut A new catalytic transesterification for the synthesis of N, N-dimethylaminoethyl acrylate with organotin catalyst 2006 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, Inc. 2006 Abstract A new transesterification method for preparing N, N-dimethylaminoethyl acrylate (DMAEA) from methyl acrylate (MA) and dimethylaminoethanol (DMAE) was carried out in the presence of organotin catalyst. Among the catalysts examined, ($ C_{8} $$ H_{17} $)2Sn($ OCOC_{11} $$ H_{23} $)2(TD) is the most active one for the reaction. The products were characterized by gas chromatography, IR spectroscopy, NMR spectroscopy and Mass spectroscopy. The effects of various reaction conditions such as the different catalysts, the reactants ratio, the amount of catalyst, the reaction time on the DMAE conversion, the selectivity to DMAEA and the DMAEA yield were investigated. Experimental results indicated that the sort of catalyst is vital to improving DMAEA yield. The reactants ratio could effect on the DMAE conversion, the selectivity to DMAEA and the DMAEA yield. The 96.28% conversion of DMAE was obtained over catalyst TD, the yield of DMAEA could reach 94.65%, the selectivity is 98.68%. A possible catalytic mechanism of transesterification of DMAE and MA with organotin catalysts was also presumed. catalytic transesterification , -dimethylaminoethylacrylate organotin catalysts Zhang, Dianpeng aut Li, Qi aut Lu, Yun aut Enthalten in Catalysis letters Kluwer Academic Publishers-Plenum Publishers, 1988 110(2006), 1-2 vom: Aug., Seite 101-106 (DE-627)130436550 (DE-600)644234-1 (DE-576)025720724 1011-372X nnns volume:110 year:2006 number:1-2 month:08 pages:101-106 https://doi.org/10.1007/s10562-006-0091-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2010 GBV_ILN_2016 GBV_ILN_4012 GBV_ILN_4305 GBV_ILN_4307 VA 2890 AR 110 2006 1-2 08 101-106 |
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10.1007/s10562-006-0091-1 doi (DE-627)OLC2040164154 (DE-He213)s10562-006-0091-1-p DE-627 ger DE-627 rakwb eng 540 660 VZ VA 2890 VZ rvk Jiang, Pingping verfasserin aut A new catalytic transesterification for the synthesis of N, N-dimethylaminoethyl acrylate with organotin catalyst 2006 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, Inc. 2006 Abstract A new transesterification method for preparing N, N-dimethylaminoethyl acrylate (DMAEA) from methyl acrylate (MA) and dimethylaminoethanol (DMAE) was carried out in the presence of organotin catalyst. Among the catalysts examined, ($ C_{8} $$ H_{17} $)2Sn($ OCOC_{11} $$ H_{23} $)2(TD) is the most active one for the reaction. The products were characterized by gas chromatography, IR spectroscopy, NMR spectroscopy and Mass spectroscopy. The effects of various reaction conditions such as the different catalysts, the reactants ratio, the amount of catalyst, the reaction time on the DMAE conversion, the selectivity to DMAEA and the DMAEA yield were investigated. Experimental results indicated that the sort of catalyst is vital to improving DMAEA yield. The reactants ratio could effect on the DMAE conversion, the selectivity to DMAEA and the DMAEA yield. The 96.28% conversion of DMAE was obtained over catalyst TD, the yield of DMAEA could reach 94.65%, the selectivity is 98.68%. A possible catalytic mechanism of transesterification of DMAE and MA with organotin catalysts was also presumed. catalytic transesterification , -dimethylaminoethylacrylate organotin catalysts Zhang, Dianpeng aut Li, Qi aut Lu, Yun aut Enthalten in Catalysis letters Kluwer Academic Publishers-Plenum Publishers, 1988 110(2006), 1-2 vom: Aug., Seite 101-106 (DE-627)130436550 (DE-600)644234-1 (DE-576)025720724 1011-372X nnns volume:110 year:2006 number:1-2 month:08 pages:101-106 https://doi.org/10.1007/s10562-006-0091-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2010 GBV_ILN_2016 GBV_ILN_4012 GBV_ILN_4305 GBV_ILN_4307 VA 2890 AR 110 2006 1-2 08 101-106 |
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A new catalytic transesterification for the synthesis of N, N-dimethylaminoethyl acrylate with organotin catalyst |
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A new catalytic transesterification for the synthesis of N, N-dimethylaminoethyl acrylate with organotin catalyst |
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Jiang, Pingping |
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Jiang, Pingping Zhang, Dianpeng Li, Qi Lu, Yun |
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a new catalytic transesterification for the synthesis of n, n-dimethylaminoethyl acrylate with organotin catalyst |
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A new catalytic transesterification for the synthesis of N, N-dimethylaminoethyl acrylate with organotin catalyst |
| abstract |
Abstract A new transesterification method for preparing N, N-dimethylaminoethyl acrylate (DMAEA) from methyl acrylate (MA) and dimethylaminoethanol (DMAE) was carried out in the presence of organotin catalyst. Among the catalysts examined, ($ C_{8} $$ H_{17} $)2Sn($ OCOC_{11} $$ H_{23} $)2(TD) is the most active one for the reaction. The products were characterized by gas chromatography, IR spectroscopy, NMR spectroscopy and Mass spectroscopy. The effects of various reaction conditions such as the different catalysts, the reactants ratio, the amount of catalyst, the reaction time on the DMAE conversion, the selectivity to DMAEA and the DMAEA yield were investigated. Experimental results indicated that the sort of catalyst is vital to improving DMAEA yield. The reactants ratio could effect on the DMAE conversion, the selectivity to DMAEA and the DMAEA yield. The 96.28% conversion of DMAE was obtained over catalyst TD, the yield of DMAEA could reach 94.65%, the selectivity is 98.68%. A possible catalytic mechanism of transesterification of DMAE and MA with organotin catalysts was also presumed. © Springer Science+Business Media, Inc. 2006 |
| abstractGer |
Abstract A new transesterification method for preparing N, N-dimethylaminoethyl acrylate (DMAEA) from methyl acrylate (MA) and dimethylaminoethanol (DMAE) was carried out in the presence of organotin catalyst. Among the catalysts examined, ($ C_{8} $$ H_{17} $)2Sn($ OCOC_{11} $$ H_{23} $)2(TD) is the most active one for the reaction. The products were characterized by gas chromatography, IR spectroscopy, NMR spectroscopy and Mass spectroscopy. The effects of various reaction conditions such as the different catalysts, the reactants ratio, the amount of catalyst, the reaction time on the DMAE conversion, the selectivity to DMAEA and the DMAEA yield were investigated. Experimental results indicated that the sort of catalyst is vital to improving DMAEA yield. The reactants ratio could effect on the DMAE conversion, the selectivity to DMAEA and the DMAEA yield. The 96.28% conversion of DMAE was obtained over catalyst TD, the yield of DMAEA could reach 94.65%, the selectivity is 98.68%. A possible catalytic mechanism of transesterification of DMAE and MA with organotin catalysts was also presumed. © Springer Science+Business Media, Inc. 2006 |
| abstract_unstemmed |
Abstract A new transesterification method for preparing N, N-dimethylaminoethyl acrylate (DMAEA) from methyl acrylate (MA) and dimethylaminoethanol (DMAE) was carried out in the presence of organotin catalyst. Among the catalysts examined, ($ C_{8} $$ H_{17} $)2Sn($ OCOC_{11} $$ H_{23} $)2(TD) is the most active one for the reaction. The products were characterized by gas chromatography, IR spectroscopy, NMR spectroscopy and Mass spectroscopy. The effects of various reaction conditions such as the different catalysts, the reactants ratio, the amount of catalyst, the reaction time on the DMAE conversion, the selectivity to DMAEA and the DMAEA yield were investigated. Experimental results indicated that the sort of catalyst is vital to improving DMAEA yield. The reactants ratio could effect on the DMAE conversion, the selectivity to DMAEA and the DMAEA yield. The 96.28% conversion of DMAE was obtained over catalyst TD, the yield of DMAEA could reach 94.65%, the selectivity is 98.68%. A possible catalytic mechanism of transesterification of DMAE and MA with organotin catalysts was also presumed. © Springer Science+Business Media, Inc. 2006 |
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