2-Methylimidazole Modified Co-BTC MOF as an Efficient Catalyst for Chemical Fixation of Carbon Dioxide

Abstract [($ CH_{3} $)2$ NH_{2} $][$ Co_{3} $(BTC)(HCOO)4($ H_{2} $O)]·$ H_{2} $O (Co-BTC) was synthesized under solvothermal conditions, further used as the precursor for the synthesis of 2-methylimidazole modified Co-BTC (2MeImCo-BTC-x). The characteristics of 2MeIm@Co-BTC-x were systematically ch...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Wu, Yuanfeng [verfasserIn] Song, Xianghai Xu, Siquan Zhang, Jiahui Zhu, Yanli Gao, Lijing Xiao, Guomin

Format:	Artikel
Sprache:	Englisch

Erschienen:	2019

Schlagwörter:	ZIF-67 Co-BTC CO Epoxide Cycloaddition

Systematik:	VA 2890

Anmerkung:	© Springer Science+Business Media, LLC, part of Springer Nature 2019

Übergeordnetes Werk:	Enthalten in: Catalysis letters - Springer US, 1988, 149(2019), 9 vom: 22. Juni, Seite 2575-2585
Übergeordnetes Werk:	volume:149 ; year:2019 ; number:9 ; day:22 ; month:06 ; pages:2575-2585

Links:	Volltext

DOI / URN:	10.1007/s10562-019-02874-9

Katalog-ID:	OLC2040200088

Internformat


LEADER	01000caa a22002652 4500
001	OLC2040200088
003	DE-627
005	20230503020749.0
007	tu
008	200819s2019 xx \|\|\|\|\| 00\| \|\|eng c
024	7		\|a 10.1007/s10562-019-02874-9 \|2 doi
035			\|a (DE-627)OLC2040200088
035			\|a (DE-He213)s10562-019-02874-9-p
040			\|a DE-627 \|b ger \|c DE-627 \|e rakwb
041			\|a eng
082	0	4	\|a 540 \|a 660 \|q VZ
084			\|a VA 2890 \|q VZ \|2 rvk
100	1		\|a Wu, Yuanfeng \|e verfasserin \|4 aut
245	1	0	\|a 2-Methylimidazole Modified Co-BTC MOF as an Efficient Catalyst for Chemical Fixation of Carbon Dioxide
264		1	\|c 2019
336			\|a Text \|b txt \|2 rdacontent
337			\|a ohne Hilfsmittel zu benutzen \|b n \|2 rdamedia
338			\|a Band \|b nc \|2 rdacarrier
500			\|a © Springer Science+Business Media, LLC, part of Springer Nature 2019
520			\|a Abstract [($ CH_{3} $)2$ NH_{2} $][$ Co_{3} $(BTC)(HCOO)4($ H_{2} $O)]·$ H_{2} $O (Co-BTC) was synthesized under solvothermal conditions, further used as the precursor for the synthesis of 2-methylimidazole modified Co-BTC (2MeImCo-BTC-x). The characteristics of 2MeIm@Co-BTC-x were systematically characterized by various technologies including XRD, FESEM, FT-IR, XPS, $ N_{2} $-adsorption, TG-DTG and $ CO_{2} $/$ NH_{3} $-TPD. It was found that except for the crystal faces (0 1 1) and (− 1 0 2) corresponding to ZIF-67 and Co-BTC, a new crystal phase appeared at 12.$ 22^{o} $ for the modified Co-BTC, which may be attributed to the coordination between 2MeIm and unsaturated Co ions of Co-BTC. Interestingly, a new structure of hexagonal prisms together with hierarchical porous were also formed for the modified Co-BTC. Besides, when this composite was explored as a heterogeneous catalyst for catalytic conversion of carbon dioxide with epichlorohydrin (ECH) as probe, an obvious enhancement in catalytic activity was obtained compared with the fresh Co-BTC, suggesting that 2MeIm ligands within the modified Co-BTC played a great role on the coupling process. Furthermore, 97.21% of ECH conversion and 98.79% of chloropropene carbonate selectivity were gained over 2MeIm@Co-BTC-1.0 under optimal conditions (3.0 MPa, 90 °C, 5 h, 0.75 wt% catalyst of ECH). Additionally, only a slight decrease in catalytic activity was found after the optimal sample was reused three times. Finally, a mechanism for interpreting the coupling process of carbon dioxide cycloaddition with epoxide was proposed. Graphic Abstract One-pot catalytic conversion of CO2 into cyclic carbonate over 2-methylimidazole modified Co-BTC
650		4	\|a ZIF-67
650		4	\|a Co-BTC
650		4	\|a CO
650		4	\|a Epoxide
650		4	\|a Cycloaddition
700	1		\|a Song, Xianghai \|4 aut
700	1		\|a Xu, Siquan \|4 aut
700	1		\|a Zhang, Jiahui \|4 aut
700	1		\|a Zhu, Yanli \|4 aut
700	1		\|a Gao, Lijing \|4 aut
700	1		\|a Xiao, Guomin \|4 aut
773	0	8	\|i Enthalten in \|t Catalysis letters \|d Springer US, 1988 \|g 149(2019), 9 vom: 22. Juni, Seite 2575-2585 \|w (DE-627)130436550 \|w (DE-600)644234-1 \|w (DE-576)025720724 \|x 1011-372X \|7 nnns
773	1	8	\|g volume:149 \|g year:2019 \|g number:9 \|g day:22 \|g month:06 \|g pages:2575-2585
856	4	1	\|u https://doi.org/10.1007/s10562-019-02874-9 \|z lizenzpflichtig \|3 Volltext
912			\|a GBV_USEFLAG_A
912			\|a SYSFLAG_A
912			\|a GBV_OLC
912			\|a SSG-OLC-TEC
912			\|a SSG-OLC-CHE
912			\|a GBV_ILN_70
936	r	v	\|a VA 2890
951			\|a AR
952			\|d 149 \|j 2019 \|e 9 \|b 22 \|c 06 \|h 2575-2585

Indexfelder

author_variant	y w yw x s xs s x sx j z jz y z yz l g lg g x gx
matchkey_str	article:1011372X:2019----::mtyiiaoeoiidotmfsnfiinctlsfrhmc
hierarchy_sort_str	2019
publishDate	2019
allfields	10.1007/s10562-019-02874-9 doi (DE-627)OLC2040200088 (DE-He213)s10562-019-02874-9-p DE-627 ger DE-627 rakwb eng 540 660 VZ VA 2890 VZ rvk Wu, Yuanfeng verfasserin aut 2-Methylimidazole Modified Co-BTC MOF as an Efficient Catalyst for Chemical Fixation of Carbon Dioxide 2019 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC, part of Springer Nature 2019 Abstract [($ CH_{3} $)2$ NH_{2} $][$ Co_{3} $(BTC)(HCOO)4($ H_{2} $O)]·$ H_{2} $O (Co-BTC) was synthesized under solvothermal conditions, further used as the precursor for the synthesis of 2-methylimidazole modified Co-BTC (2MeImCo-BTC-x). The characteristics of 2MeIm@Co-BTC-x were systematically characterized by various technologies including XRD, FESEM, FT-IR, XPS, $ N_{2} $-adsorption, TG-DTG and $ CO_{2} $/$ NH_{3} $-TPD. It was found that except for the crystal faces (0 1 1) and (− 1 0 2) corresponding to ZIF-67 and Co-BTC, a new crystal phase appeared at 12.$ 22^{o} $ for the modified Co-BTC, which may be attributed to the coordination between 2MeIm and unsaturated Co ions of Co-BTC. Interestingly, a new structure of hexagonal prisms together with hierarchical porous were also formed for the modified Co-BTC. Besides, when this composite was explored as a heterogeneous catalyst for catalytic conversion of carbon dioxide with epichlorohydrin (ECH) as probe, an obvious enhancement in catalytic activity was obtained compared with the fresh Co-BTC, suggesting that 2MeIm ligands within the modified Co-BTC played a great role on the coupling process. Furthermore, 97.21% of ECH conversion and 98.79% of chloropropene carbonate selectivity were gained over 2MeIm@Co-BTC-1.0 under optimal conditions (3.0 MPa, 90 °C, 5 h, 0.75 wt% catalyst of ECH). Additionally, only a slight decrease in catalytic activity was found after the optimal sample was reused three times. Finally, a mechanism for interpreting the coupling process of carbon dioxide cycloaddition with epoxide was proposed. Graphic Abstract One-pot catalytic conversion of CO2 into cyclic carbonate over 2-methylimidazole modified Co-BTC ZIF-67 Co-BTC CO Epoxide Cycloaddition Song, Xianghai aut Xu, Siquan aut Zhang, Jiahui aut Zhu, Yanli aut Gao, Lijing aut Xiao, Guomin aut Enthalten in Catalysis letters Springer US, 1988 149(2019), 9 vom: 22. Juni, Seite 2575-2585 (DE-627)130436550 (DE-600)644234-1 (DE-576)025720724 1011-372X nnns volume:149 year:2019 number:9 day:22 month:06 pages:2575-2585 https://doi.org/10.1007/s10562-019-02874-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 VA 2890 AR 149 2019 9 22 06 2575-2585
spelling	10.1007/s10562-019-02874-9 doi (DE-627)OLC2040200088 (DE-He213)s10562-019-02874-9-p DE-627 ger DE-627 rakwb eng 540 660 VZ VA 2890 VZ rvk Wu, Yuanfeng verfasserin aut 2-Methylimidazole Modified Co-BTC MOF as an Efficient Catalyst for Chemical Fixation of Carbon Dioxide 2019 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC, part of Springer Nature 2019 Abstract [($ CH_{3} $)2$ NH_{2} $][$ Co_{3} $(BTC)(HCOO)4($ H_{2} $O)]·$ H_{2} $O (Co-BTC) was synthesized under solvothermal conditions, further used as the precursor for the synthesis of 2-methylimidazole modified Co-BTC (2MeImCo-BTC-x). The characteristics of 2MeIm@Co-BTC-x were systematically characterized by various technologies including XRD, FESEM, FT-IR, XPS, $ N_{2} $-adsorption, TG-DTG and $ CO_{2} $/$ NH_{3} $-TPD. It was found that except for the crystal faces (0 1 1) and (− 1 0 2) corresponding to ZIF-67 and Co-BTC, a new crystal phase appeared at 12.$ 22^{o} $ for the modified Co-BTC, which may be attributed to the coordination between 2MeIm and unsaturated Co ions of Co-BTC. Interestingly, a new structure of hexagonal prisms together with hierarchical porous were also formed for the modified Co-BTC. Besides, when this composite was explored as a heterogeneous catalyst for catalytic conversion of carbon dioxide with epichlorohydrin (ECH) as probe, an obvious enhancement in catalytic activity was obtained compared with the fresh Co-BTC, suggesting that 2MeIm ligands within the modified Co-BTC played a great role on the coupling process. Furthermore, 97.21% of ECH conversion and 98.79% of chloropropene carbonate selectivity were gained over 2MeIm@Co-BTC-1.0 under optimal conditions (3.0 MPa, 90 °C, 5 h, 0.75 wt% catalyst of ECH). Additionally, only a slight decrease in catalytic activity was found after the optimal sample was reused three times. Finally, a mechanism for interpreting the coupling process of carbon dioxide cycloaddition with epoxide was proposed. Graphic Abstract One-pot catalytic conversion of CO2 into cyclic carbonate over 2-methylimidazole modified Co-BTC ZIF-67 Co-BTC CO Epoxide Cycloaddition Song, Xianghai aut Xu, Siquan aut Zhang, Jiahui aut Zhu, Yanli aut Gao, Lijing aut Xiao, Guomin aut Enthalten in Catalysis letters Springer US, 1988 149(2019), 9 vom: 22. Juni, Seite 2575-2585 (DE-627)130436550 (DE-600)644234-1 (DE-576)025720724 1011-372X nnns volume:149 year:2019 number:9 day:22 month:06 pages:2575-2585 https://doi.org/10.1007/s10562-019-02874-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 VA 2890 AR 149 2019 9 22 06 2575-2585
allfields_unstemmed	10.1007/s10562-019-02874-9 doi (DE-627)OLC2040200088 (DE-He213)s10562-019-02874-9-p DE-627 ger DE-627 rakwb eng 540 660 VZ VA 2890 VZ rvk Wu, Yuanfeng verfasserin aut 2-Methylimidazole Modified Co-BTC MOF as an Efficient Catalyst for Chemical Fixation of Carbon Dioxide 2019 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC, part of Springer Nature 2019 Abstract [($ CH_{3} $)2$ NH_{2} $][$ Co_{3} $(BTC)(HCOO)4($ H_{2} $O)]·$ H_{2} $O (Co-BTC) was synthesized under solvothermal conditions, further used as the precursor for the synthesis of 2-methylimidazole modified Co-BTC (2MeImCo-BTC-x). The characteristics of 2MeIm@Co-BTC-x were systematically characterized by various technologies including XRD, FESEM, FT-IR, XPS, $ N_{2} $-adsorption, TG-DTG and $ CO_{2} $/$ NH_{3} $-TPD. It was found that except for the crystal faces (0 1 1) and (− 1 0 2) corresponding to ZIF-67 and Co-BTC, a new crystal phase appeared at 12.$ 22^{o} $ for the modified Co-BTC, which may be attributed to the coordination between 2MeIm and unsaturated Co ions of Co-BTC. Interestingly, a new structure of hexagonal prisms together with hierarchical porous were also formed for the modified Co-BTC. Besides, when this composite was explored as a heterogeneous catalyst for catalytic conversion of carbon dioxide with epichlorohydrin (ECH) as probe, an obvious enhancement in catalytic activity was obtained compared with the fresh Co-BTC, suggesting that 2MeIm ligands within the modified Co-BTC played a great role on the coupling process. Furthermore, 97.21% of ECH conversion and 98.79% of chloropropene carbonate selectivity were gained over 2MeIm@Co-BTC-1.0 under optimal conditions (3.0 MPa, 90 °C, 5 h, 0.75 wt% catalyst of ECH). Additionally, only a slight decrease in catalytic activity was found after the optimal sample was reused three times. Finally, a mechanism for interpreting the coupling process of carbon dioxide cycloaddition with epoxide was proposed. Graphic Abstract One-pot catalytic conversion of CO2 into cyclic carbonate over 2-methylimidazole modified Co-BTC ZIF-67 Co-BTC CO Epoxide Cycloaddition Song, Xianghai aut Xu, Siquan aut Zhang, Jiahui aut Zhu, Yanli aut Gao, Lijing aut Xiao, Guomin aut Enthalten in Catalysis letters Springer US, 1988 149(2019), 9 vom: 22. Juni, Seite 2575-2585 (DE-627)130436550 (DE-600)644234-1 (DE-576)025720724 1011-372X nnns volume:149 year:2019 number:9 day:22 month:06 pages:2575-2585 https://doi.org/10.1007/s10562-019-02874-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 VA 2890 AR 149 2019 9 22 06 2575-2585
allfieldsGer	10.1007/s10562-019-02874-9 doi (DE-627)OLC2040200088 (DE-He213)s10562-019-02874-9-p DE-627 ger DE-627 rakwb eng 540 660 VZ VA 2890 VZ rvk Wu, Yuanfeng verfasserin aut 2-Methylimidazole Modified Co-BTC MOF as an Efficient Catalyst for Chemical Fixation of Carbon Dioxide 2019 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC, part of Springer Nature 2019 Abstract [($ CH_{3} $)2$ NH_{2} $][$ Co_{3} $(BTC)(HCOO)4($ H_{2} $O)]·$ H_{2} $O (Co-BTC) was synthesized under solvothermal conditions, further used as the precursor for the synthesis of 2-methylimidazole modified Co-BTC (2MeImCo-BTC-x). The characteristics of 2MeIm@Co-BTC-x were systematically characterized by various technologies including XRD, FESEM, FT-IR, XPS, $ N_{2} $-adsorption, TG-DTG and $ CO_{2} $/$ NH_{3} $-TPD. It was found that except for the crystal faces (0 1 1) and (− 1 0 2) corresponding to ZIF-67 and Co-BTC, a new crystal phase appeared at 12.$ 22^{o} $ for the modified Co-BTC, which may be attributed to the coordination between 2MeIm and unsaturated Co ions of Co-BTC. Interestingly, a new structure of hexagonal prisms together with hierarchical porous were also formed for the modified Co-BTC. Besides, when this composite was explored as a heterogeneous catalyst for catalytic conversion of carbon dioxide with epichlorohydrin (ECH) as probe, an obvious enhancement in catalytic activity was obtained compared with the fresh Co-BTC, suggesting that 2MeIm ligands within the modified Co-BTC played a great role on the coupling process. Furthermore, 97.21% of ECH conversion and 98.79% of chloropropene carbonate selectivity were gained over 2MeIm@Co-BTC-1.0 under optimal conditions (3.0 MPa, 90 °C, 5 h, 0.75 wt% catalyst of ECH). Additionally, only a slight decrease in catalytic activity was found after the optimal sample was reused three times. Finally, a mechanism for interpreting the coupling process of carbon dioxide cycloaddition with epoxide was proposed. Graphic Abstract One-pot catalytic conversion of CO2 into cyclic carbonate over 2-methylimidazole modified Co-BTC ZIF-67 Co-BTC CO Epoxide Cycloaddition Song, Xianghai aut Xu, Siquan aut Zhang, Jiahui aut Zhu, Yanli aut Gao, Lijing aut Xiao, Guomin aut Enthalten in Catalysis letters Springer US, 1988 149(2019), 9 vom: 22. Juni, Seite 2575-2585 (DE-627)130436550 (DE-600)644234-1 (DE-576)025720724 1011-372X nnns volume:149 year:2019 number:9 day:22 month:06 pages:2575-2585 https://doi.org/10.1007/s10562-019-02874-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 VA 2890 AR 149 2019 9 22 06 2575-2585
allfieldsSound	10.1007/s10562-019-02874-9 doi (DE-627)OLC2040200088 (DE-He213)s10562-019-02874-9-p DE-627 ger DE-627 rakwb eng 540 660 VZ VA 2890 VZ rvk Wu, Yuanfeng verfasserin aut 2-Methylimidazole Modified Co-BTC MOF as an Efficient Catalyst for Chemical Fixation of Carbon Dioxide 2019 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC, part of Springer Nature 2019 Abstract [($ CH_{3} $)2$ NH_{2} $][$ Co_{3} $(BTC)(HCOO)4($ H_{2} $O)]·$ H_{2} $O (Co-BTC) was synthesized under solvothermal conditions, further used as the precursor for the synthesis of 2-methylimidazole modified Co-BTC (2MeImCo-BTC-x). The characteristics of 2MeIm@Co-BTC-x were systematically characterized by various technologies including XRD, FESEM, FT-IR, XPS, $ N_{2} $-adsorption, TG-DTG and $ CO_{2} $/$ NH_{3} $-TPD. It was found that except for the crystal faces (0 1 1) and (− 1 0 2) corresponding to ZIF-67 and Co-BTC, a new crystal phase appeared at 12.$ 22^{o} $ for the modified Co-BTC, which may be attributed to the coordination between 2MeIm and unsaturated Co ions of Co-BTC. Interestingly, a new structure of hexagonal prisms together with hierarchical porous were also formed for the modified Co-BTC. Besides, when this composite was explored as a heterogeneous catalyst for catalytic conversion of carbon dioxide with epichlorohydrin (ECH) as probe, an obvious enhancement in catalytic activity was obtained compared with the fresh Co-BTC, suggesting that 2MeIm ligands within the modified Co-BTC played a great role on the coupling process. Furthermore, 97.21% of ECH conversion and 98.79% of chloropropene carbonate selectivity were gained over 2MeIm@Co-BTC-1.0 under optimal conditions (3.0 MPa, 90 °C, 5 h, 0.75 wt% catalyst of ECH). Additionally, only a slight decrease in catalytic activity was found after the optimal sample was reused three times. Finally, a mechanism for interpreting the coupling process of carbon dioxide cycloaddition with epoxide was proposed. Graphic Abstract One-pot catalytic conversion of CO2 into cyclic carbonate over 2-methylimidazole modified Co-BTC ZIF-67 Co-BTC CO Epoxide Cycloaddition Song, Xianghai aut Xu, Siquan aut Zhang, Jiahui aut Zhu, Yanli aut Gao, Lijing aut Xiao, Guomin aut Enthalten in Catalysis letters Springer US, 1988 149(2019), 9 vom: 22. Juni, Seite 2575-2585 (DE-627)130436550 (DE-600)644234-1 (DE-576)025720724 1011-372X nnns volume:149 year:2019 number:9 day:22 month:06 pages:2575-2585 https://doi.org/10.1007/s10562-019-02874-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 VA 2890 AR 149 2019 9 22 06 2575-2585
language	English
source	Enthalten in Catalysis letters 149(2019), 9 vom: 22. Juni, Seite 2575-2585 volume:149 year:2019 number:9 day:22 month:06 pages:2575-2585
sourceStr	Enthalten in Catalysis letters 149(2019), 9 vom: 22. Juni, Seite 2575-2585 volume:149 year:2019 number:9 day:22 month:06 pages:2575-2585
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	ZIF-67 Co-BTC CO Epoxide Cycloaddition
dewey-raw	540
isfreeaccess_bool	false
container_title	Catalysis letters
authorswithroles_txt_mv	Wu, Yuanfeng @@aut@@ Song, Xianghai @@aut@@ Xu, Siquan @@aut@@ Zhang, Jiahui @@aut@@ Zhu, Yanli @@aut@@ Gao, Lijing @@aut@@ Xiao, Guomin @@aut@@
publishDateDaySort_date	2019-06-22T00:00:00Z
hierarchy_top_id	130436550
dewey-sort	3540
id	OLC2040200088
language_de	englisch
fullrecord	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">OLC2040200088</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230503020749.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">200819s2019 xx \|\|\|\|\| 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10562-019-02874-9</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC2040200088</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-He213)s10562-019-02874-9-p</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">540</subfield><subfield code="a">660</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">VA 2890</subfield><subfield code="q">VZ</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Wu, Yuanfeng</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">2-Methylimidazole Modified Co-BTC MOF as an Efficient Catalyst for Chemical Fixation of Carbon Dioxide</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2019</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Springer Science+Business Media, LLC, part of Springer Nature 2019</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract [($ CH_{3} $)2$ NH_{2} $][$ Co_{3} $(BTC)(HCOO)4($ H_{2} $O)]·$ H_{2} $O (Co-BTC) was synthesized under solvothermal conditions, further used as the precursor for the synthesis of 2-methylimidazole modified Co-BTC (2MeImCo-BTC-x). The characteristics of 2MeIm@Co-BTC-x were systematically characterized by various technologies including XRD, FESEM, FT-IR, XPS, $ N_{2} $-adsorption, TG-DTG and $ CO_{2} $/$ NH_{3} $-TPD. It was found that except for the crystal faces (0 1 1) and (− 1 0 2) corresponding to ZIF-67 and Co-BTC, a new crystal phase appeared at 12.$ 22^{o} $ for the modified Co-BTC, which may be attributed to the coordination between 2MeIm and unsaturated Co ions of Co-BTC. Interestingly, a new structure of hexagonal prisms together with hierarchical porous were also formed for the modified Co-BTC. Besides, when this composite was explored as a heterogeneous catalyst for catalytic conversion of carbon dioxide with epichlorohydrin (ECH) as probe, an obvious enhancement in catalytic activity was obtained compared with the fresh Co-BTC, suggesting that 2MeIm ligands within the modified Co-BTC played a great role on the coupling process. Furthermore, 97.21% of ECH conversion and 98.79% of chloropropene carbonate selectivity were gained over 2MeIm@Co-BTC-1.0 under optimal conditions (3.0 MPa, 90 °C, 5 h, 0.75 wt% catalyst of ECH). Additionally, only a slight decrease in catalytic activity was found after the optimal sample was reused three times. Finally, a mechanism for interpreting the coupling process of carbon dioxide cycloaddition with epoxide was proposed. Graphic Abstract One-pot catalytic conversion of CO2 into cyclic carbonate over 2-methylimidazole modified Co-BTC</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">ZIF-67</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Co-BTC</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">CO</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Epoxide</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Cycloaddition</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Song, Xianghai</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Xu, Siquan</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhang, Jiahui</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhu, Yanli</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Gao, Lijing</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Xiao, Guomin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Catalysis letters</subfield><subfield code="d">Springer US, 1988</subfield><subfield code="g">149(2019), 9 vom: 22. Juni, Seite 2575-2585</subfield><subfield code="w">(DE-627)130436550</subfield><subfield code="w">(DE-600)644234-1</subfield><subfield code="w">(DE-576)025720724</subfield><subfield code="x">1011-372X</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:149</subfield><subfield code="g">year:2019</subfield><subfield code="g">number:9</subfield><subfield code="g">day:22</subfield><subfield code="g">month:06</subfield><subfield code="g">pages:2575-2585</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1007/s10562-019-02874-9</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-CHE</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="936" ind1="r" ind2="v"><subfield code="a">VA 2890</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">149</subfield><subfield code="j">2019</subfield><subfield code="e">9</subfield><subfield code="b">22</subfield><subfield code="c">06</subfield><subfield code="h">2575-2585</subfield></datafield></record></collection>
author	Wu, Yuanfeng
spellingShingle	Wu, Yuanfeng ddc 540 rvk VA 2890 misc ZIF-67 misc Co-BTC misc CO misc Epoxide misc Cycloaddition 2-Methylimidazole Modified Co-BTC MOF as an Efficient Catalyst for Chemical Fixation of Carbon Dioxide
authorStr	Wu, Yuanfeng
ppnlink_with_tag_str_mv	@@773@@(DE-627)130436550
format	Article
dewey-ones	540 - Chemistry & allied sciences 660 - Chemical engineering
delete_txt_mv	keep
author_role	aut aut aut aut aut aut aut
collection	OLC
remote_str	false
illustrated	Not Illustrated
issn	1011-372X
topic_title	540 660 VZ VA 2890 VZ rvk 2-Methylimidazole Modified Co-BTC MOF as an Efficient Catalyst for Chemical Fixation of Carbon Dioxide ZIF-67 Co-BTC CO Epoxide Cycloaddition
topic	ddc 540 rvk VA 2890 misc ZIF-67 misc Co-BTC misc CO misc Epoxide misc Cycloaddition
topic_unstemmed	ddc 540 rvk VA 2890 misc ZIF-67 misc Co-BTC misc CO misc Epoxide misc Cycloaddition
topic_browse	ddc 540 rvk VA 2890 misc ZIF-67 misc Co-BTC misc CO misc Epoxide misc Cycloaddition
format_facet	Aufsätze Gedruckte Aufsätze
format_main_str_mv	Text Zeitschrift/Artikel
carriertype_str_mv	nc
hierarchy_parent_title	Catalysis letters
hierarchy_parent_id	130436550
dewey-tens	540 - Chemistry 660 - Chemical engineering
hierarchy_top_title	Catalysis letters
isfreeaccess_txt	false
familylinks_str_mv	(DE-627)130436550 (DE-600)644234-1 (DE-576)025720724
title	2-Methylimidazole Modified Co-BTC MOF as an Efficient Catalyst for Chemical Fixation of Carbon Dioxide
ctrlnum	(DE-627)OLC2040200088 (DE-He213)s10562-019-02874-9-p
title_full	2-Methylimidazole Modified Co-BTC MOF as an Efficient Catalyst for Chemical Fixation of Carbon Dioxide
author_sort	Wu, Yuanfeng
journal	Catalysis letters
journalStr	Catalysis letters
lang_code	eng
isOA_bool	false
dewey-hundreds	500 - Science 600 - Technology
recordtype	marc
publishDateSort	2019
contenttype_str_mv	txt
container_start_page	2575
author_browse	Wu, Yuanfeng Song, Xianghai Xu, Siquan Zhang, Jiahui Zhu, Yanli Gao, Lijing Xiao, Guomin
container_volume	149
class	540 660 VZ VA 2890 VZ rvk
format_se	Aufsätze
author-letter	Wu, Yuanfeng
doi_str_mv	10.1007/s10562-019-02874-9
dewey-full	540 660
title_sort	2-methylimidazole modified co-btc mof as an efficient catalyst for chemical fixation of carbon dioxide
title_auth	2-Methylimidazole Modified Co-BTC MOF as an Efficient Catalyst for Chemical Fixation of Carbon Dioxide
abstract	Abstract [($ CH_{3} $)2$ NH_{2} $][$ Co_{3} $(BTC)(HCOO)4($ H_{2} $O)]·$ H_{2} $O (Co-BTC) was synthesized under solvothermal conditions, further used as the precursor for the synthesis of 2-methylimidazole modified Co-BTC (2MeImCo-BTC-x). The characteristics of 2MeIm@Co-BTC-x were systematically characterized by various technologies including XRD, FESEM, FT-IR, XPS, $ N_{2} $-adsorption, TG-DTG and $ CO_{2} $/$ NH_{3} $-TPD. It was found that except for the crystal faces (0 1 1) and (− 1 0 2) corresponding to ZIF-67 and Co-BTC, a new crystal phase appeared at 12.$ 22^{o} $ for the modified Co-BTC, which may be attributed to the coordination between 2MeIm and unsaturated Co ions of Co-BTC. Interestingly, a new structure of hexagonal prisms together with hierarchical porous were also formed for the modified Co-BTC. Besides, when this composite was explored as a heterogeneous catalyst for catalytic conversion of carbon dioxide with epichlorohydrin (ECH) as probe, an obvious enhancement in catalytic activity was obtained compared with the fresh Co-BTC, suggesting that 2MeIm ligands within the modified Co-BTC played a great role on the coupling process. Furthermore, 97.21% of ECH conversion and 98.79% of chloropropene carbonate selectivity were gained over 2MeIm@Co-BTC-1.0 under optimal conditions (3.0 MPa, 90 °C, 5 h, 0.75 wt% catalyst of ECH). Additionally, only a slight decrease in catalytic activity was found after the optimal sample was reused three times. Finally, a mechanism for interpreting the coupling process of carbon dioxide cycloaddition with epoxide was proposed. Graphic Abstract One-pot catalytic conversion of CO2 into cyclic carbonate over 2-methylimidazole modified Co-BTC © Springer Science+Business Media, LLC, part of Springer Nature 2019
abstractGer	Abstract [($ CH_{3} $)2$ NH_{2} $][$ Co_{3} $(BTC)(HCOO)4($ H_{2} $O)]·$ H_{2} $O (Co-BTC) was synthesized under solvothermal conditions, further used as the precursor for the synthesis of 2-methylimidazole modified Co-BTC (2MeImCo-BTC-x). The characteristics of 2MeIm@Co-BTC-x were systematically characterized by various technologies including XRD, FESEM, FT-IR, XPS, $ N_{2} $-adsorption, TG-DTG and $ CO_{2} $/$ NH_{3} $-TPD. It was found that except for the crystal faces (0 1 1) and (− 1 0 2) corresponding to ZIF-67 and Co-BTC, a new crystal phase appeared at 12.$ 22^{o} $ for the modified Co-BTC, which may be attributed to the coordination between 2MeIm and unsaturated Co ions of Co-BTC. Interestingly, a new structure of hexagonal prisms together with hierarchical porous were also formed for the modified Co-BTC. Besides, when this composite was explored as a heterogeneous catalyst for catalytic conversion of carbon dioxide with epichlorohydrin (ECH) as probe, an obvious enhancement in catalytic activity was obtained compared with the fresh Co-BTC, suggesting that 2MeIm ligands within the modified Co-BTC played a great role on the coupling process. Furthermore, 97.21% of ECH conversion and 98.79% of chloropropene carbonate selectivity were gained over 2MeIm@Co-BTC-1.0 under optimal conditions (3.0 MPa, 90 °C, 5 h, 0.75 wt% catalyst of ECH). Additionally, only a slight decrease in catalytic activity was found after the optimal sample was reused three times. Finally, a mechanism for interpreting the coupling process of carbon dioxide cycloaddition with epoxide was proposed. Graphic Abstract One-pot catalytic conversion of CO2 into cyclic carbonate over 2-methylimidazole modified Co-BTC © Springer Science+Business Media, LLC, part of Springer Nature 2019
abstract_unstemmed	Abstract [($ CH_{3} $)2$ NH_{2} $][$ Co_{3} $(BTC)(HCOO)4($ H_{2} $O)]·$ H_{2} $O (Co-BTC) was synthesized under solvothermal conditions, further used as the precursor for the synthesis of 2-methylimidazole modified Co-BTC (2MeImCo-BTC-x). The characteristics of 2MeIm@Co-BTC-x were systematically characterized by various technologies including XRD, FESEM, FT-IR, XPS, $ N_{2} $-adsorption, TG-DTG and $ CO_{2} $/$ NH_{3} $-TPD. It was found that except for the crystal faces (0 1 1) and (− 1 0 2) corresponding to ZIF-67 and Co-BTC, a new crystal phase appeared at 12.$ 22^{o} $ for the modified Co-BTC, which may be attributed to the coordination between 2MeIm and unsaturated Co ions of Co-BTC. Interestingly, a new structure of hexagonal prisms together with hierarchical porous were also formed for the modified Co-BTC. Besides, when this composite was explored as a heterogeneous catalyst for catalytic conversion of carbon dioxide with epichlorohydrin (ECH) as probe, an obvious enhancement in catalytic activity was obtained compared with the fresh Co-BTC, suggesting that 2MeIm ligands within the modified Co-BTC played a great role on the coupling process. Furthermore, 97.21% of ECH conversion and 98.79% of chloropropene carbonate selectivity were gained over 2MeIm@Co-BTC-1.0 under optimal conditions (3.0 MPa, 90 °C, 5 h, 0.75 wt% catalyst of ECH). Additionally, only a slight decrease in catalytic activity was found after the optimal sample was reused three times. Finally, a mechanism for interpreting the coupling process of carbon dioxide cycloaddition with epoxide was proposed. Graphic Abstract One-pot catalytic conversion of CO2 into cyclic carbonate over 2-methylimidazole modified Co-BTC © Springer Science+Business Media, LLC, part of Springer Nature 2019
collection_details	GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70
container_issue	9
title_short	2-Methylimidazole Modified Co-BTC MOF as an Efficient Catalyst for Chemical Fixation of Carbon Dioxide
url	https://doi.org/10.1007/s10562-019-02874-9
remote_bool	false
author2	Song, Xianghai Xu, Siquan Zhang, Jiahui Zhu, Yanli Gao, Lijing Xiao, Guomin
author2Str	Song, Xianghai Xu, Siquan Zhang, Jiahui Zhu, Yanli Gao, Lijing Xiao, Guomin
ppnlink	130436550
mediatype_str_mv	n
isOA_txt	false
hochschulschrift_bool	false
doi_str	10.1007/s10562-019-02874-9
up_date	2024-07-04T01:33:11.583Z
_version_	1803610270290935808
fullrecord_marcxml	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">OLC2040200088</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230503020749.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">200819s2019 xx \|\|\|\|\| 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10562-019-02874-9</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC2040200088</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-He213)s10562-019-02874-9-p</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">540</subfield><subfield code="a">660</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">VA 2890</subfield><subfield code="q">VZ</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Wu, Yuanfeng</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">2-Methylimidazole Modified Co-BTC MOF as an Efficient Catalyst for Chemical Fixation of Carbon Dioxide</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2019</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Springer Science+Business Media, LLC, part of Springer Nature 2019</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract [($ CH_{3} $)2$ NH_{2} $][$ Co_{3} $(BTC)(HCOO)4($ H_{2} $O)]·$ H_{2} $O (Co-BTC) was synthesized under solvothermal conditions, further used as the precursor for the synthesis of 2-methylimidazole modified Co-BTC (2MeImCo-BTC-x). The characteristics of 2MeIm@Co-BTC-x were systematically characterized by various technologies including XRD, FESEM, FT-IR, XPS, $ N_{2} $-adsorption, TG-DTG and $ CO_{2} $/$ NH_{3} $-TPD. It was found that except for the crystal faces (0 1 1) and (− 1 0 2) corresponding to ZIF-67 and Co-BTC, a new crystal phase appeared at 12.$ 22^{o} $ for the modified Co-BTC, which may be attributed to the coordination between 2MeIm and unsaturated Co ions of Co-BTC. Interestingly, a new structure of hexagonal prisms together with hierarchical porous were also formed for the modified Co-BTC. Besides, when this composite was explored as a heterogeneous catalyst for catalytic conversion of carbon dioxide with epichlorohydrin (ECH) as probe, an obvious enhancement in catalytic activity was obtained compared with the fresh Co-BTC, suggesting that 2MeIm ligands within the modified Co-BTC played a great role on the coupling process. Furthermore, 97.21% of ECH conversion and 98.79% of chloropropene carbonate selectivity were gained over 2MeIm@Co-BTC-1.0 under optimal conditions (3.0 MPa, 90 °C, 5 h, 0.75 wt% catalyst of ECH). Additionally, only a slight decrease in catalytic activity was found after the optimal sample was reused three times. Finally, a mechanism for interpreting the coupling process of carbon dioxide cycloaddition with epoxide was proposed. Graphic Abstract One-pot catalytic conversion of CO2 into cyclic carbonate over 2-methylimidazole modified Co-BTC</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">ZIF-67</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Co-BTC</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">CO</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Epoxide</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Cycloaddition</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Song, Xianghai</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Xu, Siquan</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhang, Jiahui</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhu, Yanli</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Gao, Lijing</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Xiao, Guomin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Catalysis letters</subfield><subfield code="d">Springer US, 1988</subfield><subfield code="g">149(2019), 9 vom: 22. Juni, Seite 2575-2585</subfield><subfield code="w">(DE-627)130436550</subfield><subfield code="w">(DE-600)644234-1</subfield><subfield code="w">(DE-576)025720724</subfield><subfield code="x">1011-372X</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:149</subfield><subfield code="g">year:2019</subfield><subfield code="g">number:9</subfield><subfield code="g">day:22</subfield><subfield code="g">month:06</subfield><subfield code="g">pages:2575-2585</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1007/s10562-019-02874-9</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-CHE</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="936" ind1="r" ind2="v"><subfield code="a">VA 2890</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">149</subfield><subfield code="j">2019</subfield><subfield code="e">9</subfield><subfield code="b">22</subfield><subfield code="c">06</subfield><subfield code="h">2575-2585</subfield></datafield></record></collection>
score	7.4017725

Nicht das Richtige dabei?

Schreiben Sie uns!

2-Methylimidazole Modified Co-BTC MOF as an Efficient Catalyst for Chemical Fixation of Carbon Dioxide

Nicht das Richtige dabei?

Zugang & Verfügbarkeit

Vorhandene Bände

Nicht das Richtige dabei?