Application of a biosorbent to soil: a potential method for controlling water pollution by pesticides
Abstract Different strategies are now being optimized to prevent water from agricultural areas being contaminated by pesticides. The aim of this work was to optimize the adsorption of non-polar (tebuconazole, triadimenol) and polar (cymoxanil, pirimicarb) pesticides by soils after applying the bioso...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Álvarez-Martín, Alba [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2016 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer-Verlag Berlin Heidelberg 2016 |
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| Übergeordnetes Werk: |
Enthalten in: Environmental science and pollution research - Springer Berlin Heidelberg, 1994, 23(2016), 9 vom: 01. Feb., Seite 9192-9203 |
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| Übergeordnetes Werk: |
volume:23 ; year:2016 ; number:9 ; day:01 ; month:02 ; pages:9192-9203 |
| Links: |
|---|
| DOI / URN: |
10.1007/s11356-016-6132-4 |
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OLC2040463607 |
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| 520 | |a Abstract Different strategies are now being optimized to prevent water from agricultural areas being contaminated by pesticides. The aim of this work was to optimize the adsorption of non-polar (tebuconazole, triadimenol) and polar (cymoxanil, pirimicarb) pesticides by soils after applying the biosorbent spent mushroom substrate (SMS) at different rates. The adsorption isotherms of pesticides by three soils and SMS-amended soils were obtained and the adsorption constants were calculated. The distribution coefficients (Kd) increased 1.40–23.1 times (tebuconazole), 1.08–23.7 times (triadimenol), 1.31–42.1 times (cymoxanil), and 0.55–23.8 times (pirimicarb) for soils amended with biosorbent at rates between 2 and 75 %. Increasing the SMS rates led to a constant increase in adsorption efficiency for non-polar pesticides but not for polar pesticides, due to the increase in the organic carbon (OC) content of soils as indicated by KOC values. The OC content of SMS-amended soils accounted for more than 90 % of the adsorption variability of non-polar pesticides, but it accounted for only 56.3 % for polar pesticides. The estimated adsorption of SMS-amended soils determined from the individual adsorption of soils and SMS was more consistent with real experimental values for non-polar pesticides than for polar pesticides. The results revealed the use of SMS as a tool to optimize pesticide adsorption by soils in dealing with specific contamination problems involving these compounds. | ||
| 650 | 4 | |a Biosorbent | |
| 650 | 4 | |a Spent mushroom substrate | |
| 650 | 4 | |a Immobilization | |
| 650 | 4 | |a Soil | |
| 650 | 4 | |a Non-polar pesticides | |
| 650 | 4 | |a Polar pesticides | |
| 650 | 4 | |a Water pollution | |
| 700 | 1 | |a Rodríguez-Cruz, M. Sonia |4 aut | |
| 700 | 1 | |a Andrades, M. Soledad |4 aut | |
| 700 | 1 | |a Sánchez-Martín, María J. |4 aut | |
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10.1007/s11356-016-6132-4 doi (DE-627)OLC2040463607 (DE-He213)s11356-016-6132-4-p DE-627 ger DE-627 rakwb eng 570 360 333.7 VZ 690 333.7 540 VZ BIODIV DE-30 fid Álvarez-Martín, Alba verfasserin aut Application of a biosorbent to soil: a potential method for controlling water pollution by pesticides 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag Berlin Heidelberg 2016 Abstract Different strategies are now being optimized to prevent water from agricultural areas being contaminated by pesticides. The aim of this work was to optimize the adsorption of non-polar (tebuconazole, triadimenol) and polar (cymoxanil, pirimicarb) pesticides by soils after applying the biosorbent spent mushroom substrate (SMS) at different rates. The adsorption isotherms of pesticides by three soils and SMS-amended soils were obtained and the adsorption constants were calculated. The distribution coefficients (Kd) increased 1.40–23.1 times (tebuconazole), 1.08–23.7 times (triadimenol), 1.31–42.1 times (cymoxanil), and 0.55–23.8 times (pirimicarb) for soils amended with biosorbent at rates between 2 and 75 %. Increasing the SMS rates led to a constant increase in adsorption efficiency for non-polar pesticides but not for polar pesticides, due to the increase in the organic carbon (OC) content of soils as indicated by KOC values. The OC content of SMS-amended soils accounted for more than 90 % of the adsorption variability of non-polar pesticides, but it accounted for only 56.3 % for polar pesticides. The estimated adsorption of SMS-amended soils determined from the individual adsorption of soils and SMS was more consistent with real experimental values for non-polar pesticides than for polar pesticides. The results revealed the use of SMS as a tool to optimize pesticide adsorption by soils in dealing with specific contamination problems involving these compounds. Biosorbent Spent mushroom substrate Immobilization Soil Non-polar pesticides Polar pesticides Water pollution Rodríguez-Cruz, M. Sonia aut Andrades, M. Soledad aut Sánchez-Martín, María J. aut Enthalten in Environmental science and pollution research Springer Berlin Heidelberg, 1994 23(2016), 9 vom: 01. Feb., Seite 9192-9203 (DE-627)171335805 (DE-600)1178791-0 (DE-576)038875101 0944-1344 nnns volume:23 year:2016 number:9 day:01 month:02 pages:9192-9203 https://doi.org/10.1007/s11356-016-6132-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-FOR SSG-OLC-DE-84 GBV_ILN_70 GBV_ILN_252 GBV_ILN_267 GBV_ILN_2018 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4219 GBV_ILN_4277 AR 23 2016 9 01 02 9192-9203 |
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10.1007/s11356-016-6132-4 doi (DE-627)OLC2040463607 (DE-He213)s11356-016-6132-4-p DE-627 ger DE-627 rakwb eng 570 360 333.7 VZ 690 333.7 540 VZ BIODIV DE-30 fid Álvarez-Martín, Alba verfasserin aut Application of a biosorbent to soil: a potential method for controlling water pollution by pesticides 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag Berlin Heidelberg 2016 Abstract Different strategies are now being optimized to prevent water from agricultural areas being contaminated by pesticides. The aim of this work was to optimize the adsorption of non-polar (tebuconazole, triadimenol) and polar (cymoxanil, pirimicarb) pesticides by soils after applying the biosorbent spent mushroom substrate (SMS) at different rates. The adsorption isotherms of pesticides by three soils and SMS-amended soils were obtained and the adsorption constants were calculated. The distribution coefficients (Kd) increased 1.40–23.1 times (tebuconazole), 1.08–23.7 times (triadimenol), 1.31–42.1 times (cymoxanil), and 0.55–23.8 times (pirimicarb) for soils amended with biosorbent at rates between 2 and 75 %. Increasing the SMS rates led to a constant increase in adsorption efficiency for non-polar pesticides but not for polar pesticides, due to the increase in the organic carbon (OC) content of soils as indicated by KOC values. The OC content of SMS-amended soils accounted for more than 90 % of the adsorption variability of non-polar pesticides, but it accounted for only 56.3 % for polar pesticides. The estimated adsorption of SMS-amended soils determined from the individual adsorption of soils and SMS was more consistent with real experimental values for non-polar pesticides than for polar pesticides. The results revealed the use of SMS as a tool to optimize pesticide adsorption by soils in dealing with specific contamination problems involving these compounds. Biosorbent Spent mushroom substrate Immobilization Soil Non-polar pesticides Polar pesticides Water pollution Rodríguez-Cruz, M. Sonia aut Andrades, M. Soledad aut Sánchez-Martín, María J. aut Enthalten in Environmental science and pollution research Springer Berlin Heidelberg, 1994 23(2016), 9 vom: 01. Feb., Seite 9192-9203 (DE-627)171335805 (DE-600)1178791-0 (DE-576)038875101 0944-1344 nnns volume:23 year:2016 number:9 day:01 month:02 pages:9192-9203 https://doi.org/10.1007/s11356-016-6132-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-FOR SSG-OLC-DE-84 GBV_ILN_70 GBV_ILN_252 GBV_ILN_267 GBV_ILN_2018 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4219 GBV_ILN_4277 AR 23 2016 9 01 02 9192-9203 |
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10.1007/s11356-016-6132-4 doi (DE-627)OLC2040463607 (DE-He213)s11356-016-6132-4-p DE-627 ger DE-627 rakwb eng 570 360 333.7 VZ 690 333.7 540 VZ BIODIV DE-30 fid Álvarez-Martín, Alba verfasserin aut Application of a biosorbent to soil: a potential method for controlling water pollution by pesticides 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag Berlin Heidelberg 2016 Abstract Different strategies are now being optimized to prevent water from agricultural areas being contaminated by pesticides. The aim of this work was to optimize the adsorption of non-polar (tebuconazole, triadimenol) and polar (cymoxanil, pirimicarb) pesticides by soils after applying the biosorbent spent mushroom substrate (SMS) at different rates. The adsorption isotherms of pesticides by three soils and SMS-amended soils were obtained and the adsorption constants were calculated. The distribution coefficients (Kd) increased 1.40–23.1 times (tebuconazole), 1.08–23.7 times (triadimenol), 1.31–42.1 times (cymoxanil), and 0.55–23.8 times (pirimicarb) for soils amended with biosorbent at rates between 2 and 75 %. Increasing the SMS rates led to a constant increase in adsorption efficiency for non-polar pesticides but not for polar pesticides, due to the increase in the organic carbon (OC) content of soils as indicated by KOC values. The OC content of SMS-amended soils accounted for more than 90 % of the adsorption variability of non-polar pesticides, but it accounted for only 56.3 % for polar pesticides. The estimated adsorption of SMS-amended soils determined from the individual adsorption of soils and SMS was more consistent with real experimental values for non-polar pesticides than for polar pesticides. The results revealed the use of SMS as a tool to optimize pesticide adsorption by soils in dealing with specific contamination problems involving these compounds. Biosorbent Spent mushroom substrate Immobilization Soil Non-polar pesticides Polar pesticides Water pollution Rodríguez-Cruz, M. Sonia aut Andrades, M. Soledad aut Sánchez-Martín, María J. aut Enthalten in Environmental science and pollution research Springer Berlin Heidelberg, 1994 23(2016), 9 vom: 01. Feb., Seite 9192-9203 (DE-627)171335805 (DE-600)1178791-0 (DE-576)038875101 0944-1344 nnns volume:23 year:2016 number:9 day:01 month:02 pages:9192-9203 https://doi.org/10.1007/s11356-016-6132-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-FOR SSG-OLC-DE-84 GBV_ILN_70 GBV_ILN_252 GBV_ILN_267 GBV_ILN_2018 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4219 GBV_ILN_4277 AR 23 2016 9 01 02 9192-9203 |
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10.1007/s11356-016-6132-4 doi (DE-627)OLC2040463607 (DE-He213)s11356-016-6132-4-p DE-627 ger DE-627 rakwb eng 570 360 333.7 VZ 690 333.7 540 VZ BIODIV DE-30 fid Álvarez-Martín, Alba verfasserin aut Application of a biosorbent to soil: a potential method for controlling water pollution by pesticides 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag Berlin Heidelberg 2016 Abstract Different strategies are now being optimized to prevent water from agricultural areas being contaminated by pesticides. The aim of this work was to optimize the adsorption of non-polar (tebuconazole, triadimenol) and polar (cymoxanil, pirimicarb) pesticides by soils after applying the biosorbent spent mushroom substrate (SMS) at different rates. The adsorption isotherms of pesticides by three soils and SMS-amended soils were obtained and the adsorption constants were calculated. The distribution coefficients (Kd) increased 1.40–23.1 times (tebuconazole), 1.08–23.7 times (triadimenol), 1.31–42.1 times (cymoxanil), and 0.55–23.8 times (pirimicarb) for soils amended with biosorbent at rates between 2 and 75 %. Increasing the SMS rates led to a constant increase in adsorption efficiency for non-polar pesticides but not for polar pesticides, due to the increase in the organic carbon (OC) content of soils as indicated by KOC values. The OC content of SMS-amended soils accounted for more than 90 % of the adsorption variability of non-polar pesticides, but it accounted for only 56.3 % for polar pesticides. The estimated adsorption of SMS-amended soils determined from the individual adsorption of soils and SMS was more consistent with real experimental values for non-polar pesticides than for polar pesticides. The results revealed the use of SMS as a tool to optimize pesticide adsorption by soils in dealing with specific contamination problems involving these compounds. Biosorbent Spent mushroom substrate Immobilization Soil Non-polar pesticides Polar pesticides Water pollution Rodríguez-Cruz, M. Sonia aut Andrades, M. Soledad aut Sánchez-Martín, María J. aut Enthalten in Environmental science and pollution research Springer Berlin Heidelberg, 1994 23(2016), 9 vom: 01. Feb., Seite 9192-9203 (DE-627)171335805 (DE-600)1178791-0 (DE-576)038875101 0944-1344 nnns volume:23 year:2016 number:9 day:01 month:02 pages:9192-9203 https://doi.org/10.1007/s11356-016-6132-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-FOR SSG-OLC-DE-84 GBV_ILN_70 GBV_ILN_252 GBV_ILN_267 GBV_ILN_2018 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4219 GBV_ILN_4277 AR 23 2016 9 01 02 9192-9203 |
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10.1007/s11356-016-6132-4 doi (DE-627)OLC2040463607 (DE-He213)s11356-016-6132-4-p DE-627 ger DE-627 rakwb eng 570 360 333.7 VZ 690 333.7 540 VZ BIODIV DE-30 fid Álvarez-Martín, Alba verfasserin aut Application of a biosorbent to soil: a potential method for controlling water pollution by pesticides 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag Berlin Heidelberg 2016 Abstract Different strategies are now being optimized to prevent water from agricultural areas being contaminated by pesticides. The aim of this work was to optimize the adsorption of non-polar (tebuconazole, triadimenol) and polar (cymoxanil, pirimicarb) pesticides by soils after applying the biosorbent spent mushroom substrate (SMS) at different rates. The adsorption isotherms of pesticides by three soils and SMS-amended soils were obtained and the adsorption constants were calculated. The distribution coefficients (Kd) increased 1.40–23.1 times (tebuconazole), 1.08–23.7 times (triadimenol), 1.31–42.1 times (cymoxanil), and 0.55–23.8 times (pirimicarb) for soils amended with biosorbent at rates between 2 and 75 %. Increasing the SMS rates led to a constant increase in adsorption efficiency for non-polar pesticides but not for polar pesticides, due to the increase in the organic carbon (OC) content of soils as indicated by KOC values. The OC content of SMS-amended soils accounted for more than 90 % of the adsorption variability of non-polar pesticides, but it accounted for only 56.3 % for polar pesticides. The estimated adsorption of SMS-amended soils determined from the individual adsorption of soils and SMS was more consistent with real experimental values for non-polar pesticides than for polar pesticides. The results revealed the use of SMS as a tool to optimize pesticide adsorption by soils in dealing with specific contamination problems involving these compounds. Biosorbent Spent mushroom substrate Immobilization Soil Non-polar pesticides Polar pesticides Water pollution Rodríguez-Cruz, M. Sonia aut Andrades, M. Soledad aut Sánchez-Martín, María J. aut Enthalten in Environmental science and pollution research Springer Berlin Heidelberg, 1994 23(2016), 9 vom: 01. Feb., Seite 9192-9203 (DE-627)171335805 (DE-600)1178791-0 (DE-576)038875101 0944-1344 nnns volume:23 year:2016 number:9 day:01 month:02 pages:9192-9203 https://doi.org/10.1007/s11356-016-6132-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-FOR SSG-OLC-DE-84 GBV_ILN_70 GBV_ILN_252 GBV_ILN_267 GBV_ILN_2018 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4219 GBV_ILN_4277 AR 23 2016 9 01 02 9192-9203 |
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Enthalten in Environmental science and pollution research 23(2016), 9 vom: 01. Feb., Seite 9192-9203 volume:23 year:2016 number:9 day:01 month:02 pages:9192-9203 |
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application of a biosorbent to soil: a potential method for controlling water pollution by pesticides |
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Application of a biosorbent to soil: a potential method for controlling water pollution by pesticides |
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Abstract Different strategies are now being optimized to prevent water from agricultural areas being contaminated by pesticides. The aim of this work was to optimize the adsorption of non-polar (tebuconazole, triadimenol) and polar (cymoxanil, pirimicarb) pesticides by soils after applying the biosorbent spent mushroom substrate (SMS) at different rates. The adsorption isotherms of pesticides by three soils and SMS-amended soils were obtained and the adsorption constants were calculated. The distribution coefficients (Kd) increased 1.40–23.1 times (tebuconazole), 1.08–23.7 times (triadimenol), 1.31–42.1 times (cymoxanil), and 0.55–23.8 times (pirimicarb) for soils amended with biosorbent at rates between 2 and 75 %. Increasing the SMS rates led to a constant increase in adsorption efficiency for non-polar pesticides but not for polar pesticides, due to the increase in the organic carbon (OC) content of soils as indicated by KOC values. The OC content of SMS-amended soils accounted for more than 90 % of the adsorption variability of non-polar pesticides, but it accounted for only 56.3 % for polar pesticides. The estimated adsorption of SMS-amended soils determined from the individual adsorption of soils and SMS was more consistent with real experimental values for non-polar pesticides than for polar pesticides. The results revealed the use of SMS as a tool to optimize pesticide adsorption by soils in dealing with specific contamination problems involving these compounds. © Springer-Verlag Berlin Heidelberg 2016 |
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Abstract Different strategies are now being optimized to prevent water from agricultural areas being contaminated by pesticides. The aim of this work was to optimize the adsorption of non-polar (tebuconazole, triadimenol) and polar (cymoxanil, pirimicarb) pesticides by soils after applying the biosorbent spent mushroom substrate (SMS) at different rates. The adsorption isotherms of pesticides by three soils and SMS-amended soils were obtained and the adsorption constants were calculated. The distribution coefficients (Kd) increased 1.40–23.1 times (tebuconazole), 1.08–23.7 times (triadimenol), 1.31–42.1 times (cymoxanil), and 0.55–23.8 times (pirimicarb) for soils amended with biosorbent at rates between 2 and 75 %. Increasing the SMS rates led to a constant increase in adsorption efficiency for non-polar pesticides but not for polar pesticides, due to the increase in the organic carbon (OC) content of soils as indicated by KOC values. The OC content of SMS-amended soils accounted for more than 90 % of the adsorption variability of non-polar pesticides, but it accounted for only 56.3 % for polar pesticides. The estimated adsorption of SMS-amended soils determined from the individual adsorption of soils and SMS was more consistent with real experimental values for non-polar pesticides than for polar pesticides. The results revealed the use of SMS as a tool to optimize pesticide adsorption by soils in dealing with specific contamination problems involving these compounds. © Springer-Verlag Berlin Heidelberg 2016 |
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Abstract Different strategies are now being optimized to prevent water from agricultural areas being contaminated by pesticides. The aim of this work was to optimize the adsorption of non-polar (tebuconazole, triadimenol) and polar (cymoxanil, pirimicarb) pesticides by soils after applying the biosorbent spent mushroom substrate (SMS) at different rates. The adsorption isotherms of pesticides by three soils and SMS-amended soils were obtained and the adsorption constants were calculated. The distribution coefficients (Kd) increased 1.40–23.1 times (tebuconazole), 1.08–23.7 times (triadimenol), 1.31–42.1 times (cymoxanil), and 0.55–23.8 times (pirimicarb) for soils amended with biosorbent at rates between 2 and 75 %. Increasing the SMS rates led to a constant increase in adsorption efficiency for non-polar pesticides but not for polar pesticides, due to the increase in the organic carbon (OC) content of soils as indicated by KOC values. The OC content of SMS-amended soils accounted for more than 90 % of the adsorption variability of non-polar pesticides, but it accounted for only 56.3 % for polar pesticides. The estimated adsorption of SMS-amended soils determined from the individual adsorption of soils and SMS was more consistent with real experimental values for non-polar pesticides than for polar pesticides. The results revealed the use of SMS as a tool to optimize pesticide adsorption by soils in dealing with specific contamination problems involving these compounds. © Springer-Verlag Berlin Heidelberg 2016 |
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