The different paths and potential risks of photo(-electro)-catalytic degradation for rhodamine B in water by graphene/$ TiO_{2} $ membrane
Abstract The graphene (GR)/$ TiO_{2} $ membrane was prepared by the sol-gel method and coated on the indium tin oxide (ITO) conductive glass, which showed high and stable photo(-electro)-catalytic activities to rhodamine B (Rh-B) in water. Characterization results showed that the GR was dispersed an...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Ren, Miao [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2018 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer-Verlag GmbH Germany, part of Springer Nature 2018 |
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| Übergeordnetes Werk: |
Enthalten in: Environmental science and pollution research - Springer Berlin Heidelberg, 1994, 25(2018), 14 vom: 07. März, Seite 13988-13999 |
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| Übergeordnetes Werk: |
volume:25 ; year:2018 ; number:14 ; day:07 ; month:03 ; pages:13988-13999 |
| Links: |
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| DOI / URN: |
10.1007/s11356-018-1611-4 |
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OLC2040515623 |
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| 520 | |a Abstract The graphene (GR)/$ TiO_{2} $ membrane was prepared by the sol-gel method and coated on the indium tin oxide (ITO) conductive glass, which showed high and stable photo(-electro)-catalytic activities to rhodamine B (Rh-B) in water. Characterization results showed that the GR was dispersed and wrapped in the needle-like $ TiO_{2} $. With GR/$ TiO_{2} $ membrane and simulated sunlight irradiation, the removal efficiency of Rh-B (10 mg $ l^{−1} $ and pH at 5.4) arrived at 87.6% within 300 min. However, the higher removal efficiency for Rh-B reached to 97.8% by the photo-electro-catalytic degradation with the applied voltage 4 v for 30 min. The ·OH that generated in the photo-catalytic degradation process were responsible for Rh-B decomposition. The ·$ O_{2} $− played the significant role in the photo-electro-catalytic degradation of Rh-B. Furthermore, the decarboxylation was also occurred in the photo-electro-catalytic degradation for the Rh-B in water except for the deethylation and hydroxylation in the photo-catalytic degradation. In addition, the toxicities of the intermediates were calculated using the ECOSAR program and the EPIWIN software. The results indicated that the toxicities of intermediates from photo-electro-catalytic degradation for the Rh-B were higher than photo-catalytic degradation, due to the generation of decarboxylate. | ||
| 650 | 4 | |a Photo-electro-catalytic degradation | |
| 650 | 4 | |a Photo-catalytic degradation | |
| 650 | 4 | |a Rhodamine B | |
| 650 | 4 | |a Intermediate | |
| 650 | 4 | |a Toxicity | |
| 650 | 4 | |a Potential risk | |
| 700 | 1 | |a Liu, Haiyang |4 aut | |
| 700 | 1 | |a Qu, Jiao |4 aut | |
| 700 | 1 | |a Zhang, Yanan |4 aut | |
| 700 | 1 | |a Ma, Ying |4 aut | |
| 700 | 1 | |a Yuan, Xing |4 aut | |
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10.1007/s11356-018-1611-4 doi (DE-627)OLC2040515623 (DE-He213)s11356-018-1611-4-p DE-627 ger DE-627 rakwb eng 570 360 333.7 VZ 690 333.7 540 VZ BIODIV DE-30 fid Ren, Miao verfasserin aut The different paths and potential risks of photo(-electro)-catalytic degradation for rhodamine B in water by graphene/$ TiO_{2} $ membrane 2018 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag GmbH Germany, part of Springer Nature 2018 Abstract The graphene (GR)/$ TiO_{2} $ membrane was prepared by the sol-gel method and coated on the indium tin oxide (ITO) conductive glass, which showed high and stable photo(-electro)-catalytic activities to rhodamine B (Rh-B) in water. Characterization results showed that the GR was dispersed and wrapped in the needle-like $ TiO_{2} $. With GR/$ TiO_{2} $ membrane and simulated sunlight irradiation, the removal efficiency of Rh-B (10 mg $ l^{−1} $ and pH at 5.4) arrived at 87.6% within 300 min. However, the higher removal efficiency for Rh-B reached to 97.8% by the photo-electro-catalytic degradation with the applied voltage 4 v for 30 min. The ·OH that generated in the photo-catalytic degradation process were responsible for Rh-B decomposition. The ·$ O_{2} $− played the significant role in the photo-electro-catalytic degradation of Rh-B. Furthermore, the decarboxylation was also occurred in the photo-electro-catalytic degradation for the Rh-B in water except for the deethylation and hydroxylation in the photo-catalytic degradation. In addition, the toxicities of the intermediates were calculated using the ECOSAR program and the EPIWIN software. The results indicated that the toxicities of intermediates from photo-electro-catalytic degradation for the Rh-B were higher than photo-catalytic degradation, due to the generation of decarboxylate. Photo-electro-catalytic degradation Photo-catalytic degradation Rhodamine B Intermediate Toxicity Potential risk Liu, Haiyang aut Qu, Jiao aut Zhang, Yanan aut Ma, Ying aut Yuan, Xing aut Enthalten in Environmental science and pollution research Springer Berlin Heidelberg, 1994 25(2018), 14 vom: 07. März, Seite 13988-13999 (DE-627)171335805 (DE-600)1178791-0 (DE-576)038875101 0944-1344 nnns volume:25 year:2018 number:14 day:07 month:03 pages:13988-13999 https://doi.org/10.1007/s11356-018-1611-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-FOR SSG-OLC-DE-84 GBV_ILN_70 GBV_ILN_252 GBV_ILN_267 GBV_ILN_2018 GBV_ILN_4012 GBV_ILN_4277 AR 25 2018 14 07 03 13988-13999 |
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10.1007/s11356-018-1611-4 doi (DE-627)OLC2040515623 (DE-He213)s11356-018-1611-4-p DE-627 ger DE-627 rakwb eng 570 360 333.7 VZ 690 333.7 540 VZ BIODIV DE-30 fid Ren, Miao verfasserin aut The different paths and potential risks of photo(-electro)-catalytic degradation for rhodamine B in water by graphene/$ TiO_{2} $ membrane 2018 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag GmbH Germany, part of Springer Nature 2018 Abstract The graphene (GR)/$ TiO_{2} $ membrane was prepared by the sol-gel method and coated on the indium tin oxide (ITO) conductive glass, which showed high and stable photo(-electro)-catalytic activities to rhodamine B (Rh-B) in water. Characterization results showed that the GR was dispersed and wrapped in the needle-like $ TiO_{2} $. With GR/$ TiO_{2} $ membrane and simulated sunlight irradiation, the removal efficiency of Rh-B (10 mg $ l^{−1} $ and pH at 5.4) arrived at 87.6% within 300 min. However, the higher removal efficiency for Rh-B reached to 97.8% by the photo-electro-catalytic degradation with the applied voltage 4 v for 30 min. The ·OH that generated in the photo-catalytic degradation process were responsible for Rh-B decomposition. The ·$ O_{2} $− played the significant role in the photo-electro-catalytic degradation of Rh-B. Furthermore, the decarboxylation was also occurred in the photo-electro-catalytic degradation for the Rh-B in water except for the deethylation and hydroxylation in the photo-catalytic degradation. In addition, the toxicities of the intermediates were calculated using the ECOSAR program and the EPIWIN software. The results indicated that the toxicities of intermediates from photo-electro-catalytic degradation for the Rh-B were higher than photo-catalytic degradation, due to the generation of decarboxylate. Photo-electro-catalytic degradation Photo-catalytic degradation Rhodamine B Intermediate Toxicity Potential risk Liu, Haiyang aut Qu, Jiao aut Zhang, Yanan aut Ma, Ying aut Yuan, Xing aut Enthalten in Environmental science and pollution research Springer Berlin Heidelberg, 1994 25(2018), 14 vom: 07. März, Seite 13988-13999 (DE-627)171335805 (DE-600)1178791-0 (DE-576)038875101 0944-1344 nnns volume:25 year:2018 number:14 day:07 month:03 pages:13988-13999 https://doi.org/10.1007/s11356-018-1611-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-FOR SSG-OLC-DE-84 GBV_ILN_70 GBV_ILN_252 GBV_ILN_267 GBV_ILN_2018 GBV_ILN_4012 GBV_ILN_4277 AR 25 2018 14 07 03 13988-13999 |
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10.1007/s11356-018-1611-4 doi (DE-627)OLC2040515623 (DE-He213)s11356-018-1611-4-p DE-627 ger DE-627 rakwb eng 570 360 333.7 VZ 690 333.7 540 VZ BIODIV DE-30 fid Ren, Miao verfasserin aut The different paths and potential risks of photo(-electro)-catalytic degradation for rhodamine B in water by graphene/$ TiO_{2} $ membrane 2018 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag GmbH Germany, part of Springer Nature 2018 Abstract The graphene (GR)/$ TiO_{2} $ membrane was prepared by the sol-gel method and coated on the indium tin oxide (ITO) conductive glass, which showed high and stable photo(-electro)-catalytic activities to rhodamine B (Rh-B) in water. Characterization results showed that the GR was dispersed and wrapped in the needle-like $ TiO_{2} $. With GR/$ TiO_{2} $ membrane and simulated sunlight irradiation, the removal efficiency of Rh-B (10 mg $ l^{−1} $ and pH at 5.4) arrived at 87.6% within 300 min. However, the higher removal efficiency for Rh-B reached to 97.8% by the photo-electro-catalytic degradation with the applied voltage 4 v for 30 min. The ·OH that generated in the photo-catalytic degradation process were responsible for Rh-B decomposition. The ·$ O_{2} $− played the significant role in the photo-electro-catalytic degradation of Rh-B. Furthermore, the decarboxylation was also occurred in the photo-electro-catalytic degradation for the Rh-B in water except for the deethylation and hydroxylation in the photo-catalytic degradation. In addition, the toxicities of the intermediates were calculated using the ECOSAR program and the EPIWIN software. The results indicated that the toxicities of intermediates from photo-electro-catalytic degradation for the Rh-B were higher than photo-catalytic degradation, due to the generation of decarboxylate. Photo-electro-catalytic degradation Photo-catalytic degradation Rhodamine B Intermediate Toxicity Potential risk Liu, Haiyang aut Qu, Jiao aut Zhang, Yanan aut Ma, Ying aut Yuan, Xing aut Enthalten in Environmental science and pollution research Springer Berlin Heidelberg, 1994 25(2018), 14 vom: 07. März, Seite 13988-13999 (DE-627)171335805 (DE-600)1178791-0 (DE-576)038875101 0944-1344 nnns volume:25 year:2018 number:14 day:07 month:03 pages:13988-13999 https://doi.org/10.1007/s11356-018-1611-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-FOR SSG-OLC-DE-84 GBV_ILN_70 GBV_ILN_252 GBV_ILN_267 GBV_ILN_2018 GBV_ILN_4012 GBV_ILN_4277 AR 25 2018 14 07 03 13988-13999 |
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10.1007/s11356-018-1611-4 doi (DE-627)OLC2040515623 (DE-He213)s11356-018-1611-4-p DE-627 ger DE-627 rakwb eng 570 360 333.7 VZ 690 333.7 540 VZ BIODIV DE-30 fid Ren, Miao verfasserin aut The different paths and potential risks of photo(-electro)-catalytic degradation for rhodamine B in water by graphene/$ TiO_{2} $ membrane 2018 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag GmbH Germany, part of Springer Nature 2018 Abstract The graphene (GR)/$ TiO_{2} $ membrane was prepared by the sol-gel method and coated on the indium tin oxide (ITO) conductive glass, which showed high and stable photo(-electro)-catalytic activities to rhodamine B (Rh-B) in water. Characterization results showed that the GR was dispersed and wrapped in the needle-like $ TiO_{2} $. With GR/$ TiO_{2} $ membrane and simulated sunlight irradiation, the removal efficiency of Rh-B (10 mg $ l^{−1} $ and pH at 5.4) arrived at 87.6% within 300 min. However, the higher removal efficiency for Rh-B reached to 97.8% by the photo-electro-catalytic degradation with the applied voltage 4 v for 30 min. The ·OH that generated in the photo-catalytic degradation process were responsible for Rh-B decomposition. The ·$ O_{2} $− played the significant role in the photo-electro-catalytic degradation of Rh-B. Furthermore, the decarboxylation was also occurred in the photo-electro-catalytic degradation for the Rh-B in water except for the deethylation and hydroxylation in the photo-catalytic degradation. In addition, the toxicities of the intermediates were calculated using the ECOSAR program and the EPIWIN software. The results indicated that the toxicities of intermediates from photo-electro-catalytic degradation for the Rh-B were higher than photo-catalytic degradation, due to the generation of decarboxylate. Photo-electro-catalytic degradation Photo-catalytic degradation Rhodamine B Intermediate Toxicity Potential risk Liu, Haiyang aut Qu, Jiao aut Zhang, Yanan aut Ma, Ying aut Yuan, Xing aut Enthalten in Environmental science and pollution research Springer Berlin Heidelberg, 1994 25(2018), 14 vom: 07. März, Seite 13988-13999 (DE-627)171335805 (DE-600)1178791-0 (DE-576)038875101 0944-1344 nnns volume:25 year:2018 number:14 day:07 month:03 pages:13988-13999 https://doi.org/10.1007/s11356-018-1611-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-FOR SSG-OLC-DE-84 GBV_ILN_70 GBV_ILN_252 GBV_ILN_267 GBV_ILN_2018 GBV_ILN_4012 GBV_ILN_4277 AR 25 2018 14 07 03 13988-13999 |
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10.1007/s11356-018-1611-4 doi (DE-627)OLC2040515623 (DE-He213)s11356-018-1611-4-p DE-627 ger DE-627 rakwb eng 570 360 333.7 VZ 690 333.7 540 VZ BIODIV DE-30 fid Ren, Miao verfasserin aut The different paths and potential risks of photo(-electro)-catalytic degradation for rhodamine B in water by graphene/$ TiO_{2} $ membrane 2018 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag GmbH Germany, part of Springer Nature 2018 Abstract The graphene (GR)/$ TiO_{2} $ membrane was prepared by the sol-gel method and coated on the indium tin oxide (ITO) conductive glass, which showed high and stable photo(-electro)-catalytic activities to rhodamine B (Rh-B) in water. Characterization results showed that the GR was dispersed and wrapped in the needle-like $ TiO_{2} $. With GR/$ TiO_{2} $ membrane and simulated sunlight irradiation, the removal efficiency of Rh-B (10 mg $ l^{−1} $ and pH at 5.4) arrived at 87.6% within 300 min. However, the higher removal efficiency for Rh-B reached to 97.8% by the photo-electro-catalytic degradation with the applied voltage 4 v for 30 min. The ·OH that generated in the photo-catalytic degradation process were responsible for Rh-B decomposition. The ·$ O_{2} $− played the significant role in the photo-electro-catalytic degradation of Rh-B. Furthermore, the decarboxylation was also occurred in the photo-electro-catalytic degradation for the Rh-B in water except for the deethylation and hydroxylation in the photo-catalytic degradation. In addition, the toxicities of the intermediates were calculated using the ECOSAR program and the EPIWIN software. The results indicated that the toxicities of intermediates from photo-electro-catalytic degradation for the Rh-B were higher than photo-catalytic degradation, due to the generation of decarboxylate. Photo-electro-catalytic degradation Photo-catalytic degradation Rhodamine B Intermediate Toxicity Potential risk Liu, Haiyang aut Qu, Jiao aut Zhang, Yanan aut Ma, Ying aut Yuan, Xing aut Enthalten in Environmental science and pollution research Springer Berlin Heidelberg, 1994 25(2018), 14 vom: 07. März, Seite 13988-13999 (DE-627)171335805 (DE-600)1178791-0 (DE-576)038875101 0944-1344 nnns volume:25 year:2018 number:14 day:07 month:03 pages:13988-13999 https://doi.org/10.1007/s11356-018-1611-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-FOR SSG-OLC-DE-84 GBV_ILN_70 GBV_ILN_252 GBV_ILN_267 GBV_ILN_2018 GBV_ILN_4012 GBV_ILN_4277 AR 25 2018 14 07 03 13988-13999 |
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Enthalten in Environmental science and pollution research 25(2018), 14 vom: 07. März, Seite 13988-13999 volume:25 year:2018 number:14 day:07 month:03 pages:13988-13999 |
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The different paths and potential risks of photo(-electro)-catalytic degradation for rhodamine B in water by graphene/$ TiO_{2} $ membrane |
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the different paths and potential risks of photo(-electro)-catalytic degradation for rhodamine b in water by graphene/$ tio_{2} $ membrane |
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The different paths and potential risks of photo(-electro)-catalytic degradation for rhodamine B in water by graphene/$ TiO_{2} $ membrane |
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Abstract The graphene (GR)/$ TiO_{2} $ membrane was prepared by the sol-gel method and coated on the indium tin oxide (ITO) conductive glass, which showed high and stable photo(-electro)-catalytic activities to rhodamine B (Rh-B) in water. Characterization results showed that the GR was dispersed and wrapped in the needle-like $ TiO_{2} $. With GR/$ TiO_{2} $ membrane and simulated sunlight irradiation, the removal efficiency of Rh-B (10 mg $ l^{−1} $ and pH at 5.4) arrived at 87.6% within 300 min. However, the higher removal efficiency for Rh-B reached to 97.8% by the photo-electro-catalytic degradation with the applied voltage 4 v for 30 min. The ·OH that generated in the photo-catalytic degradation process were responsible for Rh-B decomposition. The ·$ O_{2} $− played the significant role in the photo-electro-catalytic degradation of Rh-B. Furthermore, the decarboxylation was also occurred in the photo-electro-catalytic degradation for the Rh-B in water except for the deethylation and hydroxylation in the photo-catalytic degradation. In addition, the toxicities of the intermediates were calculated using the ECOSAR program and the EPIWIN software. The results indicated that the toxicities of intermediates from photo-electro-catalytic degradation for the Rh-B were higher than photo-catalytic degradation, due to the generation of decarboxylate. © Springer-Verlag GmbH Germany, part of Springer Nature 2018 |
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Abstract The graphene (GR)/$ TiO_{2} $ membrane was prepared by the sol-gel method and coated on the indium tin oxide (ITO) conductive glass, which showed high and stable photo(-electro)-catalytic activities to rhodamine B (Rh-B) in water. Characterization results showed that the GR was dispersed and wrapped in the needle-like $ TiO_{2} $. With GR/$ TiO_{2} $ membrane and simulated sunlight irradiation, the removal efficiency of Rh-B (10 mg $ l^{−1} $ and pH at 5.4) arrived at 87.6% within 300 min. However, the higher removal efficiency for Rh-B reached to 97.8% by the photo-electro-catalytic degradation with the applied voltage 4 v for 30 min. The ·OH that generated in the photo-catalytic degradation process were responsible for Rh-B decomposition. The ·$ O_{2} $− played the significant role in the photo-electro-catalytic degradation of Rh-B. Furthermore, the decarboxylation was also occurred in the photo-electro-catalytic degradation for the Rh-B in water except for the deethylation and hydroxylation in the photo-catalytic degradation. In addition, the toxicities of the intermediates were calculated using the ECOSAR program and the EPIWIN software. The results indicated that the toxicities of intermediates from photo-electro-catalytic degradation for the Rh-B were higher than photo-catalytic degradation, due to the generation of decarboxylate. © Springer-Verlag GmbH Germany, part of Springer Nature 2018 |
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Abstract The graphene (GR)/$ TiO_{2} $ membrane was prepared by the sol-gel method and coated on the indium tin oxide (ITO) conductive glass, which showed high and stable photo(-electro)-catalytic activities to rhodamine B (Rh-B) in water. Characterization results showed that the GR was dispersed and wrapped in the needle-like $ TiO_{2} $. With GR/$ TiO_{2} $ membrane and simulated sunlight irradiation, the removal efficiency of Rh-B (10 mg $ l^{−1} $ and pH at 5.4) arrived at 87.6% within 300 min. However, the higher removal efficiency for Rh-B reached to 97.8% by the photo-electro-catalytic degradation with the applied voltage 4 v for 30 min. The ·OH that generated in the photo-catalytic degradation process were responsible for Rh-B decomposition. The ·$ O_{2} $− played the significant role in the photo-electro-catalytic degradation of Rh-B. Furthermore, the decarboxylation was also occurred in the photo-electro-catalytic degradation for the Rh-B in water except for the deethylation and hydroxylation in the photo-catalytic degradation. In addition, the toxicities of the intermediates were calculated using the ECOSAR program and the EPIWIN software. The results indicated that the toxicities of intermediates from photo-electro-catalytic degradation for the Rh-B were higher than photo-catalytic degradation, due to the generation of decarboxylate. © Springer-Verlag GmbH Germany, part of Springer Nature 2018 |
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