Thermal expansion of nanocrystalline and coarse-crystalline silver sulfide $ Ag_{2} $S
Abstract In situ studies of the thermal expansion of polymorphic phases of coarse-crystalline and nanocrystalline silver sulfide, namely, monoclinic acanthite α-$ Ag_{2} $S and cubic argentite β-$ Ag_{2} $S, have been performed for the first time by high-temperature X-ray diffraction. The temperatur...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Gusev, A. I. [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2016 |
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| Schlagwörter: |
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| Anmerkung: |
© Pleiades Publishing, Ltd. 2016 |
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| Übergeordnetes Werk: |
Enthalten in: Physics of the solid state - Pleiades Publishing, 1993, 58(2016), 2 vom: Feb., Seite 251-257 |
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| Übergeordnetes Werk: |
volume:58 ; year:2016 ; number:2 ; month:02 ; pages:251-257 |
| Links: |
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| DOI / URN: |
10.1134/S1063783416020104 |
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OLC2040742883 |
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| 520 | |a Abstract In situ studies of the thermal expansion of polymorphic phases of coarse-crystalline and nanocrystalline silver sulfide, namely, monoclinic acanthite α-$ Ag_{2} $S and cubic argentite β-$ Ag_{2} $S, have been performed for the first time by high-temperature X-ray diffraction. The temperature dependences of the unit cell parameters of acanthite and argentite have been measured from temperatures in the range of 300–623 K, and the thermal expansion coefficients of acanthite and argentite have been determined. The observed difference between the thermal expansion coefficients of nano- and coarse-crystalline acanthite is shown to be due to a small size of nanocrystalline silver sulfide particles, which leads to an increase in the anharmonicity of atomic vibrations. | ||
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10.1134/S1063783416020104 doi (DE-627)OLC2040742883 (DE-He213)S1063783416020104-p DE-627 ger DE-627 rakwb eng 530 VZ Gusev, A. I. verfasserin aut Thermal expansion of nanocrystalline and coarse-crystalline silver sulfide $ Ag_{2} $S 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2016 Abstract In situ studies of the thermal expansion of polymorphic phases of coarse-crystalline and nanocrystalline silver sulfide, namely, monoclinic acanthite α-$ Ag_{2} $S and cubic argentite β-$ Ag_{2} $S, have been performed for the first time by high-temperature X-ray diffraction. The temperature dependences of the unit cell parameters of acanthite and argentite have been measured from temperatures in the range of 300–623 K, and the thermal expansion coefficients of acanthite and argentite have been determined. The observed difference between the thermal expansion coefficients of nano- and coarse-crystalline acanthite is shown to be due to a small size of nanocrystalline silver sulfide particles, which leads to an increase in the anharmonicity of atomic vibrations. Thermal Expansion Coefficient Unit Cell Volume Linear Thermal Expansion Coefficient Diffraction Reflection Thiocarbamide Sadovnikov, S. I. aut Chukin, A. V. aut Rempel, A. A. aut Enthalten in Physics of the solid state Pleiades Publishing, 1993 58(2016), 2 vom: Feb., Seite 251-257 (DE-627)16567332X (DE-600)1159011-7 (DE-576)038490706 1063-7834 nnns volume:58 year:2016 number:2 month:02 pages:251-257 https://doi.org/10.1134/S1063783416020104 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY GBV_ILN_70 AR 58 2016 2 02 251-257 |
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10.1134/S1063783416020104 doi (DE-627)OLC2040742883 (DE-He213)S1063783416020104-p DE-627 ger DE-627 rakwb eng 530 VZ Gusev, A. I. verfasserin aut Thermal expansion of nanocrystalline and coarse-crystalline silver sulfide $ Ag_{2} $S 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2016 Abstract In situ studies of the thermal expansion of polymorphic phases of coarse-crystalline and nanocrystalline silver sulfide, namely, monoclinic acanthite α-$ Ag_{2} $S and cubic argentite β-$ Ag_{2} $S, have been performed for the first time by high-temperature X-ray diffraction. The temperature dependences of the unit cell parameters of acanthite and argentite have been measured from temperatures in the range of 300–623 K, and the thermal expansion coefficients of acanthite and argentite have been determined. The observed difference between the thermal expansion coefficients of nano- and coarse-crystalline acanthite is shown to be due to a small size of nanocrystalline silver sulfide particles, which leads to an increase in the anharmonicity of atomic vibrations. Thermal Expansion Coefficient Unit Cell Volume Linear Thermal Expansion Coefficient Diffraction Reflection Thiocarbamide Sadovnikov, S. I. aut Chukin, A. V. aut Rempel, A. A. aut Enthalten in Physics of the solid state Pleiades Publishing, 1993 58(2016), 2 vom: Feb., Seite 251-257 (DE-627)16567332X (DE-600)1159011-7 (DE-576)038490706 1063-7834 nnns volume:58 year:2016 number:2 month:02 pages:251-257 https://doi.org/10.1134/S1063783416020104 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY GBV_ILN_70 AR 58 2016 2 02 251-257 |
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10.1134/S1063783416020104 doi (DE-627)OLC2040742883 (DE-He213)S1063783416020104-p DE-627 ger DE-627 rakwb eng 530 VZ Gusev, A. I. verfasserin aut Thermal expansion of nanocrystalline and coarse-crystalline silver sulfide $ Ag_{2} $S 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2016 Abstract In situ studies of the thermal expansion of polymorphic phases of coarse-crystalline and nanocrystalline silver sulfide, namely, monoclinic acanthite α-$ Ag_{2} $S and cubic argentite β-$ Ag_{2} $S, have been performed for the first time by high-temperature X-ray diffraction. The temperature dependences of the unit cell parameters of acanthite and argentite have been measured from temperatures in the range of 300–623 K, and the thermal expansion coefficients of acanthite and argentite have been determined. The observed difference between the thermal expansion coefficients of nano- and coarse-crystalline acanthite is shown to be due to a small size of nanocrystalline silver sulfide particles, which leads to an increase in the anharmonicity of atomic vibrations. Thermal Expansion Coefficient Unit Cell Volume Linear Thermal Expansion Coefficient Diffraction Reflection Thiocarbamide Sadovnikov, S. I. aut Chukin, A. V. aut Rempel, A. A. aut Enthalten in Physics of the solid state Pleiades Publishing, 1993 58(2016), 2 vom: Feb., Seite 251-257 (DE-627)16567332X (DE-600)1159011-7 (DE-576)038490706 1063-7834 nnns volume:58 year:2016 number:2 month:02 pages:251-257 https://doi.org/10.1134/S1063783416020104 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY GBV_ILN_70 AR 58 2016 2 02 251-257 |
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10.1134/S1063783416020104 doi (DE-627)OLC2040742883 (DE-He213)S1063783416020104-p DE-627 ger DE-627 rakwb eng 530 VZ Gusev, A. I. verfasserin aut Thermal expansion of nanocrystalline and coarse-crystalline silver sulfide $ Ag_{2} $S 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2016 Abstract In situ studies of the thermal expansion of polymorphic phases of coarse-crystalline and nanocrystalline silver sulfide, namely, monoclinic acanthite α-$ Ag_{2} $S and cubic argentite β-$ Ag_{2} $S, have been performed for the first time by high-temperature X-ray diffraction. The temperature dependences of the unit cell parameters of acanthite and argentite have been measured from temperatures in the range of 300–623 K, and the thermal expansion coefficients of acanthite and argentite have been determined. The observed difference between the thermal expansion coefficients of nano- and coarse-crystalline acanthite is shown to be due to a small size of nanocrystalline silver sulfide particles, which leads to an increase in the anharmonicity of atomic vibrations. Thermal Expansion Coefficient Unit Cell Volume Linear Thermal Expansion Coefficient Diffraction Reflection Thiocarbamide Sadovnikov, S. I. aut Chukin, A. V. aut Rempel, A. A. aut Enthalten in Physics of the solid state Pleiades Publishing, 1993 58(2016), 2 vom: Feb., Seite 251-257 (DE-627)16567332X (DE-600)1159011-7 (DE-576)038490706 1063-7834 nnns volume:58 year:2016 number:2 month:02 pages:251-257 https://doi.org/10.1134/S1063783416020104 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY GBV_ILN_70 AR 58 2016 2 02 251-257 |
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10.1134/S1063783416020104 doi (DE-627)OLC2040742883 (DE-He213)S1063783416020104-p DE-627 ger DE-627 rakwb eng 530 VZ Gusev, A. I. verfasserin aut Thermal expansion of nanocrystalline and coarse-crystalline silver sulfide $ Ag_{2} $S 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2016 Abstract In situ studies of the thermal expansion of polymorphic phases of coarse-crystalline and nanocrystalline silver sulfide, namely, monoclinic acanthite α-$ Ag_{2} $S and cubic argentite β-$ Ag_{2} $S, have been performed for the first time by high-temperature X-ray diffraction. The temperature dependences of the unit cell parameters of acanthite and argentite have been measured from temperatures in the range of 300–623 K, and the thermal expansion coefficients of acanthite and argentite have been determined. The observed difference between the thermal expansion coefficients of nano- and coarse-crystalline acanthite is shown to be due to a small size of nanocrystalline silver sulfide particles, which leads to an increase in the anharmonicity of atomic vibrations. Thermal Expansion Coefficient Unit Cell Volume Linear Thermal Expansion Coefficient Diffraction Reflection Thiocarbamide Sadovnikov, S. I. aut Chukin, A. V. aut Rempel, A. A. aut Enthalten in Physics of the solid state Pleiades Publishing, 1993 58(2016), 2 vom: Feb., Seite 251-257 (DE-627)16567332X (DE-600)1159011-7 (DE-576)038490706 1063-7834 nnns volume:58 year:2016 number:2 month:02 pages:251-257 https://doi.org/10.1134/S1063783416020104 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY GBV_ILN_70 AR 58 2016 2 02 251-257 |
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Abstract In situ studies of the thermal expansion of polymorphic phases of coarse-crystalline and nanocrystalline silver sulfide, namely, monoclinic acanthite α-$ Ag_{2} $S and cubic argentite β-$ Ag_{2} $S, have been performed for the first time by high-temperature X-ray diffraction. The temperature dependences of the unit cell parameters of acanthite and argentite have been measured from temperatures in the range of 300–623 K, and the thermal expansion coefficients of acanthite and argentite have been determined. The observed difference between the thermal expansion coefficients of nano- and coarse-crystalline acanthite is shown to be due to a small size of nanocrystalline silver sulfide particles, which leads to an increase in the anharmonicity of atomic vibrations. © Pleiades Publishing, Ltd. 2016 |
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Abstract In situ studies of the thermal expansion of polymorphic phases of coarse-crystalline and nanocrystalline silver sulfide, namely, monoclinic acanthite α-$ Ag_{2} $S and cubic argentite β-$ Ag_{2} $S, have been performed for the first time by high-temperature X-ray diffraction. The temperature dependences of the unit cell parameters of acanthite and argentite have been measured from temperatures in the range of 300–623 K, and the thermal expansion coefficients of acanthite and argentite have been determined. The observed difference between the thermal expansion coefficients of nano- and coarse-crystalline acanthite is shown to be due to a small size of nanocrystalline silver sulfide particles, which leads to an increase in the anharmonicity of atomic vibrations. © Pleiades Publishing, Ltd. 2016 |
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Abstract In situ studies of the thermal expansion of polymorphic phases of coarse-crystalline and nanocrystalline silver sulfide, namely, monoclinic acanthite α-$ Ag_{2} $S and cubic argentite β-$ Ag_{2} $S, have been performed for the first time by high-temperature X-ray diffraction. The temperature dependences of the unit cell parameters of acanthite and argentite have been measured from temperatures in the range of 300–623 K, and the thermal expansion coefficients of acanthite and argentite have been determined. The observed difference between the thermal expansion coefficients of nano- and coarse-crystalline acanthite is shown to be due to a small size of nanocrystalline silver sulfide particles, which leads to an increase in the anharmonicity of atomic vibrations. © Pleiades Publishing, Ltd. 2016 |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">OLC2040742883</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230504111517.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">200820s2016 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1134/S1063783416020104</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC2040742883</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-He213)S1063783416020104-p</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">530</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Gusev, A. I.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Thermal expansion of nanocrystalline and coarse-crystalline silver sulfide $ Ag_{2} $S</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2016</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Pleiades Publishing, Ltd. 2016</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract In situ studies of the thermal expansion of polymorphic phases of coarse-crystalline and nanocrystalline silver sulfide, namely, monoclinic acanthite α-$ Ag_{2} $S and cubic argentite β-$ Ag_{2} $S, have been performed for the first time by high-temperature X-ray diffraction. The temperature dependences of the unit cell parameters of acanthite and argentite have been measured from temperatures in the range of 300–623 K, and the thermal expansion coefficients of acanthite and argentite have been determined. The observed difference between the thermal expansion coefficients of nano- and coarse-crystalline acanthite is shown to be due to a small size of nanocrystalline silver sulfide particles, which leads to an increase in the anharmonicity of atomic vibrations.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Thermal Expansion Coefficient</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Unit Cell Volume</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Linear Thermal Expansion Coefficient</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Diffraction Reflection</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Thiocarbamide</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Sadovnikov, S. I.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Chukin, A. V.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Rempel, A. A.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Physics of the solid state</subfield><subfield code="d">Pleiades Publishing, 1993</subfield><subfield code="g">58(2016), 2 vom: Feb., Seite 251-257</subfield><subfield code="w">(DE-627)16567332X</subfield><subfield code="w">(DE-600)1159011-7</subfield><subfield code="w">(DE-576)038490706</subfield><subfield code="x">1063-7834</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:58</subfield><subfield code="g">year:2016</subfield><subfield code="g">number:2</subfield><subfield code="g">month:02</subfield><subfield code="g">pages:251-257</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1134/S1063783416020104</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHY</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">58</subfield><subfield code="j">2016</subfield><subfield code="e">2</subfield><subfield code="c">02</subfield><subfield code="h">251-257</subfield></datafield></record></collection>
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