Enhancement of catalytic activity for selective oligomerization of ethylene by microwave treatment
Abstract It has been found that the activity of a catalyst for selective oligomerization (trimerization) of ethylene based on a chromium salt and organoaluminum compounds (OACs) can be substantially enhanced by the microwave irradiation of organoaluminum compounds directly prior to mixing them with...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Zilbershtein, T. M. [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2012 |
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| Schlagwörter: |
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| Anmerkung: |
© Pleiades Publishing, Ltd. 2012 |
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| Übergeordnetes Werk: |
Enthalten in: Petroleum chemistry - SP MAIK Nauka/Interperiodica, 1962, 52(2012), 4 vom: Juli, Seite 253-260 |
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| Übergeordnetes Werk: |
volume:52 ; year:2012 ; number:4 ; month:07 ; pages:253-260 |
| Links: |
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| DOI / URN: |
10.1134/S0965544112040123 |
|---|
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OLC2042196614 |
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| 520 | |a Abstract It has been found that the activity of a catalyst for selective oligomerization (trimerization) of ethylene based on a chromium salt and organoaluminum compounds (OACs) can be substantially enhanced by the microwave irradiation of organoaluminum compounds directly prior to mixing them with the chromium salt and a pyrrole ligand. The effects of irradiation conditions and the nature of the reagents used have been studied. The catalyst obtained according to an optimal procedure outperforms known analogs in activity. | ||
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10.1134/S0965544112040123 doi (DE-627)OLC2042196614 (DE-He213)S0965544112040123-p DE-627 ger DE-627 rakwb eng 690 VZ Zilbershtein, T. M. verfasserin aut Enhancement of catalytic activity for selective oligomerization of ethylene by microwave treatment 2012 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2012 Abstract It has been found that the activity of a catalyst for selective oligomerization (trimerization) of ethylene based on a chromium salt and organoaluminum compounds (OACs) can be substantially enhanced by the microwave irradiation of organoaluminum compounds directly prior to mixing them with the chromium salt and a pyrrole ligand. The effects of irradiation conditions and the nature of the reagents used have been studied. The catalyst obtained according to an optimal procedure outperforms known analogs in activity. Microwave Irradiation Petroleum Chemistry Microwave Treatment DEAC Organoaluminum Compound Nosikov, A. A. aut Kochnev, A. I. aut Lipskikh, M. V. aut Golovko, A. K. aut Enthalten in Petroleum chemistry SP MAIK Nauka/Interperiodica, 1962 52(2012), 4 vom: Juli, Seite 253-260 (DE-627)129598399 (DE-600)241025-4 (DE-576)015091651 0965-5441 nnns volume:52 year:2012 number:4 month:07 pages:253-260 https://doi.org/10.1134/S0965544112040123 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 52 2012 4 07 253-260 |
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10.1134/S0965544112040123 doi (DE-627)OLC2042196614 (DE-He213)S0965544112040123-p DE-627 ger DE-627 rakwb eng 690 VZ Zilbershtein, T. M. verfasserin aut Enhancement of catalytic activity for selective oligomerization of ethylene by microwave treatment 2012 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2012 Abstract It has been found that the activity of a catalyst for selective oligomerization (trimerization) of ethylene based on a chromium salt and organoaluminum compounds (OACs) can be substantially enhanced by the microwave irradiation of organoaluminum compounds directly prior to mixing them with the chromium salt and a pyrrole ligand. The effects of irradiation conditions and the nature of the reagents used have been studied. The catalyst obtained according to an optimal procedure outperforms known analogs in activity. Microwave Irradiation Petroleum Chemistry Microwave Treatment DEAC Organoaluminum Compound Nosikov, A. A. aut Kochnev, A. I. aut Lipskikh, M. V. aut Golovko, A. K. aut Enthalten in Petroleum chemistry SP MAIK Nauka/Interperiodica, 1962 52(2012), 4 vom: Juli, Seite 253-260 (DE-627)129598399 (DE-600)241025-4 (DE-576)015091651 0965-5441 nnns volume:52 year:2012 number:4 month:07 pages:253-260 https://doi.org/10.1134/S0965544112040123 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 52 2012 4 07 253-260 |
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10.1134/S0965544112040123 doi (DE-627)OLC2042196614 (DE-He213)S0965544112040123-p DE-627 ger DE-627 rakwb eng 690 VZ Zilbershtein, T. M. verfasserin aut Enhancement of catalytic activity for selective oligomerization of ethylene by microwave treatment 2012 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2012 Abstract It has been found that the activity of a catalyst for selective oligomerization (trimerization) of ethylene based on a chromium salt and organoaluminum compounds (OACs) can be substantially enhanced by the microwave irradiation of organoaluminum compounds directly prior to mixing them with the chromium salt and a pyrrole ligand. The effects of irradiation conditions and the nature of the reagents used have been studied. The catalyst obtained according to an optimal procedure outperforms known analogs in activity. Microwave Irradiation Petroleum Chemistry Microwave Treatment DEAC Organoaluminum Compound Nosikov, A. A. aut Kochnev, A. I. aut Lipskikh, M. V. aut Golovko, A. K. aut Enthalten in Petroleum chemistry SP MAIK Nauka/Interperiodica, 1962 52(2012), 4 vom: Juli, Seite 253-260 (DE-627)129598399 (DE-600)241025-4 (DE-576)015091651 0965-5441 nnns volume:52 year:2012 number:4 month:07 pages:253-260 https://doi.org/10.1134/S0965544112040123 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 52 2012 4 07 253-260 |
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10.1134/S0965544112040123 doi (DE-627)OLC2042196614 (DE-He213)S0965544112040123-p DE-627 ger DE-627 rakwb eng 690 VZ Zilbershtein, T. M. verfasserin aut Enhancement of catalytic activity for selective oligomerization of ethylene by microwave treatment 2012 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2012 Abstract It has been found that the activity of a catalyst for selective oligomerization (trimerization) of ethylene based on a chromium salt and organoaluminum compounds (OACs) can be substantially enhanced by the microwave irradiation of organoaluminum compounds directly prior to mixing them with the chromium salt and a pyrrole ligand. The effects of irradiation conditions and the nature of the reagents used have been studied. The catalyst obtained according to an optimal procedure outperforms known analogs in activity. Microwave Irradiation Petroleum Chemistry Microwave Treatment DEAC Organoaluminum Compound Nosikov, A. A. aut Kochnev, A. I. aut Lipskikh, M. V. aut Golovko, A. K. aut Enthalten in Petroleum chemistry SP MAIK Nauka/Interperiodica, 1962 52(2012), 4 vom: Juli, Seite 253-260 (DE-627)129598399 (DE-600)241025-4 (DE-576)015091651 0965-5441 nnns volume:52 year:2012 number:4 month:07 pages:253-260 https://doi.org/10.1134/S0965544112040123 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 52 2012 4 07 253-260 |
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Abstract It has been found that the activity of a catalyst for selective oligomerization (trimerization) of ethylene based on a chromium salt and organoaluminum compounds (OACs) can be substantially enhanced by the microwave irradiation of organoaluminum compounds directly prior to mixing them with the chromium salt and a pyrrole ligand. The effects of irradiation conditions and the nature of the reagents used have been studied. The catalyst obtained according to an optimal procedure outperforms known analogs in activity. © Pleiades Publishing, Ltd. 2012 |
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Abstract It has been found that the activity of a catalyst for selective oligomerization (trimerization) of ethylene based on a chromium salt and organoaluminum compounds (OACs) can be substantially enhanced by the microwave irradiation of organoaluminum compounds directly prior to mixing them with the chromium salt and a pyrrole ligand. The effects of irradiation conditions and the nature of the reagents used have been studied. The catalyst obtained according to an optimal procedure outperforms known analogs in activity. © Pleiades Publishing, Ltd. 2012 |
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Abstract It has been found that the activity of a catalyst for selective oligomerization (trimerization) of ethylene based on a chromium salt and organoaluminum compounds (OACs) can be substantially enhanced by the microwave irradiation of organoaluminum compounds directly prior to mixing them with the chromium salt and a pyrrole ligand. The effects of irradiation conditions and the nature of the reagents used have been studied. The catalyst obtained according to an optimal procedure outperforms known analogs in activity. © Pleiades Publishing, Ltd. 2012 |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">OLC2042196614</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230511155016.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">200819s2012 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1134/S0965544112040123</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC2042196614</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-He213)S0965544112040123-p</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">690</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Zilbershtein, T. M.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Enhancement of catalytic activity for selective oligomerization of ethylene by microwave treatment</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2012</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Pleiades Publishing, Ltd. 2012</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract It has been found that the activity of a catalyst for selective oligomerization (trimerization) of ethylene based on a chromium salt and organoaluminum compounds (OACs) can be substantially enhanced by the microwave irradiation of organoaluminum compounds directly prior to mixing them with the chromium salt and a pyrrole ligand. 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