Effect of the Natural Minerals Pyrite and Hematite on the Transformation of Domanik Rock Organic Matter in Hydrothermal Processes
Abstract The effect of the natural minerals pyrite and hematite as a catalyst on the efficiency in destruction of the organic matter of Domanik rock, rich in organic matter, at a temperature of 300°C in a steam–carbon dioxide gas environment has been studied. Compared with the original rock and a co...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Kayukova, G. P. [verfasserIn] |
|---|
| Format: |
Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
2019 |
|---|
| Anmerkung: |
© Pleiades Publishing, Ltd. 2019 |
|---|
| Übergeordnetes Werk: |
Enthalten in: Petroleum chemistry - Pleiades Publishing, 1962, 59(2019), 1 vom: Jan., Seite 24-33 |
|---|---|
| Übergeordnetes Werk: |
volume:59 ; year:2019 ; number:1 ; month:01 ; pages:24-33 |
| Links: |
|---|
| DOI / URN: |
10.1134/S0965544119010080 |
|---|
| Katalog-ID: |
OLC2042205745 |
|---|
| LEADER | 01000caa a22002652 4500 | ||
|---|---|---|---|
| 001 | OLC2042205745 | ||
| 003 | DE-627 | ||
| 005 | 20230511180922.0 | ||
| 007 | tu | ||
| 008 | 200819s2019 xx ||||| 00| ||eng c | ||
| 024 | 7 | |a 10.1134/S0965544119010080 |2 doi | |
| 035 | |a (DE-627)OLC2042205745 | ||
| 035 | |a (DE-He213)S0965544119010080-p | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
| 041 | |a eng | ||
| 082 | 0 | 4 | |a 690 |q VZ |
| 100 | 1 | |a Kayukova, G. P. |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Effect of the Natural Minerals Pyrite and Hematite on the Transformation of Domanik Rock Organic Matter in Hydrothermal Processes |
| 264 | 1 | |c 2019 | |
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a ohne Hilfsmittel zu benutzen |b n |2 rdamedia | ||
| 338 | |a Band |b nc |2 rdacarrier | ||
| 500 | |a © Pleiades Publishing, Ltd. 2019 | ||
| 520 | |a Abstract The effect of the natural minerals pyrite and hematite as a catalyst on the efficiency in destruction of the organic matter of Domanik rock, rich in organic matter, at a temperature of 300°C in a steam–carbon dioxide gas environment has been studied. Compared with the original rock and a control experiment, the presence of the natural catalysts in the reaction system leads to an increase in both the amount of mobile hydrocarbons in the rock and the yield of extracts, in which the concentration of saturated hydrocarbons is increased by factors of 12 and 16 in the experiments with pyrite and hematite, respectively, and the asphaltene content is halved. The degradation processes of high-molecular-weight resinous–asphaltenic components and insoluble kerogen lead to the formation of lower n-alkanes and the structuring of asphaltenes to increase the degree of their carbonization, followed by the formation of insoluble substances of the carbene–carboid type appearing as a new dispersed solid phase in the products. The distinctive features of the structural composition of asphaltenes and carbenes–carboids have been revealed. The close composition of the products of hydrothermal–catalytic experiments suggests that pyrite and hematite exhibit similar catalytic properties under hydrothermal conditions. | ||
| 700 | 1 | |a Mikhailova, A. N. |4 aut | |
| 700 | 1 | |a Kosachev, I. P. |4 aut | |
| 700 | 1 | |a Eskin, A. A. |4 aut | |
| 700 | 1 | |a Morozov, V. I. |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Petroleum chemistry |d Pleiades Publishing, 1962 |g 59(2019), 1 vom: Jan., Seite 24-33 |w (DE-627)129598399 |w (DE-600)241025-4 |w (DE-576)015091651 |x 0965-5441 |7 nnns |
| 773 | 1 | 8 | |g volume:59 |g year:2019 |g number:1 |g month:01 |g pages:24-33 |
| 856 | 4 | 1 | |u https://doi.org/10.1134/S0965544119010080 |z lizenzpflichtig |3 Volltext |
| 912 | |a GBV_USEFLAG_A | ||
| 912 | |a SYSFLAG_A | ||
| 912 | |a GBV_OLC | ||
| 912 | |a SSG-OLC-UMW | ||
| 912 | |a SSG-OLC-ARC | ||
| 912 | |a SSG-OLC-TEC | ||
| 912 | |a SSG-OLC-PHA | ||
| 912 | |a SSG-OLC-DE-84 | ||
| 912 | |a GBV_ILN_70 | ||
| 951 | |a AR | ||
| 952 | |d 59 |j 2019 |e 1 |c 01 |h 24-33 | ||
| author_variant |
g p k gp gpk a n m an anm i p k ip ipk a a e aa aae v i m vi vim |
|---|---|
| matchkey_str |
article:09655441:2019----::fetfhntrlieasyienhmttoternfrainfoaircogn |
| hierarchy_sort_str |
2019 |
| publishDate |
2019 |
| allfields |
10.1134/S0965544119010080 doi (DE-627)OLC2042205745 (DE-He213)S0965544119010080-p DE-627 ger DE-627 rakwb eng 690 VZ Kayukova, G. P. verfasserin aut Effect of the Natural Minerals Pyrite and Hematite on the Transformation of Domanik Rock Organic Matter in Hydrothermal Processes 2019 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2019 Abstract The effect of the natural minerals pyrite and hematite as a catalyst on the efficiency in destruction of the organic matter of Domanik rock, rich in organic matter, at a temperature of 300°C in a steam–carbon dioxide gas environment has been studied. Compared with the original rock and a control experiment, the presence of the natural catalysts in the reaction system leads to an increase in both the amount of mobile hydrocarbons in the rock and the yield of extracts, in which the concentration of saturated hydrocarbons is increased by factors of 12 and 16 in the experiments with pyrite and hematite, respectively, and the asphaltene content is halved. The degradation processes of high-molecular-weight resinous–asphaltenic components and insoluble kerogen lead to the formation of lower n-alkanes and the structuring of asphaltenes to increase the degree of their carbonization, followed by the formation of insoluble substances of the carbene–carboid type appearing as a new dispersed solid phase in the products. The distinctive features of the structural composition of asphaltenes and carbenes–carboids have been revealed. The close composition of the products of hydrothermal–catalytic experiments suggests that pyrite and hematite exhibit similar catalytic properties under hydrothermal conditions. Mikhailova, A. N. aut Kosachev, I. P. aut Eskin, A. A. aut Morozov, V. I. aut Enthalten in Petroleum chemistry Pleiades Publishing, 1962 59(2019), 1 vom: Jan., Seite 24-33 (DE-627)129598399 (DE-600)241025-4 (DE-576)015091651 0965-5441 nnns volume:59 year:2019 number:1 month:01 pages:24-33 https://doi.org/10.1134/S0965544119010080 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 59 2019 1 01 24-33 |
| spelling |
10.1134/S0965544119010080 doi (DE-627)OLC2042205745 (DE-He213)S0965544119010080-p DE-627 ger DE-627 rakwb eng 690 VZ Kayukova, G. P. verfasserin aut Effect of the Natural Minerals Pyrite and Hematite on the Transformation of Domanik Rock Organic Matter in Hydrothermal Processes 2019 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2019 Abstract The effect of the natural minerals pyrite and hematite as a catalyst on the efficiency in destruction of the organic matter of Domanik rock, rich in organic matter, at a temperature of 300°C in a steam–carbon dioxide gas environment has been studied. Compared with the original rock and a control experiment, the presence of the natural catalysts in the reaction system leads to an increase in both the amount of mobile hydrocarbons in the rock and the yield of extracts, in which the concentration of saturated hydrocarbons is increased by factors of 12 and 16 in the experiments with pyrite and hematite, respectively, and the asphaltene content is halved. The degradation processes of high-molecular-weight resinous–asphaltenic components and insoluble kerogen lead to the formation of lower n-alkanes and the structuring of asphaltenes to increase the degree of their carbonization, followed by the formation of insoluble substances of the carbene–carboid type appearing as a new dispersed solid phase in the products. The distinctive features of the structural composition of asphaltenes and carbenes–carboids have been revealed. The close composition of the products of hydrothermal–catalytic experiments suggests that pyrite and hematite exhibit similar catalytic properties under hydrothermal conditions. Mikhailova, A. N. aut Kosachev, I. P. aut Eskin, A. A. aut Morozov, V. I. aut Enthalten in Petroleum chemistry Pleiades Publishing, 1962 59(2019), 1 vom: Jan., Seite 24-33 (DE-627)129598399 (DE-600)241025-4 (DE-576)015091651 0965-5441 nnns volume:59 year:2019 number:1 month:01 pages:24-33 https://doi.org/10.1134/S0965544119010080 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 59 2019 1 01 24-33 |
| allfields_unstemmed |
10.1134/S0965544119010080 doi (DE-627)OLC2042205745 (DE-He213)S0965544119010080-p DE-627 ger DE-627 rakwb eng 690 VZ Kayukova, G. P. verfasserin aut Effect of the Natural Minerals Pyrite and Hematite on the Transformation of Domanik Rock Organic Matter in Hydrothermal Processes 2019 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2019 Abstract The effect of the natural minerals pyrite and hematite as a catalyst on the efficiency in destruction of the organic matter of Domanik rock, rich in organic matter, at a temperature of 300°C in a steam–carbon dioxide gas environment has been studied. Compared with the original rock and a control experiment, the presence of the natural catalysts in the reaction system leads to an increase in both the amount of mobile hydrocarbons in the rock and the yield of extracts, in which the concentration of saturated hydrocarbons is increased by factors of 12 and 16 in the experiments with pyrite and hematite, respectively, and the asphaltene content is halved. The degradation processes of high-molecular-weight resinous–asphaltenic components and insoluble kerogen lead to the formation of lower n-alkanes and the structuring of asphaltenes to increase the degree of their carbonization, followed by the formation of insoluble substances of the carbene–carboid type appearing as a new dispersed solid phase in the products. The distinctive features of the structural composition of asphaltenes and carbenes–carboids have been revealed. The close composition of the products of hydrothermal–catalytic experiments suggests that pyrite and hematite exhibit similar catalytic properties under hydrothermal conditions. Mikhailova, A. N. aut Kosachev, I. P. aut Eskin, A. A. aut Morozov, V. I. aut Enthalten in Petroleum chemistry Pleiades Publishing, 1962 59(2019), 1 vom: Jan., Seite 24-33 (DE-627)129598399 (DE-600)241025-4 (DE-576)015091651 0965-5441 nnns volume:59 year:2019 number:1 month:01 pages:24-33 https://doi.org/10.1134/S0965544119010080 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 59 2019 1 01 24-33 |
| allfieldsGer |
10.1134/S0965544119010080 doi (DE-627)OLC2042205745 (DE-He213)S0965544119010080-p DE-627 ger DE-627 rakwb eng 690 VZ Kayukova, G. P. verfasserin aut Effect of the Natural Minerals Pyrite and Hematite on the Transformation of Domanik Rock Organic Matter in Hydrothermal Processes 2019 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2019 Abstract The effect of the natural minerals pyrite and hematite as a catalyst on the efficiency in destruction of the organic matter of Domanik rock, rich in organic matter, at a temperature of 300°C in a steam–carbon dioxide gas environment has been studied. Compared with the original rock and a control experiment, the presence of the natural catalysts in the reaction system leads to an increase in both the amount of mobile hydrocarbons in the rock and the yield of extracts, in which the concentration of saturated hydrocarbons is increased by factors of 12 and 16 in the experiments with pyrite and hematite, respectively, and the asphaltene content is halved. The degradation processes of high-molecular-weight resinous–asphaltenic components and insoluble kerogen lead to the formation of lower n-alkanes and the structuring of asphaltenes to increase the degree of their carbonization, followed by the formation of insoluble substances of the carbene–carboid type appearing as a new dispersed solid phase in the products. The distinctive features of the structural composition of asphaltenes and carbenes–carboids have been revealed. The close composition of the products of hydrothermal–catalytic experiments suggests that pyrite and hematite exhibit similar catalytic properties under hydrothermal conditions. Mikhailova, A. N. aut Kosachev, I. P. aut Eskin, A. A. aut Morozov, V. I. aut Enthalten in Petroleum chemistry Pleiades Publishing, 1962 59(2019), 1 vom: Jan., Seite 24-33 (DE-627)129598399 (DE-600)241025-4 (DE-576)015091651 0965-5441 nnns volume:59 year:2019 number:1 month:01 pages:24-33 https://doi.org/10.1134/S0965544119010080 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 59 2019 1 01 24-33 |
| allfieldsSound |
10.1134/S0965544119010080 doi (DE-627)OLC2042205745 (DE-He213)S0965544119010080-p DE-627 ger DE-627 rakwb eng 690 VZ Kayukova, G. P. verfasserin aut Effect of the Natural Minerals Pyrite and Hematite on the Transformation of Domanik Rock Organic Matter in Hydrothermal Processes 2019 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2019 Abstract The effect of the natural minerals pyrite and hematite as a catalyst on the efficiency in destruction of the organic matter of Domanik rock, rich in organic matter, at a temperature of 300°C in a steam–carbon dioxide gas environment has been studied. Compared with the original rock and a control experiment, the presence of the natural catalysts in the reaction system leads to an increase in both the amount of mobile hydrocarbons in the rock and the yield of extracts, in which the concentration of saturated hydrocarbons is increased by factors of 12 and 16 in the experiments with pyrite and hematite, respectively, and the asphaltene content is halved. The degradation processes of high-molecular-weight resinous–asphaltenic components and insoluble kerogen lead to the formation of lower n-alkanes and the structuring of asphaltenes to increase the degree of their carbonization, followed by the formation of insoluble substances of the carbene–carboid type appearing as a new dispersed solid phase in the products. The distinctive features of the structural composition of asphaltenes and carbenes–carboids have been revealed. The close composition of the products of hydrothermal–catalytic experiments suggests that pyrite and hematite exhibit similar catalytic properties under hydrothermal conditions. Mikhailova, A. N. aut Kosachev, I. P. aut Eskin, A. A. aut Morozov, V. I. aut Enthalten in Petroleum chemistry Pleiades Publishing, 1962 59(2019), 1 vom: Jan., Seite 24-33 (DE-627)129598399 (DE-600)241025-4 (DE-576)015091651 0965-5441 nnns volume:59 year:2019 number:1 month:01 pages:24-33 https://doi.org/10.1134/S0965544119010080 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 59 2019 1 01 24-33 |
| language |
English |
| source |
Enthalten in Petroleum chemistry 59(2019), 1 vom: Jan., Seite 24-33 volume:59 year:2019 number:1 month:01 pages:24-33 |
| sourceStr |
Enthalten in Petroleum chemistry 59(2019), 1 vom: Jan., Seite 24-33 volume:59 year:2019 number:1 month:01 pages:24-33 |
| format_phy_str_mv |
Article |
| institution |
findex.gbv.de |
| dewey-raw |
690 |
| isfreeaccess_bool |
false |
| container_title |
Petroleum chemistry |
| authorswithroles_txt_mv |
Kayukova, G. P. @@aut@@ Mikhailova, A. N. @@aut@@ Kosachev, I. P. @@aut@@ Eskin, A. A. @@aut@@ Morozov, V. I. @@aut@@ |
| publishDateDaySort_date |
2019-01-01T00:00:00Z |
| hierarchy_top_id |
129598399 |
| dewey-sort |
3690 |
| id |
OLC2042205745 |
| language_de |
englisch |
| fullrecord |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">OLC2042205745</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230511180922.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">200819s2019 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1134/S0965544119010080</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC2042205745</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-He213)S0965544119010080-p</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">690</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Kayukova, G. P.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Effect of the Natural Minerals Pyrite and Hematite on the Transformation of Domanik Rock Organic Matter in Hydrothermal Processes</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2019</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Pleiades Publishing, Ltd. 2019</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract The effect of the natural minerals pyrite and hematite as a catalyst on the efficiency in destruction of the organic matter of Domanik rock, rich in organic matter, at a temperature of 300°C in a steam–carbon dioxide gas environment has been studied. Compared with the original rock and a control experiment, the presence of the natural catalysts in the reaction system leads to an increase in both the amount of mobile hydrocarbons in the rock and the yield of extracts, in which the concentration of saturated hydrocarbons is increased by factors of 12 and 16 in the experiments with pyrite and hematite, respectively, and the asphaltene content is halved. The degradation processes of high-molecular-weight resinous–asphaltenic components and insoluble kerogen lead to the formation of lower n-alkanes and the structuring of asphaltenes to increase the degree of their carbonization, followed by the formation of insoluble substances of the carbene–carboid type appearing as a new dispersed solid phase in the products. The distinctive features of the structural composition of asphaltenes and carbenes–carboids have been revealed. The close composition of the products of hydrothermal–catalytic experiments suggests that pyrite and hematite exhibit similar catalytic properties under hydrothermal conditions.</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Mikhailova, A. N.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Kosachev, I. P.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Eskin, A. A.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Morozov, V. I.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Petroleum chemistry</subfield><subfield code="d">Pleiades Publishing, 1962</subfield><subfield code="g">59(2019), 1 vom: Jan., Seite 24-33</subfield><subfield code="w">(DE-627)129598399</subfield><subfield code="w">(DE-600)241025-4</subfield><subfield code="w">(DE-576)015091651</subfield><subfield code="x">0965-5441</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:59</subfield><subfield code="g">year:2019</subfield><subfield code="g">number:1</subfield><subfield code="g">month:01</subfield><subfield code="g">pages:24-33</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1134/S0965544119010080</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-UMW</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-ARC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-DE-84</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">59</subfield><subfield code="j">2019</subfield><subfield code="e">1</subfield><subfield code="c">01</subfield><subfield code="h">24-33</subfield></datafield></record></collection>
|
| author |
Kayukova, G. P. |
| spellingShingle |
Kayukova, G. P. ddc 690 Effect of the Natural Minerals Pyrite and Hematite on the Transformation of Domanik Rock Organic Matter in Hydrothermal Processes |
| authorStr |
Kayukova, G. P. |
| ppnlink_with_tag_str_mv |
@@773@@(DE-627)129598399 |
| format |
Article |
| dewey-ones |
690 - Buildings |
| delete_txt_mv |
keep |
| author_role |
aut aut aut aut aut |
| collection |
OLC |
| remote_str |
false |
| illustrated |
Not Illustrated |
| issn |
0965-5441 |
| topic_title |
690 VZ Effect of the Natural Minerals Pyrite and Hematite on the Transformation of Domanik Rock Organic Matter in Hydrothermal Processes |
| topic |
ddc 690 |
| topic_unstemmed |
ddc 690 |
| topic_browse |
ddc 690 |
| format_facet |
Aufsätze Gedruckte Aufsätze |
| format_main_str_mv |
Text Zeitschrift/Artikel |
| carriertype_str_mv |
nc |
| hierarchy_parent_title |
Petroleum chemistry |
| hierarchy_parent_id |
129598399 |
| dewey-tens |
690 - Building & construction |
| hierarchy_top_title |
Petroleum chemistry |
| isfreeaccess_txt |
false |
| familylinks_str_mv |
(DE-627)129598399 (DE-600)241025-4 (DE-576)015091651 |
| title |
Effect of the Natural Minerals Pyrite and Hematite on the Transformation of Domanik Rock Organic Matter in Hydrothermal Processes |
| ctrlnum |
(DE-627)OLC2042205745 (DE-He213)S0965544119010080-p |
| title_full |
Effect of the Natural Minerals Pyrite and Hematite on the Transformation of Domanik Rock Organic Matter in Hydrothermal Processes |
| author_sort |
Kayukova, G. P. |
| journal |
Petroleum chemistry |
| journalStr |
Petroleum chemistry |
| lang_code |
eng |
| isOA_bool |
false |
| dewey-hundreds |
600 - Technology |
| recordtype |
marc |
| publishDateSort |
2019 |
| contenttype_str_mv |
txt |
| container_start_page |
24 |
| author_browse |
Kayukova, G. P. Mikhailova, A. N. Kosachev, I. P. Eskin, A. A. Morozov, V. I. |
| container_volume |
59 |
| class |
690 VZ |
| format_se |
Aufsätze |
| author-letter |
Kayukova, G. P. |
| doi_str_mv |
10.1134/S0965544119010080 |
| dewey-full |
690 |
| title_sort |
effect of the natural minerals pyrite and hematite on the transformation of domanik rock organic matter in hydrothermal processes |
| title_auth |
Effect of the Natural Minerals Pyrite and Hematite on the Transformation of Domanik Rock Organic Matter in Hydrothermal Processes |
| abstract |
Abstract The effect of the natural minerals pyrite and hematite as a catalyst on the efficiency in destruction of the organic matter of Domanik rock, rich in organic matter, at a temperature of 300°C in a steam–carbon dioxide gas environment has been studied. Compared with the original rock and a control experiment, the presence of the natural catalysts in the reaction system leads to an increase in both the amount of mobile hydrocarbons in the rock and the yield of extracts, in which the concentration of saturated hydrocarbons is increased by factors of 12 and 16 in the experiments with pyrite and hematite, respectively, and the asphaltene content is halved. The degradation processes of high-molecular-weight resinous–asphaltenic components and insoluble kerogen lead to the formation of lower n-alkanes and the structuring of asphaltenes to increase the degree of their carbonization, followed by the formation of insoluble substances of the carbene–carboid type appearing as a new dispersed solid phase in the products. The distinctive features of the structural composition of asphaltenes and carbenes–carboids have been revealed. The close composition of the products of hydrothermal–catalytic experiments suggests that pyrite and hematite exhibit similar catalytic properties under hydrothermal conditions. © Pleiades Publishing, Ltd. 2019 |
| abstractGer |
Abstract The effect of the natural minerals pyrite and hematite as a catalyst on the efficiency in destruction of the organic matter of Domanik rock, rich in organic matter, at a temperature of 300°C in a steam–carbon dioxide gas environment has been studied. Compared with the original rock and a control experiment, the presence of the natural catalysts in the reaction system leads to an increase in both the amount of mobile hydrocarbons in the rock and the yield of extracts, in which the concentration of saturated hydrocarbons is increased by factors of 12 and 16 in the experiments with pyrite and hematite, respectively, and the asphaltene content is halved. The degradation processes of high-molecular-weight resinous–asphaltenic components and insoluble kerogen lead to the formation of lower n-alkanes and the structuring of asphaltenes to increase the degree of their carbonization, followed by the formation of insoluble substances of the carbene–carboid type appearing as a new dispersed solid phase in the products. The distinctive features of the structural composition of asphaltenes and carbenes–carboids have been revealed. The close composition of the products of hydrothermal–catalytic experiments suggests that pyrite and hematite exhibit similar catalytic properties under hydrothermal conditions. © Pleiades Publishing, Ltd. 2019 |
| abstract_unstemmed |
Abstract The effect of the natural minerals pyrite and hematite as a catalyst on the efficiency in destruction of the organic matter of Domanik rock, rich in organic matter, at a temperature of 300°C in a steam–carbon dioxide gas environment has been studied. Compared with the original rock and a control experiment, the presence of the natural catalysts in the reaction system leads to an increase in both the amount of mobile hydrocarbons in the rock and the yield of extracts, in which the concentration of saturated hydrocarbons is increased by factors of 12 and 16 in the experiments with pyrite and hematite, respectively, and the asphaltene content is halved. The degradation processes of high-molecular-weight resinous–asphaltenic components and insoluble kerogen lead to the formation of lower n-alkanes and the structuring of asphaltenes to increase the degree of their carbonization, followed by the formation of insoluble substances of the carbene–carboid type appearing as a new dispersed solid phase in the products. The distinctive features of the structural composition of asphaltenes and carbenes–carboids have been revealed. The close composition of the products of hydrothermal–catalytic experiments suggests that pyrite and hematite exhibit similar catalytic properties under hydrothermal conditions. © Pleiades Publishing, Ltd. 2019 |
| collection_details |
GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 |
| container_issue |
1 |
| title_short |
Effect of the Natural Minerals Pyrite and Hematite on the Transformation of Domanik Rock Organic Matter in Hydrothermal Processes |
| url |
https://doi.org/10.1134/S0965544119010080 |
| remote_bool |
false |
| author2 |
Mikhailova, A. N. Kosachev, I. P. Eskin, A. A. Morozov, V. I. |
| author2Str |
Mikhailova, A. N. Kosachev, I. P. Eskin, A. A. Morozov, V. I. |
| ppnlink |
129598399 |
| mediatype_str_mv |
n |
| isOA_txt |
false |
| hochschulschrift_bool |
false |
| doi_str |
10.1134/S0965544119010080 |
| up_date |
2024-07-03T14:13:30.294Z |
| _version_ |
1803567508015284224 |
| fullrecord_marcxml |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">OLC2042205745</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230511180922.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">200819s2019 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1134/S0965544119010080</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC2042205745</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-He213)S0965544119010080-p</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">690</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Kayukova, G. P.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Effect of the Natural Minerals Pyrite and Hematite on the Transformation of Domanik Rock Organic Matter in Hydrothermal Processes</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2019</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Pleiades Publishing, Ltd. 2019</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract The effect of the natural minerals pyrite and hematite as a catalyst on the efficiency in destruction of the organic matter of Domanik rock, rich in organic matter, at a temperature of 300°C in a steam–carbon dioxide gas environment has been studied. Compared with the original rock and a control experiment, the presence of the natural catalysts in the reaction system leads to an increase in both the amount of mobile hydrocarbons in the rock and the yield of extracts, in which the concentration of saturated hydrocarbons is increased by factors of 12 and 16 in the experiments with pyrite and hematite, respectively, and the asphaltene content is halved. The degradation processes of high-molecular-weight resinous–asphaltenic components and insoluble kerogen lead to the formation of lower n-alkanes and the structuring of asphaltenes to increase the degree of their carbonization, followed by the formation of insoluble substances of the carbene–carboid type appearing as a new dispersed solid phase in the products. The distinctive features of the structural composition of asphaltenes and carbenes–carboids have been revealed. The close composition of the products of hydrothermal–catalytic experiments suggests that pyrite and hematite exhibit similar catalytic properties under hydrothermal conditions.</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Mikhailova, A. N.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Kosachev, I. P.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Eskin, A. A.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Morozov, V. I.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Petroleum chemistry</subfield><subfield code="d">Pleiades Publishing, 1962</subfield><subfield code="g">59(2019), 1 vom: Jan., Seite 24-33</subfield><subfield code="w">(DE-627)129598399</subfield><subfield code="w">(DE-600)241025-4</subfield><subfield code="w">(DE-576)015091651</subfield><subfield code="x">0965-5441</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:59</subfield><subfield code="g">year:2019</subfield><subfield code="g">number:1</subfield><subfield code="g">month:01</subfield><subfield code="g">pages:24-33</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1134/S0965544119010080</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-UMW</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-ARC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-DE-84</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">59</subfield><subfield code="j">2019</subfield><subfield code="e">1</subfield><subfield code="c">01</subfield><subfield code="h">24-33</subfield></datafield></record></collection>
|
| score |
7.400528 |