Hydrothermal Transformations of Organic Matter of Carbon-Rich Domanik Rock in Carbon Dioxide Environment at Different Temperatures
Abstract The influence of temperature on the nature of transformation of organic matter (OM) of carbon-rich rocks from Upper Devonian Semilukian–Mendymian (domanik) deposits of the Berezovskaya area of the Romashkino oilfield in hydrothermal processes has been studied. The experiments have been carr...
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Gespeichert in:
| Autor*in: |
Kayukova, G. P. [verfasserIn] |
|---|
| Format: |
Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
2020 |
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| Anmerkung: |
© Pleiades Publishing, Ltd. 2020 |
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| Übergeordnetes Werk: |
Enthalten in: Petroleum chemistry - Pleiades Publishing, 1962, 60(2020), 3 vom: März, Seite 278-290 |
|---|---|
| Übergeordnetes Werk: |
volume:60 ; year:2020 ; number:3 ; month:03 ; pages:278-290 |
| Links: |
|---|
| DOI / URN: |
10.1134/S0965544120030093 |
|---|
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OLC204220773X |
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| 520 | |a Abstract The influence of temperature on the nature of transformation of organic matter (OM) of carbon-rich rocks from Upper Devonian Semilukian–Mendymian (domanik) deposits of the Berezovskaya area of the Romashkino oilfield in hydrothermal processes has been studied. The experiments have been carried out at temperatures of 200, 250, 300, and 350°C in a $ CO_{2} $ medium in the presence of water in an amount of 30% of rock mass in the reaction system. The yield and changes in the component, structural-group, and hydrocarbon-group composition of extracts obtained from rocks before and after hydrothermal experiments have been evaluated. It has been established that at temperatures of 300 and 350°C, high-molecular-weight components and insoluble kerogen undergo degradation processes, leading to a noticeable increase in the concentration of free hydrocarbons in the rock and their more complete extraction from the rocks. By the nature of molecular-mass distribution of normal and isoprenoid alkanes, the extracts from the rocks are similar to oils of the $ A^{1} $ and $ A^{2} $ types (according to the chemical classification by A.A. Petrov) from productive formations of the Devonian and Carboniferous deposits of the Romashkino field. The treatment of the domanik rock at lower temperatures of 200 and 250°C facilitates more intensive recovery of free hydrocarbons from the rock, without significantly affecting the structure of kerogen by destructive processes. The influence of temperature on the phase transformations of asphaltenes and their paramagnetic properties, as well as on the composition of biomarker hydrocarbons associated with the genotype of original OM and lithology and maturity of possible oil producing strata, has been revealed. It has been shown that carbonate–siliceous source rocks of domanik deposits of the Romashkino field can become an additional source of petroleum hydrocarbons in the case of development using hydrothermal technologies. | ||
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10.1134/S0965544120030093 doi (DE-627)OLC204220773X (DE-He213)S0965544120030093-p DE-627 ger DE-627 rakwb eng 690 VZ Kayukova, G. P. verfasserin aut Hydrothermal Transformations of Organic Matter of Carbon-Rich Domanik Rock in Carbon Dioxide Environment at Different Temperatures 2020 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2020 Abstract The influence of temperature on the nature of transformation of organic matter (OM) of carbon-rich rocks from Upper Devonian Semilukian–Mendymian (domanik) deposits of the Berezovskaya area of the Romashkino oilfield in hydrothermal processes has been studied. The experiments have been carried out at temperatures of 200, 250, 300, and 350°C in a $ CO_{2} $ medium in the presence of water in an amount of 30% of rock mass in the reaction system. The yield and changes in the component, structural-group, and hydrocarbon-group composition of extracts obtained from rocks before and after hydrothermal experiments have been evaluated. It has been established that at temperatures of 300 and 350°C, high-molecular-weight components and insoluble kerogen undergo degradation processes, leading to a noticeable increase in the concentration of free hydrocarbons in the rock and their more complete extraction from the rocks. By the nature of molecular-mass distribution of normal and isoprenoid alkanes, the extracts from the rocks are similar to oils of the $ A^{1} $ and $ A^{2} $ types (according to the chemical classification by A.A. Petrov) from productive formations of the Devonian and Carboniferous deposits of the Romashkino field. The treatment of the domanik rock at lower temperatures of 200 and 250°C facilitates more intensive recovery of free hydrocarbons from the rock, without significantly affecting the structure of kerogen by destructive processes. The influence of temperature on the phase transformations of asphaltenes and their paramagnetic properties, as well as on the composition of biomarker hydrocarbons associated with the genotype of original OM and lithology and maturity of possible oil producing strata, has been revealed. It has been shown that carbonate–siliceous source rocks of domanik deposits of the Romashkino field can become an additional source of petroleum hydrocarbons in the case of development using hydrothermal technologies. Mikhailov, A. N. aut Kosachev, I. P. aut Morozov, V. P. aut Vakhin, A. V. aut Enthalten in Petroleum chemistry Pleiades Publishing, 1962 60(2020), 3 vom: März, Seite 278-290 (DE-627)129598399 (DE-600)241025-4 (DE-576)015091651 0965-5441 nnns volume:60 year:2020 number:3 month:03 pages:278-290 https://doi.org/10.1134/S0965544120030093 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC SSG-OLC-PHA SSG-OLC-DE-84 AR 60 2020 3 03 278-290 |
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10.1134/S0965544120030093 doi (DE-627)OLC204220773X (DE-He213)S0965544120030093-p DE-627 ger DE-627 rakwb eng 690 VZ Kayukova, G. P. verfasserin aut Hydrothermal Transformations of Organic Matter of Carbon-Rich Domanik Rock in Carbon Dioxide Environment at Different Temperatures 2020 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2020 Abstract The influence of temperature on the nature of transformation of organic matter (OM) of carbon-rich rocks from Upper Devonian Semilukian–Mendymian (domanik) deposits of the Berezovskaya area of the Romashkino oilfield in hydrothermal processes has been studied. The experiments have been carried out at temperatures of 200, 250, 300, and 350°C in a $ CO_{2} $ medium in the presence of water in an amount of 30% of rock mass in the reaction system. The yield and changes in the component, structural-group, and hydrocarbon-group composition of extracts obtained from rocks before and after hydrothermal experiments have been evaluated. It has been established that at temperatures of 300 and 350°C, high-molecular-weight components and insoluble kerogen undergo degradation processes, leading to a noticeable increase in the concentration of free hydrocarbons in the rock and their more complete extraction from the rocks. By the nature of molecular-mass distribution of normal and isoprenoid alkanes, the extracts from the rocks are similar to oils of the $ A^{1} $ and $ A^{2} $ types (according to the chemical classification by A.A. Petrov) from productive formations of the Devonian and Carboniferous deposits of the Romashkino field. The treatment of the domanik rock at lower temperatures of 200 and 250°C facilitates more intensive recovery of free hydrocarbons from the rock, without significantly affecting the structure of kerogen by destructive processes. The influence of temperature on the phase transformations of asphaltenes and their paramagnetic properties, as well as on the composition of biomarker hydrocarbons associated with the genotype of original OM and lithology and maturity of possible oil producing strata, has been revealed. It has been shown that carbonate–siliceous source rocks of domanik deposits of the Romashkino field can become an additional source of petroleum hydrocarbons in the case of development using hydrothermal technologies. Mikhailov, A. N. aut Kosachev, I. P. aut Morozov, V. P. aut Vakhin, A. V. aut Enthalten in Petroleum chemistry Pleiades Publishing, 1962 60(2020), 3 vom: März, Seite 278-290 (DE-627)129598399 (DE-600)241025-4 (DE-576)015091651 0965-5441 nnns volume:60 year:2020 number:3 month:03 pages:278-290 https://doi.org/10.1134/S0965544120030093 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC SSG-OLC-PHA SSG-OLC-DE-84 AR 60 2020 3 03 278-290 |
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10.1134/S0965544120030093 doi (DE-627)OLC204220773X (DE-He213)S0965544120030093-p DE-627 ger DE-627 rakwb eng 690 VZ Kayukova, G. P. verfasserin aut Hydrothermal Transformations of Organic Matter of Carbon-Rich Domanik Rock in Carbon Dioxide Environment at Different Temperatures 2020 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2020 Abstract The influence of temperature on the nature of transformation of organic matter (OM) of carbon-rich rocks from Upper Devonian Semilukian–Mendymian (domanik) deposits of the Berezovskaya area of the Romashkino oilfield in hydrothermal processes has been studied. The experiments have been carried out at temperatures of 200, 250, 300, and 350°C in a $ CO_{2} $ medium in the presence of water in an amount of 30% of rock mass in the reaction system. The yield and changes in the component, structural-group, and hydrocarbon-group composition of extracts obtained from rocks before and after hydrothermal experiments have been evaluated. It has been established that at temperatures of 300 and 350°C, high-molecular-weight components and insoluble kerogen undergo degradation processes, leading to a noticeable increase in the concentration of free hydrocarbons in the rock and their more complete extraction from the rocks. By the nature of molecular-mass distribution of normal and isoprenoid alkanes, the extracts from the rocks are similar to oils of the $ A^{1} $ and $ A^{2} $ types (according to the chemical classification by A.A. Petrov) from productive formations of the Devonian and Carboniferous deposits of the Romashkino field. The treatment of the domanik rock at lower temperatures of 200 and 250°C facilitates more intensive recovery of free hydrocarbons from the rock, without significantly affecting the structure of kerogen by destructive processes. The influence of temperature on the phase transformations of asphaltenes and their paramagnetic properties, as well as on the composition of biomarker hydrocarbons associated with the genotype of original OM and lithology and maturity of possible oil producing strata, has been revealed. It has been shown that carbonate–siliceous source rocks of domanik deposits of the Romashkino field can become an additional source of petroleum hydrocarbons in the case of development using hydrothermal technologies. Mikhailov, A. N. aut Kosachev, I. P. aut Morozov, V. P. aut Vakhin, A. V. aut Enthalten in Petroleum chemistry Pleiades Publishing, 1962 60(2020), 3 vom: März, Seite 278-290 (DE-627)129598399 (DE-600)241025-4 (DE-576)015091651 0965-5441 nnns volume:60 year:2020 number:3 month:03 pages:278-290 https://doi.org/10.1134/S0965544120030093 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC SSG-OLC-PHA SSG-OLC-DE-84 AR 60 2020 3 03 278-290 |
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10.1134/S0965544120030093 doi (DE-627)OLC204220773X (DE-He213)S0965544120030093-p DE-627 ger DE-627 rakwb eng 690 VZ Kayukova, G. P. verfasserin aut Hydrothermal Transformations of Organic Matter of Carbon-Rich Domanik Rock in Carbon Dioxide Environment at Different Temperatures 2020 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2020 Abstract The influence of temperature on the nature of transformation of organic matter (OM) of carbon-rich rocks from Upper Devonian Semilukian–Mendymian (domanik) deposits of the Berezovskaya area of the Romashkino oilfield in hydrothermal processes has been studied. The experiments have been carried out at temperatures of 200, 250, 300, and 350°C in a $ CO_{2} $ medium in the presence of water in an amount of 30% of rock mass in the reaction system. The yield and changes in the component, structural-group, and hydrocarbon-group composition of extracts obtained from rocks before and after hydrothermal experiments have been evaluated. It has been established that at temperatures of 300 and 350°C, high-molecular-weight components and insoluble kerogen undergo degradation processes, leading to a noticeable increase in the concentration of free hydrocarbons in the rock and their more complete extraction from the rocks. By the nature of molecular-mass distribution of normal and isoprenoid alkanes, the extracts from the rocks are similar to oils of the $ A^{1} $ and $ A^{2} $ types (according to the chemical classification by A.A. Petrov) from productive formations of the Devonian and Carboniferous deposits of the Romashkino field. The treatment of the domanik rock at lower temperatures of 200 and 250°C facilitates more intensive recovery of free hydrocarbons from the rock, without significantly affecting the structure of kerogen by destructive processes. The influence of temperature on the phase transformations of asphaltenes and their paramagnetic properties, as well as on the composition of biomarker hydrocarbons associated with the genotype of original OM and lithology and maturity of possible oil producing strata, has been revealed. It has been shown that carbonate–siliceous source rocks of domanik deposits of the Romashkino field can become an additional source of petroleum hydrocarbons in the case of development using hydrothermal technologies. Mikhailov, A. N. aut Kosachev, I. P. aut Morozov, V. P. aut Vakhin, A. V. aut Enthalten in Petroleum chemistry Pleiades Publishing, 1962 60(2020), 3 vom: März, Seite 278-290 (DE-627)129598399 (DE-600)241025-4 (DE-576)015091651 0965-5441 nnns volume:60 year:2020 number:3 month:03 pages:278-290 https://doi.org/10.1134/S0965544120030093 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC SSG-OLC-PHA SSG-OLC-DE-84 AR 60 2020 3 03 278-290 |
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10.1134/S0965544120030093 doi (DE-627)OLC204220773X (DE-He213)S0965544120030093-p DE-627 ger DE-627 rakwb eng 690 VZ Kayukova, G. P. verfasserin aut Hydrothermal Transformations of Organic Matter of Carbon-Rich Domanik Rock in Carbon Dioxide Environment at Different Temperatures 2020 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Pleiades Publishing, Ltd. 2020 Abstract The influence of temperature on the nature of transformation of organic matter (OM) of carbon-rich rocks from Upper Devonian Semilukian–Mendymian (domanik) deposits of the Berezovskaya area of the Romashkino oilfield in hydrothermal processes has been studied. The experiments have been carried out at temperatures of 200, 250, 300, and 350°C in a $ CO_{2} $ medium in the presence of water in an amount of 30% of rock mass in the reaction system. The yield and changes in the component, structural-group, and hydrocarbon-group composition of extracts obtained from rocks before and after hydrothermal experiments have been evaluated. It has been established that at temperatures of 300 and 350°C, high-molecular-weight components and insoluble kerogen undergo degradation processes, leading to a noticeable increase in the concentration of free hydrocarbons in the rock and their more complete extraction from the rocks. By the nature of molecular-mass distribution of normal and isoprenoid alkanes, the extracts from the rocks are similar to oils of the $ A^{1} $ and $ A^{2} $ types (according to the chemical classification by A.A. Petrov) from productive formations of the Devonian and Carboniferous deposits of the Romashkino field. The treatment of the domanik rock at lower temperatures of 200 and 250°C facilitates more intensive recovery of free hydrocarbons from the rock, without significantly affecting the structure of kerogen by destructive processes. The influence of temperature on the phase transformations of asphaltenes and their paramagnetic properties, as well as on the composition of biomarker hydrocarbons associated with the genotype of original OM and lithology and maturity of possible oil producing strata, has been revealed. It has been shown that carbonate–siliceous source rocks of domanik deposits of the Romashkino field can become an additional source of petroleum hydrocarbons in the case of development using hydrothermal technologies. Mikhailov, A. N. aut Kosachev, I. P. aut Morozov, V. P. aut Vakhin, A. V. aut Enthalten in Petroleum chemistry Pleiades Publishing, 1962 60(2020), 3 vom: März, Seite 278-290 (DE-627)129598399 (DE-600)241025-4 (DE-576)015091651 0965-5441 nnns volume:60 year:2020 number:3 month:03 pages:278-290 https://doi.org/10.1134/S0965544120030093 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-UMW SSG-OLC-ARC SSG-OLC-TEC SSG-OLC-PHA SSG-OLC-DE-84 AR 60 2020 3 03 278-290 |
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690 VZ Hydrothermal Transformations of Organic Matter of Carbon-Rich Domanik Rock in Carbon Dioxide Environment at Different Temperatures |
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Hydrothermal Transformations of Organic Matter of Carbon-Rich Domanik Rock in Carbon Dioxide Environment at Different Temperatures |
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Hydrothermal Transformations of Organic Matter of Carbon-Rich Domanik Rock in Carbon Dioxide Environment at Different Temperatures |
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Kayukova, G. P. |
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Petroleum chemistry |
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Kayukova, G. P. Mikhailov, A. N. Kosachev, I. P. Morozov, V. P. Vakhin, A. V. |
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Kayukova, G. P. |
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690 |
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hydrothermal transformations of organic matter of carbon-rich domanik rock in carbon dioxide environment at different temperatures |
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Hydrothermal Transformations of Organic Matter of Carbon-Rich Domanik Rock in Carbon Dioxide Environment at Different Temperatures |
| abstract |
Abstract The influence of temperature on the nature of transformation of organic matter (OM) of carbon-rich rocks from Upper Devonian Semilukian–Mendymian (domanik) deposits of the Berezovskaya area of the Romashkino oilfield in hydrothermal processes has been studied. The experiments have been carried out at temperatures of 200, 250, 300, and 350°C in a $ CO_{2} $ medium in the presence of water in an amount of 30% of rock mass in the reaction system. The yield and changes in the component, structural-group, and hydrocarbon-group composition of extracts obtained from rocks before and after hydrothermal experiments have been evaluated. It has been established that at temperatures of 300 and 350°C, high-molecular-weight components and insoluble kerogen undergo degradation processes, leading to a noticeable increase in the concentration of free hydrocarbons in the rock and their more complete extraction from the rocks. By the nature of molecular-mass distribution of normal and isoprenoid alkanes, the extracts from the rocks are similar to oils of the $ A^{1} $ and $ A^{2} $ types (according to the chemical classification by A.A. Petrov) from productive formations of the Devonian and Carboniferous deposits of the Romashkino field. The treatment of the domanik rock at lower temperatures of 200 and 250°C facilitates more intensive recovery of free hydrocarbons from the rock, without significantly affecting the structure of kerogen by destructive processes. The influence of temperature on the phase transformations of asphaltenes and their paramagnetic properties, as well as on the composition of biomarker hydrocarbons associated with the genotype of original OM and lithology and maturity of possible oil producing strata, has been revealed. It has been shown that carbonate–siliceous source rocks of domanik deposits of the Romashkino field can become an additional source of petroleum hydrocarbons in the case of development using hydrothermal technologies. © Pleiades Publishing, Ltd. 2020 |
| abstractGer |
Abstract The influence of temperature on the nature of transformation of organic matter (OM) of carbon-rich rocks from Upper Devonian Semilukian–Mendymian (domanik) deposits of the Berezovskaya area of the Romashkino oilfield in hydrothermal processes has been studied. The experiments have been carried out at temperatures of 200, 250, 300, and 350°C in a $ CO_{2} $ medium in the presence of water in an amount of 30% of rock mass in the reaction system. The yield and changes in the component, structural-group, and hydrocarbon-group composition of extracts obtained from rocks before and after hydrothermal experiments have been evaluated. It has been established that at temperatures of 300 and 350°C, high-molecular-weight components and insoluble kerogen undergo degradation processes, leading to a noticeable increase in the concentration of free hydrocarbons in the rock and their more complete extraction from the rocks. By the nature of molecular-mass distribution of normal and isoprenoid alkanes, the extracts from the rocks are similar to oils of the $ A^{1} $ and $ A^{2} $ types (according to the chemical classification by A.A. Petrov) from productive formations of the Devonian and Carboniferous deposits of the Romashkino field. The treatment of the domanik rock at lower temperatures of 200 and 250°C facilitates more intensive recovery of free hydrocarbons from the rock, without significantly affecting the structure of kerogen by destructive processes. The influence of temperature on the phase transformations of asphaltenes and their paramagnetic properties, as well as on the composition of biomarker hydrocarbons associated with the genotype of original OM and lithology and maturity of possible oil producing strata, has been revealed. It has been shown that carbonate–siliceous source rocks of domanik deposits of the Romashkino field can become an additional source of petroleum hydrocarbons in the case of development using hydrothermal technologies. © Pleiades Publishing, Ltd. 2020 |
| abstract_unstemmed |
Abstract The influence of temperature on the nature of transformation of organic matter (OM) of carbon-rich rocks from Upper Devonian Semilukian–Mendymian (domanik) deposits of the Berezovskaya area of the Romashkino oilfield in hydrothermal processes has been studied. The experiments have been carried out at temperatures of 200, 250, 300, and 350°C in a $ CO_{2} $ medium in the presence of water in an amount of 30% of rock mass in the reaction system. The yield and changes in the component, structural-group, and hydrocarbon-group composition of extracts obtained from rocks before and after hydrothermal experiments have been evaluated. It has been established that at temperatures of 300 and 350°C, high-molecular-weight components and insoluble kerogen undergo degradation processes, leading to a noticeable increase in the concentration of free hydrocarbons in the rock and their more complete extraction from the rocks. By the nature of molecular-mass distribution of normal and isoprenoid alkanes, the extracts from the rocks are similar to oils of the $ A^{1} $ and $ A^{2} $ types (according to the chemical classification by A.A. Petrov) from productive formations of the Devonian and Carboniferous deposits of the Romashkino field. The treatment of the domanik rock at lower temperatures of 200 and 250°C facilitates more intensive recovery of free hydrocarbons from the rock, without significantly affecting the structure of kerogen by destructive processes. The influence of temperature on the phase transformations of asphaltenes and their paramagnetic properties, as well as on the composition of biomarker hydrocarbons associated with the genotype of original OM and lithology and maturity of possible oil producing strata, has been revealed. It has been shown that carbonate–siliceous source rocks of domanik deposits of the Romashkino field can become an additional source of petroleum hydrocarbons in the case of development using hydrothermal technologies. © Pleiades Publishing, Ltd. 2020 |
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Hydrothermal Transformations of Organic Matter of Carbon-Rich Domanik Rock in Carbon Dioxide Environment at Different Temperatures |
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