Kinetics of isomerization and doping of poly(t-butyl-acetylene)

Summary The kinetics of doping with $ I_{2} $and isomerization of poly(t-butylacetylene) has been studied. A first-order reaction in polymer and iodine was observed during the doping process, as was found for unsubstituted polyacetylene. However, for the isomerization process, a reaction order of 0....
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Leclerc, Mario [verfasserIn] Prud'homme, Robert E.

Format:	Artikel
Sprache:	Englisch

Erschienen:	1986

Schlagwörter:	Polymer Free Radical Iodine Reaction Order Radical Mechanism

Anmerkung:	© Springer-Verlag 1986

Übergeordnetes Werk:	Enthalten in: Polymer bulletin - Springer-Verlag, 1978, 16(1986), 1 vom: Juli, Seite 7-12
Übergeordnetes Werk:	volume:16 ; year:1986 ; number:1 ; month:07 ; pages:7-12

Links:	Volltext

DOI / URN:	10.1007/BF01046602

Katalog-ID:	OLC204259217X

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520			\|a Summary The kinetics of doping with $ I_{2} $and isomerization of poly(t-butylacetylene) has been studied. A first-order reaction in polymer and iodine was observed during the doping process, as was found for unsubstituted polyacetylene. However, for the isomerization process, a reaction order of 0.5 in iodine and no simple order in poly(t-butylacetylene) were determined. These results can be explained using a free radical mechanism where the free radicals catalyze the isomerization. In contrast to unsubstituted polyacetylene, the isomerization and doping processes are not related; isomerization occurs first, within about 30 min, and it is followed by doping at much later times.
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allfields	10.1007/BF01046602 doi (DE-627)OLC204259217X (DE-He213)BF01046602-p DE-627 ger DE-627 rakwb eng 540 530 660 VZ BIODIV DE-30 fid Leclerc, Mario verfasserin aut Kinetics of isomerization and doping of poly(t-butyl-acetylene) 1986 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 1986 Summary The kinetics of doping with $ I_{2} $and isomerization of poly(t-butylacetylene) has been studied. A first-order reaction in polymer and iodine was observed during the doping process, as was found for unsubstituted polyacetylene. However, for the isomerization process, a reaction order of 0.5 in iodine and no simple order in poly(t-butylacetylene) were determined. These results can be explained using a free radical mechanism where the free radicals catalyze the isomerization. In contrast to unsubstituted polyacetylene, the isomerization and doping processes are not related; isomerization occurs first, within about 30 min, and it is followed by doping at much later times. Polymer Free Radical Iodine Reaction Order Radical Mechanism Prud'homme, Robert E. aut Enthalten in Polymer bulletin Springer-Verlag, 1978 16(1986), 1 vom: Juli, Seite 7-12 (DE-627)129092916 (DE-600)6871-8 (DE-576)01442861X 0170-0839 nnns volume:16 year:1986 number:1 month:07 pages:7-12 https://doi.org/10.1007/BF01046602 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-TEC SSG-OLC-PHY SSG-OLC-CHE GBV_ILN_22 GBV_ILN_23 GBV_ILN_40 GBV_ILN_65 GBV_ILN_70 GBV_ILN_95 GBV_ILN_2006 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4103 GBV_ILN_4315 GBV_ILN_4319 GBV_ILN_4323 AR 16 1986 1 07 7-12
spelling	10.1007/BF01046602 doi (DE-627)OLC204259217X (DE-He213)BF01046602-p DE-627 ger DE-627 rakwb eng 540 530 660 VZ BIODIV DE-30 fid Leclerc, Mario verfasserin aut Kinetics of isomerization and doping of poly(t-butyl-acetylene) 1986 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 1986 Summary The kinetics of doping with $ I_{2} $and isomerization of poly(t-butylacetylene) has been studied. A first-order reaction in polymer and iodine was observed during the doping process, as was found for unsubstituted polyacetylene. However, for the isomerization process, a reaction order of 0.5 in iodine and no simple order in poly(t-butylacetylene) were determined. These results can be explained using a free radical mechanism where the free radicals catalyze the isomerization. In contrast to unsubstituted polyacetylene, the isomerization and doping processes are not related; isomerization occurs first, within about 30 min, and it is followed by doping at much later times. Polymer Free Radical Iodine Reaction Order Radical Mechanism Prud'homme, Robert E. aut Enthalten in Polymer bulletin Springer-Verlag, 1978 16(1986), 1 vom: Juli, Seite 7-12 (DE-627)129092916 (DE-600)6871-8 (DE-576)01442861X 0170-0839 nnns volume:16 year:1986 number:1 month:07 pages:7-12 https://doi.org/10.1007/BF01046602 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-TEC SSG-OLC-PHY SSG-OLC-CHE GBV_ILN_22 GBV_ILN_23 GBV_ILN_40 GBV_ILN_65 GBV_ILN_70 GBV_ILN_95 GBV_ILN_2006 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4103 GBV_ILN_4315 GBV_ILN_4319 GBV_ILN_4323 AR 16 1986 1 07 7-12
allfields_unstemmed	10.1007/BF01046602 doi (DE-627)OLC204259217X (DE-He213)BF01046602-p DE-627 ger DE-627 rakwb eng 540 530 660 VZ BIODIV DE-30 fid Leclerc, Mario verfasserin aut Kinetics of isomerization and doping of poly(t-butyl-acetylene) 1986 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 1986 Summary The kinetics of doping with $ I_{2} $and isomerization of poly(t-butylacetylene) has been studied. A first-order reaction in polymer and iodine was observed during the doping process, as was found for unsubstituted polyacetylene. However, for the isomerization process, a reaction order of 0.5 in iodine and no simple order in poly(t-butylacetylene) were determined. These results can be explained using a free radical mechanism where the free radicals catalyze the isomerization. In contrast to unsubstituted polyacetylene, the isomerization and doping processes are not related; isomerization occurs first, within about 30 min, and it is followed by doping at much later times. Polymer Free Radical Iodine Reaction Order Radical Mechanism Prud'homme, Robert E. aut Enthalten in Polymer bulletin Springer-Verlag, 1978 16(1986), 1 vom: Juli, Seite 7-12 (DE-627)129092916 (DE-600)6871-8 (DE-576)01442861X 0170-0839 nnns volume:16 year:1986 number:1 month:07 pages:7-12 https://doi.org/10.1007/BF01046602 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-TEC SSG-OLC-PHY SSG-OLC-CHE GBV_ILN_22 GBV_ILN_23 GBV_ILN_40 GBV_ILN_65 GBV_ILN_70 GBV_ILN_95 GBV_ILN_2006 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4103 GBV_ILN_4315 GBV_ILN_4319 GBV_ILN_4323 AR 16 1986 1 07 7-12
allfieldsGer	10.1007/BF01046602 doi (DE-627)OLC204259217X (DE-He213)BF01046602-p DE-627 ger DE-627 rakwb eng 540 530 660 VZ BIODIV DE-30 fid Leclerc, Mario verfasserin aut Kinetics of isomerization and doping of poly(t-butyl-acetylene) 1986 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 1986 Summary The kinetics of doping with $ I_{2} $and isomerization of poly(t-butylacetylene) has been studied. A first-order reaction in polymer and iodine was observed during the doping process, as was found for unsubstituted polyacetylene. However, for the isomerization process, a reaction order of 0.5 in iodine and no simple order in poly(t-butylacetylene) were determined. These results can be explained using a free radical mechanism where the free radicals catalyze the isomerization. In contrast to unsubstituted polyacetylene, the isomerization and doping processes are not related; isomerization occurs first, within about 30 min, and it is followed by doping at much later times. Polymer Free Radical Iodine Reaction Order Radical Mechanism Prud'homme, Robert E. aut Enthalten in Polymer bulletin Springer-Verlag, 1978 16(1986), 1 vom: Juli, Seite 7-12 (DE-627)129092916 (DE-600)6871-8 (DE-576)01442861X 0170-0839 nnns volume:16 year:1986 number:1 month:07 pages:7-12 https://doi.org/10.1007/BF01046602 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-TEC SSG-OLC-PHY SSG-OLC-CHE GBV_ILN_22 GBV_ILN_23 GBV_ILN_40 GBV_ILN_65 GBV_ILN_70 GBV_ILN_95 GBV_ILN_2006 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4103 GBV_ILN_4315 GBV_ILN_4319 GBV_ILN_4323 AR 16 1986 1 07 7-12
allfieldsSound	10.1007/BF01046602 doi (DE-627)OLC204259217X (DE-He213)BF01046602-p DE-627 ger DE-627 rakwb eng 540 530 660 VZ BIODIV DE-30 fid Leclerc, Mario verfasserin aut Kinetics of isomerization and doping of poly(t-butyl-acetylene) 1986 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 1986 Summary The kinetics of doping with $ I_{2} $and isomerization of poly(t-butylacetylene) has been studied. A first-order reaction in polymer and iodine was observed during the doping process, as was found for unsubstituted polyacetylene. However, for the isomerization process, a reaction order of 0.5 in iodine and no simple order in poly(t-butylacetylene) were determined. These results can be explained using a free radical mechanism where the free radicals catalyze the isomerization. In contrast to unsubstituted polyacetylene, the isomerization and doping processes are not related; isomerization occurs first, within about 30 min, and it is followed by doping at much later times. Polymer Free Radical Iodine Reaction Order Radical Mechanism Prud'homme, Robert E. aut Enthalten in Polymer bulletin Springer-Verlag, 1978 16(1986), 1 vom: Juli, Seite 7-12 (DE-627)129092916 (DE-600)6871-8 (DE-576)01442861X 0170-0839 nnns volume:16 year:1986 number:1 month:07 pages:7-12 https://doi.org/10.1007/BF01046602 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-TEC SSG-OLC-PHY SSG-OLC-CHE GBV_ILN_22 GBV_ILN_23 GBV_ILN_40 GBV_ILN_65 GBV_ILN_70 GBV_ILN_95 GBV_ILN_2006 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4103 GBV_ILN_4315 GBV_ILN_4319 GBV_ILN_4323 AR 16 1986 1 07 7-12
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author	Leclerc, Mario
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title_sort	kinetics of isomerization and doping of poly(t-butyl-acetylene)
title_auth	Kinetics of isomerization and doping of poly(t-butyl-acetylene)
abstract	Summary The kinetics of doping with $ I_{2} $and isomerization of poly(t-butylacetylene) has been studied. A first-order reaction in polymer and iodine was observed during the doping process, as was found for unsubstituted polyacetylene. However, for the isomerization process, a reaction order of 0.5 in iodine and no simple order in poly(t-butylacetylene) were determined. These results can be explained using a free radical mechanism where the free radicals catalyze the isomerization. In contrast to unsubstituted polyacetylene, the isomerization and doping processes are not related; isomerization occurs first, within about 30 min, and it is followed by doping at much later times. © Springer-Verlag 1986
abstractGer	Summary The kinetics of doping with $ I_{2} $and isomerization of poly(t-butylacetylene) has been studied. A first-order reaction in polymer and iodine was observed during the doping process, as was found for unsubstituted polyacetylene. However, for the isomerization process, a reaction order of 0.5 in iodine and no simple order in poly(t-butylacetylene) were determined. These results can be explained using a free radical mechanism where the free radicals catalyze the isomerization. In contrast to unsubstituted polyacetylene, the isomerization and doping processes are not related; isomerization occurs first, within about 30 min, and it is followed by doping at much later times. © Springer-Verlag 1986
abstract_unstemmed	Summary The kinetics of doping with $ I_{2} $and isomerization of poly(t-butylacetylene) has been studied. A first-order reaction in polymer and iodine was observed during the doping process, as was found for unsubstituted polyacetylene. However, for the isomerization process, a reaction order of 0.5 in iodine and no simple order in poly(t-butylacetylene) were determined. These results can be explained using a free radical mechanism where the free radicals catalyze the isomerization. In contrast to unsubstituted polyacetylene, the isomerization and doping processes are not related; isomerization occurs first, within about 30 min, and it is followed by doping at much later times. © Springer-Verlag 1986
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title_short	Kinetics of isomerization and doping of poly(t-butyl-acetylene)
url	https://doi.org/10.1007/BF01046602
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author2	Prud'homme, Robert E.
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doi_str	10.1007/BF01046602
up_date	2024-07-03T15:53:21.515Z
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