Polymerization of 4-n-alkylstyrenes with typical Ziegler-Natta and metallocene catalysts
Summary Polymerization of 4-n-alkylstyrenes (alkyl side group; methyl, ethyl, propyl and buthyl) was carried out with the η-$ C_{5} $($ CH_{3} $)5$ TiCl_{3} $-methylaluminoxane (MAO) and $ TiCl_{3} $-triethylaluminum (TEA) catalyst systems. When the η-$ C_{5} $($ CH_{3} $)5$ TiCl_{3} $-MAO catalyst...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Nakatani, Hisayuki [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1997 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer-Verlag 1997 |
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| Übergeordnetes Werk: |
Enthalten in: Polymer bulletin - Springer-Verlag, 1978, 38(1997), 1 vom: Jan., Seite 43-48 |
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| Übergeordnetes Werk: |
volume:38 ; year:1997 ; number:1 ; month:01 ; pages:43-48 |
| Links: |
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| DOI / URN: |
10.1007/s002890050017 |
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| Katalog-ID: |
OLC2042614726 |
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| 245 | 1 | 0 | |a Polymerization of 4-n-alkylstyrenes with typical Ziegler-Natta and metallocene catalysts |
| 264 | 1 | |c 1997 | |
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| 520 | |a Summary Polymerization of 4-n-alkylstyrenes (alkyl side group; methyl, ethyl, propyl and buthyl) was carried out with the η-$ C_{5} $($ CH_{3} $)5$ TiCl_{3} $-methylaluminoxane (MAO) and $ TiCl_{3} $-triethylaluminum (TEA) catalyst systems. When the η-$ C_{5} $($ CH_{3} $)5$ TiCl_{3} $-MAO catalyst was used, the stereoregularity of resulting polymers markedly depended on the length of substituted alkyl groups, i.e., the catalyst gave highly syndriotactic poly(4-methylstryrene), but produced atactic polymers for the monomers with ethyl, propyl and buthyl substituents. On the other hand, all the poly(4-n-alkylstyrene)s obtained with the $ TiCl_{3} $-TEA catalyst were highly isotactic. As a result, a large difference was observed in the thermal properties of polymers obtained between the two catalyst systems. | ||
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| 650 | 4 | |a Hydrobromic Acid | |
| 650 | 4 | |a Metallocene Catalyst | |
| 650 | 4 | |a Substitute Alkyl Group | |
| 700 | 1 | |a Nitta, Koh-hei |4 aut | |
| 700 | 1 | |a Takata, Toshikazu |4 aut | |
| 700 | 1 | |a Soga, Kazuo |4 aut | |
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10.1007/s002890050017 doi (DE-627)OLC2042614726 (DE-He213)s002890050017-p DE-627 ger DE-627 rakwb eng 540 530 660 VZ BIODIV DE-30 fid Nakatani, Hisayuki verfasserin aut Polymerization of 4-n-alkylstyrenes with typical Ziegler-Natta and metallocene catalysts 1997 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 1997 Summary Polymerization of 4-n-alkylstyrenes (alkyl side group; methyl, ethyl, propyl and buthyl) was carried out with the η-$ C_{5} $($ CH_{3} $)5$ TiCl_{3} $-methylaluminoxane (MAO) and $ TiCl_{3} $-triethylaluminum (TEA) catalyst systems. When the η-$ C_{5} $($ CH_{3} $)5$ TiCl_{3} $-MAO catalyst was used, the stereoregularity of resulting polymers markedly depended on the length of substituted alkyl groups, i.e., the catalyst gave highly syndriotactic poly(4-methylstryrene), but produced atactic polymers for the monomers with ethyl, propyl and buthyl substituents. On the other hand, all the poly(4-n-alkylstyrene)s obtained with the $ TiCl_{3} $-TEA catalyst were highly isotactic. As a result, a large difference was observed in the thermal properties of polymers obtained between the two catalyst systems. Molecular Mass Distribution Dppp Hydrobromic Acid Metallocene Catalyst Substitute Alkyl Group Nitta, Koh-hei aut Takata, Toshikazu aut Soga, Kazuo aut Enthalten in Polymer bulletin Springer-Verlag, 1978 38(1997), 1 vom: Jan., Seite 43-48 (DE-627)129092916 (DE-600)6871-8 (DE-576)01442861X 0170-0839 nnns volume:38 year:1997 number:1 month:01 pages:43-48 https://doi.org/10.1007/s002890050017 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-TEC SSG-OLC-PHY SSG-OLC-CHE GBV_ILN_22 GBV_ILN_40 GBV_ILN_70 GBV_ILN_95 GBV_ILN_130 GBV_ILN_2006 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2411 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4277 GBV_ILN_4315 GBV_ILN_4319 GBV_ILN_4323 AR 38 1997 1 01 43-48 |
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10.1007/s002890050017 doi (DE-627)OLC2042614726 (DE-He213)s002890050017-p DE-627 ger DE-627 rakwb eng 540 530 660 VZ BIODIV DE-30 fid Nakatani, Hisayuki verfasserin aut Polymerization of 4-n-alkylstyrenes with typical Ziegler-Natta and metallocene catalysts 1997 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 1997 Summary Polymerization of 4-n-alkylstyrenes (alkyl side group; methyl, ethyl, propyl and buthyl) was carried out with the η-$ C_{5} $($ CH_{3} $)5$ TiCl_{3} $-methylaluminoxane (MAO) and $ TiCl_{3} $-triethylaluminum (TEA) catalyst systems. When the η-$ C_{5} $($ CH_{3} $)5$ TiCl_{3} $-MAO catalyst was used, the stereoregularity of resulting polymers markedly depended on the length of substituted alkyl groups, i.e., the catalyst gave highly syndriotactic poly(4-methylstryrene), but produced atactic polymers for the monomers with ethyl, propyl and buthyl substituents. On the other hand, all the poly(4-n-alkylstyrene)s obtained with the $ TiCl_{3} $-TEA catalyst were highly isotactic. As a result, a large difference was observed in the thermal properties of polymers obtained between the two catalyst systems. Molecular Mass Distribution Dppp Hydrobromic Acid Metallocene Catalyst Substitute Alkyl Group Nitta, Koh-hei aut Takata, Toshikazu aut Soga, Kazuo aut Enthalten in Polymer bulletin Springer-Verlag, 1978 38(1997), 1 vom: Jan., Seite 43-48 (DE-627)129092916 (DE-600)6871-8 (DE-576)01442861X 0170-0839 nnns volume:38 year:1997 number:1 month:01 pages:43-48 https://doi.org/10.1007/s002890050017 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-TEC SSG-OLC-PHY SSG-OLC-CHE GBV_ILN_22 GBV_ILN_40 GBV_ILN_70 GBV_ILN_95 GBV_ILN_130 GBV_ILN_2006 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2411 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4277 GBV_ILN_4315 GBV_ILN_4319 GBV_ILN_4323 AR 38 1997 1 01 43-48 |
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10.1007/s002890050017 doi (DE-627)OLC2042614726 (DE-He213)s002890050017-p DE-627 ger DE-627 rakwb eng 540 530 660 VZ BIODIV DE-30 fid Nakatani, Hisayuki verfasserin aut Polymerization of 4-n-alkylstyrenes with typical Ziegler-Natta and metallocene catalysts 1997 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 1997 Summary Polymerization of 4-n-alkylstyrenes (alkyl side group; methyl, ethyl, propyl and buthyl) was carried out with the η-$ C_{5} $($ CH_{3} $)5$ TiCl_{3} $-methylaluminoxane (MAO) and $ TiCl_{3} $-triethylaluminum (TEA) catalyst systems. When the η-$ C_{5} $($ CH_{3} $)5$ TiCl_{3} $-MAO catalyst was used, the stereoregularity of resulting polymers markedly depended on the length of substituted alkyl groups, i.e., the catalyst gave highly syndriotactic poly(4-methylstryrene), but produced atactic polymers for the monomers with ethyl, propyl and buthyl substituents. On the other hand, all the poly(4-n-alkylstyrene)s obtained with the $ TiCl_{3} $-TEA catalyst were highly isotactic. As a result, a large difference was observed in the thermal properties of polymers obtained between the two catalyst systems. Molecular Mass Distribution Dppp Hydrobromic Acid Metallocene Catalyst Substitute Alkyl Group Nitta, Koh-hei aut Takata, Toshikazu aut Soga, Kazuo aut Enthalten in Polymer bulletin Springer-Verlag, 1978 38(1997), 1 vom: Jan., Seite 43-48 (DE-627)129092916 (DE-600)6871-8 (DE-576)01442861X 0170-0839 nnns volume:38 year:1997 number:1 month:01 pages:43-48 https://doi.org/10.1007/s002890050017 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-TEC SSG-OLC-PHY SSG-OLC-CHE GBV_ILN_22 GBV_ILN_40 GBV_ILN_70 GBV_ILN_95 GBV_ILN_130 GBV_ILN_2006 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2411 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4277 GBV_ILN_4315 GBV_ILN_4319 GBV_ILN_4323 AR 38 1997 1 01 43-48 |
| allfieldsGer |
10.1007/s002890050017 doi (DE-627)OLC2042614726 (DE-He213)s002890050017-p DE-627 ger DE-627 rakwb eng 540 530 660 VZ BIODIV DE-30 fid Nakatani, Hisayuki verfasserin aut Polymerization of 4-n-alkylstyrenes with typical Ziegler-Natta and metallocene catalysts 1997 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 1997 Summary Polymerization of 4-n-alkylstyrenes (alkyl side group; methyl, ethyl, propyl and buthyl) was carried out with the η-$ C_{5} $($ CH_{3} $)5$ TiCl_{3} $-methylaluminoxane (MAO) and $ TiCl_{3} $-triethylaluminum (TEA) catalyst systems. When the η-$ C_{5} $($ CH_{3} $)5$ TiCl_{3} $-MAO catalyst was used, the stereoregularity of resulting polymers markedly depended on the length of substituted alkyl groups, i.e., the catalyst gave highly syndriotactic poly(4-methylstryrene), but produced atactic polymers for the monomers with ethyl, propyl and buthyl substituents. On the other hand, all the poly(4-n-alkylstyrene)s obtained with the $ TiCl_{3} $-TEA catalyst were highly isotactic. As a result, a large difference was observed in the thermal properties of polymers obtained between the two catalyst systems. Molecular Mass Distribution Dppp Hydrobromic Acid Metallocene Catalyst Substitute Alkyl Group Nitta, Koh-hei aut Takata, Toshikazu aut Soga, Kazuo aut Enthalten in Polymer bulletin Springer-Verlag, 1978 38(1997), 1 vom: Jan., Seite 43-48 (DE-627)129092916 (DE-600)6871-8 (DE-576)01442861X 0170-0839 nnns volume:38 year:1997 number:1 month:01 pages:43-48 https://doi.org/10.1007/s002890050017 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-TEC SSG-OLC-PHY SSG-OLC-CHE GBV_ILN_22 GBV_ILN_40 GBV_ILN_70 GBV_ILN_95 GBV_ILN_130 GBV_ILN_2006 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2411 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4277 GBV_ILN_4315 GBV_ILN_4319 GBV_ILN_4323 AR 38 1997 1 01 43-48 |
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10.1007/s002890050017 doi (DE-627)OLC2042614726 (DE-He213)s002890050017-p DE-627 ger DE-627 rakwb eng 540 530 660 VZ BIODIV DE-30 fid Nakatani, Hisayuki verfasserin aut Polymerization of 4-n-alkylstyrenes with typical Ziegler-Natta and metallocene catalysts 1997 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 1997 Summary Polymerization of 4-n-alkylstyrenes (alkyl side group; methyl, ethyl, propyl and buthyl) was carried out with the η-$ C_{5} $($ CH_{3} $)5$ TiCl_{3} $-methylaluminoxane (MAO) and $ TiCl_{3} $-triethylaluminum (TEA) catalyst systems. When the η-$ C_{5} $($ CH_{3} $)5$ TiCl_{3} $-MAO catalyst was used, the stereoregularity of resulting polymers markedly depended on the length of substituted alkyl groups, i.e., the catalyst gave highly syndriotactic poly(4-methylstryrene), but produced atactic polymers for the monomers with ethyl, propyl and buthyl substituents. On the other hand, all the poly(4-n-alkylstyrene)s obtained with the $ TiCl_{3} $-TEA catalyst were highly isotactic. As a result, a large difference was observed in the thermal properties of polymers obtained between the two catalyst systems. Molecular Mass Distribution Dppp Hydrobromic Acid Metallocene Catalyst Substitute Alkyl Group Nitta, Koh-hei aut Takata, Toshikazu aut Soga, Kazuo aut Enthalten in Polymer bulletin Springer-Verlag, 1978 38(1997), 1 vom: Jan., Seite 43-48 (DE-627)129092916 (DE-600)6871-8 (DE-576)01442861X 0170-0839 nnns volume:38 year:1997 number:1 month:01 pages:43-48 https://doi.org/10.1007/s002890050017 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-TEC SSG-OLC-PHY SSG-OLC-CHE GBV_ILN_22 GBV_ILN_40 GBV_ILN_70 GBV_ILN_95 GBV_ILN_130 GBV_ILN_2006 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2411 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4277 GBV_ILN_4315 GBV_ILN_4319 GBV_ILN_4323 AR 38 1997 1 01 43-48 |
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Enthalten in Polymer bulletin 38(1997), 1 vom: Jan., Seite 43-48 volume:38 year:1997 number:1 month:01 pages:43-48 |
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Nakatani, Hisayuki @@aut@@ Nitta, Koh-hei @@aut@@ Takata, Toshikazu @@aut@@ Soga, Kazuo @@aut@@ |
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polymerization of 4-n-alkylstyrenes with typical ziegler-natta and metallocene catalysts |
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Polymerization of 4-n-alkylstyrenes with typical Ziegler-Natta and metallocene catalysts |
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Summary Polymerization of 4-n-alkylstyrenes (alkyl side group; methyl, ethyl, propyl and buthyl) was carried out with the η-$ C_{5} $($ CH_{3} $)5$ TiCl_{3} $-methylaluminoxane (MAO) and $ TiCl_{3} $-triethylaluminum (TEA) catalyst systems. When the η-$ C_{5} $($ CH_{3} $)5$ TiCl_{3} $-MAO catalyst was used, the stereoregularity of resulting polymers markedly depended on the length of substituted alkyl groups, i.e., the catalyst gave highly syndriotactic poly(4-methylstryrene), but produced atactic polymers for the monomers with ethyl, propyl and buthyl substituents. On the other hand, all the poly(4-n-alkylstyrene)s obtained with the $ TiCl_{3} $-TEA catalyst were highly isotactic. As a result, a large difference was observed in the thermal properties of polymers obtained between the two catalyst systems. © Springer-Verlag 1997 |
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Summary Polymerization of 4-n-alkylstyrenes (alkyl side group; methyl, ethyl, propyl and buthyl) was carried out with the η-$ C_{5} $($ CH_{3} $)5$ TiCl_{3} $-methylaluminoxane (MAO) and $ TiCl_{3} $-triethylaluminum (TEA) catalyst systems. When the η-$ C_{5} $($ CH_{3} $)5$ TiCl_{3} $-MAO catalyst was used, the stereoregularity of resulting polymers markedly depended on the length of substituted alkyl groups, i.e., the catalyst gave highly syndriotactic poly(4-methylstryrene), but produced atactic polymers for the monomers with ethyl, propyl and buthyl substituents. On the other hand, all the poly(4-n-alkylstyrene)s obtained with the $ TiCl_{3} $-TEA catalyst were highly isotactic. As a result, a large difference was observed in the thermal properties of polymers obtained between the two catalyst systems. © Springer-Verlag 1997 |
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Summary Polymerization of 4-n-alkylstyrenes (alkyl side group; methyl, ethyl, propyl and buthyl) was carried out with the η-$ C_{5} $($ CH_{3} $)5$ TiCl_{3} $-methylaluminoxane (MAO) and $ TiCl_{3} $-triethylaluminum (TEA) catalyst systems. When the η-$ C_{5} $($ CH_{3} $)5$ TiCl_{3} $-MAO catalyst was used, the stereoregularity of resulting polymers markedly depended on the length of substituted alkyl groups, i.e., the catalyst gave highly syndriotactic poly(4-methylstryrene), but produced atactic polymers for the monomers with ethyl, propyl and buthyl substituents. On the other hand, all the poly(4-n-alkylstyrene)s obtained with the $ TiCl_{3} $-TEA catalyst were highly isotactic. As a result, a large difference was observed in the thermal properties of polymers obtained between the two catalyst systems. © Springer-Verlag 1997 |
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