Fuel cell performance of polymer electrolyte membrane based on hexafluorinated sulfonated poly(ether sulfone)

Abstract The potential-current fuel cell characteristics of membrane electrode assemblies (MEAs) using hexafluorinated sulfonated poly(ether sulfone) copolymer are compared to those of $ Nafion^{®} $ based MEAs in the case of proton exchange membrane fuel cell (PEMFC) and direct methanol fuel cell (...
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Autor*in:	Krishnan, N. Nambi [verfasserIn] Kim, Hyoung-Juhn Jang, Jong Hyun Cho, EunAe Lee, Sang-Yeop Lim, Tae-Hoon Hong, Seong Ahn

Format:	Artikel
Sprache:	Englisch

Erschienen:	2008

Schlagwörter:	Membrane electrode assembly Electrolyte membrane Polymer electrolyte fuel cell

Anmerkung:	© Springer-Verlag 2008

Übergeordnetes Werk:	Enthalten in: Polymer bulletin - Springer-Verlag, 1978, 62(2008), 4 vom: 24. Dez., Seite 457-468
Übergeordnetes Werk:	volume:62 ; year:2008 ; number:4 ; day:24 ; month:12 ; pages:457-468

Links:	Volltext

DOI / URN:	10.1007/s00289-008-0022-y

Katalog-ID:	OLC2042633496

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520			\|a Abstract The potential-current fuel cell characteristics of membrane electrode assemblies (MEAs) using hexafluorinated sulfonated poly(ether sulfone) copolymer are compared to those of $ Nafion^{®} $ based MEAs in the case of proton exchange membrane fuel cell (PEMFC) and direct methanol fuel cell (DMFC). The hexafluorinated copolymer with 60 mol% of monosulfonated comonomer based acid form membrane is chosen for this study due to its high proton conductivity, high thermal stability, low methanol permeability, and its insolubility in boiling water. The catalyst powder is directly coated on the membrane and the catalyst coated membrane is used to fabricate MEAs for both fuel cells. A current density of 530 mA $ cm^{−2} $ at 0.6 V is obtained at 70 °C with $ H_{2} $/air as the fuel and oxidant. The peak power density of 110 mW $ cm^{−2} $ is obtained at 80 °C under specific DMFC operating conditions. Other electrochemical characteristics such as electrochemical impedance spectroscopy, cyclic voltammetry, and linear sweep voltammetry are also studied.
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allfields	10.1007/s00289-008-0022-y doi (DE-627)OLC2042633496 (DE-He213)s00289-008-0022-y-p DE-627 ger DE-627 rakwb eng 540 530 660 VZ BIODIV DE-30 fid Krishnan, N. Nambi verfasserin aut Fuel cell performance of polymer electrolyte membrane based on hexafluorinated sulfonated poly(ether sulfone) 2008 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 2008 Abstract The potential-current fuel cell characteristics of membrane electrode assemblies (MEAs) using hexafluorinated sulfonated poly(ether sulfone) copolymer are compared to those of $ Nafion^{®} $ based MEAs in the case of proton exchange membrane fuel cell (PEMFC) and direct methanol fuel cell (DMFC). The hexafluorinated copolymer with 60 mol% of monosulfonated comonomer based acid form membrane is chosen for this study due to its high proton conductivity, high thermal stability, low methanol permeability, and its insolubility in boiling water. The catalyst powder is directly coated on the membrane and the catalyst coated membrane is used to fabricate MEAs for both fuel cells. A current density of 530 mA $ cm^{−2} $ at 0.6 V is obtained at 70 °C with $ H_{2} $/air as the fuel and oxidant. The peak power density of 110 mW $ cm^{−2} $ is obtained at 80 °C under specific DMFC operating conditions. Other electrochemical characteristics such as electrochemical impedance spectroscopy, cyclic voltammetry, and linear sweep voltammetry are also studied. Membrane electrode assembly Electrolyte membrane Polymer electrolyte fuel cell Kim, Hyoung-Juhn aut Jang, Jong Hyun aut Cho, EunAe aut Lee, Sang-Yeop aut Lim, Tae-Hoon aut Hong, Seong Ahn aut Enthalten in Polymer bulletin Springer-Verlag, 1978 62(2008), 4 vom: 24. Dez., Seite 457-468 (DE-627)129092916 (DE-600)6871-8 (DE-576)01442861X 0170-0839 nnns volume:62 year:2008 number:4 day:24 month:12 pages:457-468 https://doi.org/10.1007/s00289-008-0022-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-TEC SSG-OLC-PHY SSG-OLC-CHE GBV_ILN_40 GBV_ILN_70 GBV_ILN_285 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2018 GBV_ILN_2411 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4277 AR 62 2008 4 24 12 457-468
spelling	10.1007/s00289-008-0022-y doi (DE-627)OLC2042633496 (DE-He213)s00289-008-0022-y-p DE-627 ger DE-627 rakwb eng 540 530 660 VZ BIODIV DE-30 fid Krishnan, N. Nambi verfasserin aut Fuel cell performance of polymer electrolyte membrane based on hexafluorinated sulfonated poly(ether sulfone) 2008 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 2008 Abstract The potential-current fuel cell characteristics of membrane electrode assemblies (MEAs) using hexafluorinated sulfonated poly(ether sulfone) copolymer are compared to those of $ Nafion^{®} $ based MEAs in the case of proton exchange membrane fuel cell (PEMFC) and direct methanol fuel cell (DMFC). The hexafluorinated copolymer with 60 mol% of monosulfonated comonomer based acid form membrane is chosen for this study due to its high proton conductivity, high thermal stability, low methanol permeability, and its insolubility in boiling water. The catalyst powder is directly coated on the membrane and the catalyst coated membrane is used to fabricate MEAs for both fuel cells. A current density of 530 mA $ cm^{−2} $ at 0.6 V is obtained at 70 °C with $ H_{2} $/air as the fuel and oxidant. The peak power density of 110 mW $ cm^{−2} $ is obtained at 80 °C under specific DMFC operating conditions. Other electrochemical characteristics such as electrochemical impedance spectroscopy, cyclic voltammetry, and linear sweep voltammetry are also studied. Membrane electrode assembly Electrolyte membrane Polymer electrolyte fuel cell Kim, Hyoung-Juhn aut Jang, Jong Hyun aut Cho, EunAe aut Lee, Sang-Yeop aut Lim, Tae-Hoon aut Hong, Seong Ahn aut Enthalten in Polymer bulletin Springer-Verlag, 1978 62(2008), 4 vom: 24. Dez., Seite 457-468 (DE-627)129092916 (DE-600)6871-8 (DE-576)01442861X 0170-0839 nnns volume:62 year:2008 number:4 day:24 month:12 pages:457-468 https://doi.org/10.1007/s00289-008-0022-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-TEC SSG-OLC-PHY SSG-OLC-CHE GBV_ILN_40 GBV_ILN_70 GBV_ILN_285 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2018 GBV_ILN_2411 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4277 AR 62 2008 4 24 12 457-468
allfields_unstemmed	10.1007/s00289-008-0022-y doi (DE-627)OLC2042633496 (DE-He213)s00289-008-0022-y-p DE-627 ger DE-627 rakwb eng 540 530 660 VZ BIODIV DE-30 fid Krishnan, N. Nambi verfasserin aut Fuel cell performance of polymer electrolyte membrane based on hexafluorinated sulfonated poly(ether sulfone) 2008 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 2008 Abstract The potential-current fuel cell characteristics of membrane electrode assemblies (MEAs) using hexafluorinated sulfonated poly(ether sulfone) copolymer are compared to those of $ Nafion^{®} $ based MEAs in the case of proton exchange membrane fuel cell (PEMFC) and direct methanol fuel cell (DMFC). The hexafluorinated copolymer with 60 mol% of monosulfonated comonomer based acid form membrane is chosen for this study due to its high proton conductivity, high thermal stability, low methanol permeability, and its insolubility in boiling water. The catalyst powder is directly coated on the membrane and the catalyst coated membrane is used to fabricate MEAs for both fuel cells. A current density of 530 mA $ cm^{−2} $ at 0.6 V is obtained at 70 °C with $ H_{2} $/air as the fuel and oxidant. The peak power density of 110 mW $ cm^{−2} $ is obtained at 80 °C under specific DMFC operating conditions. Other electrochemical characteristics such as electrochemical impedance spectroscopy, cyclic voltammetry, and linear sweep voltammetry are also studied. Membrane electrode assembly Electrolyte membrane Polymer electrolyte fuel cell Kim, Hyoung-Juhn aut Jang, Jong Hyun aut Cho, EunAe aut Lee, Sang-Yeop aut Lim, Tae-Hoon aut Hong, Seong Ahn aut Enthalten in Polymer bulletin Springer-Verlag, 1978 62(2008), 4 vom: 24. Dez., Seite 457-468 (DE-627)129092916 (DE-600)6871-8 (DE-576)01442861X 0170-0839 nnns volume:62 year:2008 number:4 day:24 month:12 pages:457-468 https://doi.org/10.1007/s00289-008-0022-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-TEC SSG-OLC-PHY SSG-OLC-CHE GBV_ILN_40 GBV_ILN_70 GBV_ILN_285 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2018 GBV_ILN_2411 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4277 AR 62 2008 4 24 12 457-468
allfieldsGer	10.1007/s00289-008-0022-y doi (DE-627)OLC2042633496 (DE-He213)s00289-008-0022-y-p DE-627 ger DE-627 rakwb eng 540 530 660 VZ BIODIV DE-30 fid Krishnan, N. Nambi verfasserin aut Fuel cell performance of polymer electrolyte membrane based on hexafluorinated sulfonated poly(ether sulfone) 2008 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 2008 Abstract The potential-current fuel cell characteristics of membrane electrode assemblies (MEAs) using hexafluorinated sulfonated poly(ether sulfone) copolymer are compared to those of $ Nafion^{®} $ based MEAs in the case of proton exchange membrane fuel cell (PEMFC) and direct methanol fuel cell (DMFC). The hexafluorinated copolymer with 60 mol% of monosulfonated comonomer based acid form membrane is chosen for this study due to its high proton conductivity, high thermal stability, low methanol permeability, and its insolubility in boiling water. The catalyst powder is directly coated on the membrane and the catalyst coated membrane is used to fabricate MEAs for both fuel cells. A current density of 530 mA $ cm^{−2} $ at 0.6 V is obtained at 70 °C with $ H_{2} $/air as the fuel and oxidant. The peak power density of 110 mW $ cm^{−2} $ is obtained at 80 °C under specific DMFC operating conditions. Other electrochemical characteristics such as electrochemical impedance spectroscopy, cyclic voltammetry, and linear sweep voltammetry are also studied. Membrane electrode assembly Electrolyte membrane Polymer electrolyte fuel cell Kim, Hyoung-Juhn aut Jang, Jong Hyun aut Cho, EunAe aut Lee, Sang-Yeop aut Lim, Tae-Hoon aut Hong, Seong Ahn aut Enthalten in Polymer bulletin Springer-Verlag, 1978 62(2008), 4 vom: 24. Dez., Seite 457-468 (DE-627)129092916 (DE-600)6871-8 (DE-576)01442861X 0170-0839 nnns volume:62 year:2008 number:4 day:24 month:12 pages:457-468 https://doi.org/10.1007/s00289-008-0022-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-TEC SSG-OLC-PHY SSG-OLC-CHE GBV_ILN_40 GBV_ILN_70 GBV_ILN_285 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2018 GBV_ILN_2411 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4277 AR 62 2008 4 24 12 457-468
allfieldsSound	10.1007/s00289-008-0022-y doi (DE-627)OLC2042633496 (DE-He213)s00289-008-0022-y-p DE-627 ger DE-627 rakwb eng 540 530 660 VZ BIODIV DE-30 fid Krishnan, N. Nambi verfasserin aut Fuel cell performance of polymer electrolyte membrane based on hexafluorinated sulfonated poly(ether sulfone) 2008 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 2008 Abstract The potential-current fuel cell characteristics of membrane electrode assemblies (MEAs) using hexafluorinated sulfonated poly(ether sulfone) copolymer are compared to those of $ Nafion^{®} $ based MEAs in the case of proton exchange membrane fuel cell (PEMFC) and direct methanol fuel cell (DMFC). The hexafluorinated copolymer with 60 mol% of monosulfonated comonomer based acid form membrane is chosen for this study due to its high proton conductivity, high thermal stability, low methanol permeability, and its insolubility in boiling water. The catalyst powder is directly coated on the membrane and the catalyst coated membrane is used to fabricate MEAs for both fuel cells. A current density of 530 mA $ cm^{−2} $ at 0.6 V is obtained at 70 °C with $ H_{2} $/air as the fuel and oxidant. The peak power density of 110 mW $ cm^{−2} $ is obtained at 80 °C under specific DMFC operating conditions. Other electrochemical characteristics such as electrochemical impedance spectroscopy, cyclic voltammetry, and linear sweep voltammetry are also studied. Membrane electrode assembly Electrolyte membrane Polymer electrolyte fuel cell Kim, Hyoung-Juhn aut Jang, Jong Hyun aut Cho, EunAe aut Lee, Sang-Yeop aut Lim, Tae-Hoon aut Hong, Seong Ahn aut Enthalten in Polymer bulletin Springer-Verlag, 1978 62(2008), 4 vom: 24. Dez., Seite 457-468 (DE-627)129092916 (DE-600)6871-8 (DE-576)01442861X 0170-0839 nnns volume:62 year:2008 number:4 day:24 month:12 pages:457-468 https://doi.org/10.1007/s00289-008-0022-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-TEC SSG-OLC-PHY SSG-OLC-CHE GBV_ILN_40 GBV_ILN_70 GBV_ILN_285 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2018 GBV_ILN_2411 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4277 AR 62 2008 4 24 12 457-468
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topic_title	540 530 660 VZ BIODIV DE-30 fid Fuel cell performance of polymer electrolyte membrane based on hexafluorinated sulfonated poly(ether sulfone) Membrane electrode assembly Electrolyte membrane Polymer electrolyte fuel cell
topic	ddc 540 fid BIODIV misc Membrane electrode assembly misc Electrolyte membrane misc Polymer electrolyte fuel cell
topic_unstemmed	ddc 540 fid BIODIV misc Membrane electrode assembly misc Electrolyte membrane misc Polymer electrolyte fuel cell
topic_browse	ddc 540 fid BIODIV misc Membrane electrode assembly misc Electrolyte membrane misc Polymer electrolyte fuel cell
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title	Fuel cell performance of polymer electrolyte membrane based on hexafluorinated sulfonated poly(ether sulfone)
ctrlnum	(DE-627)OLC2042633496 (DE-He213)s00289-008-0022-y-p
title_full	Fuel cell performance of polymer electrolyte membrane based on hexafluorinated sulfonated poly(ether sulfone)
author_sort	Krishnan, N. Nambi
journal	Polymer bulletin
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author_browse	Krishnan, N. Nambi Kim, Hyoung-Juhn Jang, Jong Hyun Cho, EunAe Lee, Sang-Yeop Lim, Tae-Hoon Hong, Seong Ahn
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class	540 530 660 VZ BIODIV DE-30 fid
format_se	Aufsätze
author-letter	Krishnan, N. Nambi
doi_str_mv	10.1007/s00289-008-0022-y
dewey-full	540 530 660
title_sort	fuel cell performance of polymer electrolyte membrane based on hexafluorinated sulfonated poly(ether sulfone)
title_auth	Fuel cell performance of polymer electrolyte membrane based on hexafluorinated sulfonated poly(ether sulfone)
abstract	Abstract The potential-current fuel cell characteristics of membrane electrode assemblies (MEAs) using hexafluorinated sulfonated poly(ether sulfone) copolymer are compared to those of $ Nafion^{®} $ based MEAs in the case of proton exchange membrane fuel cell (PEMFC) and direct methanol fuel cell (DMFC). The hexafluorinated copolymer with 60 mol% of monosulfonated comonomer based acid form membrane is chosen for this study due to its high proton conductivity, high thermal stability, low methanol permeability, and its insolubility in boiling water. The catalyst powder is directly coated on the membrane and the catalyst coated membrane is used to fabricate MEAs for both fuel cells. A current density of 530 mA $ cm^{−2} $ at 0.6 V is obtained at 70 °C with $ H_{2} $/air as the fuel and oxidant. The peak power density of 110 mW $ cm^{−2} $ is obtained at 80 °C under specific DMFC operating conditions. Other electrochemical characteristics such as electrochemical impedance spectroscopy, cyclic voltammetry, and linear sweep voltammetry are also studied. © Springer-Verlag 2008
abstractGer	Abstract The potential-current fuel cell characteristics of membrane electrode assemblies (MEAs) using hexafluorinated sulfonated poly(ether sulfone) copolymer are compared to those of $ Nafion^{®} $ based MEAs in the case of proton exchange membrane fuel cell (PEMFC) and direct methanol fuel cell (DMFC). The hexafluorinated copolymer with 60 mol% of monosulfonated comonomer based acid form membrane is chosen for this study due to its high proton conductivity, high thermal stability, low methanol permeability, and its insolubility in boiling water. The catalyst powder is directly coated on the membrane and the catalyst coated membrane is used to fabricate MEAs for both fuel cells. A current density of 530 mA $ cm^{−2} $ at 0.6 V is obtained at 70 °C with $ H_{2} $/air as the fuel and oxidant. The peak power density of 110 mW $ cm^{−2} $ is obtained at 80 °C under specific DMFC operating conditions. Other electrochemical characteristics such as electrochemical impedance spectroscopy, cyclic voltammetry, and linear sweep voltammetry are also studied. © Springer-Verlag 2008
abstract_unstemmed	Abstract The potential-current fuel cell characteristics of membrane electrode assemblies (MEAs) using hexafluorinated sulfonated poly(ether sulfone) copolymer are compared to those of $ Nafion^{®} $ based MEAs in the case of proton exchange membrane fuel cell (PEMFC) and direct methanol fuel cell (DMFC). The hexafluorinated copolymer with 60 mol% of monosulfonated comonomer based acid form membrane is chosen for this study due to its high proton conductivity, high thermal stability, low methanol permeability, and its insolubility in boiling water. The catalyst powder is directly coated on the membrane and the catalyst coated membrane is used to fabricate MEAs for both fuel cells. A current density of 530 mA $ cm^{−2} $ at 0.6 V is obtained at 70 °C with $ H_{2} $/air as the fuel and oxidant. The peak power density of 110 mW $ cm^{−2} $ is obtained at 80 °C under specific DMFC operating conditions. Other electrochemical characteristics such as electrochemical impedance spectroscopy, cyclic voltammetry, and linear sweep voltammetry are also studied. © Springer-Verlag 2008
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container_issue	4
title_short	Fuel cell performance of polymer electrolyte membrane based on hexafluorinated sulfonated poly(ether sulfone)
url	https://doi.org/10.1007/s00289-008-0022-y
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author2	Kim, Hyoung-Juhn Jang, Jong Hyun Cho, EunAe Lee, Sang-Yeop Lim, Tae-Hoon Hong, Seong Ahn
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up_date	2024-07-03T16:02:59.398Z
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