The catalytic activity of CuNi-containing hydrotalcites in the transesterification of dimethyl oxalate with phenol
Abstract Under microwave irradiation, a series of hydrotalcite-like compounds (HTL) were prepared in a short time of 10 min. The thus synthesized samples were applied to the catalytic transesterification of dimethyl oxalate (DMO) with phenol, CuNi-containing hydrotalcites (CuNi-HTLR) were found to e...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Chen, Chunxia [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2008 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer Science+Business Media, LLC 2008 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of porous materials - Springer US, 1995, 16(2008), 2 vom: 10. März, Seite 233-238 |
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| Übergeordnetes Werk: |
volume:16 ; year:2008 ; number:2 ; day:10 ; month:03 ; pages:233-238 |
| Links: |
|---|
| DOI / URN: |
10.1007/s10934-008-9191-1 |
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| 520 | |a Abstract Under microwave irradiation, a series of hydrotalcite-like compounds (HTL) were prepared in a short time of 10 min. The thus synthesized samples were applied to the catalytic transesterification of dimethyl oxalate (DMO) with phenol, CuNi-containing hydrotalcites (CuNi-HTLR) were found to exhibit good catalytic properties. When the reaction was performed with phenol/DMO molar ratio of 4:1 and 1.9% CuNi-HTLR based on the total weight of reactants as catalyst, at 180 °C for 10 h, the conversion of DMO and the selectivity of MPO + DPO reached over 66% and 95%, respectively. | ||
| 650 | 4 | |a Transesterification | |
| 650 | 4 | |a CuNi-containing hydrotalcites | |
| 650 | 4 | |a Microwave irradiation | |
| 650 | 4 | |a Dimethyl oxalate | |
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| 700 | 1 | |a Qiu, Fali |4 aut | |
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10.1007/s10934-008-9191-1 doi (DE-627)OLC2043002503 (DE-He213)s10934-008-9191-1-p DE-627 ger DE-627 rakwb eng 530 VZ Chen, Chunxia verfasserin aut The catalytic activity of CuNi-containing hydrotalcites in the transesterification of dimethyl oxalate with phenol 2008 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2008 Abstract Under microwave irradiation, a series of hydrotalcite-like compounds (HTL) were prepared in a short time of 10 min. The thus synthesized samples were applied to the catalytic transesterification of dimethyl oxalate (DMO) with phenol, CuNi-containing hydrotalcites (CuNi-HTLR) were found to exhibit good catalytic properties. When the reaction was performed with phenol/DMO molar ratio of 4:1 and 1.9% CuNi-HTLR based on the total weight of reactants as catalyst, at 180 °C for 10 h, the conversion of DMO and the selectivity of MPO + DPO reached over 66% and 95%, respectively. Transesterification CuNi-containing hydrotalcites Microwave irradiation Dimethyl oxalate Phenol Peng, Jinsong aut Li, Bin aut Hu, Zhongqin aut Zhang, Hua aut Qiu, Fali aut Enthalten in Journal of porous materials Springer US, 1995 16(2008), 2 vom: 10. März, Seite 233-238 (DE-627)211471933 (DE-600)1322952-7 (DE-576)121196038 1380-2224 nnns volume:16 year:2008 number:2 day:10 month:03 pages:233-238 https://doi.org/10.1007/s10934-008-9191-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO GBV_ILN_70 AR 16 2008 2 10 03 233-238 |
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10.1007/s10934-008-9191-1 doi (DE-627)OLC2043002503 (DE-He213)s10934-008-9191-1-p DE-627 ger DE-627 rakwb eng 530 VZ Chen, Chunxia verfasserin aut The catalytic activity of CuNi-containing hydrotalcites in the transesterification of dimethyl oxalate with phenol 2008 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2008 Abstract Under microwave irradiation, a series of hydrotalcite-like compounds (HTL) were prepared in a short time of 10 min. The thus synthesized samples were applied to the catalytic transesterification of dimethyl oxalate (DMO) with phenol, CuNi-containing hydrotalcites (CuNi-HTLR) were found to exhibit good catalytic properties. When the reaction was performed with phenol/DMO molar ratio of 4:1 and 1.9% CuNi-HTLR based on the total weight of reactants as catalyst, at 180 °C for 10 h, the conversion of DMO and the selectivity of MPO + DPO reached over 66% and 95%, respectively. Transesterification CuNi-containing hydrotalcites Microwave irradiation Dimethyl oxalate Phenol Peng, Jinsong aut Li, Bin aut Hu, Zhongqin aut Zhang, Hua aut Qiu, Fali aut Enthalten in Journal of porous materials Springer US, 1995 16(2008), 2 vom: 10. März, Seite 233-238 (DE-627)211471933 (DE-600)1322952-7 (DE-576)121196038 1380-2224 nnns volume:16 year:2008 number:2 day:10 month:03 pages:233-238 https://doi.org/10.1007/s10934-008-9191-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO GBV_ILN_70 AR 16 2008 2 10 03 233-238 |
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10.1007/s10934-008-9191-1 doi (DE-627)OLC2043002503 (DE-He213)s10934-008-9191-1-p DE-627 ger DE-627 rakwb eng 530 VZ Chen, Chunxia verfasserin aut The catalytic activity of CuNi-containing hydrotalcites in the transesterification of dimethyl oxalate with phenol 2008 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2008 Abstract Under microwave irradiation, a series of hydrotalcite-like compounds (HTL) were prepared in a short time of 10 min. The thus synthesized samples were applied to the catalytic transesterification of dimethyl oxalate (DMO) with phenol, CuNi-containing hydrotalcites (CuNi-HTLR) were found to exhibit good catalytic properties. When the reaction was performed with phenol/DMO molar ratio of 4:1 and 1.9% CuNi-HTLR based on the total weight of reactants as catalyst, at 180 °C for 10 h, the conversion of DMO and the selectivity of MPO + DPO reached over 66% and 95%, respectively. Transesterification CuNi-containing hydrotalcites Microwave irradiation Dimethyl oxalate Phenol Peng, Jinsong aut Li, Bin aut Hu, Zhongqin aut Zhang, Hua aut Qiu, Fali aut Enthalten in Journal of porous materials Springer US, 1995 16(2008), 2 vom: 10. März, Seite 233-238 (DE-627)211471933 (DE-600)1322952-7 (DE-576)121196038 1380-2224 nnns volume:16 year:2008 number:2 day:10 month:03 pages:233-238 https://doi.org/10.1007/s10934-008-9191-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO GBV_ILN_70 AR 16 2008 2 10 03 233-238 |
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10.1007/s10934-008-9191-1 doi (DE-627)OLC2043002503 (DE-He213)s10934-008-9191-1-p DE-627 ger DE-627 rakwb eng 530 VZ Chen, Chunxia verfasserin aut The catalytic activity of CuNi-containing hydrotalcites in the transesterification of dimethyl oxalate with phenol 2008 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2008 Abstract Under microwave irradiation, a series of hydrotalcite-like compounds (HTL) were prepared in a short time of 10 min. The thus synthesized samples were applied to the catalytic transesterification of dimethyl oxalate (DMO) with phenol, CuNi-containing hydrotalcites (CuNi-HTLR) were found to exhibit good catalytic properties. When the reaction was performed with phenol/DMO molar ratio of 4:1 and 1.9% CuNi-HTLR based on the total weight of reactants as catalyst, at 180 °C for 10 h, the conversion of DMO and the selectivity of MPO + DPO reached over 66% and 95%, respectively. Transesterification CuNi-containing hydrotalcites Microwave irradiation Dimethyl oxalate Phenol Peng, Jinsong aut Li, Bin aut Hu, Zhongqin aut Zhang, Hua aut Qiu, Fali aut Enthalten in Journal of porous materials Springer US, 1995 16(2008), 2 vom: 10. März, Seite 233-238 (DE-627)211471933 (DE-600)1322952-7 (DE-576)121196038 1380-2224 nnns volume:16 year:2008 number:2 day:10 month:03 pages:233-238 https://doi.org/10.1007/s10934-008-9191-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO GBV_ILN_70 AR 16 2008 2 10 03 233-238 |
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10.1007/s10934-008-9191-1 doi (DE-627)OLC2043002503 (DE-He213)s10934-008-9191-1-p DE-627 ger DE-627 rakwb eng 530 VZ Chen, Chunxia verfasserin aut The catalytic activity of CuNi-containing hydrotalcites in the transesterification of dimethyl oxalate with phenol 2008 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2008 Abstract Under microwave irradiation, a series of hydrotalcite-like compounds (HTL) were prepared in a short time of 10 min. The thus synthesized samples were applied to the catalytic transesterification of dimethyl oxalate (DMO) with phenol, CuNi-containing hydrotalcites (CuNi-HTLR) were found to exhibit good catalytic properties. When the reaction was performed with phenol/DMO molar ratio of 4:1 and 1.9% CuNi-HTLR based on the total weight of reactants as catalyst, at 180 °C for 10 h, the conversion of DMO and the selectivity of MPO + DPO reached over 66% and 95%, respectively. Transesterification CuNi-containing hydrotalcites Microwave irradiation Dimethyl oxalate Phenol Peng, Jinsong aut Li, Bin aut Hu, Zhongqin aut Zhang, Hua aut Qiu, Fali aut Enthalten in Journal of porous materials Springer US, 1995 16(2008), 2 vom: 10. März, Seite 233-238 (DE-627)211471933 (DE-600)1322952-7 (DE-576)121196038 1380-2224 nnns volume:16 year:2008 number:2 day:10 month:03 pages:233-238 https://doi.org/10.1007/s10934-008-9191-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-GEO GBV_ILN_70 AR 16 2008 2 10 03 233-238 |
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Abstract Under microwave irradiation, a series of hydrotalcite-like compounds (HTL) were prepared in a short time of 10 min. The thus synthesized samples were applied to the catalytic transesterification of dimethyl oxalate (DMO) with phenol, CuNi-containing hydrotalcites (CuNi-HTLR) were found to exhibit good catalytic properties. When the reaction was performed with phenol/DMO molar ratio of 4:1 and 1.9% CuNi-HTLR based on the total weight of reactants as catalyst, at 180 °C for 10 h, the conversion of DMO and the selectivity of MPO + DPO reached over 66% and 95%, respectively. © Springer Science+Business Media, LLC 2008 |
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Abstract Under microwave irradiation, a series of hydrotalcite-like compounds (HTL) were prepared in a short time of 10 min. The thus synthesized samples were applied to the catalytic transesterification of dimethyl oxalate (DMO) with phenol, CuNi-containing hydrotalcites (CuNi-HTLR) were found to exhibit good catalytic properties. When the reaction was performed with phenol/DMO molar ratio of 4:1 and 1.9% CuNi-HTLR based on the total weight of reactants as catalyst, at 180 °C for 10 h, the conversion of DMO and the selectivity of MPO + DPO reached over 66% and 95%, respectively. © Springer Science+Business Media, LLC 2008 |
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Abstract Under microwave irradiation, a series of hydrotalcite-like compounds (HTL) were prepared in a short time of 10 min. The thus synthesized samples were applied to the catalytic transesterification of dimethyl oxalate (DMO) with phenol, CuNi-containing hydrotalcites (CuNi-HTLR) were found to exhibit good catalytic properties. When the reaction was performed with phenol/DMO molar ratio of 4:1 and 1.9% CuNi-HTLR based on the total weight of reactants as catalyst, at 180 °C for 10 h, the conversion of DMO and the selectivity of MPO + DPO reached over 66% and 95%, respectively. © Springer Science+Business Media, LLC 2008 |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">OLC2043002503</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230503150306.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">200819s2008 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10934-008-9191-1</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC2043002503</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-He213)s10934-008-9191-1-p</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">530</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Chen, Chunxia</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">The catalytic activity of CuNi-containing hydrotalcites in the transesterification of dimethyl oxalate with phenol</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2008</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Springer Science+Business Media, LLC 2008</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Under microwave irradiation, a series of hydrotalcite-like compounds (HTL) were prepared in a short time of 10 min. The thus synthesized samples were applied to the catalytic transesterification of dimethyl oxalate (DMO) with phenol, CuNi-containing hydrotalcites (CuNi-HTLR) were found to exhibit good catalytic properties. When the reaction was performed with phenol/DMO molar ratio of 4:1 and 1.9% CuNi-HTLR based on the total weight of reactants as catalyst, at 180 °C for 10 h, the conversion of DMO and the selectivity of MPO + DPO reached over 66% and 95%, respectively.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Transesterification</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">CuNi-containing hydrotalcites</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Microwave irradiation</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Dimethyl oxalate</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Phenol</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Peng, Jinsong</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Li, Bin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Hu, Zhongqin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhang, Hua</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Qiu, Fali</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of porous materials</subfield><subfield code="d">Springer US, 1995</subfield><subfield code="g">16(2008), 2 vom: 10. März, Seite 233-238</subfield><subfield code="w">(DE-627)211471933</subfield><subfield code="w">(DE-600)1322952-7</subfield><subfield code="w">(DE-576)121196038</subfield><subfield code="x">1380-2224</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:16</subfield><subfield code="g">year:2008</subfield><subfield code="g">number:2</subfield><subfield code="g">day:10</subfield><subfield code="g">month:03</subfield><subfield code="g">pages:233-238</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1007/s10934-008-9191-1</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-GEO</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">16</subfield><subfield code="j">2008</subfield><subfield code="e">2</subfield><subfield code="b">10</subfield><subfield code="c">03</subfield><subfield code="h">233-238</subfield></datafield></record></collection>
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