Theoretical investigation of the EPR parameters and the crystal lattice defects of the trigonal symmetry in $ RbCdF_{3} $:$ Cr^{3+} $
Abstract In this paper, the electron paramagnetic resonance (EPR) parameters in $ RbCdF_{3} $:$ Cr^{3+} $ have been studied by means of energy matrices and the Newman superposition model, the theoretical results are in excellent agreement with the experimental ones. The existence of $ Rb^{+} $ vacan...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Yang, Z. -Y. [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2000 |
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| Anmerkung: |
© Springer 2000 |
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| Übergeordnetes Werk: |
Enthalten in: Applied magnetic resonance - Springer-Verlag, 1990, 18(2000), 4 vom: Apr., Seite 455-461 |
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| Übergeordnetes Werk: |
volume:18 ; year:2000 ; number:4 ; month:04 ; pages:455-461 |
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| DOI / URN: |
10.1007/BF03162291 |
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| 245 | 1 | 0 | |a Theoretical investigation of the EPR parameters and the crystal lattice defects of the trigonal symmetry in $ RbCdF_{3} $:$ Cr^{3+} $ |
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| 520 | |a Abstract In this paper, the electron paramagnetic resonance (EPR) parameters in $ RbCdF_{3} $:$ Cr^{3+} $ have been studied by means of energy matrices and the Newman superposition model, the theoretical results are in excellent agreement with the experimental ones. The existence of $ Rb^{+} $ vacancy and the lattice distortion have been verified. The EPR parameters arising from the $ Rb^{+} $ vacancy itself and the crystal lattice distortion are analyzed and calculated. We obtain that the six ligand $ F^{−} $ ions move to the central $ Cr^{3+} $ ion by Δ = 0.0013 nm, and the front three $ F^{−} $ ions rotate 2.98° away from the [111] axis while the back three $ F^{−} $ ions rotate 1.016° toward it. | ||
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10.1007/BF03162291 doi (DE-627)OLC204391832X (DE-He213)BF03162291-p DE-627 ger DE-627 rakwb eng 530 620 VZ UA 2242.9 VZ rvk 53.00 bkl 33.00 bkl Yang, Z. -Y. verfasserin aut Theoretical investigation of the EPR parameters and the crystal lattice defects of the trigonal symmetry in $ RbCdF_{3} $:$ Cr^{3+} $ 2000 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer 2000 Abstract In this paper, the electron paramagnetic resonance (EPR) parameters in $ RbCdF_{3} $:$ Cr^{3+} $ have been studied by means of energy matrices and the Newman superposition model, the theoretical results are in excellent agreement with the experimental ones. The existence of $ Rb^{+} $ vacancy and the lattice distortion have been verified. The EPR parameters arising from the $ Rb^{+} $ vacancy itself and the crystal lattice distortion are analyzed and calculated. We obtain that the six ligand $ F^{−} $ ions move to the central $ Cr^{3+} $ ion by Δ = 0.0013 nm, and the front three $ F^{−} $ ions rotate 2.98° away from the [111] axis while the back three $ F^{−} $ ions rotate 1.016° toward it. Electron Paramagnetic Reso Crystal Field Lattice Distortion Electron Paramagnetic Reso Parameter Trigonal Symmetry Enthalten in Applied magnetic resonance Springer-Verlag, 1990 18(2000), 4 vom: Apr., Seite 455-461 (DE-627)13092427X (DE-600)1054553-0 (DE-576)02803757X 0937-9347 nnns volume:18 year:2000 number:4 month:04 pages:455-461 https://doi.org/10.1007/BF03162291 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2010 GBV_ILN_2015 GBV_ILN_4012 GBV_ILN_4036 GBV_ILN_4116 UA 2242.9 53.00 VZ 33.00 VZ AR 18 2000 4 04 455-461 |
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10.1007/BF03162291 doi (DE-627)OLC204391832X (DE-He213)BF03162291-p DE-627 ger DE-627 rakwb eng 530 620 VZ UA 2242.9 VZ rvk 53.00 bkl 33.00 bkl Yang, Z. -Y. verfasserin aut Theoretical investigation of the EPR parameters and the crystal lattice defects of the trigonal symmetry in $ RbCdF_{3} $:$ Cr^{3+} $ 2000 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer 2000 Abstract In this paper, the electron paramagnetic resonance (EPR) parameters in $ RbCdF_{3} $:$ Cr^{3+} $ have been studied by means of energy matrices and the Newman superposition model, the theoretical results are in excellent agreement with the experimental ones. The existence of $ Rb^{+} $ vacancy and the lattice distortion have been verified. The EPR parameters arising from the $ Rb^{+} $ vacancy itself and the crystal lattice distortion are analyzed and calculated. We obtain that the six ligand $ F^{−} $ ions move to the central $ Cr^{3+} $ ion by Δ = 0.0013 nm, and the front three $ F^{−} $ ions rotate 2.98° away from the [111] axis while the back three $ F^{−} $ ions rotate 1.016° toward it. Electron Paramagnetic Reso Crystal Field Lattice Distortion Electron Paramagnetic Reso Parameter Trigonal Symmetry Enthalten in Applied magnetic resonance Springer-Verlag, 1990 18(2000), 4 vom: Apr., Seite 455-461 (DE-627)13092427X (DE-600)1054553-0 (DE-576)02803757X 0937-9347 nnns volume:18 year:2000 number:4 month:04 pages:455-461 https://doi.org/10.1007/BF03162291 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2010 GBV_ILN_2015 GBV_ILN_4012 GBV_ILN_4036 GBV_ILN_4116 UA 2242.9 53.00 VZ 33.00 VZ AR 18 2000 4 04 455-461 |
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10.1007/BF03162291 doi (DE-627)OLC204391832X (DE-He213)BF03162291-p DE-627 ger DE-627 rakwb eng 530 620 VZ UA 2242.9 VZ rvk 53.00 bkl 33.00 bkl Yang, Z. -Y. verfasserin aut Theoretical investigation of the EPR parameters and the crystal lattice defects of the trigonal symmetry in $ RbCdF_{3} $:$ Cr^{3+} $ 2000 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer 2000 Abstract In this paper, the electron paramagnetic resonance (EPR) parameters in $ RbCdF_{3} $:$ Cr^{3+} $ have been studied by means of energy matrices and the Newman superposition model, the theoretical results are in excellent agreement with the experimental ones. The existence of $ Rb^{+} $ vacancy and the lattice distortion have been verified. The EPR parameters arising from the $ Rb^{+} $ vacancy itself and the crystal lattice distortion are analyzed and calculated. We obtain that the six ligand $ F^{−} $ ions move to the central $ Cr^{3+} $ ion by Δ = 0.0013 nm, and the front three $ F^{−} $ ions rotate 2.98° away from the [111] axis while the back three $ F^{−} $ ions rotate 1.016° toward it. Electron Paramagnetic Reso Crystal Field Lattice Distortion Electron Paramagnetic Reso Parameter Trigonal Symmetry Enthalten in Applied magnetic resonance Springer-Verlag, 1990 18(2000), 4 vom: Apr., Seite 455-461 (DE-627)13092427X (DE-600)1054553-0 (DE-576)02803757X 0937-9347 nnns volume:18 year:2000 number:4 month:04 pages:455-461 https://doi.org/10.1007/BF03162291 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2010 GBV_ILN_2015 GBV_ILN_4012 GBV_ILN_4036 GBV_ILN_4116 UA 2242.9 53.00 VZ 33.00 VZ AR 18 2000 4 04 455-461 |
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10.1007/BF03162291 doi (DE-627)OLC204391832X (DE-He213)BF03162291-p DE-627 ger DE-627 rakwb eng 530 620 VZ UA 2242.9 VZ rvk 53.00 bkl 33.00 bkl Yang, Z. -Y. verfasserin aut Theoretical investigation of the EPR parameters and the crystal lattice defects of the trigonal symmetry in $ RbCdF_{3} $:$ Cr^{3+} $ 2000 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer 2000 Abstract In this paper, the electron paramagnetic resonance (EPR) parameters in $ RbCdF_{3} $:$ Cr^{3+} $ have been studied by means of energy matrices and the Newman superposition model, the theoretical results are in excellent agreement with the experimental ones. The existence of $ Rb^{+} $ vacancy and the lattice distortion have been verified. The EPR parameters arising from the $ Rb^{+} $ vacancy itself and the crystal lattice distortion are analyzed and calculated. We obtain that the six ligand $ F^{−} $ ions move to the central $ Cr^{3+} $ ion by Δ = 0.0013 nm, and the front three $ F^{−} $ ions rotate 2.98° away from the [111] axis while the back three $ F^{−} $ ions rotate 1.016° toward it. Electron Paramagnetic Reso Crystal Field Lattice Distortion Electron Paramagnetic Reso Parameter Trigonal Symmetry Enthalten in Applied magnetic resonance Springer-Verlag, 1990 18(2000), 4 vom: Apr., Seite 455-461 (DE-627)13092427X (DE-600)1054553-0 (DE-576)02803757X 0937-9347 nnns volume:18 year:2000 number:4 month:04 pages:455-461 https://doi.org/10.1007/BF03162291 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2010 GBV_ILN_2015 GBV_ILN_4012 GBV_ILN_4036 GBV_ILN_4116 UA 2242.9 53.00 VZ 33.00 VZ AR 18 2000 4 04 455-461 |
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10.1007/BF03162291 doi (DE-627)OLC204391832X (DE-He213)BF03162291-p DE-627 ger DE-627 rakwb eng 530 620 VZ UA 2242.9 VZ rvk 53.00 bkl 33.00 bkl Yang, Z. -Y. verfasserin aut Theoretical investigation of the EPR parameters and the crystal lattice defects of the trigonal symmetry in $ RbCdF_{3} $:$ Cr^{3+} $ 2000 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer 2000 Abstract In this paper, the electron paramagnetic resonance (EPR) parameters in $ RbCdF_{3} $:$ Cr^{3+} $ have been studied by means of energy matrices and the Newman superposition model, the theoretical results are in excellent agreement with the experimental ones. The existence of $ Rb^{+} $ vacancy and the lattice distortion have been verified. The EPR parameters arising from the $ Rb^{+} $ vacancy itself and the crystal lattice distortion are analyzed and calculated. We obtain that the six ligand $ F^{−} $ ions move to the central $ Cr^{3+} $ ion by Δ = 0.0013 nm, and the front three $ F^{−} $ ions rotate 2.98° away from the [111] axis while the back three $ F^{−} $ ions rotate 1.016° toward it. Electron Paramagnetic Reso Crystal Field Lattice Distortion Electron Paramagnetic Reso Parameter Trigonal Symmetry Enthalten in Applied magnetic resonance Springer-Verlag, 1990 18(2000), 4 vom: Apr., Seite 455-461 (DE-627)13092427X (DE-600)1054553-0 (DE-576)02803757X 0937-9347 nnns volume:18 year:2000 number:4 month:04 pages:455-461 https://doi.org/10.1007/BF03162291 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2010 GBV_ILN_2015 GBV_ILN_4012 GBV_ILN_4036 GBV_ILN_4116 UA 2242.9 53.00 VZ 33.00 VZ AR 18 2000 4 04 455-461 |
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Yang, Z. -Y. |
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10.1007/BF03162291 |
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theoretical investigation of the epr parameters and the crystal lattice defects of the trigonal symmetry in $ rbcdf_{3} $:$ cr^{3+} $ |
| title_auth |
Theoretical investigation of the EPR parameters and the crystal lattice defects of the trigonal symmetry in $ RbCdF_{3} $:$ Cr^{3+} $ |
| abstract |
Abstract In this paper, the electron paramagnetic resonance (EPR) parameters in $ RbCdF_{3} $:$ Cr^{3+} $ have been studied by means of energy matrices and the Newman superposition model, the theoretical results are in excellent agreement with the experimental ones. The existence of $ Rb^{+} $ vacancy and the lattice distortion have been verified. The EPR parameters arising from the $ Rb^{+} $ vacancy itself and the crystal lattice distortion are analyzed and calculated. We obtain that the six ligand $ F^{−} $ ions move to the central $ Cr^{3+} $ ion by Δ = 0.0013 nm, and the front three $ F^{−} $ ions rotate 2.98° away from the [111] axis while the back three $ F^{−} $ ions rotate 1.016° toward it. © Springer 2000 |
| abstractGer |
Abstract In this paper, the electron paramagnetic resonance (EPR) parameters in $ RbCdF_{3} $:$ Cr^{3+} $ have been studied by means of energy matrices and the Newman superposition model, the theoretical results are in excellent agreement with the experimental ones. The existence of $ Rb^{+} $ vacancy and the lattice distortion have been verified. The EPR parameters arising from the $ Rb^{+} $ vacancy itself and the crystal lattice distortion are analyzed and calculated. We obtain that the six ligand $ F^{−} $ ions move to the central $ Cr^{3+} $ ion by Δ = 0.0013 nm, and the front three $ F^{−} $ ions rotate 2.98° away from the [111] axis while the back three $ F^{−} $ ions rotate 1.016° toward it. © Springer 2000 |
| abstract_unstemmed |
Abstract In this paper, the electron paramagnetic resonance (EPR) parameters in $ RbCdF_{3} $:$ Cr^{3+} $ have been studied by means of energy matrices and the Newman superposition model, the theoretical results are in excellent agreement with the experimental ones. The existence of $ Rb^{+} $ vacancy and the lattice distortion have been verified. The EPR parameters arising from the $ Rb^{+} $ vacancy itself and the crystal lattice distortion are analyzed and calculated. We obtain that the six ligand $ F^{−} $ ions move to the central $ Cr^{3+} $ ion by Δ = 0.0013 nm, and the front three $ F^{−} $ ions rotate 2.98° away from the [111] axis while the back three $ F^{−} $ ions rotate 1.016° toward it. © Springer 2000 |
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| title_short |
Theoretical investigation of the EPR parameters and the crystal lattice defects of the trigonal symmetry in $ RbCdF_{3} $:$ Cr^{3+} $ |
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