Hydrous zirconium dioxide: interfacial properties, the formation of monodisperse spherical particles, and its crystallization at high temperatures

Abstract The characteristics of hydrous zirconia gels obtained by hydrolysis of highly acidic $ ZrOCl_{2} $ · $ 8H_{2} $O solutions at ∼100‡C are described. Under adequate conditions, monodisperse spherical hydrous zirconia is obtained. The role of sulphate and chloride ions is described. The gel ha...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Blesa, M. A. [verfasserIn] Maroto, A. J. G. Passaggio, S. I. Figliolia, N. E. Rigotti, G.

Format:	Artikel
Sprache:	Englisch

Erschienen:	1985

Schlagwörter:	Crystallization Zirconia Interfacial Property Binding Model ZrOCl2

Anmerkung:	© Chapman and Hall Ltd. 1985

Übergeordnetes Werk:	Enthalten in: Journal of materials science - Kluwer Academic Publishers, 1966, 20(1985), 12 vom: Dez., Seite 4601-4609
Übergeordnetes Werk:	volume:20 ; year:1985 ; number:12 ; month:12 ; pages:4601-4609

Links:	Volltext

DOI / URN:	10.1007/BF00559350

Katalog-ID:	OLC2046136802

Internformat


LEADER	01000caa a22002652 4500
001	OLC2046136802
003	DE-627
005	20230503121229.0
007	tu
008	200820s1985 xx \|\|\|\|\| 00\| \|\|eng c
024	7		\|a 10.1007/BF00559350 \|2 doi
035			\|a (DE-627)OLC2046136802
035			\|a (DE-He213)BF00559350-p
040			\|a DE-627 \|b ger \|c DE-627 \|e rakwb
041			\|a eng
082	0	4	\|a 670 \|q VZ
100	1		\|a Blesa, M. A. \|e verfasserin \|4 aut
245	1	0	\|a Hydrous zirconium dioxide: interfacial properties, the formation of monodisperse spherical particles, and its crystallization at high temperatures
264		1	\|c 1985
336			\|a Text \|b txt \|2 rdacontent
337			\|a ohne Hilfsmittel zu benutzen \|b n \|2 rdamedia
338			\|a Band \|b nc \|2 rdacarrier
500			\|a © Chapman and Hall Ltd. 1985
520			\|a Abstract The characteristics of hydrous zirconia gels obtained by hydrolysis of highly acidic $ ZrOCl_{2} $ · $ 8H_{2} $O solutions at ∼100‡C are described. Under adequate conditions, monodisperse spherical hydrous zirconia is obtained. The role of sulphate and chloride ions is described. The gel has a large water content, indicating only modest crosslinking. Crystallization upon heating takes place with the formation of both monoclinic and tetragonal zirconia polymorphs; X-ray line widening studies do not indicate a particle size-crystal structure correlation. On the basis of this observation and using Stranki's rule, the crystallization sequence upon heating is rationalized. Surface properties of hydrous zirconia are discussed on the basis of electrophoretic measurements, and compared with those of baddeleyte. The site binding model is not very adequate to describe these systems, and the existence of a very thin gel-like region at the baddeleyte-water interface is postulated.
650		4	\|a Crystallization
650		4	\|a Zirconia
650		4	\|a Interfacial Property
650		4	\|a Binding Model
650		4	\|a ZrOCl2
700	1		\|a Maroto, A. J. G. \|4 aut
700	1		\|a Passaggio, S. I. \|4 aut
700	1		\|a Figliolia, N. E. \|4 aut
700	1		\|a Rigotti, G. \|4 aut
773	0	8	\|i Enthalten in \|t Journal of materials science \|d Kluwer Academic Publishers, 1966 \|g 20(1985), 12 vom: Dez., Seite 4601-4609 \|w (DE-627)129546372 \|w (DE-600)218324-9 \|w (DE-576)014996774 \|x 0022-2461 \|7 nnns
773	1	8	\|g volume:20 \|g year:1985 \|g number:12 \|g month:12 \|g pages:4601-4609
856	4	1	\|u https://doi.org/10.1007/BF00559350 \|z lizenzpflichtig \|3 Volltext
912			\|a GBV_USEFLAG_A
912			\|a SYSFLAG_A
912			\|a GBV_OLC
912			\|a SSG-OLC-TEC
912			\|a GBV_ILN_11
912			\|a GBV_ILN_20
912			\|a GBV_ILN_23
912			\|a GBV_ILN_30
912			\|a GBV_ILN_31
912			\|a GBV_ILN_32
912			\|a GBV_ILN_40
912			\|a GBV_ILN_62
912			\|a GBV_ILN_65
912			\|a GBV_ILN_70
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2006
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2057
912			\|a GBV_ILN_2333
912			\|a GBV_ILN_4082
912			\|a GBV_ILN_4305
912			\|a GBV_ILN_4306
912			\|a GBV_ILN_4319
912			\|a GBV_ILN_4323
912			\|a GBV_ILN_4700
951			\|a AR
952			\|d 20 \|j 1985 \|e 12 \|c 12 \|h 4601-4609

Indexfelder

author_variant	m a b ma mab a j g m ajg ajgm s i p si sip n e f ne nef g r gr
matchkey_str	article:00222461:1985----::yruzroimixditrailrprishfrainfooiprepeiaprilsni
hierarchy_sort_str	1985
publishDate	1985
allfields	10.1007/BF00559350 doi (DE-627)OLC2046136802 (DE-He213)BF00559350-p DE-627 ger DE-627 rakwb eng 670 VZ Blesa, M. A. verfasserin aut Hydrous zirconium dioxide: interfacial properties, the formation of monodisperse spherical particles, and its crystallization at high temperatures 1985 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chapman and Hall Ltd. 1985 Abstract The characteristics of hydrous zirconia gels obtained by hydrolysis of highly acidic $ ZrOCl_{2} $ · $ 8H_{2} $O solutions at ∼100‡C are described. Under adequate conditions, monodisperse spherical hydrous zirconia is obtained. The role of sulphate and chloride ions is described. The gel has a large water content, indicating only modest crosslinking. Crystallization upon heating takes place with the formation of both monoclinic and tetragonal zirconia polymorphs; X-ray line widening studies do not indicate a particle size-crystal structure correlation. On the basis of this observation and using Stranki's rule, the crystallization sequence upon heating is rationalized. Surface properties of hydrous zirconia are discussed on the basis of electrophoretic measurements, and compared with those of baddeleyte. The site binding model is not very adequate to describe these systems, and the existence of a very thin gel-like region at the baddeleyte-water interface is postulated. Crystallization Zirconia Interfacial Property Binding Model ZrOCl2 Maroto, A. J. G. aut Passaggio, S. I. aut Figliolia, N. E. aut Rigotti, G. aut Enthalten in Journal of materials science Kluwer Academic Publishers, 1966 20(1985), 12 vom: Dez., Seite 4601-4609 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:20 year:1985 number:12 month:12 pages:4601-4609 https://doi.org/10.1007/BF00559350 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_11 GBV_ILN_20 GBV_ILN_23 GBV_ILN_30 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2057 GBV_ILN_2333 GBV_ILN_4082 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4319 GBV_ILN_4323 GBV_ILN_4700 AR 20 1985 12 12 4601-4609
spelling	10.1007/BF00559350 doi (DE-627)OLC2046136802 (DE-He213)BF00559350-p DE-627 ger DE-627 rakwb eng 670 VZ Blesa, M. A. verfasserin aut Hydrous zirconium dioxide: interfacial properties, the formation of monodisperse spherical particles, and its crystallization at high temperatures 1985 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chapman and Hall Ltd. 1985 Abstract The characteristics of hydrous zirconia gels obtained by hydrolysis of highly acidic $ ZrOCl_{2} $ · $ 8H_{2} $O solutions at ∼100‡C are described. Under adequate conditions, monodisperse spherical hydrous zirconia is obtained. The role of sulphate and chloride ions is described. The gel has a large water content, indicating only modest crosslinking. Crystallization upon heating takes place with the formation of both monoclinic and tetragonal zirconia polymorphs; X-ray line widening studies do not indicate a particle size-crystal structure correlation. On the basis of this observation and using Stranki's rule, the crystallization sequence upon heating is rationalized. Surface properties of hydrous zirconia are discussed on the basis of electrophoretic measurements, and compared with those of baddeleyte. The site binding model is not very adequate to describe these systems, and the existence of a very thin gel-like region at the baddeleyte-water interface is postulated. Crystallization Zirconia Interfacial Property Binding Model ZrOCl2 Maroto, A. J. G. aut Passaggio, S. I. aut Figliolia, N. E. aut Rigotti, G. aut Enthalten in Journal of materials science Kluwer Academic Publishers, 1966 20(1985), 12 vom: Dez., Seite 4601-4609 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:20 year:1985 number:12 month:12 pages:4601-4609 https://doi.org/10.1007/BF00559350 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_11 GBV_ILN_20 GBV_ILN_23 GBV_ILN_30 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2057 GBV_ILN_2333 GBV_ILN_4082 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4319 GBV_ILN_4323 GBV_ILN_4700 AR 20 1985 12 12 4601-4609
allfields_unstemmed	10.1007/BF00559350 doi (DE-627)OLC2046136802 (DE-He213)BF00559350-p DE-627 ger DE-627 rakwb eng 670 VZ Blesa, M. A. verfasserin aut Hydrous zirconium dioxide: interfacial properties, the formation of monodisperse spherical particles, and its crystallization at high temperatures 1985 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chapman and Hall Ltd. 1985 Abstract The characteristics of hydrous zirconia gels obtained by hydrolysis of highly acidic $ ZrOCl_{2} $ · $ 8H_{2} $O solutions at ∼100‡C are described. Under adequate conditions, monodisperse spherical hydrous zirconia is obtained. The role of sulphate and chloride ions is described. The gel has a large water content, indicating only modest crosslinking. Crystallization upon heating takes place with the formation of both monoclinic and tetragonal zirconia polymorphs; X-ray line widening studies do not indicate a particle size-crystal structure correlation. On the basis of this observation and using Stranki's rule, the crystallization sequence upon heating is rationalized. Surface properties of hydrous zirconia are discussed on the basis of electrophoretic measurements, and compared with those of baddeleyte. The site binding model is not very adequate to describe these systems, and the existence of a very thin gel-like region at the baddeleyte-water interface is postulated. Crystallization Zirconia Interfacial Property Binding Model ZrOCl2 Maroto, A. J. G. aut Passaggio, S. I. aut Figliolia, N. E. aut Rigotti, G. aut Enthalten in Journal of materials science Kluwer Academic Publishers, 1966 20(1985), 12 vom: Dez., Seite 4601-4609 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:20 year:1985 number:12 month:12 pages:4601-4609 https://doi.org/10.1007/BF00559350 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_11 GBV_ILN_20 GBV_ILN_23 GBV_ILN_30 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2057 GBV_ILN_2333 GBV_ILN_4082 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4319 GBV_ILN_4323 GBV_ILN_4700 AR 20 1985 12 12 4601-4609
allfieldsGer	10.1007/BF00559350 doi (DE-627)OLC2046136802 (DE-He213)BF00559350-p DE-627 ger DE-627 rakwb eng 670 VZ Blesa, M. A. verfasserin aut Hydrous zirconium dioxide: interfacial properties, the formation of monodisperse spherical particles, and its crystallization at high temperatures 1985 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chapman and Hall Ltd. 1985 Abstract The characteristics of hydrous zirconia gels obtained by hydrolysis of highly acidic $ ZrOCl_{2} $ · $ 8H_{2} $O solutions at ∼100‡C are described. Under adequate conditions, monodisperse spherical hydrous zirconia is obtained. The role of sulphate and chloride ions is described. The gel has a large water content, indicating only modest crosslinking. Crystallization upon heating takes place with the formation of both monoclinic and tetragonal zirconia polymorphs; X-ray line widening studies do not indicate a particle size-crystal structure correlation. On the basis of this observation and using Stranki's rule, the crystallization sequence upon heating is rationalized. Surface properties of hydrous zirconia are discussed on the basis of electrophoretic measurements, and compared with those of baddeleyte. The site binding model is not very adequate to describe these systems, and the existence of a very thin gel-like region at the baddeleyte-water interface is postulated. Crystallization Zirconia Interfacial Property Binding Model ZrOCl2 Maroto, A. J. G. aut Passaggio, S. I. aut Figliolia, N. E. aut Rigotti, G. aut Enthalten in Journal of materials science Kluwer Academic Publishers, 1966 20(1985), 12 vom: Dez., Seite 4601-4609 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:20 year:1985 number:12 month:12 pages:4601-4609 https://doi.org/10.1007/BF00559350 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_11 GBV_ILN_20 GBV_ILN_23 GBV_ILN_30 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2057 GBV_ILN_2333 GBV_ILN_4082 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4319 GBV_ILN_4323 GBV_ILN_4700 AR 20 1985 12 12 4601-4609
allfieldsSound	10.1007/BF00559350 doi (DE-627)OLC2046136802 (DE-He213)BF00559350-p DE-627 ger DE-627 rakwb eng 670 VZ Blesa, M. A. verfasserin aut Hydrous zirconium dioxide: interfacial properties, the formation of monodisperse spherical particles, and its crystallization at high temperatures 1985 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chapman and Hall Ltd. 1985 Abstract The characteristics of hydrous zirconia gels obtained by hydrolysis of highly acidic $ ZrOCl_{2} $ · $ 8H_{2} $O solutions at ∼100‡C are described. Under adequate conditions, monodisperse spherical hydrous zirconia is obtained. The role of sulphate and chloride ions is described. The gel has a large water content, indicating only modest crosslinking. Crystallization upon heating takes place with the formation of both monoclinic and tetragonal zirconia polymorphs; X-ray line widening studies do not indicate a particle size-crystal structure correlation. On the basis of this observation and using Stranki's rule, the crystallization sequence upon heating is rationalized. Surface properties of hydrous zirconia are discussed on the basis of electrophoretic measurements, and compared with those of baddeleyte. The site binding model is not very adequate to describe these systems, and the existence of a very thin gel-like region at the baddeleyte-water interface is postulated. Crystallization Zirconia Interfacial Property Binding Model ZrOCl2 Maroto, A. J. G. aut Passaggio, S. I. aut Figliolia, N. E. aut Rigotti, G. aut Enthalten in Journal of materials science Kluwer Academic Publishers, 1966 20(1985), 12 vom: Dez., Seite 4601-4609 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:20 year:1985 number:12 month:12 pages:4601-4609 https://doi.org/10.1007/BF00559350 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_11 GBV_ILN_20 GBV_ILN_23 GBV_ILN_30 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2057 GBV_ILN_2333 GBV_ILN_4082 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4319 GBV_ILN_4323 GBV_ILN_4700 AR 20 1985 12 12 4601-4609
language	English
source	Enthalten in Journal of materials science 20(1985), 12 vom: Dez., Seite 4601-4609 volume:20 year:1985 number:12 month:12 pages:4601-4609
sourceStr	Enthalten in Journal of materials science 20(1985), 12 vom: Dez., Seite 4601-4609 volume:20 year:1985 number:12 month:12 pages:4601-4609
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Crystallization Zirconia Interfacial Property Binding Model ZrOCl2
dewey-raw	670
isfreeaccess_bool	false
container_title	Journal of materials science
authorswithroles_txt_mv	Blesa, M. A. @@aut@@ Maroto, A. J. G. @@aut@@ Passaggio, S. I. @@aut@@ Figliolia, N. E. @@aut@@ Rigotti, G. @@aut@@
publishDateDaySort_date	1985-12-01T00:00:00Z
hierarchy_top_id	129546372
dewey-sort	3670
id	OLC2046136802
language_de	englisch
fullrecord	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">OLC2046136802</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230503121229.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">200820s1985 xx \|\|\|\|\| 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/BF00559350</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC2046136802</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-He213)BF00559350-p</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">670</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Blesa, M. A.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Hydrous zirconium dioxide: interfacial properties, the formation of monodisperse spherical particles, and its crystallization at high temperatures</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">1985</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Chapman and Hall Ltd. 1985</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract The characteristics of hydrous zirconia gels obtained by hydrolysis of highly acidic $ ZrOCl_{2} $ · $ 8H_{2} $O solutions at ∼100‡C are described. Under adequate conditions, monodisperse spherical hydrous zirconia is obtained. The role of sulphate and chloride ions is described. The gel has a large water content, indicating only modest crosslinking. Crystallization upon heating takes place with the formation of both monoclinic and tetragonal zirconia polymorphs; X-ray line widening studies do not indicate a particle size-crystal structure correlation. On the basis of this observation and using Stranki's rule, the crystallization sequence upon heating is rationalized. Surface properties of hydrous zirconia are discussed on the basis of electrophoretic measurements, and compared with those of baddeleyte. The site binding model is not very adequate to describe these systems, and the existence of a very thin gel-like region at the baddeleyte-water interface is postulated.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Crystallization</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Zirconia</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Interfacial Property</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Binding Model</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">ZrOCl2</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Maroto, A. J. G.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Passaggio, S. I.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Figliolia, N. E.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Rigotti, G.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of materials science</subfield><subfield code="d">Kluwer Academic Publishers, 1966</subfield><subfield code="g">20(1985), 12 vom: Dez., Seite 4601-4609</subfield><subfield code="w">(DE-627)129546372</subfield><subfield code="w">(DE-600)218324-9</subfield><subfield code="w">(DE-576)014996774</subfield><subfield code="x">0022-2461</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:20</subfield><subfield code="g">year:1985</subfield><subfield code="g">number:12</subfield><subfield code="g">month:12</subfield><subfield code="g">pages:4601-4609</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1007/BF00559350</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_11</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_30</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2006</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2020</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2057</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2333</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4082</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4306</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4319</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4700</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">20</subfield><subfield code="j">1985</subfield><subfield code="e">12</subfield><subfield code="c">12</subfield><subfield code="h">4601-4609</subfield></datafield></record></collection>
author	Blesa, M. A.
spellingShingle	Blesa, M. A. ddc 670 misc Crystallization misc Zirconia misc Interfacial Property misc Binding Model misc ZrOCl2 Hydrous zirconium dioxide: interfacial properties, the formation of monodisperse spherical particles, and its crystallization at high temperatures
authorStr	Blesa, M. A.
ppnlink_with_tag_str_mv	@@773@@(DE-627)129546372
format	Article
dewey-ones	670 - Manufacturing
delete_txt_mv	keep
author_role	aut aut aut aut aut
collection	OLC
remote_str	false
illustrated	Not Illustrated
issn	0022-2461
topic_title	670 VZ Hydrous zirconium dioxide: interfacial properties, the formation of monodisperse spherical particles, and its crystallization at high temperatures Crystallization Zirconia Interfacial Property Binding Model ZrOCl2
topic	ddc 670 misc Crystallization misc Zirconia misc Interfacial Property misc Binding Model misc ZrOCl2
topic_unstemmed	ddc 670 misc Crystallization misc Zirconia misc Interfacial Property misc Binding Model misc ZrOCl2
topic_browse	ddc 670 misc Crystallization misc Zirconia misc Interfacial Property misc Binding Model misc ZrOCl2
format_facet	Aufsätze Gedruckte Aufsätze
format_main_str_mv	Text Zeitschrift/Artikel
carriertype_str_mv	nc
hierarchy_parent_title	Journal of materials science
hierarchy_parent_id	129546372
dewey-tens	670 - Manufacturing
hierarchy_top_title	Journal of materials science
isfreeaccess_txt	false
familylinks_str_mv	(DE-627)129546372 (DE-600)218324-9 (DE-576)014996774
title	Hydrous zirconium dioxide: interfacial properties, the formation of monodisperse spherical particles, and its crystallization at high temperatures
ctrlnum	(DE-627)OLC2046136802 (DE-He213)BF00559350-p
title_full	Hydrous zirconium dioxide: interfacial properties, the formation of monodisperse spherical particles, and its crystallization at high temperatures
author_sort	Blesa, M. A.
journal	Journal of materials science
journalStr	Journal of materials science
lang_code	eng
isOA_bool	false
dewey-hundreds	600 - Technology
recordtype	marc
publishDateSort	1985
contenttype_str_mv	txt
container_start_page	4601
author_browse	Blesa, M. A. Maroto, A. J. G. Passaggio, S. I. Figliolia, N. E. Rigotti, G.
container_volume	20
class	670 VZ
format_se	Aufsätze
author-letter	Blesa, M. A.
doi_str_mv	10.1007/BF00559350
dewey-full	670
title_sort	hydrous zirconium dioxide: interfacial properties, the formation of monodisperse spherical particles, and its crystallization at high temperatures
title_auth	Hydrous zirconium dioxide: interfacial properties, the formation of monodisperse spherical particles, and its crystallization at high temperatures
abstract	Abstract The characteristics of hydrous zirconia gels obtained by hydrolysis of highly acidic $ ZrOCl_{2} $ · $ 8H_{2} $O solutions at ∼100‡C are described. Under adequate conditions, monodisperse spherical hydrous zirconia is obtained. The role of sulphate and chloride ions is described. The gel has a large water content, indicating only modest crosslinking. Crystallization upon heating takes place with the formation of both monoclinic and tetragonal zirconia polymorphs; X-ray line widening studies do not indicate a particle size-crystal structure correlation. On the basis of this observation and using Stranki's rule, the crystallization sequence upon heating is rationalized. Surface properties of hydrous zirconia are discussed on the basis of electrophoretic measurements, and compared with those of baddeleyte. The site binding model is not very adequate to describe these systems, and the existence of a very thin gel-like region at the baddeleyte-water interface is postulated. © Chapman and Hall Ltd. 1985
abstractGer	Abstract The characteristics of hydrous zirconia gels obtained by hydrolysis of highly acidic $ ZrOCl_{2} $ · $ 8H_{2} $O solutions at ∼100‡C are described. Under adequate conditions, monodisperse spherical hydrous zirconia is obtained. The role of sulphate and chloride ions is described. The gel has a large water content, indicating only modest crosslinking. Crystallization upon heating takes place with the formation of both monoclinic and tetragonal zirconia polymorphs; X-ray line widening studies do not indicate a particle size-crystal structure correlation. On the basis of this observation and using Stranki's rule, the crystallization sequence upon heating is rationalized. Surface properties of hydrous zirconia are discussed on the basis of electrophoretic measurements, and compared with those of baddeleyte. The site binding model is not very adequate to describe these systems, and the existence of a very thin gel-like region at the baddeleyte-water interface is postulated. © Chapman and Hall Ltd. 1985
abstract_unstemmed	Abstract The characteristics of hydrous zirconia gels obtained by hydrolysis of highly acidic $ ZrOCl_{2} $ · $ 8H_{2} $O solutions at ∼100‡C are described. Under adequate conditions, monodisperse spherical hydrous zirconia is obtained. The role of sulphate and chloride ions is described. The gel has a large water content, indicating only modest crosslinking. Crystallization upon heating takes place with the formation of both monoclinic and tetragonal zirconia polymorphs; X-ray line widening studies do not indicate a particle size-crystal structure correlation. On the basis of this observation and using Stranki's rule, the crystallization sequence upon heating is rationalized. Surface properties of hydrous zirconia are discussed on the basis of electrophoretic measurements, and compared with those of baddeleyte. The site binding model is not very adequate to describe these systems, and the existence of a very thin gel-like region at the baddeleyte-water interface is postulated. © Chapman and Hall Ltd. 1985
collection_details	GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_11 GBV_ILN_20 GBV_ILN_23 GBV_ILN_30 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2057 GBV_ILN_2333 GBV_ILN_4082 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4319 GBV_ILN_4323 GBV_ILN_4700
container_issue	12
title_short	Hydrous zirconium dioxide: interfacial properties, the formation of monodisperse spherical particles, and its crystallization at high temperatures
url	https://doi.org/10.1007/BF00559350
remote_bool	false
author2	Maroto, A. J. G. Passaggio, S. I. Figliolia, N. E. Rigotti, G.
author2Str	Maroto, A. J. G. Passaggio, S. I. Figliolia, N. E. Rigotti, G.
ppnlink	129546372
mediatype_str_mv	n
isOA_txt	false
hochschulschrift_bool	false
doi_str	10.1007/BF00559350
up_date	2024-07-04T04:20:22.954Z
_version_	1803620788947910656
fullrecord_marcxml	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">OLC2046136802</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230503121229.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">200820s1985 xx \|\|\|\|\| 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/BF00559350</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC2046136802</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-He213)BF00559350-p</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">670</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Blesa, M. A.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Hydrous zirconium dioxide: interfacial properties, the formation of monodisperse spherical particles, and its crystallization at high temperatures</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">1985</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Chapman and Hall Ltd. 1985</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract The characteristics of hydrous zirconia gels obtained by hydrolysis of highly acidic $ ZrOCl_{2} $ · $ 8H_{2} $O solutions at ∼100‡C are described. Under adequate conditions, monodisperse spherical hydrous zirconia is obtained. The role of sulphate and chloride ions is described. The gel has a large water content, indicating only modest crosslinking. Crystallization upon heating takes place with the formation of both monoclinic and tetragonal zirconia polymorphs; X-ray line widening studies do not indicate a particle size-crystal structure correlation. On the basis of this observation and using Stranki's rule, the crystallization sequence upon heating is rationalized. Surface properties of hydrous zirconia are discussed on the basis of electrophoretic measurements, and compared with those of baddeleyte. The site binding model is not very adequate to describe these systems, and the existence of a very thin gel-like region at the baddeleyte-water interface is postulated.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Crystallization</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Zirconia</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Interfacial Property</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Binding Model</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">ZrOCl2</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Maroto, A. J. G.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Passaggio, S. I.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Figliolia, N. E.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Rigotti, G.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of materials science</subfield><subfield code="d">Kluwer Academic Publishers, 1966</subfield><subfield code="g">20(1985), 12 vom: Dez., Seite 4601-4609</subfield><subfield code="w">(DE-627)129546372</subfield><subfield code="w">(DE-600)218324-9</subfield><subfield code="w">(DE-576)014996774</subfield><subfield code="x">0022-2461</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:20</subfield><subfield code="g">year:1985</subfield><subfield code="g">number:12</subfield><subfield code="g">month:12</subfield><subfield code="g">pages:4601-4609</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1007/BF00559350</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_11</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_30</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2006</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2020</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2057</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2333</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4082</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4306</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4319</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4700</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">20</subfield><subfield code="j">1985</subfield><subfield code="e">12</subfield><subfield code="c">12</subfield><subfield code="h">4601-4609</subfield></datafield></record></collection>
score	7.401515

Nicht das Richtige dabei?

Schreiben Sie uns!

Hydrous zirconium dioxide: interfacial properties, the formation of monodisperse spherical particles, and its crystallization at high temperatures

Nicht das Richtige dabei?

Zugang & Verfügbarkeit

Vorhandene Bände

Nicht das Richtige dabei?