The effect of pressure on metastable phase formation in the undercooled Bi-Sn system
Abstract A metastable phase was produced by the solidification of highly undercooled Bi-48.6 at% Sn alloy droplet samples. During heating the metastable phase was observed to melt at 116° C at ambient pressure. The onset of the metastable endotherm was found to increase with increasing pressure, whi...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Yoon, W. [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1988 |
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| Schlagwörter: |
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| Anmerkung: |
© Chapman and Hall Ltd. 1988 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of materials science - Kluwer Academic Publishers, 1966, 23(1988), 12 vom: Dez., Seite 4300-4306 |
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| Übergeordnetes Werk: |
volume:23 ; year:1988 ; number:12 ; month:12 ; pages:4300-4306 |
| Links: |
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| DOI / URN: |
10.1007/BF00551923 |
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| Katalog-ID: |
OLC204615763X |
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| 245 | 1 | 0 | |a The effect of pressure on metastable phase formation in the undercooled Bi-Sn system |
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| 520 | |a Abstract A metastable phase was produced by the solidification of highly undercooled Bi-48.6 at% Sn alloy droplet samples. During heating the metastable phase was observed to melt at 116° C at ambient pressure. The onset of the metastable endotherm was found to increase with increasing pressure, while the liquidus and eutectic temperature for the structure stable at ambient pressure decreased with increasing pressure. Based on the pressure dependence of the melting trend, the metastable phase will be stable at the expense of the stable ambient pressure structure under high hydrostatic pressure conditions (above ∼ 1 GPa). Both microstructural observations and X-ray examinations at ambient pressure revealed that the metastable phase was present in droplet samples and that the X-ray diffraction pattern was close to that of the high-pressure stable phase previously reported as a rhombic cell. High-pressure thermal analysis has also allowed for identification of the effect of pressure in promoting favourable formation kinetics and the kinetic transition from the equilibrium phases to the metastable phase at high undercooling. | ||
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| 650 | 4 | |a Metastable Phase | |
| 650 | 4 | |a Eutectic Temperature | |
| 650 | 4 | |a High Hydrostatic Pressure | |
| 700 | 1 | |a Perepezko, J. H. |4 aut | |
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10.1007/BF00551923 doi (DE-627)OLC204615763X (DE-He213)BF00551923-p DE-627 ger DE-627 rakwb eng 670 VZ Yoon, W. verfasserin aut The effect of pressure on metastable phase formation in the undercooled Bi-Sn system 1988 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chapman and Hall Ltd. 1988 Abstract A metastable phase was produced by the solidification of highly undercooled Bi-48.6 at% Sn alloy droplet samples. During heating the metastable phase was observed to melt at 116° C at ambient pressure. The onset of the metastable endotherm was found to increase with increasing pressure, while the liquidus and eutectic temperature for the structure stable at ambient pressure decreased with increasing pressure. Based on the pressure dependence of the melting trend, the metastable phase will be stable at the expense of the stable ambient pressure structure under high hydrostatic pressure conditions (above ∼ 1 GPa). Both microstructural observations and X-ray examinations at ambient pressure revealed that the metastable phase was present in droplet samples and that the X-ray diffraction pattern was close to that of the high-pressure stable phase previously reported as a rhombic cell. High-pressure thermal analysis has also allowed for identification of the effect of pressure in promoting favourable formation kinetics and the kinetic transition from the equilibrium phases to the metastable phase at high undercooling. Hydrostatic Pressure Ambient Pressure Metastable Phase Eutectic Temperature High Hydrostatic Pressure Perepezko, J. H. aut Enthalten in Journal of materials science Kluwer Academic Publishers, 1966 23(1988), 12 vom: Dez., Seite 4300-4306 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:23 year:1988 number:12 month:12 pages:4300-4306 https://doi.org/10.1007/BF00551923 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_11 GBV_ILN_20 GBV_ILN_23 GBV_ILN_30 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2057 GBV_ILN_2333 GBV_ILN_4082 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4316 GBV_ILN_4319 GBV_ILN_4323 GBV_ILN_4700 AR 23 1988 12 12 4300-4306 |
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10.1007/BF00551923 doi (DE-627)OLC204615763X (DE-He213)BF00551923-p DE-627 ger DE-627 rakwb eng 670 VZ Yoon, W. verfasserin aut The effect of pressure on metastable phase formation in the undercooled Bi-Sn system 1988 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chapman and Hall Ltd. 1988 Abstract A metastable phase was produced by the solidification of highly undercooled Bi-48.6 at% Sn alloy droplet samples. During heating the metastable phase was observed to melt at 116° C at ambient pressure. The onset of the metastable endotherm was found to increase with increasing pressure, while the liquidus and eutectic temperature for the structure stable at ambient pressure decreased with increasing pressure. Based on the pressure dependence of the melting trend, the metastable phase will be stable at the expense of the stable ambient pressure structure under high hydrostatic pressure conditions (above ∼ 1 GPa). Both microstructural observations and X-ray examinations at ambient pressure revealed that the metastable phase was present in droplet samples and that the X-ray diffraction pattern was close to that of the high-pressure stable phase previously reported as a rhombic cell. High-pressure thermal analysis has also allowed for identification of the effect of pressure in promoting favourable formation kinetics and the kinetic transition from the equilibrium phases to the metastable phase at high undercooling. Hydrostatic Pressure Ambient Pressure Metastable Phase Eutectic Temperature High Hydrostatic Pressure Perepezko, J. H. aut Enthalten in Journal of materials science Kluwer Academic Publishers, 1966 23(1988), 12 vom: Dez., Seite 4300-4306 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:23 year:1988 number:12 month:12 pages:4300-4306 https://doi.org/10.1007/BF00551923 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_11 GBV_ILN_20 GBV_ILN_23 GBV_ILN_30 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2057 GBV_ILN_2333 GBV_ILN_4082 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4316 GBV_ILN_4319 GBV_ILN_4323 GBV_ILN_4700 AR 23 1988 12 12 4300-4306 |
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10.1007/BF00551923 doi (DE-627)OLC204615763X (DE-He213)BF00551923-p DE-627 ger DE-627 rakwb eng 670 VZ Yoon, W. verfasserin aut The effect of pressure on metastable phase formation in the undercooled Bi-Sn system 1988 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chapman and Hall Ltd. 1988 Abstract A metastable phase was produced by the solidification of highly undercooled Bi-48.6 at% Sn alloy droplet samples. During heating the metastable phase was observed to melt at 116° C at ambient pressure. The onset of the metastable endotherm was found to increase with increasing pressure, while the liquidus and eutectic temperature for the structure stable at ambient pressure decreased with increasing pressure. Based on the pressure dependence of the melting trend, the metastable phase will be stable at the expense of the stable ambient pressure structure under high hydrostatic pressure conditions (above ∼ 1 GPa). Both microstructural observations and X-ray examinations at ambient pressure revealed that the metastable phase was present in droplet samples and that the X-ray diffraction pattern was close to that of the high-pressure stable phase previously reported as a rhombic cell. High-pressure thermal analysis has also allowed for identification of the effect of pressure in promoting favourable formation kinetics and the kinetic transition from the equilibrium phases to the metastable phase at high undercooling. Hydrostatic Pressure Ambient Pressure Metastable Phase Eutectic Temperature High Hydrostatic Pressure Perepezko, J. H. aut Enthalten in Journal of materials science Kluwer Academic Publishers, 1966 23(1988), 12 vom: Dez., Seite 4300-4306 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:23 year:1988 number:12 month:12 pages:4300-4306 https://doi.org/10.1007/BF00551923 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_11 GBV_ILN_20 GBV_ILN_23 GBV_ILN_30 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2057 GBV_ILN_2333 GBV_ILN_4082 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4316 GBV_ILN_4319 GBV_ILN_4323 GBV_ILN_4700 AR 23 1988 12 12 4300-4306 |
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10.1007/BF00551923 doi (DE-627)OLC204615763X (DE-He213)BF00551923-p DE-627 ger DE-627 rakwb eng 670 VZ Yoon, W. verfasserin aut The effect of pressure on metastable phase formation in the undercooled Bi-Sn system 1988 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chapman and Hall Ltd. 1988 Abstract A metastable phase was produced by the solidification of highly undercooled Bi-48.6 at% Sn alloy droplet samples. During heating the metastable phase was observed to melt at 116° C at ambient pressure. The onset of the metastable endotherm was found to increase with increasing pressure, while the liquidus and eutectic temperature for the structure stable at ambient pressure decreased with increasing pressure. Based on the pressure dependence of the melting trend, the metastable phase will be stable at the expense of the stable ambient pressure structure under high hydrostatic pressure conditions (above ∼ 1 GPa). Both microstructural observations and X-ray examinations at ambient pressure revealed that the metastable phase was present in droplet samples and that the X-ray diffraction pattern was close to that of the high-pressure stable phase previously reported as a rhombic cell. High-pressure thermal analysis has also allowed for identification of the effect of pressure in promoting favourable formation kinetics and the kinetic transition from the equilibrium phases to the metastable phase at high undercooling. Hydrostatic Pressure Ambient Pressure Metastable Phase Eutectic Temperature High Hydrostatic Pressure Perepezko, J. H. aut Enthalten in Journal of materials science Kluwer Academic Publishers, 1966 23(1988), 12 vom: Dez., Seite 4300-4306 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:23 year:1988 number:12 month:12 pages:4300-4306 https://doi.org/10.1007/BF00551923 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_11 GBV_ILN_20 GBV_ILN_23 GBV_ILN_30 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2057 GBV_ILN_2333 GBV_ILN_4082 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4316 GBV_ILN_4319 GBV_ILN_4323 GBV_ILN_4700 AR 23 1988 12 12 4300-4306 |
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10.1007/BF00551923 doi (DE-627)OLC204615763X (DE-He213)BF00551923-p DE-627 ger DE-627 rakwb eng 670 VZ Yoon, W. verfasserin aut The effect of pressure on metastable phase formation in the undercooled Bi-Sn system 1988 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chapman and Hall Ltd. 1988 Abstract A metastable phase was produced by the solidification of highly undercooled Bi-48.6 at% Sn alloy droplet samples. During heating the metastable phase was observed to melt at 116° C at ambient pressure. The onset of the metastable endotherm was found to increase with increasing pressure, while the liquidus and eutectic temperature for the structure stable at ambient pressure decreased with increasing pressure. Based on the pressure dependence of the melting trend, the metastable phase will be stable at the expense of the stable ambient pressure structure under high hydrostatic pressure conditions (above ∼ 1 GPa). Both microstructural observations and X-ray examinations at ambient pressure revealed that the metastable phase was present in droplet samples and that the X-ray diffraction pattern was close to that of the high-pressure stable phase previously reported as a rhombic cell. High-pressure thermal analysis has also allowed for identification of the effect of pressure in promoting favourable formation kinetics and the kinetic transition from the equilibrium phases to the metastable phase at high undercooling. Hydrostatic Pressure Ambient Pressure Metastable Phase Eutectic Temperature High Hydrostatic Pressure Perepezko, J. H. aut Enthalten in Journal of materials science Kluwer Academic Publishers, 1966 23(1988), 12 vom: Dez., Seite 4300-4306 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:23 year:1988 number:12 month:12 pages:4300-4306 https://doi.org/10.1007/BF00551923 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_11 GBV_ILN_20 GBV_ILN_23 GBV_ILN_30 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2057 GBV_ILN_2333 GBV_ILN_4082 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4316 GBV_ILN_4319 GBV_ILN_4323 GBV_ILN_4700 AR 23 1988 12 12 4300-4306 |
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Enthalten in Journal of materials science 23(1988), 12 vom: Dez., Seite 4300-4306 volume:23 year:1988 number:12 month:12 pages:4300-4306 |
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Enthalten in Journal of materials science 23(1988), 12 vom: Dez., Seite 4300-4306 volume:23 year:1988 number:12 month:12 pages:4300-4306 |
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the effect of pressure on metastable phase formation in the undercooled bi-sn system |
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The effect of pressure on metastable phase formation in the undercooled Bi-Sn system |
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Abstract A metastable phase was produced by the solidification of highly undercooled Bi-48.6 at% Sn alloy droplet samples. During heating the metastable phase was observed to melt at 116° C at ambient pressure. The onset of the metastable endotherm was found to increase with increasing pressure, while the liquidus and eutectic temperature for the structure stable at ambient pressure decreased with increasing pressure. Based on the pressure dependence of the melting trend, the metastable phase will be stable at the expense of the stable ambient pressure structure under high hydrostatic pressure conditions (above ∼ 1 GPa). Both microstructural observations and X-ray examinations at ambient pressure revealed that the metastable phase was present in droplet samples and that the X-ray diffraction pattern was close to that of the high-pressure stable phase previously reported as a rhombic cell. High-pressure thermal analysis has also allowed for identification of the effect of pressure in promoting favourable formation kinetics and the kinetic transition from the equilibrium phases to the metastable phase at high undercooling. © Chapman and Hall Ltd. 1988 |
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Abstract A metastable phase was produced by the solidification of highly undercooled Bi-48.6 at% Sn alloy droplet samples. During heating the metastable phase was observed to melt at 116° C at ambient pressure. The onset of the metastable endotherm was found to increase with increasing pressure, while the liquidus and eutectic temperature for the structure stable at ambient pressure decreased with increasing pressure. Based on the pressure dependence of the melting trend, the metastable phase will be stable at the expense of the stable ambient pressure structure under high hydrostatic pressure conditions (above ∼ 1 GPa). Both microstructural observations and X-ray examinations at ambient pressure revealed that the metastable phase was present in droplet samples and that the X-ray diffraction pattern was close to that of the high-pressure stable phase previously reported as a rhombic cell. High-pressure thermal analysis has also allowed for identification of the effect of pressure in promoting favourable formation kinetics and the kinetic transition from the equilibrium phases to the metastable phase at high undercooling. © Chapman and Hall Ltd. 1988 |
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Abstract A metastable phase was produced by the solidification of highly undercooled Bi-48.6 at% Sn alloy droplet samples. During heating the metastable phase was observed to melt at 116° C at ambient pressure. The onset of the metastable endotherm was found to increase with increasing pressure, while the liquidus and eutectic temperature for the structure stable at ambient pressure decreased with increasing pressure. Based on the pressure dependence of the melting trend, the metastable phase will be stable at the expense of the stable ambient pressure structure under high hydrostatic pressure conditions (above ∼ 1 GPa). Both microstructural observations and X-ray examinations at ambient pressure revealed that the metastable phase was present in droplet samples and that the X-ray diffraction pattern was close to that of the high-pressure stable phase previously reported as a rhombic cell. High-pressure thermal analysis has also allowed for identification of the effect of pressure in promoting favourable formation kinetics and the kinetic transition from the equilibrium phases to the metastable phase at high undercooling. © Chapman and Hall Ltd. 1988 |
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