Synthesis and characterization of new bimetallic transition metal oxynitrides: $ M_{I} $-$ M_{II} $-O-N ($ M_{I} $, $ M_{II} $=V, Mo, W and Nb)
Abstract A new class of materials, $ M_{I} $-$ M_{II} $-O-N (where $ M_{I} $, $ M_{II} $ = V, Mo, W, and Nb), has been synthesized by nitriding bimetallic oxide precursors with ammonia gas via a temperature programmed reaction. The oxide precursors are prepared by conventional solid state reaction b...
Ausführliche Beschreibung
Autor*in: |
Yu, C. C. [verfasserIn] |
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Format: |
Artikel |
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Sprache: |
Englisch |
Erschienen: |
1995 |
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Schlagwörter: |
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Anmerkung: |
© Chapman & Hall 1995 |
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Übergeordnetes Werk: |
Enthalten in: Journal of materials science - Kluwer Academic Publishers-Plenum Publishers, 1966, 30(1995), 16 vom: Aug., Seite 4037-4042 |
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Übergeordnetes Werk: |
volume:30 ; year:1995 ; number:16 ; month:08 ; pages:4037-4042 |
Links: |
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DOI / URN: |
10.1007/BF00360706 |
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Katalog-ID: |
OLC2046220358 |
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245 | 1 | 0 | |a Synthesis and characterization of new bimetallic transition metal oxynitrides: $ M_{I} $-$ M_{II} $-O-N ($ M_{I} $, $ M_{II} $=V, Mo, W and Nb) |
264 | 1 | |c 1995 | |
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520 | |a Abstract A new class of materials, $ M_{I} $-$ M_{II} $-O-N (where $ M_{I} $, $ M_{II} $ = V, Mo, W, and Nb), has been synthesized by nitriding bimetallic oxide precursors with ammonia gas via a temperature programmed reaction. The oxide precursors are prepared by conventional solid state reaction between two appropriate monometallic oxides. The synthesis of the oxynitrides involves passing $ NH_{3} $ gas over the oxide precursors at a flow rate of 6.80×$ 10^{2} $ $ μmols^{−1} $ (1000 $ cm^{3} $ $ min^{−1} $), and raising the temperature at a rate of 8.3×$ 10^{−2} $ $ Ks^{−1} $ (5K $ min^{−1} $) to a final temperature which is held constant for a short period of time. The oxynitrides thus obtained are pyrophoric and need to be passivated before exposing them to air. All these new bimetallic oxynitrides have a face centered cubic (f.c.c.) metal arrangement and high values of surface area. Their surface activity is assessed from their ability to chemisorb CO. | ||
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10.1007/BF00360706 doi (DE-627)OLC2046220358 (DE-He213)BF00360706-p DE-627 ger DE-627 rakwb eng 670 VZ Yu, C. C. verfasserin aut Synthesis and characterization of new bimetallic transition metal oxynitrides: $ M_{I} $-$ M_{II} $-O-N ($ M_{I} $, $ M_{II} $=V, Mo, W and Nb) 1995 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chapman & Hall 1995 Abstract A new class of materials, $ M_{I} $-$ M_{II} $-O-N (where $ M_{I} $, $ M_{II} $ = V, Mo, W, and Nb), has been synthesized by nitriding bimetallic oxide precursors with ammonia gas via a temperature programmed reaction. The oxide precursors are prepared by conventional solid state reaction between two appropriate monometallic oxides. The synthesis of the oxynitrides involves passing $ NH_{3} $ gas over the oxide precursors at a flow rate of 6.80×$ 10^{2} $ $ μmols^{−1} $ (1000 $ cm^{3} $ $ min^{−1} $), and raising the temperature at a rate of 8.3×$ 10^{−2} $ $ Ks^{−1} $ (5K $ min^{−1} $) to a final temperature which is held constant for a short period of time. The oxynitrides thus obtained are pyrophoric and need to be passivated before exposing them to air. All these new bimetallic oxynitrides have a face centered cubic (f.c.c.) metal arrangement and high values of surface area. Their surface activity is assessed from their ability to chemisorb CO. Polymer Solid State Surface Activity Material Processing Solid State Reaction Oyama, S. T. aut Enthalten in Journal of materials science Kluwer Academic Publishers-Plenum Publishers, 1966 30(1995), 16 vom: Aug., Seite 4037-4042 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:30 year:1995 number:16 month:08 pages:4037-4042 https://doi.org/10.1007/BF00360706 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_11 GBV_ILN_20 GBV_ILN_23 GBV_ILN_24 GBV_ILN_30 GBV_ILN_32 GBV_ILN_40 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_4082 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4316 GBV_ILN_4319 GBV_ILN_4323 GBV_ILN_4700 AR 30 1995 16 08 4037-4042 |
spelling |
10.1007/BF00360706 doi (DE-627)OLC2046220358 (DE-He213)BF00360706-p DE-627 ger DE-627 rakwb eng 670 VZ Yu, C. C. verfasserin aut Synthesis and characterization of new bimetallic transition metal oxynitrides: $ M_{I} $-$ M_{II} $-O-N ($ M_{I} $, $ M_{II} $=V, Mo, W and Nb) 1995 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chapman & Hall 1995 Abstract A new class of materials, $ M_{I} $-$ M_{II} $-O-N (where $ M_{I} $, $ M_{II} $ = V, Mo, W, and Nb), has been synthesized by nitriding bimetallic oxide precursors with ammonia gas via a temperature programmed reaction. The oxide precursors are prepared by conventional solid state reaction between two appropriate monometallic oxides. The synthesis of the oxynitrides involves passing $ NH_{3} $ gas over the oxide precursors at a flow rate of 6.80×$ 10^{2} $ $ μmols^{−1} $ (1000 $ cm^{3} $ $ min^{−1} $), and raising the temperature at a rate of 8.3×$ 10^{−2} $ $ Ks^{−1} $ (5K $ min^{−1} $) to a final temperature which is held constant for a short period of time. The oxynitrides thus obtained are pyrophoric and need to be passivated before exposing them to air. All these new bimetallic oxynitrides have a face centered cubic (f.c.c.) metal arrangement and high values of surface area. Their surface activity is assessed from their ability to chemisorb CO. Polymer Solid State Surface Activity Material Processing Solid State Reaction Oyama, S. T. aut Enthalten in Journal of materials science Kluwer Academic Publishers-Plenum Publishers, 1966 30(1995), 16 vom: Aug., Seite 4037-4042 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:30 year:1995 number:16 month:08 pages:4037-4042 https://doi.org/10.1007/BF00360706 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_11 GBV_ILN_20 GBV_ILN_23 GBV_ILN_24 GBV_ILN_30 GBV_ILN_32 GBV_ILN_40 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_4082 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4316 GBV_ILN_4319 GBV_ILN_4323 GBV_ILN_4700 AR 30 1995 16 08 4037-4042 |
allfields_unstemmed |
10.1007/BF00360706 doi (DE-627)OLC2046220358 (DE-He213)BF00360706-p DE-627 ger DE-627 rakwb eng 670 VZ Yu, C. C. verfasserin aut Synthesis and characterization of new bimetallic transition metal oxynitrides: $ M_{I} $-$ M_{II} $-O-N ($ M_{I} $, $ M_{II} $=V, Mo, W and Nb) 1995 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chapman & Hall 1995 Abstract A new class of materials, $ M_{I} $-$ M_{II} $-O-N (where $ M_{I} $, $ M_{II} $ = V, Mo, W, and Nb), has been synthesized by nitriding bimetallic oxide precursors with ammonia gas via a temperature programmed reaction. The oxide precursors are prepared by conventional solid state reaction between two appropriate monometallic oxides. The synthesis of the oxynitrides involves passing $ NH_{3} $ gas over the oxide precursors at a flow rate of 6.80×$ 10^{2} $ $ μmols^{−1} $ (1000 $ cm^{3} $ $ min^{−1} $), and raising the temperature at a rate of 8.3×$ 10^{−2} $ $ Ks^{−1} $ (5K $ min^{−1} $) to a final temperature which is held constant for a short period of time. The oxynitrides thus obtained are pyrophoric and need to be passivated before exposing them to air. All these new bimetallic oxynitrides have a face centered cubic (f.c.c.) metal arrangement and high values of surface area. Their surface activity is assessed from their ability to chemisorb CO. Polymer Solid State Surface Activity Material Processing Solid State Reaction Oyama, S. T. aut Enthalten in Journal of materials science Kluwer Academic Publishers-Plenum Publishers, 1966 30(1995), 16 vom: Aug., Seite 4037-4042 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:30 year:1995 number:16 month:08 pages:4037-4042 https://doi.org/10.1007/BF00360706 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_11 GBV_ILN_20 GBV_ILN_23 GBV_ILN_24 GBV_ILN_30 GBV_ILN_32 GBV_ILN_40 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_4082 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4316 GBV_ILN_4319 GBV_ILN_4323 GBV_ILN_4700 AR 30 1995 16 08 4037-4042 |
allfieldsGer |
10.1007/BF00360706 doi (DE-627)OLC2046220358 (DE-He213)BF00360706-p DE-627 ger DE-627 rakwb eng 670 VZ Yu, C. C. verfasserin aut Synthesis and characterization of new bimetallic transition metal oxynitrides: $ M_{I} $-$ M_{II} $-O-N ($ M_{I} $, $ M_{II} $=V, Mo, W and Nb) 1995 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chapman & Hall 1995 Abstract A new class of materials, $ M_{I} $-$ M_{II} $-O-N (where $ M_{I} $, $ M_{II} $ = V, Mo, W, and Nb), has been synthesized by nitriding bimetallic oxide precursors with ammonia gas via a temperature programmed reaction. The oxide precursors are prepared by conventional solid state reaction between two appropriate monometallic oxides. The synthesis of the oxynitrides involves passing $ NH_{3} $ gas over the oxide precursors at a flow rate of 6.80×$ 10^{2} $ $ μmols^{−1} $ (1000 $ cm^{3} $ $ min^{−1} $), and raising the temperature at a rate of 8.3×$ 10^{−2} $ $ Ks^{−1} $ (5K $ min^{−1} $) to a final temperature which is held constant for a short period of time. The oxynitrides thus obtained are pyrophoric and need to be passivated before exposing them to air. All these new bimetallic oxynitrides have a face centered cubic (f.c.c.) metal arrangement and high values of surface area. Their surface activity is assessed from their ability to chemisorb CO. Polymer Solid State Surface Activity Material Processing Solid State Reaction Oyama, S. T. aut Enthalten in Journal of materials science Kluwer Academic Publishers-Plenum Publishers, 1966 30(1995), 16 vom: Aug., Seite 4037-4042 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:30 year:1995 number:16 month:08 pages:4037-4042 https://doi.org/10.1007/BF00360706 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_11 GBV_ILN_20 GBV_ILN_23 GBV_ILN_24 GBV_ILN_30 GBV_ILN_32 GBV_ILN_40 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_4082 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4316 GBV_ILN_4319 GBV_ILN_4323 GBV_ILN_4700 AR 30 1995 16 08 4037-4042 |
allfieldsSound |
10.1007/BF00360706 doi (DE-627)OLC2046220358 (DE-He213)BF00360706-p DE-627 ger DE-627 rakwb eng 670 VZ Yu, C. C. verfasserin aut Synthesis and characterization of new bimetallic transition metal oxynitrides: $ M_{I} $-$ M_{II} $-O-N ($ M_{I} $, $ M_{II} $=V, Mo, W and Nb) 1995 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chapman & Hall 1995 Abstract A new class of materials, $ M_{I} $-$ M_{II} $-O-N (where $ M_{I} $, $ M_{II} $ = V, Mo, W, and Nb), has been synthesized by nitriding bimetallic oxide precursors with ammonia gas via a temperature programmed reaction. The oxide precursors are prepared by conventional solid state reaction between two appropriate monometallic oxides. The synthesis of the oxynitrides involves passing $ NH_{3} $ gas over the oxide precursors at a flow rate of 6.80×$ 10^{2} $ $ μmols^{−1} $ (1000 $ cm^{3} $ $ min^{−1} $), and raising the temperature at a rate of 8.3×$ 10^{−2} $ $ Ks^{−1} $ (5K $ min^{−1} $) to a final temperature which is held constant for a short period of time. The oxynitrides thus obtained are pyrophoric and need to be passivated before exposing them to air. All these new bimetallic oxynitrides have a face centered cubic (f.c.c.) metal arrangement and high values of surface area. Their surface activity is assessed from their ability to chemisorb CO. Polymer Solid State Surface Activity Material Processing Solid State Reaction Oyama, S. T. aut Enthalten in Journal of materials science Kluwer Academic Publishers-Plenum Publishers, 1966 30(1995), 16 vom: Aug., Seite 4037-4042 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:30 year:1995 number:16 month:08 pages:4037-4042 https://doi.org/10.1007/BF00360706 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_11 GBV_ILN_20 GBV_ILN_23 GBV_ILN_24 GBV_ILN_30 GBV_ILN_32 GBV_ILN_40 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_4082 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4316 GBV_ILN_4319 GBV_ILN_4323 GBV_ILN_4700 AR 30 1995 16 08 4037-4042 |
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Enthalten in Journal of materials science 30(1995), 16 vom: Aug., Seite 4037-4042 volume:30 year:1995 number:16 month:08 pages:4037-4042 |
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Yu, C. C. |
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Yu, C. C. ddc 670 misc Polymer misc Solid State misc Surface Activity misc Material Processing misc Solid State Reaction Synthesis and characterization of new bimetallic transition metal oxynitrides: $ M_{I} $-$ M_{II} $-O-N ($ M_{I} $, $ M_{II} $=V, Mo, W and Nb) |
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Synthesis and characterization of new bimetallic transition metal oxynitrides: $ M_{I} $-$ M_{II} $-O-N ($ M_{I} $, $ M_{II} $=V, Mo, W and Nb) |
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Synthesis and characterization of new bimetallic transition metal oxynitrides: $ M_{I} $-$ M_{II} $-O-N ($ M_{I} $, $ M_{II} $=V, Mo, W and Nb) |
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synthesis and characterization of new bimetallic transition metal oxynitrides: $ m_{i} $-$ m_{ii} $-o-n ($ m_{i} $, $ m_{ii} $=v, mo, w and nb) |
title_auth |
Synthesis and characterization of new bimetallic transition metal oxynitrides: $ M_{I} $-$ M_{II} $-O-N ($ M_{I} $, $ M_{II} $=V, Mo, W and Nb) |
abstract |
Abstract A new class of materials, $ M_{I} $-$ M_{II} $-O-N (where $ M_{I} $, $ M_{II} $ = V, Mo, W, and Nb), has been synthesized by nitriding bimetallic oxide precursors with ammonia gas via a temperature programmed reaction. The oxide precursors are prepared by conventional solid state reaction between two appropriate monometallic oxides. The synthesis of the oxynitrides involves passing $ NH_{3} $ gas over the oxide precursors at a flow rate of 6.80×$ 10^{2} $ $ μmols^{−1} $ (1000 $ cm^{3} $ $ min^{−1} $), and raising the temperature at a rate of 8.3×$ 10^{−2} $ $ Ks^{−1} $ (5K $ min^{−1} $) to a final temperature which is held constant for a short period of time. The oxynitrides thus obtained are pyrophoric and need to be passivated before exposing them to air. All these new bimetallic oxynitrides have a face centered cubic (f.c.c.) metal arrangement and high values of surface area. Their surface activity is assessed from their ability to chemisorb CO. © Chapman & Hall 1995 |
abstractGer |
Abstract A new class of materials, $ M_{I} $-$ M_{II} $-O-N (where $ M_{I} $, $ M_{II} $ = V, Mo, W, and Nb), has been synthesized by nitriding bimetallic oxide precursors with ammonia gas via a temperature programmed reaction. The oxide precursors are prepared by conventional solid state reaction between two appropriate monometallic oxides. The synthesis of the oxynitrides involves passing $ NH_{3} $ gas over the oxide precursors at a flow rate of 6.80×$ 10^{2} $ $ μmols^{−1} $ (1000 $ cm^{3} $ $ min^{−1} $), and raising the temperature at a rate of 8.3×$ 10^{−2} $ $ Ks^{−1} $ (5K $ min^{−1} $) to a final temperature which is held constant for a short period of time. The oxynitrides thus obtained are pyrophoric and need to be passivated before exposing them to air. All these new bimetallic oxynitrides have a face centered cubic (f.c.c.) metal arrangement and high values of surface area. Their surface activity is assessed from their ability to chemisorb CO. © Chapman & Hall 1995 |
abstract_unstemmed |
Abstract A new class of materials, $ M_{I} $-$ M_{II} $-O-N (where $ M_{I} $, $ M_{II} $ = V, Mo, W, and Nb), has been synthesized by nitriding bimetallic oxide precursors with ammonia gas via a temperature programmed reaction. The oxide precursors are prepared by conventional solid state reaction between two appropriate monometallic oxides. The synthesis of the oxynitrides involves passing $ NH_{3} $ gas over the oxide precursors at a flow rate of 6.80×$ 10^{2} $ $ μmols^{−1} $ (1000 $ cm^{3} $ $ min^{−1} $), and raising the temperature at a rate of 8.3×$ 10^{−2} $ $ Ks^{−1} $ (5K $ min^{−1} $) to a final temperature which is held constant for a short period of time. The oxynitrides thus obtained are pyrophoric and need to be passivated before exposing them to air. All these new bimetallic oxynitrides have a face centered cubic (f.c.c.) metal arrangement and high values of surface area. Their surface activity is assessed from their ability to chemisorb CO. © Chapman & Hall 1995 |
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Synthesis and characterization of new bimetallic transition metal oxynitrides: $ M_{I} $-$ M_{II} $-O-N ($ M_{I} $, $ M_{II} $=V, Mo, W and Nb) |
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