Crystallization kinetics of fluorophosphate glasses: Part I Effect of composition and heating rate

Abstract Crystallization behaviour of glasses from the system AlF3-MF2-Ba(PO3)2 (M=Ca, Mg, Sr, Ba) have been studied using differential thermal analysis as a function of Ba(PO3)2. The kinetic parameters for crystallization, namely, the activation energy, E, frequency factor, ν, and Avrami exponent,...
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Gespeichert in:

Autor*in:	OZTURK, A [verfasserIn]

Format:	Artikel
Sprache:	Englisch

Erschienen:	1997

Schlagwörter:	Crystallization Crystallization Behaviour Crystallization Kinetic High Heating Rate Surface Crystallization

Anmerkung:	© Chapman and Hall 1997

Übergeordnetes Werk:	Enthalten in: Journal of materials science - Kluwer Academic Publishers, 1966, 32(1997), 10 vom: Mai, Seite 2623-2627
Übergeordnetes Werk:	volume:32 ; year:1997 ; number:10 ; month:05 ; pages:2623-2627

Links:	Volltext

DOI / URN:	10.1023/A:1018662703668

Katalog-ID:	OLC204623619X

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520			\|a Abstract Crystallization behaviour of glasses from the system AlF3-MF2-Ba(PO3)2 (M=Ca, Mg, Sr, Ba) have been studied using differential thermal analysis as a function of Ba(PO3)2. The kinetic parameters for crystallization, namely, the activation energy, E, frequency factor, ν, and Avrami exponent, n, were determined. E, ν and n decreased with increasing Ba(PO3)2. Crystallization commenced at higher temperatures and the crystal growth mechanism changed from bulk to surface with increasing Ba(PO3)2. X-ray diffraction analysis revealed that CaAlF5, SrAlF5, CaAlF7 and CaSrAlF7 crystallize from these glasses when heated. The infrared transmission spectra indicated that AlF6, PO3F and Ba(Ca,Mg,Sr)P2O7 groups were present in these glasses.
650		4	\|a Crystallization
650		4	\|a Crystallization Behaviour
650		4	\|a Crystallization Kinetic
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650		4	\|a Surface Crystallization
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allfields	10.1023/A:1018662703668 doi (DE-627)OLC204623619X (DE-He213)A:1018662703668-p DE-627 ger DE-627 rakwb eng 670 VZ OZTURK, A verfasserin aut Crystallization kinetics of fluorophosphate glasses: Part I Effect of composition and heating rate 1997 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chapman and Hall 1997 Abstract Crystallization behaviour of glasses from the system AlF3-MF2-Ba(PO3)2 (M=Ca, Mg, Sr, Ba) have been studied using differential thermal analysis as a function of Ba(PO3)2. The kinetic parameters for crystallization, namely, the activation energy, E, frequency factor, ν, and Avrami exponent, n, were determined. E, ν and n decreased with increasing Ba(PO3)2. Crystallization commenced at higher temperatures and the crystal growth mechanism changed from bulk to surface with increasing Ba(PO3)2. X-ray diffraction analysis revealed that CaAlF5, SrAlF5, CaAlF7 and CaSrAlF7 crystallize from these glasses when heated. The infrared transmission spectra indicated that AlF6, PO3F and Ba(Ca,Mg,Sr)P2O7 groups were present in these glasses. Crystallization Crystallization Behaviour Crystallization Kinetic High Heating Rate Surface Crystallization Enthalten in Journal of materials science Kluwer Academic Publishers, 1966 32(1997), 10 vom: Mai, Seite 2623-2627 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:32 year:1997 number:10 month:05 pages:2623-2627 https://doi.org/10.1023/A:1018662703668 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_11 GBV_ILN_20 GBV_ILN_23 GBV_ILN_24 GBV_ILN_30 GBV_ILN_32 GBV_ILN_40 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4316 GBV_ILN_4319 GBV_ILN_4323 GBV_ILN_4700 AR 32 1997 10 05 2623-2627
spelling	10.1023/A:1018662703668 doi (DE-627)OLC204623619X (DE-He213)A:1018662703668-p DE-627 ger DE-627 rakwb eng 670 VZ OZTURK, A verfasserin aut Crystallization kinetics of fluorophosphate glasses: Part I Effect of composition and heating rate 1997 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chapman and Hall 1997 Abstract Crystallization behaviour of glasses from the system AlF3-MF2-Ba(PO3)2 (M=Ca, Mg, Sr, Ba) have been studied using differential thermal analysis as a function of Ba(PO3)2. The kinetic parameters for crystallization, namely, the activation energy, E, frequency factor, ν, and Avrami exponent, n, were determined. E, ν and n decreased with increasing Ba(PO3)2. Crystallization commenced at higher temperatures and the crystal growth mechanism changed from bulk to surface with increasing Ba(PO3)2. X-ray diffraction analysis revealed that CaAlF5, SrAlF5, CaAlF7 and CaSrAlF7 crystallize from these glasses when heated. The infrared transmission spectra indicated that AlF6, PO3F and Ba(Ca,Mg,Sr)P2O7 groups were present in these glasses. Crystallization Crystallization Behaviour Crystallization Kinetic High Heating Rate Surface Crystallization Enthalten in Journal of materials science Kluwer Academic Publishers, 1966 32(1997), 10 vom: Mai, Seite 2623-2627 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:32 year:1997 number:10 month:05 pages:2623-2627 https://doi.org/10.1023/A:1018662703668 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_11 GBV_ILN_20 GBV_ILN_23 GBV_ILN_24 GBV_ILN_30 GBV_ILN_32 GBV_ILN_40 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4316 GBV_ILN_4319 GBV_ILN_4323 GBV_ILN_4700 AR 32 1997 10 05 2623-2627
allfields_unstemmed	10.1023/A:1018662703668 doi (DE-627)OLC204623619X (DE-He213)A:1018662703668-p DE-627 ger DE-627 rakwb eng 670 VZ OZTURK, A verfasserin aut Crystallization kinetics of fluorophosphate glasses: Part I Effect of composition and heating rate 1997 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chapman and Hall 1997 Abstract Crystallization behaviour of glasses from the system AlF3-MF2-Ba(PO3)2 (M=Ca, Mg, Sr, Ba) have been studied using differential thermal analysis as a function of Ba(PO3)2. The kinetic parameters for crystallization, namely, the activation energy, E, frequency factor, ν, and Avrami exponent, n, were determined. E, ν and n decreased with increasing Ba(PO3)2. Crystallization commenced at higher temperatures and the crystal growth mechanism changed from bulk to surface with increasing Ba(PO3)2. X-ray diffraction analysis revealed that CaAlF5, SrAlF5, CaAlF7 and CaSrAlF7 crystallize from these glasses when heated. The infrared transmission spectra indicated that AlF6, PO3F and Ba(Ca,Mg,Sr)P2O7 groups were present in these glasses. Crystallization Crystallization Behaviour Crystallization Kinetic High Heating Rate Surface Crystallization Enthalten in Journal of materials science Kluwer Academic Publishers, 1966 32(1997), 10 vom: Mai, Seite 2623-2627 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:32 year:1997 number:10 month:05 pages:2623-2627 https://doi.org/10.1023/A:1018662703668 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_11 GBV_ILN_20 GBV_ILN_23 GBV_ILN_24 GBV_ILN_30 GBV_ILN_32 GBV_ILN_40 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4316 GBV_ILN_4319 GBV_ILN_4323 GBV_ILN_4700 AR 32 1997 10 05 2623-2627
allfieldsGer	10.1023/A:1018662703668 doi (DE-627)OLC204623619X (DE-He213)A:1018662703668-p DE-627 ger DE-627 rakwb eng 670 VZ OZTURK, A verfasserin aut Crystallization kinetics of fluorophosphate glasses: Part I Effect of composition and heating rate 1997 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chapman and Hall 1997 Abstract Crystallization behaviour of glasses from the system AlF3-MF2-Ba(PO3)2 (M=Ca, Mg, Sr, Ba) have been studied using differential thermal analysis as a function of Ba(PO3)2. The kinetic parameters for crystallization, namely, the activation energy, E, frequency factor, ν, and Avrami exponent, n, were determined. E, ν and n decreased with increasing Ba(PO3)2. Crystallization commenced at higher temperatures and the crystal growth mechanism changed from bulk to surface with increasing Ba(PO3)2. X-ray diffraction analysis revealed that CaAlF5, SrAlF5, CaAlF7 and CaSrAlF7 crystallize from these glasses when heated. The infrared transmission spectra indicated that AlF6, PO3F and Ba(Ca,Mg,Sr)P2O7 groups were present in these glasses. Crystallization Crystallization Behaviour Crystallization Kinetic High Heating Rate Surface Crystallization Enthalten in Journal of materials science Kluwer Academic Publishers, 1966 32(1997), 10 vom: Mai, Seite 2623-2627 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:32 year:1997 number:10 month:05 pages:2623-2627 https://doi.org/10.1023/A:1018662703668 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_11 GBV_ILN_20 GBV_ILN_23 GBV_ILN_24 GBV_ILN_30 GBV_ILN_32 GBV_ILN_40 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4316 GBV_ILN_4319 GBV_ILN_4323 GBV_ILN_4700 AR 32 1997 10 05 2623-2627
allfieldsSound	10.1023/A:1018662703668 doi (DE-627)OLC204623619X (DE-He213)A:1018662703668-p DE-627 ger DE-627 rakwb eng 670 VZ OZTURK, A verfasserin aut Crystallization kinetics of fluorophosphate glasses: Part I Effect of composition and heating rate 1997 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chapman and Hall 1997 Abstract Crystallization behaviour of glasses from the system AlF3-MF2-Ba(PO3)2 (M=Ca, Mg, Sr, Ba) have been studied using differential thermal analysis as a function of Ba(PO3)2. The kinetic parameters for crystallization, namely, the activation energy, E, frequency factor, ν, and Avrami exponent, n, were determined. E, ν and n decreased with increasing Ba(PO3)2. Crystallization commenced at higher temperatures and the crystal growth mechanism changed from bulk to surface with increasing Ba(PO3)2. X-ray diffraction analysis revealed that CaAlF5, SrAlF5, CaAlF7 and CaSrAlF7 crystallize from these glasses when heated. The infrared transmission spectra indicated that AlF6, PO3F and Ba(Ca,Mg,Sr)P2O7 groups were present in these glasses. Crystallization Crystallization Behaviour Crystallization Kinetic High Heating Rate Surface Crystallization Enthalten in Journal of materials science Kluwer Academic Publishers, 1966 32(1997), 10 vom: Mai, Seite 2623-2627 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:32 year:1997 number:10 month:05 pages:2623-2627 https://doi.org/10.1023/A:1018662703668 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_11 GBV_ILN_20 GBV_ILN_23 GBV_ILN_24 GBV_ILN_30 GBV_ILN_32 GBV_ILN_40 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4316 GBV_ILN_4319 GBV_ILN_4323 GBV_ILN_4700 AR 32 1997 10 05 2623-2627
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title_sort	crystallization kinetics of fluorophosphate glasses: part i effect of composition and heating rate
title_auth	Crystallization kinetics of fluorophosphate glasses: Part I Effect of composition and heating rate
abstract	Abstract Crystallization behaviour of glasses from the system AlF3-MF2-Ba(PO3)2 (M=Ca, Mg, Sr, Ba) have been studied using differential thermal analysis as a function of Ba(PO3)2. The kinetic parameters for crystallization, namely, the activation energy, E, frequency factor, ν, and Avrami exponent, n, were determined. E, ν and n decreased with increasing Ba(PO3)2. Crystallization commenced at higher temperatures and the crystal growth mechanism changed from bulk to surface with increasing Ba(PO3)2. X-ray diffraction analysis revealed that CaAlF5, SrAlF5, CaAlF7 and CaSrAlF7 crystallize from these glasses when heated. The infrared transmission spectra indicated that AlF6, PO3F and Ba(Ca,Mg,Sr)P2O7 groups were present in these glasses. © Chapman and Hall 1997
abstractGer	Abstract Crystallization behaviour of glasses from the system AlF3-MF2-Ba(PO3)2 (M=Ca, Mg, Sr, Ba) have been studied using differential thermal analysis as a function of Ba(PO3)2. The kinetic parameters for crystallization, namely, the activation energy, E, frequency factor, ν, and Avrami exponent, n, were determined. E, ν and n decreased with increasing Ba(PO3)2. Crystallization commenced at higher temperatures and the crystal growth mechanism changed from bulk to surface with increasing Ba(PO3)2. X-ray diffraction analysis revealed that CaAlF5, SrAlF5, CaAlF7 and CaSrAlF7 crystallize from these glasses when heated. The infrared transmission spectra indicated that AlF6, PO3F and Ba(Ca,Mg,Sr)P2O7 groups were present in these glasses. © Chapman and Hall 1997
abstract_unstemmed	Abstract Crystallization behaviour of glasses from the system AlF3-MF2-Ba(PO3)2 (M=Ca, Mg, Sr, Ba) have been studied using differential thermal analysis as a function of Ba(PO3)2. The kinetic parameters for crystallization, namely, the activation energy, E, frequency factor, ν, and Avrami exponent, n, were determined. E, ν and n decreased with increasing Ba(PO3)2. Crystallization commenced at higher temperatures and the crystal growth mechanism changed from bulk to surface with increasing Ba(PO3)2. X-ray diffraction analysis revealed that CaAlF5, SrAlF5, CaAlF7 and CaSrAlF7 crystallize from these glasses when heated. The infrared transmission spectra indicated that AlF6, PO3F and Ba(Ca,Mg,Sr)P2O7 groups were present in these glasses. © Chapman and Hall 1997
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container_issue	10
title_short	Crystallization kinetics of fluorophosphate glasses: Part I Effect of composition and heating rate
url	https://doi.org/10.1023/A:1018662703668
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doi_str	10.1023/A:1018662703668
up_date	2024-07-04T04:34:44.886Z
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Crystallization kinetics of fluorophosphate glasses: Part I Effect of composition and heating rate

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