Chemical stability of MgO/CaO/Cr2O3–Al2O3–B2O3–phosphate glasses in solid oxide fuel cell environment

Abstract The thermal properties, glass forming tendency and glass stability in solid oxide fuel cell (SOFC) relevant atmospheres have been determined for four different refractory MgO/CaO/Cr2O3–Al2O3–B2O3 phosphate based glasses. Also, the bonding ability and interaction as a function of temperature...
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Gespeichert in:

Autor*in:	Larsen, P. H [verfasserIn] James, P. F

Format:	Artikel
Sprache:	Englisch

Erschienen:	1998

Schlagwörter:	Polymer Phosphate Al2O3 Liquid Phase Thermal Property

Anmerkung:	© Chapman and Hall 1998

Übergeordnetes Werk:	Enthalten in: Journal of materials science - Kluwer Academic Publishers, 1966, 33(1998), 10 vom: Mai, Seite 2499-2507
Übergeordnetes Werk:	volume:33 ; year:1998 ; number:10 ; month:05 ; pages:2499-2507

Links:	Volltext

DOI / URN:	10.1023/A:1004332614379

Katalog-ID:	OLC2046244583

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allfields	10.1023/A:1004332614379 doi (DE-627)OLC2046244583 (DE-He213)A:1004332614379-p DE-627 ger DE-627 rakwb eng 670 VZ Larsen, P. H verfasserin aut Chemical stability of MgO/CaO/Cr2O3–Al2O3–B2O3–phosphate glasses in solid oxide fuel cell environment 1998 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chapman and Hall 1998 Abstract The thermal properties, glass forming tendency and glass stability in solid oxide fuel cell (SOFC) relevant atmospheres have been determined for four different refractory MgO/CaO/Cr2O3–Al2O3–B2O3 phosphate based glasses. Also, the bonding ability and interaction as a function of temperature between the glasses and La0.8Ca0.22CrO3 interconnect material have been studied. The microstructural characterization and elemental analysis of reaction couples reveal that the bonding ability and interface interaction is closely related to the CaO content and the relative glass forming tendency. The reactions at 1000°C between the glass and the solid interconnect material for the high CaO or MgO containing compositions occur by a liquid phase or a vapour phase mechanism, respectively. The reaction at 1200°C in both cases occurs by a liquid phase mechanism. © 1998 Chapman & Hall Polymer Phosphate Al2O3 Liquid Phase Thermal Property James, P. F aut Enthalten in Journal of materials science Kluwer Academic Publishers, 1966 33(1998), 10 vom: Mai, Seite 2499-2507 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:33 year:1998 number:10 month:05 pages:2499-2507 https://doi.org/10.1023/A:1004332614379 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_11 GBV_ILN_20 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_40 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4316 GBV_ILN_4319 GBV_ILN_4323 GBV_ILN_4700 AR 33 1998 10 05 2499-2507
spelling	10.1023/A:1004332614379 doi (DE-627)OLC2046244583 (DE-He213)A:1004332614379-p DE-627 ger DE-627 rakwb eng 670 VZ Larsen, P. H verfasserin aut Chemical stability of MgO/CaO/Cr2O3–Al2O3–B2O3–phosphate glasses in solid oxide fuel cell environment 1998 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chapman and Hall 1998 Abstract The thermal properties, glass forming tendency and glass stability in solid oxide fuel cell (SOFC) relevant atmospheres have been determined for four different refractory MgO/CaO/Cr2O3–Al2O3–B2O3 phosphate based glasses. Also, the bonding ability and interaction as a function of temperature between the glasses and La0.8Ca0.22CrO3 interconnect material have been studied. The microstructural characterization and elemental analysis of reaction couples reveal that the bonding ability and interface interaction is closely related to the CaO content and the relative glass forming tendency. The reactions at 1000°C between the glass and the solid interconnect material for the high CaO or MgO containing compositions occur by a liquid phase or a vapour phase mechanism, respectively. The reaction at 1200°C in both cases occurs by a liquid phase mechanism. © 1998 Chapman & Hall Polymer Phosphate Al2O3 Liquid Phase Thermal Property James, P. F aut Enthalten in Journal of materials science Kluwer Academic Publishers, 1966 33(1998), 10 vom: Mai, Seite 2499-2507 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:33 year:1998 number:10 month:05 pages:2499-2507 https://doi.org/10.1023/A:1004332614379 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_11 GBV_ILN_20 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_40 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4316 GBV_ILN_4319 GBV_ILN_4323 GBV_ILN_4700 AR 33 1998 10 05 2499-2507
allfields_unstemmed	10.1023/A:1004332614379 doi (DE-627)OLC2046244583 (DE-He213)A:1004332614379-p DE-627 ger DE-627 rakwb eng 670 VZ Larsen, P. H verfasserin aut Chemical stability of MgO/CaO/Cr2O3–Al2O3–B2O3–phosphate glasses in solid oxide fuel cell environment 1998 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chapman and Hall 1998 Abstract The thermal properties, glass forming tendency and glass stability in solid oxide fuel cell (SOFC) relevant atmospheres have been determined for four different refractory MgO/CaO/Cr2O3–Al2O3–B2O3 phosphate based glasses. Also, the bonding ability and interaction as a function of temperature between the glasses and La0.8Ca0.22CrO3 interconnect material have been studied. The microstructural characterization and elemental analysis of reaction couples reveal that the bonding ability and interface interaction is closely related to the CaO content and the relative glass forming tendency. The reactions at 1000°C between the glass and the solid interconnect material for the high CaO or MgO containing compositions occur by a liquid phase or a vapour phase mechanism, respectively. The reaction at 1200°C in both cases occurs by a liquid phase mechanism. © 1998 Chapman & Hall Polymer Phosphate Al2O3 Liquid Phase Thermal Property James, P. F aut Enthalten in Journal of materials science Kluwer Academic Publishers, 1966 33(1998), 10 vom: Mai, Seite 2499-2507 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:33 year:1998 number:10 month:05 pages:2499-2507 https://doi.org/10.1023/A:1004332614379 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_11 GBV_ILN_20 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_40 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4316 GBV_ILN_4319 GBV_ILN_4323 GBV_ILN_4700 AR 33 1998 10 05 2499-2507
allfieldsGer	10.1023/A:1004332614379 doi (DE-627)OLC2046244583 (DE-He213)A:1004332614379-p DE-627 ger DE-627 rakwb eng 670 VZ Larsen, P. H verfasserin aut Chemical stability of MgO/CaO/Cr2O3–Al2O3–B2O3–phosphate glasses in solid oxide fuel cell environment 1998 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chapman and Hall 1998 Abstract The thermal properties, glass forming tendency and glass stability in solid oxide fuel cell (SOFC) relevant atmospheres have been determined for four different refractory MgO/CaO/Cr2O3–Al2O3–B2O3 phosphate based glasses. Also, the bonding ability and interaction as a function of temperature between the glasses and La0.8Ca0.22CrO3 interconnect material have been studied. The microstructural characterization and elemental analysis of reaction couples reveal that the bonding ability and interface interaction is closely related to the CaO content and the relative glass forming tendency. The reactions at 1000°C between the glass and the solid interconnect material for the high CaO or MgO containing compositions occur by a liquid phase or a vapour phase mechanism, respectively. The reaction at 1200°C in both cases occurs by a liquid phase mechanism. © 1998 Chapman & Hall Polymer Phosphate Al2O3 Liquid Phase Thermal Property James, P. F aut Enthalten in Journal of materials science Kluwer Academic Publishers, 1966 33(1998), 10 vom: Mai, Seite 2499-2507 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:33 year:1998 number:10 month:05 pages:2499-2507 https://doi.org/10.1023/A:1004332614379 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_11 GBV_ILN_20 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_40 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4316 GBV_ILN_4319 GBV_ILN_4323 GBV_ILN_4700 AR 33 1998 10 05 2499-2507
allfieldsSound	10.1023/A:1004332614379 doi (DE-627)OLC2046244583 (DE-He213)A:1004332614379-p DE-627 ger DE-627 rakwb eng 670 VZ Larsen, P. H verfasserin aut Chemical stability of MgO/CaO/Cr2O3–Al2O3–B2O3–phosphate glasses in solid oxide fuel cell environment 1998 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chapman and Hall 1998 Abstract The thermal properties, glass forming tendency and glass stability in solid oxide fuel cell (SOFC) relevant atmospheres have been determined for four different refractory MgO/CaO/Cr2O3–Al2O3–B2O3 phosphate based glasses. Also, the bonding ability and interaction as a function of temperature between the glasses and La0.8Ca0.22CrO3 interconnect material have been studied. The microstructural characterization and elemental analysis of reaction couples reveal that the bonding ability and interface interaction is closely related to the CaO content and the relative glass forming tendency. The reactions at 1000°C between the glass and the solid interconnect material for the high CaO or MgO containing compositions occur by a liquid phase or a vapour phase mechanism, respectively. The reaction at 1200°C in both cases occurs by a liquid phase mechanism. © 1998 Chapman & Hall Polymer Phosphate Al2O3 Liquid Phase Thermal Property James, P. F aut Enthalten in Journal of materials science Kluwer Academic Publishers, 1966 33(1998), 10 vom: Mai, Seite 2499-2507 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:33 year:1998 number:10 month:05 pages:2499-2507 https://doi.org/10.1023/A:1004332614379 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_11 GBV_ILN_20 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_40 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4316 GBV_ILN_4319 GBV_ILN_4323 GBV_ILN_4700 AR 33 1998 10 05 2499-2507
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title_sort	chemical stability of mgo/cao/cr2o3–al2o3–b2o3–phosphate glasses in solid oxide fuel cell environment
title_auth	Chemical stability of MgO/CaO/Cr2O3–Al2O3–B2O3–phosphate glasses in solid oxide fuel cell environment
abstract	Abstract The thermal properties, glass forming tendency and glass stability in solid oxide fuel cell (SOFC) relevant atmospheres have been determined for four different refractory MgO/CaO/Cr2O3–Al2O3–B2O3 phosphate based glasses. Also, the bonding ability and interaction as a function of temperature between the glasses and La0.8Ca0.22CrO3 interconnect material have been studied. The microstructural characterization and elemental analysis of reaction couples reveal that the bonding ability and interface interaction is closely related to the CaO content and the relative glass forming tendency. The reactions at 1000°C between the glass and the solid interconnect material for the high CaO or MgO containing compositions occur by a liquid phase or a vapour phase mechanism, respectively. The reaction at 1200°C in both cases occurs by a liquid phase mechanism. © 1998 Chapman & Hall © Chapman and Hall 1998
abstractGer	Abstract The thermal properties, glass forming tendency and glass stability in solid oxide fuel cell (SOFC) relevant atmospheres have been determined for four different refractory MgO/CaO/Cr2O3–Al2O3–B2O3 phosphate based glasses. Also, the bonding ability and interaction as a function of temperature between the glasses and La0.8Ca0.22CrO3 interconnect material have been studied. The microstructural characterization and elemental analysis of reaction couples reveal that the bonding ability and interface interaction is closely related to the CaO content and the relative glass forming tendency. The reactions at 1000°C between the glass and the solid interconnect material for the high CaO or MgO containing compositions occur by a liquid phase or a vapour phase mechanism, respectively. The reaction at 1200°C in both cases occurs by a liquid phase mechanism. © 1998 Chapman & Hall © Chapman and Hall 1998
abstract_unstemmed	Abstract The thermal properties, glass forming tendency and glass stability in solid oxide fuel cell (SOFC) relevant atmospheres have been determined for four different refractory MgO/CaO/Cr2O3–Al2O3–B2O3 phosphate based glasses. Also, the bonding ability and interaction as a function of temperature between the glasses and La0.8Ca0.22CrO3 interconnect material have been studied. The microstructural characterization and elemental analysis of reaction couples reveal that the bonding ability and interface interaction is closely related to the CaO content and the relative glass forming tendency. The reactions at 1000°C between the glass and the solid interconnect material for the high CaO or MgO containing compositions occur by a liquid phase or a vapour phase mechanism, respectively. The reaction at 1200°C in both cases occurs by a liquid phase mechanism. © 1998 Chapman & Hall © Chapman and Hall 1998
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container_issue	10
title_short	Chemical stability of MgO/CaO/Cr2O3–Al2O3–B2O3–phosphate glasses in solid oxide fuel cell environment
url	https://doi.org/10.1023/A:1004332614379
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author2	James, P. F
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doi_str	10.1023/A:1004332614379
up_date	2024-07-04T04:36:01.226Z
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Chemical stability of MgO/CaO/Cr2O3–Al2O3–B2O3–phosphate glasses in solid oxide fuel cell environment

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