Rheological properties of aqueous silicon nitride suspensions
Abstract The effect of surface modification of $ Si_{3} $$ N_{4} $ particle on the colloidal behavior and the rheological properties of aqueous $ Si_{3} $$ N_{4} $ suspensions under steady and oscillatory conditions are investigated in detail. Due to the decrease of the oxidizing level, the isoelect...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Xue-Jian, Liu [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2001 |
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| Schlagwörter: |
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| Anmerkung: |
© Kluwer Academic Publishers 2001 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of materials science - Kluwer Academic Publishers, 1966, 36(2001), 14 vom: Juli, Seite 3379-3384 |
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| Übergeordnetes Werk: |
volume:36 ; year:2001 ; number:14 ; month:07 ; pages:3379-3384 |
| Links: |
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| DOI / URN: |
10.1023/A:1017991408037 |
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| Katalog-ID: |
OLC2046268547 |
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| 245 | 1 | 0 | |a Rheological properties of aqueous silicon nitride suspensions |
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| 520 | |a Abstract The effect of surface modification of $ Si_{3} $$ N_{4} $ particle on the colloidal behavior and the rheological properties of aqueous $ Si_{3} $$ N_{4} $ suspensions under steady and oscillatory conditions are investigated in detail. Due to the decrease of the oxidizing level, the isoelectric point (IEP) of the modified particle shifts to basic region gently. Attempts have been made to apply rheological models to the suspensions with various solid volume fraction (φ). For the as-received suspensions, the Sisco model provides the best fit in the range of φ ≤ 0.30 while the Casson model in 0.35 ≤ φ ≤ 0.45. The shear behavior of modified suspensions fits to Sisco model in the range of φ ≤ 0.40 and Casson model in 0.45 ≤ φ ≤ 0.54. The rheological behavior of modified suspensions is improved efficiently. The critical strain decreases and the linear viscoelastic regime narrows continuously with increasing solid concentration. For the modified suspensions, the linear viscoelastic regime broadens and the corresponding elastic modulus decreases sharply. With increasing solid concentration, the characteristic frequency shifts toward lower frequencies and the suspension transforms from more viscous to more elastic. | ||
| 650 | 4 | |a Elastic Modulus | |
| 650 | 4 | |a Rheological Property | |
| 650 | 4 | |a Silicon Nitride | |
| 650 | 4 | |a Rheological Behavior | |
| 650 | 4 | |a Critical Strain | |
| 700 | 1 | |a Li-Ping, Huang |4 aut | |
| 700 | 1 | |a Xing-Wei, Sun |4 aut | |
| 700 | 1 | |a Xin, Xu |4 aut | |
| 700 | 1 | |a Xi-Ren, Fu |4 aut | |
| 700 | 1 | |a Hong-Chen, Gu |4 aut | |
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10.1023/A:1017991408037 doi (DE-627)OLC2046268547 (DE-He213)A:1017991408037-p DE-627 ger DE-627 rakwb eng 670 VZ Xue-Jian, Liu verfasserin aut Rheological properties of aqueous silicon nitride suspensions 2001 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Kluwer Academic Publishers 2001 Abstract The effect of surface modification of $ Si_{3} $$ N_{4} $ particle on the colloidal behavior and the rheological properties of aqueous $ Si_{3} $$ N_{4} $ suspensions under steady and oscillatory conditions are investigated in detail. Due to the decrease of the oxidizing level, the isoelectric point (IEP) of the modified particle shifts to basic region gently. Attempts have been made to apply rheological models to the suspensions with various solid volume fraction (φ). For the as-received suspensions, the Sisco model provides the best fit in the range of φ ≤ 0.30 while the Casson model in 0.35 ≤ φ ≤ 0.45. The shear behavior of modified suspensions fits to Sisco model in the range of φ ≤ 0.40 and Casson model in 0.45 ≤ φ ≤ 0.54. The rheological behavior of modified suspensions is improved efficiently. The critical strain decreases and the linear viscoelastic regime narrows continuously with increasing solid concentration. For the modified suspensions, the linear viscoelastic regime broadens and the corresponding elastic modulus decreases sharply. With increasing solid concentration, the characteristic frequency shifts toward lower frequencies and the suspension transforms from more viscous to more elastic. Elastic Modulus Rheological Property Silicon Nitride Rheological Behavior Critical Strain Li-Ping, Huang aut Xing-Wei, Sun aut Xin, Xu aut Xi-Ren, Fu aut Hong-Chen, Gu aut Enthalten in Journal of materials science Kluwer Academic Publishers, 1966 36(2001), 14 vom: Juli, Seite 3379-3384 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:36 year:2001 number:14 month:07 pages:3379-3384 https://doi.org/10.1023/A:1017991408037 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_11 GBV_ILN_20 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_40 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4316 GBV_ILN_4319 GBV_ILN_4323 AR 36 2001 14 07 3379-3384 |
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10.1023/A:1017991408037 doi (DE-627)OLC2046268547 (DE-He213)A:1017991408037-p DE-627 ger DE-627 rakwb eng 670 VZ Xue-Jian, Liu verfasserin aut Rheological properties of aqueous silicon nitride suspensions 2001 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Kluwer Academic Publishers 2001 Abstract The effect of surface modification of $ Si_{3} $$ N_{4} $ particle on the colloidal behavior and the rheological properties of aqueous $ Si_{3} $$ N_{4} $ suspensions under steady and oscillatory conditions are investigated in detail. Due to the decrease of the oxidizing level, the isoelectric point (IEP) of the modified particle shifts to basic region gently. Attempts have been made to apply rheological models to the suspensions with various solid volume fraction (φ). For the as-received suspensions, the Sisco model provides the best fit in the range of φ ≤ 0.30 while the Casson model in 0.35 ≤ φ ≤ 0.45. The shear behavior of modified suspensions fits to Sisco model in the range of φ ≤ 0.40 and Casson model in 0.45 ≤ φ ≤ 0.54. The rheological behavior of modified suspensions is improved efficiently. The critical strain decreases and the linear viscoelastic regime narrows continuously with increasing solid concentration. For the modified suspensions, the linear viscoelastic regime broadens and the corresponding elastic modulus decreases sharply. With increasing solid concentration, the characteristic frequency shifts toward lower frequencies and the suspension transforms from more viscous to more elastic. Elastic Modulus Rheological Property Silicon Nitride Rheological Behavior Critical Strain Li-Ping, Huang aut Xing-Wei, Sun aut Xin, Xu aut Xi-Ren, Fu aut Hong-Chen, Gu aut Enthalten in Journal of materials science Kluwer Academic Publishers, 1966 36(2001), 14 vom: Juli, Seite 3379-3384 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:36 year:2001 number:14 month:07 pages:3379-3384 https://doi.org/10.1023/A:1017991408037 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_11 GBV_ILN_20 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_40 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4316 GBV_ILN_4319 GBV_ILN_4323 AR 36 2001 14 07 3379-3384 |
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10.1023/A:1017991408037 doi (DE-627)OLC2046268547 (DE-He213)A:1017991408037-p DE-627 ger DE-627 rakwb eng 670 VZ Xue-Jian, Liu verfasserin aut Rheological properties of aqueous silicon nitride suspensions 2001 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Kluwer Academic Publishers 2001 Abstract The effect of surface modification of $ Si_{3} $$ N_{4} $ particle on the colloidal behavior and the rheological properties of aqueous $ Si_{3} $$ N_{4} $ suspensions under steady and oscillatory conditions are investigated in detail. Due to the decrease of the oxidizing level, the isoelectric point (IEP) of the modified particle shifts to basic region gently. Attempts have been made to apply rheological models to the suspensions with various solid volume fraction (φ). For the as-received suspensions, the Sisco model provides the best fit in the range of φ ≤ 0.30 while the Casson model in 0.35 ≤ φ ≤ 0.45. The shear behavior of modified suspensions fits to Sisco model in the range of φ ≤ 0.40 and Casson model in 0.45 ≤ φ ≤ 0.54. The rheological behavior of modified suspensions is improved efficiently. The critical strain decreases and the linear viscoelastic regime narrows continuously with increasing solid concentration. For the modified suspensions, the linear viscoelastic regime broadens and the corresponding elastic modulus decreases sharply. With increasing solid concentration, the characteristic frequency shifts toward lower frequencies and the suspension transforms from more viscous to more elastic. Elastic Modulus Rheological Property Silicon Nitride Rheological Behavior Critical Strain Li-Ping, Huang aut Xing-Wei, Sun aut Xin, Xu aut Xi-Ren, Fu aut Hong-Chen, Gu aut Enthalten in Journal of materials science Kluwer Academic Publishers, 1966 36(2001), 14 vom: Juli, Seite 3379-3384 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:36 year:2001 number:14 month:07 pages:3379-3384 https://doi.org/10.1023/A:1017991408037 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_11 GBV_ILN_20 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_40 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4316 GBV_ILN_4319 GBV_ILN_4323 AR 36 2001 14 07 3379-3384 |
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10.1023/A:1017991408037 doi (DE-627)OLC2046268547 (DE-He213)A:1017991408037-p DE-627 ger DE-627 rakwb eng 670 VZ Xue-Jian, Liu verfasserin aut Rheological properties of aqueous silicon nitride suspensions 2001 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Kluwer Academic Publishers 2001 Abstract The effect of surface modification of $ Si_{3} $$ N_{4} $ particle on the colloidal behavior and the rheological properties of aqueous $ Si_{3} $$ N_{4} $ suspensions under steady and oscillatory conditions are investigated in detail. Due to the decrease of the oxidizing level, the isoelectric point (IEP) of the modified particle shifts to basic region gently. Attempts have been made to apply rheological models to the suspensions with various solid volume fraction (φ). For the as-received suspensions, the Sisco model provides the best fit in the range of φ ≤ 0.30 while the Casson model in 0.35 ≤ φ ≤ 0.45. The shear behavior of modified suspensions fits to Sisco model in the range of φ ≤ 0.40 and Casson model in 0.45 ≤ φ ≤ 0.54. The rheological behavior of modified suspensions is improved efficiently. The critical strain decreases and the linear viscoelastic regime narrows continuously with increasing solid concentration. For the modified suspensions, the linear viscoelastic regime broadens and the corresponding elastic modulus decreases sharply. With increasing solid concentration, the characteristic frequency shifts toward lower frequencies and the suspension transforms from more viscous to more elastic. Elastic Modulus Rheological Property Silicon Nitride Rheological Behavior Critical Strain Li-Ping, Huang aut Xing-Wei, Sun aut Xin, Xu aut Xi-Ren, Fu aut Hong-Chen, Gu aut Enthalten in Journal of materials science Kluwer Academic Publishers, 1966 36(2001), 14 vom: Juli, Seite 3379-3384 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:36 year:2001 number:14 month:07 pages:3379-3384 https://doi.org/10.1023/A:1017991408037 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_11 GBV_ILN_20 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_40 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4316 GBV_ILN_4319 GBV_ILN_4323 AR 36 2001 14 07 3379-3384 |
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10.1023/A:1017991408037 doi (DE-627)OLC2046268547 (DE-He213)A:1017991408037-p DE-627 ger DE-627 rakwb eng 670 VZ Xue-Jian, Liu verfasserin aut Rheological properties of aqueous silicon nitride suspensions 2001 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Kluwer Academic Publishers 2001 Abstract The effect of surface modification of $ Si_{3} $$ N_{4} $ particle on the colloidal behavior and the rheological properties of aqueous $ Si_{3} $$ N_{4} $ suspensions under steady and oscillatory conditions are investigated in detail. Due to the decrease of the oxidizing level, the isoelectric point (IEP) of the modified particle shifts to basic region gently. Attempts have been made to apply rheological models to the suspensions with various solid volume fraction (φ). For the as-received suspensions, the Sisco model provides the best fit in the range of φ ≤ 0.30 while the Casson model in 0.35 ≤ φ ≤ 0.45. The shear behavior of modified suspensions fits to Sisco model in the range of φ ≤ 0.40 and Casson model in 0.45 ≤ φ ≤ 0.54. The rheological behavior of modified suspensions is improved efficiently. The critical strain decreases and the linear viscoelastic regime narrows continuously with increasing solid concentration. For the modified suspensions, the linear viscoelastic regime broadens and the corresponding elastic modulus decreases sharply. With increasing solid concentration, the characteristic frequency shifts toward lower frequencies and the suspension transforms from more viscous to more elastic. Elastic Modulus Rheological Property Silicon Nitride Rheological Behavior Critical Strain Li-Ping, Huang aut Xing-Wei, Sun aut Xin, Xu aut Xi-Ren, Fu aut Hong-Chen, Gu aut Enthalten in Journal of materials science Kluwer Academic Publishers, 1966 36(2001), 14 vom: Juli, Seite 3379-3384 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:36 year:2001 number:14 month:07 pages:3379-3384 https://doi.org/10.1023/A:1017991408037 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_11 GBV_ILN_20 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_40 GBV_ILN_62 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4316 GBV_ILN_4319 GBV_ILN_4323 AR 36 2001 14 07 3379-3384 |
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Enthalten in Journal of materials science 36(2001), 14 vom: Juli, Seite 3379-3384 volume:36 year:2001 number:14 month:07 pages:3379-3384 |
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Enthalten in Journal of materials science 36(2001), 14 vom: Juli, Seite 3379-3384 volume:36 year:2001 number:14 month:07 pages:3379-3384 |
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Xue-Jian, Liu @@aut@@ Li-Ping, Huang @@aut@@ Xing-Wei, Sun @@aut@@ Xin, Xu @@aut@@ Xi-Ren, Fu @@aut@@ Hong-Chen, Gu @@aut@@ |
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Abstract The effect of surface modification of $ Si_{3} $$ N_{4} $ particle on the colloidal behavior and the rheological properties of aqueous $ Si_{3} $$ N_{4} $ suspensions under steady and oscillatory conditions are investigated in detail. Due to the decrease of the oxidizing level, the isoelectric point (IEP) of the modified particle shifts to basic region gently. Attempts have been made to apply rheological models to the suspensions with various solid volume fraction (φ). For the as-received suspensions, the Sisco model provides the best fit in the range of φ ≤ 0.30 while the Casson model in 0.35 ≤ φ ≤ 0.45. The shear behavior of modified suspensions fits to Sisco model in the range of φ ≤ 0.40 and Casson model in 0.45 ≤ φ ≤ 0.54. The rheological behavior of modified suspensions is improved efficiently. The critical strain decreases and the linear viscoelastic regime narrows continuously with increasing solid concentration. For the modified suspensions, the linear viscoelastic regime broadens and the corresponding elastic modulus decreases sharply. With increasing solid concentration, the characteristic frequency shifts toward lower frequencies and the suspension transforms from more viscous to more elastic. © Kluwer Academic Publishers 2001 |
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Abstract The effect of surface modification of $ Si_{3} $$ N_{4} $ particle on the colloidal behavior and the rheological properties of aqueous $ Si_{3} $$ N_{4} $ suspensions under steady and oscillatory conditions are investigated in detail. Due to the decrease of the oxidizing level, the isoelectric point (IEP) of the modified particle shifts to basic region gently. Attempts have been made to apply rheological models to the suspensions with various solid volume fraction (φ). For the as-received suspensions, the Sisco model provides the best fit in the range of φ ≤ 0.30 while the Casson model in 0.35 ≤ φ ≤ 0.45. The shear behavior of modified suspensions fits to Sisco model in the range of φ ≤ 0.40 and Casson model in 0.45 ≤ φ ≤ 0.54. The rheological behavior of modified suspensions is improved efficiently. The critical strain decreases and the linear viscoelastic regime narrows continuously with increasing solid concentration. For the modified suspensions, the linear viscoelastic regime broadens and the corresponding elastic modulus decreases sharply. With increasing solid concentration, the characteristic frequency shifts toward lower frequencies and the suspension transforms from more viscous to more elastic. © Kluwer Academic Publishers 2001 |
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Abstract The effect of surface modification of $ Si_{3} $$ N_{4} $ particle on the colloidal behavior and the rheological properties of aqueous $ Si_{3} $$ N_{4} $ suspensions under steady and oscillatory conditions are investigated in detail. Due to the decrease of the oxidizing level, the isoelectric point (IEP) of the modified particle shifts to basic region gently. Attempts have been made to apply rheological models to the suspensions with various solid volume fraction (φ). For the as-received suspensions, the Sisco model provides the best fit in the range of φ ≤ 0.30 while the Casson model in 0.35 ≤ φ ≤ 0.45. The shear behavior of modified suspensions fits to Sisco model in the range of φ ≤ 0.40 and Casson model in 0.45 ≤ φ ≤ 0.54. The rheological behavior of modified suspensions is improved efficiently. The critical strain decreases and the linear viscoelastic regime narrows continuously with increasing solid concentration. For the modified suspensions, the linear viscoelastic regime broadens and the corresponding elastic modulus decreases sharply. With increasing solid concentration, the characteristic frequency shifts toward lower frequencies and the suspension transforms from more viscous to more elastic. © Kluwer Academic Publishers 2001 |
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