Electrochemical copolymerization of benzanthrone and 3-methylthiophene and characterization of their fluorescent copolymer
Abstract Poly(3-methylthiophene-co-benzanthrone), a novel copolymer, was successfully achieved by electrochemical oxidation of the monomer mixtures of 3-methylthiophene (3MeT) and benzanthrone in the binary solvent system containing boron trifluoride diethyl etherate and acetonitrile. A series of ex...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Yue, Ruirui [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2009 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer Science+Business Media, LLC 2009 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of materials science - Springer US, 1966, 44(2009), 21 vom: 02. Sept., Seite 5909-5918 |
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| Übergeordnetes Werk: |
volume:44 ; year:2009 ; number:21 ; day:02 ; month:09 ; pages:5909-5918 |
| Links: |
|---|
| DOI / URN: |
10.1007/s10853-009-3836-6 |
|---|
| Katalog-ID: |
OLC2046352165 |
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| 520 | |a Abstract Poly(3-methylthiophene-co-benzanthrone), a novel copolymer, was successfully achieved by electrochemical oxidation of the monomer mixtures of 3-methylthiophene (3MeT) and benzanthrone in the binary solvent system containing boron trifluoride diethyl etherate and acetonitrile. A series of experiments with different monomer feed ratios were carried out to investigate the influence of monomer feed ratio on the electrochemical copolymerization and the overall properties of the copolymer films. The resulting copolymer possesses the advantages of both polybenzanthrone and poly(3-methylthiophene), such as considerable fluorescence property, good redox activity, high thermal stability, and relatively high electrical conductivity. Ultraviolet–visible, FT-IR, and thermal analysis were used to characterize and investigate the structure and thermal stability of the copolymers. Fluorescence spectroscopic studies revealed that the copolymer dissolved in common organic solvents was a good green or yellow-green light emitter, with a strong emission at 499 nm in doped state and 529 nm in dedoped state. | ||
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10.1007/s10853-009-3836-6 doi (DE-627)OLC2046352165 (DE-He213)s10853-009-3836-6-p DE-627 ger DE-627 rakwb eng 670 VZ Yue, Ruirui verfasserin aut Electrochemical copolymerization of benzanthrone and 3-methylthiophene and characterization of their fluorescent copolymer 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2009 Abstract Poly(3-methylthiophene-co-benzanthrone), a novel copolymer, was successfully achieved by electrochemical oxidation of the monomer mixtures of 3-methylthiophene (3MeT) and benzanthrone in the binary solvent system containing boron trifluoride diethyl etherate and acetonitrile. A series of experiments with different monomer feed ratios were carried out to investigate the influence of monomer feed ratio on the electrochemical copolymerization and the overall properties of the copolymer films. The resulting copolymer possesses the advantages of both polybenzanthrone and poly(3-methylthiophene), such as considerable fluorescence property, good redox activity, high thermal stability, and relatively high electrical conductivity. Ultraviolet–visible, FT-IR, and thermal analysis were used to characterize and investigate the structure and thermal stability of the copolymers. Fluorescence spectroscopic studies revealed that the copolymer dissolved in common organic solvents was a good green or yellow-green light emitter, with a strong emission at 499 nm in doped state and 529 nm in dedoped state. Feed Ratio Common Organic Solvent Copolymer Film Monomer Mixture Dope State Xu, Jingkun aut Lu, Baoyang aut Liu, Congcong aut Li, Yuzhen aut Zhu, Zhaojin aut Chen, Shuai aut Enthalten in Journal of materials science Springer US, 1966 44(2009), 21 vom: 02. Sept., Seite 5909-5918 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:44 year:2009 number:21 day:02 month:09 pages:5909-5918 https://doi.org/10.1007/s10853-009-3836-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_40 GBV_ILN_70 GBV_ILN_100 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 44 2009 21 02 09 5909-5918 |
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10.1007/s10853-009-3836-6 doi (DE-627)OLC2046352165 (DE-He213)s10853-009-3836-6-p DE-627 ger DE-627 rakwb eng 670 VZ Yue, Ruirui verfasserin aut Electrochemical copolymerization of benzanthrone and 3-methylthiophene and characterization of their fluorescent copolymer 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2009 Abstract Poly(3-methylthiophene-co-benzanthrone), a novel copolymer, was successfully achieved by electrochemical oxidation of the monomer mixtures of 3-methylthiophene (3MeT) and benzanthrone in the binary solvent system containing boron trifluoride diethyl etherate and acetonitrile. A series of experiments with different monomer feed ratios were carried out to investigate the influence of monomer feed ratio on the electrochemical copolymerization and the overall properties of the copolymer films. The resulting copolymer possesses the advantages of both polybenzanthrone and poly(3-methylthiophene), such as considerable fluorescence property, good redox activity, high thermal stability, and relatively high electrical conductivity. Ultraviolet–visible, FT-IR, and thermal analysis were used to characterize and investigate the structure and thermal stability of the copolymers. Fluorescence spectroscopic studies revealed that the copolymer dissolved in common organic solvents was a good green or yellow-green light emitter, with a strong emission at 499 nm in doped state and 529 nm in dedoped state. Feed Ratio Common Organic Solvent Copolymer Film Monomer Mixture Dope State Xu, Jingkun aut Lu, Baoyang aut Liu, Congcong aut Li, Yuzhen aut Zhu, Zhaojin aut Chen, Shuai aut Enthalten in Journal of materials science Springer US, 1966 44(2009), 21 vom: 02. Sept., Seite 5909-5918 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:44 year:2009 number:21 day:02 month:09 pages:5909-5918 https://doi.org/10.1007/s10853-009-3836-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_40 GBV_ILN_70 GBV_ILN_100 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 44 2009 21 02 09 5909-5918 |
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10.1007/s10853-009-3836-6 doi (DE-627)OLC2046352165 (DE-He213)s10853-009-3836-6-p DE-627 ger DE-627 rakwb eng 670 VZ Yue, Ruirui verfasserin aut Electrochemical copolymerization of benzanthrone and 3-methylthiophene and characterization of their fluorescent copolymer 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2009 Abstract Poly(3-methylthiophene-co-benzanthrone), a novel copolymer, was successfully achieved by electrochemical oxidation of the monomer mixtures of 3-methylthiophene (3MeT) and benzanthrone in the binary solvent system containing boron trifluoride diethyl etherate and acetonitrile. A series of experiments with different monomer feed ratios were carried out to investigate the influence of monomer feed ratio on the electrochemical copolymerization and the overall properties of the copolymer films. The resulting copolymer possesses the advantages of both polybenzanthrone and poly(3-methylthiophene), such as considerable fluorescence property, good redox activity, high thermal stability, and relatively high electrical conductivity. Ultraviolet–visible, FT-IR, and thermal analysis were used to characterize and investigate the structure and thermal stability of the copolymers. Fluorescence spectroscopic studies revealed that the copolymer dissolved in common organic solvents was a good green or yellow-green light emitter, with a strong emission at 499 nm in doped state and 529 nm in dedoped state. Feed Ratio Common Organic Solvent Copolymer Film Monomer Mixture Dope State Xu, Jingkun aut Lu, Baoyang aut Liu, Congcong aut Li, Yuzhen aut Zhu, Zhaojin aut Chen, Shuai aut Enthalten in Journal of materials science Springer US, 1966 44(2009), 21 vom: 02. Sept., Seite 5909-5918 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:44 year:2009 number:21 day:02 month:09 pages:5909-5918 https://doi.org/10.1007/s10853-009-3836-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_40 GBV_ILN_70 GBV_ILN_100 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 44 2009 21 02 09 5909-5918 |
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10.1007/s10853-009-3836-6 doi (DE-627)OLC2046352165 (DE-He213)s10853-009-3836-6-p DE-627 ger DE-627 rakwb eng 670 VZ Yue, Ruirui verfasserin aut Electrochemical copolymerization of benzanthrone and 3-methylthiophene and characterization of their fluorescent copolymer 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2009 Abstract Poly(3-methylthiophene-co-benzanthrone), a novel copolymer, was successfully achieved by electrochemical oxidation of the monomer mixtures of 3-methylthiophene (3MeT) and benzanthrone in the binary solvent system containing boron trifluoride diethyl etherate and acetonitrile. A series of experiments with different monomer feed ratios were carried out to investigate the influence of monomer feed ratio on the electrochemical copolymerization and the overall properties of the copolymer films. The resulting copolymer possesses the advantages of both polybenzanthrone and poly(3-methylthiophene), such as considerable fluorescence property, good redox activity, high thermal stability, and relatively high electrical conductivity. Ultraviolet–visible, FT-IR, and thermal analysis were used to characterize and investigate the structure and thermal stability of the copolymers. Fluorescence spectroscopic studies revealed that the copolymer dissolved in common organic solvents was a good green or yellow-green light emitter, with a strong emission at 499 nm in doped state and 529 nm in dedoped state. Feed Ratio Common Organic Solvent Copolymer Film Monomer Mixture Dope State Xu, Jingkun aut Lu, Baoyang aut Liu, Congcong aut Li, Yuzhen aut Zhu, Zhaojin aut Chen, Shuai aut Enthalten in Journal of materials science Springer US, 1966 44(2009), 21 vom: 02. Sept., Seite 5909-5918 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:44 year:2009 number:21 day:02 month:09 pages:5909-5918 https://doi.org/10.1007/s10853-009-3836-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_40 GBV_ILN_70 GBV_ILN_100 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 44 2009 21 02 09 5909-5918 |
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10.1007/s10853-009-3836-6 doi (DE-627)OLC2046352165 (DE-He213)s10853-009-3836-6-p DE-627 ger DE-627 rakwb eng 670 VZ Yue, Ruirui verfasserin aut Electrochemical copolymerization of benzanthrone and 3-methylthiophene and characterization of their fluorescent copolymer 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2009 Abstract Poly(3-methylthiophene-co-benzanthrone), a novel copolymer, was successfully achieved by electrochemical oxidation of the monomer mixtures of 3-methylthiophene (3MeT) and benzanthrone in the binary solvent system containing boron trifluoride diethyl etherate and acetonitrile. A series of experiments with different monomer feed ratios were carried out to investigate the influence of monomer feed ratio on the electrochemical copolymerization and the overall properties of the copolymer films. The resulting copolymer possesses the advantages of both polybenzanthrone and poly(3-methylthiophene), such as considerable fluorescence property, good redox activity, high thermal stability, and relatively high electrical conductivity. Ultraviolet–visible, FT-IR, and thermal analysis were used to characterize and investigate the structure and thermal stability of the copolymers. Fluorescence spectroscopic studies revealed that the copolymer dissolved in common organic solvents was a good green or yellow-green light emitter, with a strong emission at 499 nm in doped state and 529 nm in dedoped state. Feed Ratio Common Organic Solvent Copolymer Film Monomer Mixture Dope State Xu, Jingkun aut Lu, Baoyang aut Liu, Congcong aut Li, Yuzhen aut Zhu, Zhaojin aut Chen, Shuai aut Enthalten in Journal of materials science Springer US, 1966 44(2009), 21 vom: 02. Sept., Seite 5909-5918 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:44 year:2009 number:21 day:02 month:09 pages:5909-5918 https://doi.org/10.1007/s10853-009-3836-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_40 GBV_ILN_70 GBV_ILN_100 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 44 2009 21 02 09 5909-5918 |
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| author |
Yue, Ruirui |
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670 VZ Electrochemical copolymerization of benzanthrone and 3-methylthiophene and characterization of their fluorescent copolymer Feed Ratio Common Organic Solvent Copolymer Film Monomer Mixture Dope State |
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Electrochemical copolymerization of benzanthrone and 3-methylthiophene and characterization of their fluorescent copolymer |
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Electrochemical copolymerization of benzanthrone and 3-methylthiophene and characterization of their fluorescent copolymer |
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Yue, Ruirui |
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Journal of materials science |
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Yue, Ruirui Xu, Jingkun Lu, Baoyang Liu, Congcong Li, Yuzhen Zhu, Zhaojin Chen, Shuai |
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electrochemical copolymerization of benzanthrone and 3-methylthiophene and characterization of their fluorescent copolymer |
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Electrochemical copolymerization of benzanthrone and 3-methylthiophene and characterization of their fluorescent copolymer |
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Abstract Poly(3-methylthiophene-co-benzanthrone), a novel copolymer, was successfully achieved by electrochemical oxidation of the monomer mixtures of 3-methylthiophene (3MeT) and benzanthrone in the binary solvent system containing boron trifluoride diethyl etherate and acetonitrile. A series of experiments with different monomer feed ratios were carried out to investigate the influence of monomer feed ratio on the electrochemical copolymerization and the overall properties of the copolymer films. The resulting copolymer possesses the advantages of both polybenzanthrone and poly(3-methylthiophene), such as considerable fluorescence property, good redox activity, high thermal stability, and relatively high electrical conductivity. Ultraviolet–visible, FT-IR, and thermal analysis were used to characterize and investigate the structure and thermal stability of the copolymers. Fluorescence spectroscopic studies revealed that the copolymer dissolved in common organic solvents was a good green or yellow-green light emitter, with a strong emission at 499 nm in doped state and 529 nm in dedoped state. © Springer Science+Business Media, LLC 2009 |
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Abstract Poly(3-methylthiophene-co-benzanthrone), a novel copolymer, was successfully achieved by electrochemical oxidation of the monomer mixtures of 3-methylthiophene (3MeT) and benzanthrone in the binary solvent system containing boron trifluoride diethyl etherate and acetonitrile. A series of experiments with different monomer feed ratios were carried out to investigate the influence of monomer feed ratio on the electrochemical copolymerization and the overall properties of the copolymer films. The resulting copolymer possesses the advantages of both polybenzanthrone and poly(3-methylthiophene), such as considerable fluorescence property, good redox activity, high thermal stability, and relatively high electrical conductivity. Ultraviolet–visible, FT-IR, and thermal analysis were used to characterize and investigate the structure and thermal stability of the copolymers. Fluorescence spectroscopic studies revealed that the copolymer dissolved in common organic solvents was a good green or yellow-green light emitter, with a strong emission at 499 nm in doped state and 529 nm in dedoped state. © Springer Science+Business Media, LLC 2009 |
| abstract_unstemmed |
Abstract Poly(3-methylthiophene-co-benzanthrone), a novel copolymer, was successfully achieved by electrochemical oxidation of the monomer mixtures of 3-methylthiophene (3MeT) and benzanthrone in the binary solvent system containing boron trifluoride diethyl etherate and acetonitrile. A series of experiments with different monomer feed ratios were carried out to investigate the influence of monomer feed ratio on the electrochemical copolymerization and the overall properties of the copolymer films. The resulting copolymer possesses the advantages of both polybenzanthrone and poly(3-methylthiophene), such as considerable fluorescence property, good redox activity, high thermal stability, and relatively high electrical conductivity. Ultraviolet–visible, FT-IR, and thermal analysis were used to characterize and investigate the structure and thermal stability of the copolymers. Fluorescence spectroscopic studies revealed that the copolymer dissolved in common organic solvents was a good green or yellow-green light emitter, with a strong emission at 499 nm in doped state and 529 nm in dedoped state. © Springer Science+Business Media, LLC 2009 |
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Electrochemical copolymerization of benzanthrone and 3-methylthiophene and characterization of their fluorescent copolymer |
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