Synthesis and electrochemical polymerization of 9,9-bis(carbazolylalkyl)fluorene and characterization of its conducting polymer film with high tensile strength
Abstract Free-standing poly(9,9-bis(carbazolylalkyl)fluorene) (P2Cz-A-F, alkyl = hexyl or dodecyl) films with high tensile strength (185–200 kg $ cm^{−2} $) were electrochemically synthesized by direct anodic oxidation of the monomer 9,9-bis(carbazolylalkyl)fluorene (2Cz-A-F) in a mixed electrolyte...
Ausführliche Beschreibung
Autor*in: |
Wang, Xingcong [verfasserIn] |
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Format: |
Artikel |
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Sprache: |
Englisch |
Erschienen: |
2010 |
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Schlagwörter: |
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Anmerkung: |
© Springer Science+Business Media, LLC 2010 |
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Übergeordnetes Werk: |
Enthalten in: Journal of materials science - Springer US, 1966, 45(2010), 7 vom: 13. Jan., Seite 1963-1971 |
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Übergeordnetes Werk: |
volume:45 ; year:2010 ; number:7 ; day:13 ; month:01 ; pages:1963-1971 |
Links: |
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DOI / URN: |
10.1007/s10853-009-4188-y |
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Katalog-ID: |
OLC2046355733 |
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10.1007/s10853-009-4188-y doi (DE-627)OLC2046355733 (DE-He213)s10853-009-4188-y-p DE-627 ger DE-627 rakwb eng 670 VZ Wang, Xingcong verfasserin aut Synthesis and electrochemical polymerization of 9,9-bis(carbazolylalkyl)fluorene and characterization of its conducting polymer film with high tensile strength 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2010 Abstract Free-standing poly(9,9-bis(carbazolylalkyl)fluorene) (P2Cz-A-F, alkyl = hexyl or dodecyl) films with high tensile strength (185–200 kg $ cm^{−2} $) were electrochemically synthesized by direct anodic oxidation of the monomer 9,9-bis(carbazolylalkyl)fluorene (2Cz-A-F) in a mixed electrolyte of boron trifluoride diethyl etherate containing 30% $ CH_{2} $$ Cl_{2} $ (by volume). The electrochemical and physical properties show that the quality of P2Cz-A-F films are much better than that of polycarbazole (PCz) and polyfluorene (PF) films due to the specially designed structure consisting of stiff bicarbazyl chromophores linked by a flexible long alkyl spacer at the fluorene unit. The structure of free-standing P2Cz-A-F films was investigated by UV–visible and infrared spectroscopy. Thermal analysis shows that the polymer films have good thermal stability. Fluorescent spectral studies indicate that polymer films in the solid state are blue-light emitters, which may meet potential applications in polymer light-emitting diodes. Polymer Film Carbazole Electrochemical Polymerization Mixed Electrolyte Alkyl Spacer Yue, Ruirui aut Lu, Baoyang aut Wei, Zhenhong aut Xu, Jingkun aut Enthalten in Journal of materials science Springer US, 1966 45(2010), 7 vom: 13. Jan., Seite 1963-1971 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:45 year:2010 number:7 day:13 month:01 pages:1963-1971 https://doi.org/10.1007/s10853-009-4188-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_100 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 45 2010 7 13 01 1963-1971 |
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10.1007/s10853-009-4188-y doi (DE-627)OLC2046355733 (DE-He213)s10853-009-4188-y-p DE-627 ger DE-627 rakwb eng 670 VZ Wang, Xingcong verfasserin aut Synthesis and electrochemical polymerization of 9,9-bis(carbazolylalkyl)fluorene and characterization of its conducting polymer film with high tensile strength 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2010 Abstract Free-standing poly(9,9-bis(carbazolylalkyl)fluorene) (P2Cz-A-F, alkyl = hexyl or dodecyl) films with high tensile strength (185–200 kg $ cm^{−2} $) were electrochemically synthesized by direct anodic oxidation of the monomer 9,9-bis(carbazolylalkyl)fluorene (2Cz-A-F) in a mixed electrolyte of boron trifluoride diethyl etherate containing 30% $ CH_{2} $$ Cl_{2} $ (by volume). The electrochemical and physical properties show that the quality of P2Cz-A-F films are much better than that of polycarbazole (PCz) and polyfluorene (PF) films due to the specially designed structure consisting of stiff bicarbazyl chromophores linked by a flexible long alkyl spacer at the fluorene unit. The structure of free-standing P2Cz-A-F films was investigated by UV–visible and infrared spectroscopy. Thermal analysis shows that the polymer films have good thermal stability. Fluorescent spectral studies indicate that polymer films in the solid state are blue-light emitters, which may meet potential applications in polymer light-emitting diodes. Polymer Film Carbazole Electrochemical Polymerization Mixed Electrolyte Alkyl Spacer Yue, Ruirui aut Lu, Baoyang aut Wei, Zhenhong aut Xu, Jingkun aut Enthalten in Journal of materials science Springer US, 1966 45(2010), 7 vom: 13. Jan., Seite 1963-1971 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:45 year:2010 number:7 day:13 month:01 pages:1963-1971 https://doi.org/10.1007/s10853-009-4188-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_100 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 45 2010 7 13 01 1963-1971 |
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10.1007/s10853-009-4188-y doi (DE-627)OLC2046355733 (DE-He213)s10853-009-4188-y-p DE-627 ger DE-627 rakwb eng 670 VZ Wang, Xingcong verfasserin aut Synthesis and electrochemical polymerization of 9,9-bis(carbazolylalkyl)fluorene and characterization of its conducting polymer film with high tensile strength 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2010 Abstract Free-standing poly(9,9-bis(carbazolylalkyl)fluorene) (P2Cz-A-F, alkyl = hexyl or dodecyl) films with high tensile strength (185–200 kg $ cm^{−2} $) were electrochemically synthesized by direct anodic oxidation of the monomer 9,9-bis(carbazolylalkyl)fluorene (2Cz-A-F) in a mixed electrolyte of boron trifluoride diethyl etherate containing 30% $ CH_{2} $$ Cl_{2} $ (by volume). The electrochemical and physical properties show that the quality of P2Cz-A-F films are much better than that of polycarbazole (PCz) and polyfluorene (PF) films due to the specially designed structure consisting of stiff bicarbazyl chromophores linked by a flexible long alkyl spacer at the fluorene unit. The structure of free-standing P2Cz-A-F films was investigated by UV–visible and infrared spectroscopy. Thermal analysis shows that the polymer films have good thermal stability. Fluorescent spectral studies indicate that polymer films in the solid state are blue-light emitters, which may meet potential applications in polymer light-emitting diodes. Polymer Film Carbazole Electrochemical Polymerization Mixed Electrolyte Alkyl Spacer Yue, Ruirui aut Lu, Baoyang aut Wei, Zhenhong aut Xu, Jingkun aut Enthalten in Journal of materials science Springer US, 1966 45(2010), 7 vom: 13. Jan., Seite 1963-1971 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:45 year:2010 number:7 day:13 month:01 pages:1963-1971 https://doi.org/10.1007/s10853-009-4188-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_100 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 45 2010 7 13 01 1963-1971 |
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10.1007/s10853-009-4188-y doi (DE-627)OLC2046355733 (DE-He213)s10853-009-4188-y-p DE-627 ger DE-627 rakwb eng 670 VZ Wang, Xingcong verfasserin aut Synthesis and electrochemical polymerization of 9,9-bis(carbazolylalkyl)fluorene and characterization of its conducting polymer film with high tensile strength 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2010 Abstract Free-standing poly(9,9-bis(carbazolylalkyl)fluorene) (P2Cz-A-F, alkyl = hexyl or dodecyl) films with high tensile strength (185–200 kg $ cm^{−2} $) were electrochemically synthesized by direct anodic oxidation of the monomer 9,9-bis(carbazolylalkyl)fluorene (2Cz-A-F) in a mixed electrolyte of boron trifluoride diethyl etherate containing 30% $ CH_{2} $$ Cl_{2} $ (by volume). The electrochemical and physical properties show that the quality of P2Cz-A-F films are much better than that of polycarbazole (PCz) and polyfluorene (PF) films due to the specially designed structure consisting of stiff bicarbazyl chromophores linked by a flexible long alkyl spacer at the fluorene unit. The structure of free-standing P2Cz-A-F films was investigated by UV–visible and infrared spectroscopy. Thermal analysis shows that the polymer films have good thermal stability. Fluorescent spectral studies indicate that polymer films in the solid state are blue-light emitters, which may meet potential applications in polymer light-emitting diodes. Polymer Film Carbazole Electrochemical Polymerization Mixed Electrolyte Alkyl Spacer Yue, Ruirui aut Lu, Baoyang aut Wei, Zhenhong aut Xu, Jingkun aut Enthalten in Journal of materials science Springer US, 1966 45(2010), 7 vom: 13. Jan., Seite 1963-1971 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:45 year:2010 number:7 day:13 month:01 pages:1963-1971 https://doi.org/10.1007/s10853-009-4188-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_100 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 45 2010 7 13 01 1963-1971 |
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10.1007/s10853-009-4188-y doi (DE-627)OLC2046355733 (DE-He213)s10853-009-4188-y-p DE-627 ger DE-627 rakwb eng 670 VZ Wang, Xingcong verfasserin aut Synthesis and electrochemical polymerization of 9,9-bis(carbazolylalkyl)fluorene and characterization of its conducting polymer film with high tensile strength 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2010 Abstract Free-standing poly(9,9-bis(carbazolylalkyl)fluorene) (P2Cz-A-F, alkyl = hexyl or dodecyl) films with high tensile strength (185–200 kg $ cm^{−2} $) were electrochemically synthesized by direct anodic oxidation of the monomer 9,9-bis(carbazolylalkyl)fluorene (2Cz-A-F) in a mixed electrolyte of boron trifluoride diethyl etherate containing 30% $ CH_{2} $$ Cl_{2} $ (by volume). The electrochemical and physical properties show that the quality of P2Cz-A-F films are much better than that of polycarbazole (PCz) and polyfluorene (PF) films due to the specially designed structure consisting of stiff bicarbazyl chromophores linked by a flexible long alkyl spacer at the fluorene unit. The structure of free-standing P2Cz-A-F films was investigated by UV–visible and infrared spectroscopy. Thermal analysis shows that the polymer films have good thermal stability. Fluorescent spectral studies indicate that polymer films in the solid state are blue-light emitters, which may meet potential applications in polymer light-emitting diodes. Polymer Film Carbazole Electrochemical Polymerization Mixed Electrolyte Alkyl Spacer Yue, Ruirui aut Lu, Baoyang aut Wei, Zhenhong aut Xu, Jingkun aut Enthalten in Journal of materials science Springer US, 1966 45(2010), 7 vom: 13. Jan., Seite 1963-1971 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:45 year:2010 number:7 day:13 month:01 pages:1963-1971 https://doi.org/10.1007/s10853-009-4188-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_100 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 45 2010 7 13 01 1963-1971 |
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author |
Wang, Xingcong |
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Wang, Xingcong ddc 670 misc Polymer Film misc Carbazole misc Electrochemical Polymerization misc Mixed Electrolyte misc Alkyl Spacer Synthesis and electrochemical polymerization of 9,9-bis(carbazolylalkyl)fluorene and characterization of its conducting polymer film with high tensile strength |
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670 VZ Synthesis and electrochemical polymerization of 9,9-bis(carbazolylalkyl)fluorene and characterization of its conducting polymer film with high tensile strength Polymer Film Carbazole Electrochemical Polymerization Mixed Electrolyte Alkyl Spacer |
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ddc 670 misc Polymer Film misc Carbazole misc Electrochemical Polymerization misc Mixed Electrolyte misc Alkyl Spacer |
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ddc 670 misc Polymer Film misc Carbazole misc Electrochemical Polymerization misc Mixed Electrolyte misc Alkyl Spacer |
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title |
Synthesis and electrochemical polymerization of 9,9-bis(carbazolylalkyl)fluorene and characterization of its conducting polymer film with high tensile strength |
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(DE-627)OLC2046355733 (DE-He213)s10853-009-4188-y-p |
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Synthesis and electrochemical polymerization of 9,9-bis(carbazolylalkyl)fluorene and characterization of its conducting polymer film with high tensile strength |
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Wang, Xingcong |
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Journal of materials science |
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1963 |
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Wang, Xingcong Yue, Ruirui Lu, Baoyang Wei, Zhenhong Xu, Jingkun |
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title_sort |
synthesis and electrochemical polymerization of 9,9-bis(carbazolylalkyl)fluorene and characterization of its conducting polymer film with high tensile strength |
title_auth |
Synthesis and electrochemical polymerization of 9,9-bis(carbazolylalkyl)fluorene and characterization of its conducting polymer film with high tensile strength |
abstract |
Abstract Free-standing poly(9,9-bis(carbazolylalkyl)fluorene) (P2Cz-A-F, alkyl = hexyl or dodecyl) films with high tensile strength (185–200 kg $ cm^{−2} $) were electrochemically synthesized by direct anodic oxidation of the monomer 9,9-bis(carbazolylalkyl)fluorene (2Cz-A-F) in a mixed electrolyte of boron trifluoride diethyl etherate containing 30% $ CH_{2} $$ Cl_{2} $ (by volume). The electrochemical and physical properties show that the quality of P2Cz-A-F films are much better than that of polycarbazole (PCz) and polyfluorene (PF) films due to the specially designed structure consisting of stiff bicarbazyl chromophores linked by a flexible long alkyl spacer at the fluorene unit. The structure of free-standing P2Cz-A-F films was investigated by UV–visible and infrared spectroscopy. Thermal analysis shows that the polymer films have good thermal stability. Fluorescent spectral studies indicate that polymer films in the solid state are blue-light emitters, which may meet potential applications in polymer light-emitting diodes. © Springer Science+Business Media, LLC 2010 |
abstractGer |
Abstract Free-standing poly(9,9-bis(carbazolylalkyl)fluorene) (P2Cz-A-F, alkyl = hexyl or dodecyl) films with high tensile strength (185–200 kg $ cm^{−2} $) were electrochemically synthesized by direct anodic oxidation of the monomer 9,9-bis(carbazolylalkyl)fluorene (2Cz-A-F) in a mixed electrolyte of boron trifluoride diethyl etherate containing 30% $ CH_{2} $$ Cl_{2} $ (by volume). The electrochemical and physical properties show that the quality of P2Cz-A-F films are much better than that of polycarbazole (PCz) and polyfluorene (PF) films due to the specially designed structure consisting of stiff bicarbazyl chromophores linked by a flexible long alkyl spacer at the fluorene unit. The structure of free-standing P2Cz-A-F films was investigated by UV–visible and infrared spectroscopy. Thermal analysis shows that the polymer films have good thermal stability. Fluorescent spectral studies indicate that polymer films in the solid state are blue-light emitters, which may meet potential applications in polymer light-emitting diodes. © Springer Science+Business Media, LLC 2010 |
abstract_unstemmed |
Abstract Free-standing poly(9,9-bis(carbazolylalkyl)fluorene) (P2Cz-A-F, alkyl = hexyl or dodecyl) films with high tensile strength (185–200 kg $ cm^{−2} $) were electrochemically synthesized by direct anodic oxidation of the monomer 9,9-bis(carbazolylalkyl)fluorene (2Cz-A-F) in a mixed electrolyte of boron trifluoride diethyl etherate containing 30% $ CH_{2} $$ Cl_{2} $ (by volume). The electrochemical and physical properties show that the quality of P2Cz-A-F films are much better than that of polycarbazole (PCz) and polyfluorene (PF) films due to the specially designed structure consisting of stiff bicarbazyl chromophores linked by a flexible long alkyl spacer at the fluorene unit. The structure of free-standing P2Cz-A-F films was investigated by UV–visible and infrared spectroscopy. Thermal analysis shows that the polymer films have good thermal stability. Fluorescent spectral studies indicate that polymer films in the solid state are blue-light emitters, which may meet potential applications in polymer light-emitting diodes. © Springer Science+Business Media, LLC 2010 |
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title_short |
Synthesis and electrochemical polymerization of 9,9-bis(carbazolylalkyl)fluorene and characterization of its conducting polymer film with high tensile strength |
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