Synthesis and electrochemical polymerization of 9,9-bis(carbazolylalkyl)fluorene and characterization of its conducting polymer film with high tensile strength

Abstract Free-standing poly(9,9-bis(carbazolylalkyl)fluorene) (P2Cz-A-F, alkyl = hexyl or dodecyl) films with high tensile strength (185–200 kg $ cm^{−2} $) were electrochemically synthesized by direct anodic oxidation of the monomer 9,9-bis(carbazolylalkyl)fluorene (2Cz-A-F) in a mixed electrolyte...
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Autor*in:	Wang, Xingcong [verfasserIn] Yue, Ruirui Lu, Baoyang Wei, Zhenhong Xu, Jingkun

Format:	Artikel
Sprache:	Englisch

Erschienen:	2010

Schlagwörter:	Polymer Film Carbazole Electrochemical Polymerization Mixed Electrolyte Alkyl Spacer

Anmerkung:	© Springer Science+Business Media, LLC 2010

Übergeordnetes Werk:	Enthalten in: Journal of materials science - Springer US, 1966, 45(2010), 7 vom: 13. Jan., Seite 1963-1971
Übergeordnetes Werk:	volume:45 ; year:2010 ; number:7 ; day:13 ; month:01 ; pages:1963-1971

Links:	Volltext

DOI / URN:	10.1007/s10853-009-4188-y

Katalog-ID:	OLC2046355733

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520			\|a Abstract Free-standing poly(9,9-bis(carbazolylalkyl)fluorene) (P2Cz-A-F, alkyl = hexyl or dodecyl) films with high tensile strength (185–200 kg $ cm^{−2} $) were electrochemically synthesized by direct anodic oxidation of the monomer 9,9-bis(carbazolylalkyl)fluorene (2Cz-A-F) in a mixed electrolyte of boron trifluoride diethyl etherate containing 30% $ CH_{2} $$ Cl_{2} $ (by volume). The electrochemical and physical properties show that the quality of P2Cz-A-F films are much better than that of polycarbazole (PCz) and polyfluorene (PF) films due to the specially designed structure consisting of stiff bicarbazyl chromophores linked by a flexible long alkyl spacer at the fluorene unit. The structure of free-standing P2Cz-A-F films was investigated by UV–visible and infrared spectroscopy. Thermal analysis shows that the polymer films have good thermal stability. Fluorescent spectral studies indicate that polymer films in the solid state are blue-light emitters, which may meet potential applications in polymer light-emitting diodes.
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allfields	10.1007/s10853-009-4188-y doi (DE-627)OLC2046355733 (DE-He213)s10853-009-4188-y-p DE-627 ger DE-627 rakwb eng 670 VZ Wang, Xingcong verfasserin aut Synthesis and electrochemical polymerization of 9,9-bis(carbazolylalkyl)fluorene and characterization of its conducting polymer film with high tensile strength 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2010 Abstract Free-standing poly(9,9-bis(carbazolylalkyl)fluorene) (P2Cz-A-F, alkyl = hexyl or dodecyl) films with high tensile strength (185–200 kg $ cm^{−2} $) were electrochemically synthesized by direct anodic oxidation of the monomer 9,9-bis(carbazolylalkyl)fluorene (2Cz-A-F) in a mixed electrolyte of boron trifluoride diethyl etherate containing 30% $ CH_{2} $$ Cl_{2} $ (by volume). The electrochemical and physical properties show that the quality of P2Cz-A-F films are much better than that of polycarbazole (PCz) and polyfluorene (PF) films due to the specially designed structure consisting of stiff bicarbazyl chromophores linked by a flexible long alkyl spacer at the fluorene unit. The structure of free-standing P2Cz-A-F films was investigated by UV–visible and infrared spectroscopy. Thermal analysis shows that the polymer films have good thermal stability. Fluorescent spectral studies indicate that polymer films in the solid state are blue-light emitters, which may meet potential applications in polymer light-emitting diodes. Polymer Film Carbazole Electrochemical Polymerization Mixed Electrolyte Alkyl Spacer Yue, Ruirui aut Lu, Baoyang aut Wei, Zhenhong aut Xu, Jingkun aut Enthalten in Journal of materials science Springer US, 1966 45(2010), 7 vom: 13. Jan., Seite 1963-1971 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:45 year:2010 number:7 day:13 month:01 pages:1963-1971 https://doi.org/10.1007/s10853-009-4188-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_100 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 45 2010 7 13 01 1963-1971
spelling	10.1007/s10853-009-4188-y doi (DE-627)OLC2046355733 (DE-He213)s10853-009-4188-y-p DE-627 ger DE-627 rakwb eng 670 VZ Wang, Xingcong verfasserin aut Synthesis and electrochemical polymerization of 9,9-bis(carbazolylalkyl)fluorene and characterization of its conducting polymer film with high tensile strength 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2010 Abstract Free-standing poly(9,9-bis(carbazolylalkyl)fluorene) (P2Cz-A-F, alkyl = hexyl or dodecyl) films with high tensile strength (185–200 kg $ cm^{−2} $) were electrochemically synthesized by direct anodic oxidation of the monomer 9,9-bis(carbazolylalkyl)fluorene (2Cz-A-F) in a mixed electrolyte of boron trifluoride diethyl etherate containing 30% $ CH_{2} $$ Cl_{2} $ (by volume). The electrochemical and physical properties show that the quality of P2Cz-A-F films are much better than that of polycarbazole (PCz) and polyfluorene (PF) films due to the specially designed structure consisting of stiff bicarbazyl chromophores linked by a flexible long alkyl spacer at the fluorene unit. The structure of free-standing P2Cz-A-F films was investigated by UV–visible and infrared spectroscopy. Thermal analysis shows that the polymer films have good thermal stability. Fluorescent spectral studies indicate that polymer films in the solid state are blue-light emitters, which may meet potential applications in polymer light-emitting diodes. Polymer Film Carbazole Electrochemical Polymerization Mixed Electrolyte Alkyl Spacer Yue, Ruirui aut Lu, Baoyang aut Wei, Zhenhong aut Xu, Jingkun aut Enthalten in Journal of materials science Springer US, 1966 45(2010), 7 vom: 13. Jan., Seite 1963-1971 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:45 year:2010 number:7 day:13 month:01 pages:1963-1971 https://doi.org/10.1007/s10853-009-4188-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_100 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 45 2010 7 13 01 1963-1971
allfields_unstemmed	10.1007/s10853-009-4188-y doi (DE-627)OLC2046355733 (DE-He213)s10853-009-4188-y-p DE-627 ger DE-627 rakwb eng 670 VZ Wang, Xingcong verfasserin aut Synthesis and electrochemical polymerization of 9,9-bis(carbazolylalkyl)fluorene and characterization of its conducting polymer film with high tensile strength 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2010 Abstract Free-standing poly(9,9-bis(carbazolylalkyl)fluorene) (P2Cz-A-F, alkyl = hexyl or dodecyl) films with high tensile strength (185–200 kg $ cm^{−2} $) were electrochemically synthesized by direct anodic oxidation of the monomer 9,9-bis(carbazolylalkyl)fluorene (2Cz-A-F) in a mixed electrolyte of boron trifluoride diethyl etherate containing 30% $ CH_{2} $$ Cl_{2} $ (by volume). The electrochemical and physical properties show that the quality of P2Cz-A-F films are much better than that of polycarbazole (PCz) and polyfluorene (PF) films due to the specially designed structure consisting of stiff bicarbazyl chromophores linked by a flexible long alkyl spacer at the fluorene unit. The structure of free-standing P2Cz-A-F films was investigated by UV–visible and infrared spectroscopy. Thermal analysis shows that the polymer films have good thermal stability. Fluorescent spectral studies indicate that polymer films in the solid state are blue-light emitters, which may meet potential applications in polymer light-emitting diodes. Polymer Film Carbazole Electrochemical Polymerization Mixed Electrolyte Alkyl Spacer Yue, Ruirui aut Lu, Baoyang aut Wei, Zhenhong aut Xu, Jingkun aut Enthalten in Journal of materials science Springer US, 1966 45(2010), 7 vom: 13. Jan., Seite 1963-1971 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:45 year:2010 number:7 day:13 month:01 pages:1963-1971 https://doi.org/10.1007/s10853-009-4188-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_100 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 45 2010 7 13 01 1963-1971
allfieldsGer	10.1007/s10853-009-4188-y doi (DE-627)OLC2046355733 (DE-He213)s10853-009-4188-y-p DE-627 ger DE-627 rakwb eng 670 VZ Wang, Xingcong verfasserin aut Synthesis and electrochemical polymerization of 9,9-bis(carbazolylalkyl)fluorene and characterization of its conducting polymer film with high tensile strength 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2010 Abstract Free-standing poly(9,9-bis(carbazolylalkyl)fluorene) (P2Cz-A-F, alkyl = hexyl or dodecyl) films with high tensile strength (185–200 kg $ cm^{−2} $) were electrochemically synthesized by direct anodic oxidation of the monomer 9,9-bis(carbazolylalkyl)fluorene (2Cz-A-F) in a mixed electrolyte of boron trifluoride diethyl etherate containing 30% $ CH_{2} $$ Cl_{2} $ (by volume). The electrochemical and physical properties show that the quality of P2Cz-A-F films are much better than that of polycarbazole (PCz) and polyfluorene (PF) films due to the specially designed structure consisting of stiff bicarbazyl chromophores linked by a flexible long alkyl spacer at the fluorene unit. The structure of free-standing P2Cz-A-F films was investigated by UV–visible and infrared spectroscopy. Thermal analysis shows that the polymer films have good thermal stability. Fluorescent spectral studies indicate that polymer films in the solid state are blue-light emitters, which may meet potential applications in polymer light-emitting diodes. Polymer Film Carbazole Electrochemical Polymerization Mixed Electrolyte Alkyl Spacer Yue, Ruirui aut Lu, Baoyang aut Wei, Zhenhong aut Xu, Jingkun aut Enthalten in Journal of materials science Springer US, 1966 45(2010), 7 vom: 13. Jan., Seite 1963-1971 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:45 year:2010 number:7 day:13 month:01 pages:1963-1971 https://doi.org/10.1007/s10853-009-4188-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_100 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 45 2010 7 13 01 1963-1971
allfieldsSound	10.1007/s10853-009-4188-y doi (DE-627)OLC2046355733 (DE-He213)s10853-009-4188-y-p DE-627 ger DE-627 rakwb eng 670 VZ Wang, Xingcong verfasserin aut Synthesis and electrochemical polymerization of 9,9-bis(carbazolylalkyl)fluorene and characterization of its conducting polymer film with high tensile strength 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2010 Abstract Free-standing poly(9,9-bis(carbazolylalkyl)fluorene) (P2Cz-A-F, alkyl = hexyl or dodecyl) films with high tensile strength (185–200 kg $ cm^{−2} $) were electrochemically synthesized by direct anodic oxidation of the monomer 9,9-bis(carbazolylalkyl)fluorene (2Cz-A-F) in a mixed electrolyte of boron trifluoride diethyl etherate containing 30% $ CH_{2} $$ Cl_{2} $ (by volume). The electrochemical and physical properties show that the quality of P2Cz-A-F films are much better than that of polycarbazole (PCz) and polyfluorene (PF) films due to the specially designed structure consisting of stiff bicarbazyl chromophores linked by a flexible long alkyl spacer at the fluorene unit. The structure of free-standing P2Cz-A-F films was investigated by UV–visible and infrared spectroscopy. Thermal analysis shows that the polymer films have good thermal stability. Fluorescent spectral studies indicate that polymer films in the solid state are blue-light emitters, which may meet potential applications in polymer light-emitting diodes. Polymer Film Carbazole Electrochemical Polymerization Mixed Electrolyte Alkyl Spacer Yue, Ruirui aut Lu, Baoyang aut Wei, Zhenhong aut Xu, Jingkun aut Enthalten in Journal of materials science Springer US, 1966 45(2010), 7 vom: 13. Jan., Seite 1963-1971 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:45 year:2010 number:7 day:13 month:01 pages:1963-1971 https://doi.org/10.1007/s10853-009-4188-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_100 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 45 2010 7 13 01 1963-1971
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topic_title	670 VZ Synthesis and electrochemical polymerization of 9,9-bis(carbazolylalkyl)fluorene and characterization of its conducting polymer film with high tensile strength Polymer Film Carbazole Electrochemical Polymerization Mixed Electrolyte Alkyl Spacer
topic	ddc 670 misc Polymer Film misc Carbazole misc Electrochemical Polymerization misc Mixed Electrolyte misc Alkyl Spacer
topic_unstemmed	ddc 670 misc Polymer Film misc Carbazole misc Electrochemical Polymerization misc Mixed Electrolyte misc Alkyl Spacer
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title	Synthesis and electrochemical polymerization of 9,9-bis(carbazolylalkyl)fluorene and characterization of its conducting polymer film with high tensile strength
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title_full	Synthesis and electrochemical polymerization of 9,9-bis(carbazolylalkyl)fluorene and characterization of its conducting polymer film with high tensile strength
author_sort	Wang, Xingcong
journal	Journal of materials science
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container_start_page	1963
author_browse	Wang, Xingcong Yue, Ruirui Lu, Baoyang Wei, Zhenhong Xu, Jingkun
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class	670 VZ
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author-letter	Wang, Xingcong
doi_str_mv	10.1007/s10853-009-4188-y
dewey-full	670
title_sort	synthesis and electrochemical polymerization of 9,9-bis(carbazolylalkyl)fluorene and characterization of its conducting polymer film with high tensile strength
title_auth	Synthesis and electrochemical polymerization of 9,9-bis(carbazolylalkyl)fluorene and characterization of its conducting polymer film with high tensile strength
abstract	Abstract Free-standing poly(9,9-bis(carbazolylalkyl)fluorene) (P2Cz-A-F, alkyl = hexyl or dodecyl) films with high tensile strength (185–200 kg $ cm^{−2} $) were electrochemically synthesized by direct anodic oxidation of the monomer 9,9-bis(carbazolylalkyl)fluorene (2Cz-A-F) in a mixed electrolyte of boron trifluoride diethyl etherate containing 30% $ CH_{2} $$ Cl_{2} $ (by volume). The electrochemical and physical properties show that the quality of P2Cz-A-F films are much better than that of polycarbazole (PCz) and polyfluorene (PF) films due to the specially designed structure consisting of stiff bicarbazyl chromophores linked by a flexible long alkyl spacer at the fluorene unit. The structure of free-standing P2Cz-A-F films was investigated by UV–visible and infrared spectroscopy. Thermal analysis shows that the polymer films have good thermal stability. Fluorescent spectral studies indicate that polymer films in the solid state are blue-light emitters, which may meet potential applications in polymer light-emitting diodes. © Springer Science+Business Media, LLC 2010
abstractGer	Abstract Free-standing poly(9,9-bis(carbazolylalkyl)fluorene) (P2Cz-A-F, alkyl = hexyl or dodecyl) films with high tensile strength (185–200 kg $ cm^{−2} $) were electrochemically synthesized by direct anodic oxidation of the monomer 9,9-bis(carbazolylalkyl)fluorene (2Cz-A-F) in a mixed electrolyte of boron trifluoride diethyl etherate containing 30% $ CH_{2} $$ Cl_{2} $ (by volume). The electrochemical and physical properties show that the quality of P2Cz-A-F films are much better than that of polycarbazole (PCz) and polyfluorene (PF) films due to the specially designed structure consisting of stiff bicarbazyl chromophores linked by a flexible long alkyl spacer at the fluorene unit. The structure of free-standing P2Cz-A-F films was investigated by UV–visible and infrared spectroscopy. Thermal analysis shows that the polymer films have good thermal stability. Fluorescent spectral studies indicate that polymer films in the solid state are blue-light emitters, which may meet potential applications in polymer light-emitting diodes. © Springer Science+Business Media, LLC 2010
abstract_unstemmed	Abstract Free-standing poly(9,9-bis(carbazolylalkyl)fluorene) (P2Cz-A-F, alkyl = hexyl or dodecyl) films with high tensile strength (185–200 kg $ cm^{−2} $) were electrochemically synthesized by direct anodic oxidation of the monomer 9,9-bis(carbazolylalkyl)fluorene (2Cz-A-F) in a mixed electrolyte of boron trifluoride diethyl etherate containing 30% $ CH_{2} $$ Cl_{2} $ (by volume). The electrochemical and physical properties show that the quality of P2Cz-A-F films are much better than that of polycarbazole (PCz) and polyfluorene (PF) films due to the specially designed structure consisting of stiff bicarbazyl chromophores linked by a flexible long alkyl spacer at the fluorene unit. The structure of free-standing P2Cz-A-F films was investigated by UV–visible and infrared spectroscopy. Thermal analysis shows that the polymer films have good thermal stability. Fluorescent spectral studies indicate that polymer films in the solid state are blue-light emitters, which may meet potential applications in polymer light-emitting diodes. © Springer Science+Business Media, LLC 2010
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container_issue	7
title_short	Synthesis and electrochemical polymerization of 9,9-bis(carbazolylalkyl)fluorene and characterization of its conducting polymer film with high tensile strength
url	https://doi.org/10.1007/s10853-009-4188-y
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author2	Yue, Ruirui Lu, Baoyang Wei, Zhenhong Xu, Jingkun
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up_date	2024-07-04T04:52:36.117Z
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