Stabilization of metastable tetragonal zirconia nanocrystallites by surface modification
Abstract Metastable tetragonal zirconia nanocrystallites were studied in humid air and in water at room temperature (RT). A stabilizing effect of different surfactants on the tetragonal phase was observed. Furthermore, the phase stability of silanized metastable tetragonal zirconia nanocrystallites...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Skovgaard, M. [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2010 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer Science+Business Media, LLC 2010 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of materials science - Springer US, 1966, 46(2010), 6 vom: 28. Okt., Seite 1824-1829 |
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| Übergeordnetes Werk: |
volume:46 ; year:2010 ; number:6 ; day:28 ; month:10 ; pages:1824-1829 |
| Links: |
|---|
| DOI / URN: |
10.1007/s10853-010-5007-1 |
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OLC2046364473 |
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| 520 | |a Abstract Metastable tetragonal zirconia nanocrystallites were studied in humid air and in water at room temperature (RT). A stabilizing effect of different surfactants on the tetragonal phase was observed. Furthermore, the phase stability of silanized metastable tetragonal zirconia nanocrystallites was tested by prolonged boiling in water. The samples were analyzed with X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). Changes in the monoclinic volume fraction in the samples were calculated. A number of surfactants were screened for their ability to stabilize the tetragonal phase upon exposure to humidity. Only silanes and phosphate esters of these were able to stabilize the tetragonal phase in water. Even as small amounts of silanes as 0.25 silane molecule per $ nm^{2} $ are able to stabilize the tetragonal phase in water at RT. Aminopropyl trimethoxy silane and γ-methacryloxypropyl trimethoxy silane were even capable of preventing phase transformation during boiling for 48 h in water. | ||
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10.1007/s10853-010-5007-1 doi (DE-627)OLC2046364473 (DE-He213)s10853-010-5007-1-p DE-627 ger DE-627 rakwb eng 670 VZ Skovgaard, M. verfasserin aut Stabilization of metastable tetragonal zirconia nanocrystallites by surface modification 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2010 Abstract Metastable tetragonal zirconia nanocrystallites were studied in humid air and in water at room temperature (RT). A stabilizing effect of different surfactants on the tetragonal phase was observed. Furthermore, the phase stability of silanized metastable tetragonal zirconia nanocrystallites was tested by prolonged boiling in water. The samples were analyzed with X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). Changes in the monoclinic volume fraction in the samples were calculated. A number of surfactants were screened for their ability to stabilize the tetragonal phase upon exposure to humidity. Only silanes and phosphate esters of these were able to stabilize the tetragonal phase in water. Even as small amounts of silanes as 0.25 silane molecule per $ nm^{2} $ are able to stabilize the tetragonal phase in water at RT. Aminopropyl trimethoxy silane and γ-methacryloxypropyl trimethoxy silane were even capable of preventing phase transformation during boiling for 48 h in water. Zirconia Tetragonal Phase Tetragonal Zirconia Anhydrous Methanol Zirconia Particle Almdal, K. aut van Lelieveld, A. aut Enthalten in Journal of materials science Springer US, 1966 46(2010), 6 vom: 28. Okt., Seite 1824-1829 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:46 year:2010 number:6 day:28 month:10 pages:1824-1829 https://doi.org/10.1007/s10853-010-5007-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_100 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 46 2010 6 28 10 1824-1829 |
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10.1007/s10853-010-5007-1 doi (DE-627)OLC2046364473 (DE-He213)s10853-010-5007-1-p DE-627 ger DE-627 rakwb eng 670 VZ Skovgaard, M. verfasserin aut Stabilization of metastable tetragonal zirconia nanocrystallites by surface modification 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2010 Abstract Metastable tetragonal zirconia nanocrystallites were studied in humid air and in water at room temperature (RT). A stabilizing effect of different surfactants on the tetragonal phase was observed. Furthermore, the phase stability of silanized metastable tetragonal zirconia nanocrystallites was tested by prolonged boiling in water. The samples were analyzed with X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). Changes in the monoclinic volume fraction in the samples were calculated. A number of surfactants were screened for their ability to stabilize the tetragonal phase upon exposure to humidity. Only silanes and phosphate esters of these were able to stabilize the tetragonal phase in water. Even as small amounts of silanes as 0.25 silane molecule per $ nm^{2} $ are able to stabilize the tetragonal phase in water at RT. Aminopropyl trimethoxy silane and γ-methacryloxypropyl trimethoxy silane were even capable of preventing phase transformation during boiling for 48 h in water. Zirconia Tetragonal Phase Tetragonal Zirconia Anhydrous Methanol Zirconia Particle Almdal, K. aut van Lelieveld, A. aut Enthalten in Journal of materials science Springer US, 1966 46(2010), 6 vom: 28. Okt., Seite 1824-1829 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:46 year:2010 number:6 day:28 month:10 pages:1824-1829 https://doi.org/10.1007/s10853-010-5007-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_100 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 46 2010 6 28 10 1824-1829 |
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10.1007/s10853-010-5007-1 doi (DE-627)OLC2046364473 (DE-He213)s10853-010-5007-1-p DE-627 ger DE-627 rakwb eng 670 VZ Skovgaard, M. verfasserin aut Stabilization of metastable tetragonal zirconia nanocrystallites by surface modification 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2010 Abstract Metastable tetragonal zirconia nanocrystallites were studied in humid air and in water at room temperature (RT). A stabilizing effect of different surfactants on the tetragonal phase was observed. Furthermore, the phase stability of silanized metastable tetragonal zirconia nanocrystallites was tested by prolonged boiling in water. The samples were analyzed with X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). Changes in the monoclinic volume fraction in the samples were calculated. A number of surfactants were screened for their ability to stabilize the tetragonal phase upon exposure to humidity. Only silanes and phosphate esters of these were able to stabilize the tetragonal phase in water. Even as small amounts of silanes as 0.25 silane molecule per $ nm^{2} $ are able to stabilize the tetragonal phase in water at RT. Aminopropyl trimethoxy silane and γ-methacryloxypropyl trimethoxy silane were even capable of preventing phase transformation during boiling for 48 h in water. Zirconia Tetragonal Phase Tetragonal Zirconia Anhydrous Methanol Zirconia Particle Almdal, K. aut van Lelieveld, A. aut Enthalten in Journal of materials science Springer US, 1966 46(2010), 6 vom: 28. Okt., Seite 1824-1829 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:46 year:2010 number:6 day:28 month:10 pages:1824-1829 https://doi.org/10.1007/s10853-010-5007-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_100 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 46 2010 6 28 10 1824-1829 |
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10.1007/s10853-010-5007-1 doi (DE-627)OLC2046364473 (DE-He213)s10853-010-5007-1-p DE-627 ger DE-627 rakwb eng 670 VZ Skovgaard, M. verfasserin aut Stabilization of metastable tetragonal zirconia nanocrystallites by surface modification 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2010 Abstract Metastable tetragonal zirconia nanocrystallites were studied in humid air and in water at room temperature (RT). A stabilizing effect of different surfactants on the tetragonal phase was observed. Furthermore, the phase stability of silanized metastable tetragonal zirconia nanocrystallites was tested by prolonged boiling in water. The samples were analyzed with X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). Changes in the monoclinic volume fraction in the samples were calculated. A number of surfactants were screened for their ability to stabilize the tetragonal phase upon exposure to humidity. Only silanes and phosphate esters of these were able to stabilize the tetragonal phase in water. Even as small amounts of silanes as 0.25 silane molecule per $ nm^{2} $ are able to stabilize the tetragonal phase in water at RT. Aminopropyl trimethoxy silane and γ-methacryloxypropyl trimethoxy silane were even capable of preventing phase transformation during boiling for 48 h in water. Zirconia Tetragonal Phase Tetragonal Zirconia Anhydrous Methanol Zirconia Particle Almdal, K. aut van Lelieveld, A. aut Enthalten in Journal of materials science Springer US, 1966 46(2010), 6 vom: 28. Okt., Seite 1824-1829 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:46 year:2010 number:6 day:28 month:10 pages:1824-1829 https://doi.org/10.1007/s10853-010-5007-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_100 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 46 2010 6 28 10 1824-1829 |
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10.1007/s10853-010-5007-1 doi (DE-627)OLC2046364473 (DE-He213)s10853-010-5007-1-p DE-627 ger DE-627 rakwb eng 670 VZ Skovgaard, M. verfasserin aut Stabilization of metastable tetragonal zirconia nanocrystallites by surface modification 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2010 Abstract Metastable tetragonal zirconia nanocrystallites were studied in humid air and in water at room temperature (RT). A stabilizing effect of different surfactants on the tetragonal phase was observed. Furthermore, the phase stability of silanized metastable tetragonal zirconia nanocrystallites was tested by prolonged boiling in water. The samples were analyzed with X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). Changes in the monoclinic volume fraction in the samples were calculated. A number of surfactants were screened for their ability to stabilize the tetragonal phase upon exposure to humidity. Only silanes and phosphate esters of these were able to stabilize the tetragonal phase in water. Even as small amounts of silanes as 0.25 silane molecule per $ nm^{2} $ are able to stabilize the tetragonal phase in water at RT. Aminopropyl trimethoxy silane and γ-methacryloxypropyl trimethoxy silane were even capable of preventing phase transformation during boiling for 48 h in water. Zirconia Tetragonal Phase Tetragonal Zirconia Anhydrous Methanol Zirconia Particle Almdal, K. aut van Lelieveld, A. aut Enthalten in Journal of materials science Springer US, 1966 46(2010), 6 vom: 28. Okt., Seite 1824-1829 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:46 year:2010 number:6 day:28 month:10 pages:1824-1829 https://doi.org/10.1007/s10853-010-5007-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_100 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 46 2010 6 28 10 1824-1829 |
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Stabilization of metastable tetragonal zirconia nanocrystallites by surface modification |
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Stabilization of metastable tetragonal zirconia nanocrystallites by surface modification |
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Skovgaard, M. |
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Journal of materials science |
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Skovgaard, M. Almdal, K. van Lelieveld, A. |
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Skovgaard, M. |
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10.1007/s10853-010-5007-1 |
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670 |
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stabilization of metastable tetragonal zirconia nanocrystallites by surface modification |
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Stabilization of metastable tetragonal zirconia nanocrystallites by surface modification |
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Abstract Metastable tetragonal zirconia nanocrystallites were studied in humid air and in water at room temperature (RT). A stabilizing effect of different surfactants on the tetragonal phase was observed. Furthermore, the phase stability of silanized metastable tetragonal zirconia nanocrystallites was tested by prolonged boiling in water. The samples were analyzed with X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). Changes in the monoclinic volume fraction in the samples were calculated. A number of surfactants were screened for their ability to stabilize the tetragonal phase upon exposure to humidity. Only silanes and phosphate esters of these were able to stabilize the tetragonal phase in water. Even as small amounts of silanes as 0.25 silane molecule per $ nm^{2} $ are able to stabilize the tetragonal phase in water at RT. Aminopropyl trimethoxy silane and γ-methacryloxypropyl trimethoxy silane were even capable of preventing phase transformation during boiling for 48 h in water. © Springer Science+Business Media, LLC 2010 |
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Abstract Metastable tetragonal zirconia nanocrystallites were studied in humid air and in water at room temperature (RT). A stabilizing effect of different surfactants on the tetragonal phase was observed. Furthermore, the phase stability of silanized metastable tetragonal zirconia nanocrystallites was tested by prolonged boiling in water. The samples were analyzed with X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). Changes in the monoclinic volume fraction in the samples were calculated. A number of surfactants were screened for their ability to stabilize the tetragonal phase upon exposure to humidity. Only silanes and phosphate esters of these were able to stabilize the tetragonal phase in water. Even as small amounts of silanes as 0.25 silane molecule per $ nm^{2} $ are able to stabilize the tetragonal phase in water at RT. Aminopropyl trimethoxy silane and γ-methacryloxypropyl trimethoxy silane were even capable of preventing phase transformation during boiling for 48 h in water. © Springer Science+Business Media, LLC 2010 |
| abstract_unstemmed |
Abstract Metastable tetragonal zirconia nanocrystallites were studied in humid air and in water at room temperature (RT). A stabilizing effect of different surfactants on the tetragonal phase was observed. Furthermore, the phase stability of silanized metastable tetragonal zirconia nanocrystallites was tested by prolonged boiling in water. The samples were analyzed with X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). Changes in the monoclinic volume fraction in the samples were calculated. A number of surfactants were screened for their ability to stabilize the tetragonal phase upon exposure to humidity. Only silanes and phosphate esters of these were able to stabilize the tetragonal phase in water. Even as small amounts of silanes as 0.25 silane molecule per $ nm^{2} $ are able to stabilize the tetragonal phase in water at RT. Aminopropyl trimethoxy silane and γ-methacryloxypropyl trimethoxy silane were even capable of preventing phase transformation during boiling for 48 h in water. © Springer Science+Business Media, LLC 2010 |
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Stabilization of metastable tetragonal zirconia nanocrystallites by surface modification |
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