Electrosynthesis and characterization of a polyfluorene derivative with green-light-emitting property
Abstract Green-light-emitting poly(diphenylmethylenefluorene) (PDPMF) was synthesized electrochemically by direct anodic oxidation of diphenylmethylenefluorene (DPMF) in dichloromethane ($ CH_{2} $$ Cl_{2} $) and boron trifluoride diethyl etherate (BFEE) binary solution. The oxidation potential of D...
Ausführliche Beschreibung
Autor*in: |
Lu, Baoyang [verfasserIn] |
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Format: |
Artikel |
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Sprache: |
Englisch |
Erschienen: |
2011 |
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Anmerkung: |
© Springer Science+Business Media, LLC 2011 |
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Übergeordnetes Werk: |
Enthalten in: Journal of materials science - Springer US, 1966, 47(2011), 1 vom: 29. Juli, Seite 315-322 |
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Übergeordnetes Werk: |
volume:47 ; year:2011 ; number:1 ; day:29 ; month:07 ; pages:315-322 |
Links: |
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DOI / URN: |
10.1007/s10853-011-5800-5 |
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Katalog-ID: |
OLC2046372204 |
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10.1007/s10853-011-5800-5 doi (DE-627)OLC2046372204 (DE-He213)s10853-011-5800-5-p DE-627 ger DE-627 rakwb eng 670 VZ Lu, Baoyang verfasserin aut Electrosynthesis and characterization of a polyfluorene derivative with green-light-emitting property 2011 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2011 Abstract Green-light-emitting poly(diphenylmethylenefluorene) (PDPMF) was synthesized electrochemically by direct anodic oxidation of diphenylmethylenefluorene (DPMF) in dichloromethane ($ CH_{2} $$ Cl_{2} $) and boron trifluoride diethyl etherate (BFEE) binary solution. The oxidation potential of DPMF in this medium was measured to be only 0.78 V versus Ag/AgCl, which was lower than that determined in $ CH_{2} $$ Cl_{2} $ (1.0 V versus Ag/AgCl) or acetonitrile (ACN) (1.16 V versus Ag/AgCl) with 0.1 mol $ L^{−1} $ tetrabutylammonium tetrafluoroborate ($ Bu_{4} $$ NBF_{4} $) as the supporting electrolyte. The as-formed PDPMF films showed good electrochemical behavior and high thermal stability. Fluorescent spectra indicate that PDPMF is a good green-light-emitter with strong and bright green or yellow-green photoluminescence under 365 nm UV light. CH2Cl2 Polymer Film Fluorescence Quantum Yield Electrochemical Polymerization Molar Mass Distribution Wang, Jiong aut Yue, Ruirui aut Xu, Jingkun aut Pei, Meishan aut Enthalten in Journal of materials science Springer US, 1966 47(2011), 1 vom: 29. Juli, Seite 315-322 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:47 year:2011 number:1 day:29 month:07 pages:315-322 https://doi.org/10.1007/s10853-011-5800-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 47 2011 1 29 07 315-322 |
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10.1007/s10853-011-5800-5 doi (DE-627)OLC2046372204 (DE-He213)s10853-011-5800-5-p DE-627 ger DE-627 rakwb eng 670 VZ Lu, Baoyang verfasserin aut Electrosynthesis and characterization of a polyfluorene derivative with green-light-emitting property 2011 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2011 Abstract Green-light-emitting poly(diphenylmethylenefluorene) (PDPMF) was synthesized electrochemically by direct anodic oxidation of diphenylmethylenefluorene (DPMF) in dichloromethane ($ CH_{2} $$ Cl_{2} $) and boron trifluoride diethyl etherate (BFEE) binary solution. The oxidation potential of DPMF in this medium was measured to be only 0.78 V versus Ag/AgCl, which was lower than that determined in $ CH_{2} $$ Cl_{2} $ (1.0 V versus Ag/AgCl) or acetonitrile (ACN) (1.16 V versus Ag/AgCl) with 0.1 mol $ L^{−1} $ tetrabutylammonium tetrafluoroborate ($ Bu_{4} $$ NBF_{4} $) as the supporting electrolyte. The as-formed PDPMF films showed good electrochemical behavior and high thermal stability. Fluorescent spectra indicate that PDPMF is a good green-light-emitter with strong and bright green or yellow-green photoluminescence under 365 nm UV light. CH2Cl2 Polymer Film Fluorescence Quantum Yield Electrochemical Polymerization Molar Mass Distribution Wang, Jiong aut Yue, Ruirui aut Xu, Jingkun aut Pei, Meishan aut Enthalten in Journal of materials science Springer US, 1966 47(2011), 1 vom: 29. Juli, Seite 315-322 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:47 year:2011 number:1 day:29 month:07 pages:315-322 https://doi.org/10.1007/s10853-011-5800-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 47 2011 1 29 07 315-322 |
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10.1007/s10853-011-5800-5 doi (DE-627)OLC2046372204 (DE-He213)s10853-011-5800-5-p DE-627 ger DE-627 rakwb eng 670 VZ Lu, Baoyang verfasserin aut Electrosynthesis and characterization of a polyfluorene derivative with green-light-emitting property 2011 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2011 Abstract Green-light-emitting poly(diphenylmethylenefluorene) (PDPMF) was synthesized electrochemically by direct anodic oxidation of diphenylmethylenefluorene (DPMF) in dichloromethane ($ CH_{2} $$ Cl_{2} $) and boron trifluoride diethyl etherate (BFEE) binary solution. The oxidation potential of DPMF in this medium was measured to be only 0.78 V versus Ag/AgCl, which was lower than that determined in $ CH_{2} $$ Cl_{2} $ (1.0 V versus Ag/AgCl) or acetonitrile (ACN) (1.16 V versus Ag/AgCl) with 0.1 mol $ L^{−1} $ tetrabutylammonium tetrafluoroborate ($ Bu_{4} $$ NBF_{4} $) as the supporting electrolyte. The as-formed PDPMF films showed good electrochemical behavior and high thermal stability. Fluorescent spectra indicate that PDPMF is a good green-light-emitter with strong and bright green or yellow-green photoluminescence under 365 nm UV light. CH2Cl2 Polymer Film Fluorescence Quantum Yield Electrochemical Polymerization Molar Mass Distribution Wang, Jiong aut Yue, Ruirui aut Xu, Jingkun aut Pei, Meishan aut Enthalten in Journal of materials science Springer US, 1966 47(2011), 1 vom: 29. Juli, Seite 315-322 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:47 year:2011 number:1 day:29 month:07 pages:315-322 https://doi.org/10.1007/s10853-011-5800-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 47 2011 1 29 07 315-322 |
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10.1007/s10853-011-5800-5 doi (DE-627)OLC2046372204 (DE-He213)s10853-011-5800-5-p DE-627 ger DE-627 rakwb eng 670 VZ Lu, Baoyang verfasserin aut Electrosynthesis and characterization of a polyfluorene derivative with green-light-emitting property 2011 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2011 Abstract Green-light-emitting poly(diphenylmethylenefluorene) (PDPMF) was synthesized electrochemically by direct anodic oxidation of diphenylmethylenefluorene (DPMF) in dichloromethane ($ CH_{2} $$ Cl_{2} $) and boron trifluoride diethyl etherate (BFEE) binary solution. The oxidation potential of DPMF in this medium was measured to be only 0.78 V versus Ag/AgCl, which was lower than that determined in $ CH_{2} $$ Cl_{2} $ (1.0 V versus Ag/AgCl) or acetonitrile (ACN) (1.16 V versus Ag/AgCl) with 0.1 mol $ L^{−1} $ tetrabutylammonium tetrafluoroborate ($ Bu_{4} $$ NBF_{4} $) as the supporting electrolyte. The as-formed PDPMF films showed good electrochemical behavior and high thermal stability. Fluorescent spectra indicate that PDPMF is a good green-light-emitter with strong and bright green or yellow-green photoluminescence under 365 nm UV light. CH2Cl2 Polymer Film Fluorescence Quantum Yield Electrochemical Polymerization Molar Mass Distribution Wang, Jiong aut Yue, Ruirui aut Xu, Jingkun aut Pei, Meishan aut Enthalten in Journal of materials science Springer US, 1966 47(2011), 1 vom: 29. Juli, Seite 315-322 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:47 year:2011 number:1 day:29 month:07 pages:315-322 https://doi.org/10.1007/s10853-011-5800-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 47 2011 1 29 07 315-322 |
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10.1007/s10853-011-5800-5 doi (DE-627)OLC2046372204 (DE-He213)s10853-011-5800-5-p DE-627 ger DE-627 rakwb eng 670 VZ Lu, Baoyang verfasserin aut Electrosynthesis and characterization of a polyfluorene derivative with green-light-emitting property 2011 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2011 Abstract Green-light-emitting poly(diphenylmethylenefluorene) (PDPMF) was synthesized electrochemically by direct anodic oxidation of diphenylmethylenefluorene (DPMF) in dichloromethane ($ CH_{2} $$ Cl_{2} $) and boron trifluoride diethyl etherate (BFEE) binary solution. The oxidation potential of DPMF in this medium was measured to be only 0.78 V versus Ag/AgCl, which was lower than that determined in $ CH_{2} $$ Cl_{2} $ (1.0 V versus Ag/AgCl) or acetonitrile (ACN) (1.16 V versus Ag/AgCl) with 0.1 mol $ L^{−1} $ tetrabutylammonium tetrafluoroborate ($ Bu_{4} $$ NBF_{4} $) as the supporting electrolyte. The as-formed PDPMF films showed good electrochemical behavior and high thermal stability. Fluorescent spectra indicate that PDPMF is a good green-light-emitter with strong and bright green or yellow-green photoluminescence under 365 nm UV light. CH2Cl2 Polymer Film Fluorescence Quantum Yield Electrochemical Polymerization Molar Mass Distribution Wang, Jiong aut Yue, Ruirui aut Xu, Jingkun aut Pei, Meishan aut Enthalten in Journal of materials science Springer US, 1966 47(2011), 1 vom: 29. Juli, Seite 315-322 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:47 year:2011 number:1 day:29 month:07 pages:315-322 https://doi.org/10.1007/s10853-011-5800-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 47 2011 1 29 07 315-322 |
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Electrosynthesis and characterization of a polyfluorene derivative with green-light-emitting property |
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Electrosynthesis and characterization of a polyfluorene derivative with green-light-emitting property |
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Lu, Baoyang |
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Lu, Baoyang Wang, Jiong Yue, Ruirui Xu, Jingkun Pei, Meishan |
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electrosynthesis and characterization of a polyfluorene derivative with green-light-emitting property |
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Electrosynthesis and characterization of a polyfluorene derivative with green-light-emitting property |
abstract |
Abstract Green-light-emitting poly(diphenylmethylenefluorene) (PDPMF) was synthesized electrochemically by direct anodic oxidation of diphenylmethylenefluorene (DPMF) in dichloromethane ($ CH_{2} $$ Cl_{2} $) and boron trifluoride diethyl etherate (BFEE) binary solution. The oxidation potential of DPMF in this medium was measured to be only 0.78 V versus Ag/AgCl, which was lower than that determined in $ CH_{2} $$ Cl_{2} $ (1.0 V versus Ag/AgCl) or acetonitrile (ACN) (1.16 V versus Ag/AgCl) with 0.1 mol $ L^{−1} $ tetrabutylammonium tetrafluoroborate ($ Bu_{4} $$ NBF_{4} $) as the supporting electrolyte. The as-formed PDPMF films showed good electrochemical behavior and high thermal stability. Fluorescent spectra indicate that PDPMF is a good green-light-emitter with strong and bright green or yellow-green photoluminescence under 365 nm UV light. © Springer Science+Business Media, LLC 2011 |
abstractGer |
Abstract Green-light-emitting poly(diphenylmethylenefluorene) (PDPMF) was synthesized electrochemically by direct anodic oxidation of diphenylmethylenefluorene (DPMF) in dichloromethane ($ CH_{2} $$ Cl_{2} $) and boron trifluoride diethyl etherate (BFEE) binary solution. The oxidation potential of DPMF in this medium was measured to be only 0.78 V versus Ag/AgCl, which was lower than that determined in $ CH_{2} $$ Cl_{2} $ (1.0 V versus Ag/AgCl) or acetonitrile (ACN) (1.16 V versus Ag/AgCl) with 0.1 mol $ L^{−1} $ tetrabutylammonium tetrafluoroborate ($ Bu_{4} $$ NBF_{4} $) as the supporting electrolyte. The as-formed PDPMF films showed good electrochemical behavior and high thermal stability. Fluorescent spectra indicate that PDPMF is a good green-light-emitter with strong and bright green or yellow-green photoluminescence under 365 nm UV light. © Springer Science+Business Media, LLC 2011 |
abstract_unstemmed |
Abstract Green-light-emitting poly(diphenylmethylenefluorene) (PDPMF) was synthesized electrochemically by direct anodic oxidation of diphenylmethylenefluorene (DPMF) in dichloromethane ($ CH_{2} $$ Cl_{2} $) and boron trifluoride diethyl etherate (BFEE) binary solution. The oxidation potential of DPMF in this medium was measured to be only 0.78 V versus Ag/AgCl, which was lower than that determined in $ CH_{2} $$ Cl_{2} $ (1.0 V versus Ag/AgCl) or acetonitrile (ACN) (1.16 V versus Ag/AgCl) with 0.1 mol $ L^{−1} $ tetrabutylammonium tetrafluoroborate ($ Bu_{4} $$ NBF_{4} $) as the supporting electrolyte. The as-formed PDPMF films showed good electrochemical behavior and high thermal stability. Fluorescent spectra indicate that PDPMF is a good green-light-emitter with strong and bright green or yellow-green photoluminescence under 365 nm UV light. © Springer Science+Business Media, LLC 2011 |
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Electrosynthesis and characterization of a polyfluorene derivative with green-light-emitting property |
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