Electrosynthesis and characterization of a polyfluorene derivative with green-light-emitting property

Abstract Green-light-emitting poly(diphenylmethylenefluorene) (PDPMF) was synthesized electrochemically by direct anodic oxidation of diphenylmethylenefluorene (DPMF) in dichloromethane ($ CH_{2} $$ Cl_{2} $) and boron trifluoride diethyl etherate (BFEE) binary solution. The oxidation potential of D...
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Autor*in:	Lu, Baoyang [verfasserIn] Wang, Jiong Yue, Ruirui Xu, Jingkun Pei, Meishan

Format:	Artikel
Sprache:	Englisch

Erschienen:	2011

Schlagwörter:	CH2Cl2 Polymer Film Fluorescence Quantum Yield Electrochemical Polymerization Molar Mass Distribution

Anmerkung:	© Springer Science+Business Media, LLC 2011

Übergeordnetes Werk:	Enthalten in: Journal of materials science - Springer US, 1966, 47(2011), 1 vom: 29. Juli, Seite 315-322
Übergeordnetes Werk:	volume:47 ; year:2011 ; number:1 ; day:29 ; month:07 ; pages:315-322

Links:	Volltext

DOI / URN:	10.1007/s10853-011-5800-5

Katalog-ID:	OLC2046372204

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520			\|a Abstract Green-light-emitting poly(diphenylmethylenefluorene) (PDPMF) was synthesized electrochemically by direct anodic oxidation of diphenylmethylenefluorene (DPMF) in dichloromethane ($ CH_{2} $$ Cl_{2} $) and boron trifluoride diethyl etherate (BFEE) binary solution. The oxidation potential of DPMF in this medium was measured to be only 0.78 V versus Ag/AgCl, which was lower than that determined in $ CH_{2} $$ Cl_{2} $ (1.0 V versus Ag/AgCl) or acetonitrile (ACN) (1.16 V versus Ag/AgCl) with 0.1 mol $ L^{−1} $ tetrabutylammonium tetrafluoroborate ($ Bu_{4} $$ NBF_{4} $) as the supporting electrolyte. The as-formed PDPMF films showed good electrochemical behavior and high thermal stability. Fluorescent spectra indicate that PDPMF is a good green-light-emitter with strong and bright green or yellow-green photoluminescence under 365 nm UV light.
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allfields	10.1007/s10853-011-5800-5 doi (DE-627)OLC2046372204 (DE-He213)s10853-011-5800-5-p DE-627 ger DE-627 rakwb eng 670 VZ Lu, Baoyang verfasserin aut Electrosynthesis and characterization of a polyfluorene derivative with green-light-emitting property 2011 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2011 Abstract Green-light-emitting poly(diphenylmethylenefluorene) (PDPMF) was synthesized electrochemically by direct anodic oxidation of diphenylmethylenefluorene (DPMF) in dichloromethane ($ CH_{2} $$ Cl_{2} $) and boron trifluoride diethyl etherate (BFEE) binary solution. The oxidation potential of DPMF in this medium was measured to be only 0.78 V versus Ag/AgCl, which was lower than that determined in $ CH_{2} $$ Cl_{2} $ (1.0 V versus Ag/AgCl) or acetonitrile (ACN) (1.16 V versus Ag/AgCl) with 0.1 mol $ L^{−1} $ tetrabutylammonium tetrafluoroborate ($ Bu_{4} $$ NBF_{4} $) as the supporting electrolyte. The as-formed PDPMF films showed good electrochemical behavior and high thermal stability. Fluorescent spectra indicate that PDPMF is a good green-light-emitter with strong and bright green or yellow-green photoluminescence under 365 nm UV light. CH2Cl2 Polymer Film Fluorescence Quantum Yield Electrochemical Polymerization Molar Mass Distribution Wang, Jiong aut Yue, Ruirui aut Xu, Jingkun aut Pei, Meishan aut Enthalten in Journal of materials science Springer US, 1966 47(2011), 1 vom: 29. Juli, Seite 315-322 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:47 year:2011 number:1 day:29 month:07 pages:315-322 https://doi.org/10.1007/s10853-011-5800-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 47 2011 1 29 07 315-322
spelling	10.1007/s10853-011-5800-5 doi (DE-627)OLC2046372204 (DE-He213)s10853-011-5800-5-p DE-627 ger DE-627 rakwb eng 670 VZ Lu, Baoyang verfasserin aut Electrosynthesis and characterization of a polyfluorene derivative with green-light-emitting property 2011 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2011 Abstract Green-light-emitting poly(diphenylmethylenefluorene) (PDPMF) was synthesized electrochemically by direct anodic oxidation of diphenylmethylenefluorene (DPMF) in dichloromethane ($ CH_{2} $$ Cl_{2} $) and boron trifluoride diethyl etherate (BFEE) binary solution. The oxidation potential of DPMF in this medium was measured to be only 0.78 V versus Ag/AgCl, which was lower than that determined in $ CH_{2} $$ Cl_{2} $ (1.0 V versus Ag/AgCl) or acetonitrile (ACN) (1.16 V versus Ag/AgCl) with 0.1 mol $ L^{−1} $ tetrabutylammonium tetrafluoroborate ($ Bu_{4} $$ NBF_{4} $) as the supporting electrolyte. The as-formed PDPMF films showed good electrochemical behavior and high thermal stability. Fluorescent spectra indicate that PDPMF is a good green-light-emitter with strong and bright green or yellow-green photoluminescence under 365 nm UV light. CH2Cl2 Polymer Film Fluorescence Quantum Yield Electrochemical Polymerization Molar Mass Distribution Wang, Jiong aut Yue, Ruirui aut Xu, Jingkun aut Pei, Meishan aut Enthalten in Journal of materials science Springer US, 1966 47(2011), 1 vom: 29. Juli, Seite 315-322 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:47 year:2011 number:1 day:29 month:07 pages:315-322 https://doi.org/10.1007/s10853-011-5800-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 47 2011 1 29 07 315-322
allfields_unstemmed	10.1007/s10853-011-5800-5 doi (DE-627)OLC2046372204 (DE-He213)s10853-011-5800-5-p DE-627 ger DE-627 rakwb eng 670 VZ Lu, Baoyang verfasserin aut Electrosynthesis and characterization of a polyfluorene derivative with green-light-emitting property 2011 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2011 Abstract Green-light-emitting poly(diphenylmethylenefluorene) (PDPMF) was synthesized electrochemically by direct anodic oxidation of diphenylmethylenefluorene (DPMF) in dichloromethane ($ CH_{2} $$ Cl_{2} $) and boron trifluoride diethyl etherate (BFEE) binary solution. The oxidation potential of DPMF in this medium was measured to be only 0.78 V versus Ag/AgCl, which was lower than that determined in $ CH_{2} $$ Cl_{2} $ (1.0 V versus Ag/AgCl) or acetonitrile (ACN) (1.16 V versus Ag/AgCl) with 0.1 mol $ L^{−1} $ tetrabutylammonium tetrafluoroborate ($ Bu_{4} $$ NBF_{4} $) as the supporting electrolyte. The as-formed PDPMF films showed good electrochemical behavior and high thermal stability. Fluorescent spectra indicate that PDPMF is a good green-light-emitter with strong and bright green or yellow-green photoluminescence under 365 nm UV light. CH2Cl2 Polymer Film Fluorescence Quantum Yield Electrochemical Polymerization Molar Mass Distribution Wang, Jiong aut Yue, Ruirui aut Xu, Jingkun aut Pei, Meishan aut Enthalten in Journal of materials science Springer US, 1966 47(2011), 1 vom: 29. Juli, Seite 315-322 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:47 year:2011 number:1 day:29 month:07 pages:315-322 https://doi.org/10.1007/s10853-011-5800-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 47 2011 1 29 07 315-322
allfieldsGer	10.1007/s10853-011-5800-5 doi (DE-627)OLC2046372204 (DE-He213)s10853-011-5800-5-p DE-627 ger DE-627 rakwb eng 670 VZ Lu, Baoyang verfasserin aut Electrosynthesis and characterization of a polyfluorene derivative with green-light-emitting property 2011 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2011 Abstract Green-light-emitting poly(diphenylmethylenefluorene) (PDPMF) was synthesized electrochemically by direct anodic oxidation of diphenylmethylenefluorene (DPMF) in dichloromethane ($ CH_{2} $$ Cl_{2} $) and boron trifluoride diethyl etherate (BFEE) binary solution. The oxidation potential of DPMF in this medium was measured to be only 0.78 V versus Ag/AgCl, which was lower than that determined in $ CH_{2} $$ Cl_{2} $ (1.0 V versus Ag/AgCl) or acetonitrile (ACN) (1.16 V versus Ag/AgCl) with 0.1 mol $ L^{−1} $ tetrabutylammonium tetrafluoroborate ($ Bu_{4} $$ NBF_{4} $) as the supporting electrolyte. The as-formed PDPMF films showed good electrochemical behavior and high thermal stability. Fluorescent spectra indicate that PDPMF is a good green-light-emitter with strong and bright green or yellow-green photoluminescence under 365 nm UV light. CH2Cl2 Polymer Film Fluorescence Quantum Yield Electrochemical Polymerization Molar Mass Distribution Wang, Jiong aut Yue, Ruirui aut Xu, Jingkun aut Pei, Meishan aut Enthalten in Journal of materials science Springer US, 1966 47(2011), 1 vom: 29. Juli, Seite 315-322 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:47 year:2011 number:1 day:29 month:07 pages:315-322 https://doi.org/10.1007/s10853-011-5800-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 47 2011 1 29 07 315-322
allfieldsSound	10.1007/s10853-011-5800-5 doi (DE-627)OLC2046372204 (DE-He213)s10853-011-5800-5-p DE-627 ger DE-627 rakwb eng 670 VZ Lu, Baoyang verfasserin aut Electrosynthesis and characterization of a polyfluorene derivative with green-light-emitting property 2011 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2011 Abstract Green-light-emitting poly(diphenylmethylenefluorene) (PDPMF) was synthesized electrochemically by direct anodic oxidation of diphenylmethylenefluorene (DPMF) in dichloromethane ($ CH_{2} $$ Cl_{2} $) and boron trifluoride diethyl etherate (BFEE) binary solution. The oxidation potential of DPMF in this medium was measured to be only 0.78 V versus Ag/AgCl, which was lower than that determined in $ CH_{2} $$ Cl_{2} $ (1.0 V versus Ag/AgCl) or acetonitrile (ACN) (1.16 V versus Ag/AgCl) with 0.1 mol $ L^{−1} $ tetrabutylammonium tetrafluoroborate ($ Bu_{4} $$ NBF_{4} $) as the supporting electrolyte. The as-formed PDPMF films showed good electrochemical behavior and high thermal stability. Fluorescent spectra indicate that PDPMF is a good green-light-emitter with strong and bright green or yellow-green photoluminescence under 365 nm UV light. CH2Cl2 Polymer Film Fluorescence Quantum Yield Electrochemical Polymerization Molar Mass Distribution Wang, Jiong aut Yue, Ruirui aut Xu, Jingkun aut Pei, Meishan aut Enthalten in Journal of materials science Springer US, 1966 47(2011), 1 vom: 29. Juli, Seite 315-322 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:47 year:2011 number:1 day:29 month:07 pages:315-322 https://doi.org/10.1007/s10853-011-5800-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 47 2011 1 29 07 315-322
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title	Electrosynthesis and characterization of a polyfluorene derivative with green-light-emitting property
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title_full	Electrosynthesis and characterization of a polyfluorene derivative with green-light-emitting property
author_sort	Lu, Baoyang
journal	Journal of materials science
journalStr	Journal of materials science
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author_browse	Lu, Baoyang Wang, Jiong Yue, Ruirui Xu, Jingkun Pei, Meishan
container_volume	47
class	670 VZ
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author-letter	Lu, Baoyang
doi_str_mv	10.1007/s10853-011-5800-5
dewey-full	670
title_sort	electrosynthesis and characterization of a polyfluorene derivative with green-light-emitting property
title_auth	Electrosynthesis and characterization of a polyfluorene derivative with green-light-emitting property
abstract	Abstract Green-light-emitting poly(diphenylmethylenefluorene) (PDPMF) was synthesized electrochemically by direct anodic oxidation of diphenylmethylenefluorene (DPMF) in dichloromethane ($ CH_{2} $$ Cl_{2} $) and boron trifluoride diethyl etherate (BFEE) binary solution. The oxidation potential of DPMF in this medium was measured to be only 0.78 V versus Ag/AgCl, which was lower than that determined in $ CH_{2} $$ Cl_{2} $ (1.0 V versus Ag/AgCl) or acetonitrile (ACN) (1.16 V versus Ag/AgCl) with 0.1 mol $ L^{−1} $ tetrabutylammonium tetrafluoroborate ($ Bu_{4} $$ NBF_{4} $) as the supporting electrolyte. The as-formed PDPMF films showed good electrochemical behavior and high thermal stability. Fluorescent spectra indicate that PDPMF is a good green-light-emitter with strong and bright green or yellow-green photoluminescence under 365 nm UV light. © Springer Science+Business Media, LLC 2011
abstractGer	Abstract Green-light-emitting poly(diphenylmethylenefluorene) (PDPMF) was synthesized electrochemically by direct anodic oxidation of diphenylmethylenefluorene (DPMF) in dichloromethane ($ CH_{2} $$ Cl_{2} $) and boron trifluoride diethyl etherate (BFEE) binary solution. The oxidation potential of DPMF in this medium was measured to be only 0.78 V versus Ag/AgCl, which was lower than that determined in $ CH_{2} $$ Cl_{2} $ (1.0 V versus Ag/AgCl) or acetonitrile (ACN) (1.16 V versus Ag/AgCl) with 0.1 mol $ L^{−1} $ tetrabutylammonium tetrafluoroborate ($ Bu_{4} $$ NBF_{4} $) as the supporting electrolyte. The as-formed PDPMF films showed good electrochemical behavior and high thermal stability. Fluorescent spectra indicate that PDPMF is a good green-light-emitter with strong and bright green or yellow-green photoluminescence under 365 nm UV light. © Springer Science+Business Media, LLC 2011
abstract_unstemmed	Abstract Green-light-emitting poly(diphenylmethylenefluorene) (PDPMF) was synthesized electrochemically by direct anodic oxidation of diphenylmethylenefluorene (DPMF) in dichloromethane ($ CH_{2} $$ Cl_{2} $) and boron trifluoride diethyl etherate (BFEE) binary solution. The oxidation potential of DPMF in this medium was measured to be only 0.78 V versus Ag/AgCl, which was lower than that determined in $ CH_{2} $$ Cl_{2} $ (1.0 V versus Ag/AgCl) or acetonitrile (ACN) (1.16 V versus Ag/AgCl) with 0.1 mol $ L^{−1} $ tetrabutylammonium tetrafluoroborate ($ Bu_{4} $$ NBF_{4} $) as the supporting electrolyte. The as-formed PDPMF films showed good electrochemical behavior and high thermal stability. Fluorescent spectra indicate that PDPMF is a good green-light-emitter with strong and bright green or yellow-green photoluminescence under 365 nm UV light. © Springer Science+Business Media, LLC 2011
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container_issue	1
title_short	Electrosynthesis and characterization of a polyfluorene derivative with green-light-emitting property
url	https://doi.org/10.1007/s10853-011-5800-5
remote_bool	false
author2	Wang, Jiong Yue, Ruirui Xu, Jingkun Pei, Meishan
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doi_str	10.1007/s10853-011-5800-5
up_date	2024-07-04T04:55:14.277Z
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