Study of relationships among synthesis, microstructure and mechanical properties of lithium aluminosilicate glass-ceramics containing ZnO and $ MgF_{2} $ by synchrotron XRD and XANES
Abstract The effect of $ MgF_{2} $ and ZnO as additives on the microstructure evolution of a lithium aluminosilicate glass-ceramic is studied by X-ray powder diffraction and X-ray absorption near edge structure. The changes of main, secondary phase development and morphology under different additive...
Ausführliche Beschreibung
Autor*in: |
Wu, Yu-Han [verfasserIn] |
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Format: |
Artikel |
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Sprache: |
Englisch |
Erschienen: |
2013 |
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Schlagwörter: |
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Anmerkung: |
© Springer Science+Business Media New York 2013 |
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Übergeordnetes Werk: |
Enthalten in: Journal of materials science - Springer US, 1966, 48(2013), 12 vom: 08. März, Seite 4427-4437 |
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Übergeordnetes Werk: |
volume:48 ; year:2013 ; number:12 ; day:08 ; month:03 ; pages:4427-4437 |
Links: |
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DOI / URN: |
10.1007/s10853-013-7261-5 |
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Katalog-ID: |
OLC2046386094 |
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10.1007/s10853-013-7261-5 doi (DE-627)OLC2046386094 (DE-He213)s10853-013-7261-5-p DE-627 ger DE-627 rakwb eng 670 VZ Wu, Yu-Han verfasserin aut Study of relationships among synthesis, microstructure and mechanical properties of lithium aluminosilicate glass-ceramics containing ZnO and $ MgF_{2} $ by synchrotron XRD and XANES 2013 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2013 Abstract The effect of $ MgF_{2} $ and ZnO as additives on the microstructure evolution of a lithium aluminosilicate glass-ceramic is studied by X-ray powder diffraction and X-ray absorption near edge structure. The changes of main, secondary phase development and morphology under different additive concentrations are responsible for the variation in flexural strength. The decreased flexural strength (>50 %) of $ MgF_{2} $-bearing samples can be attributed to the non-uniform microstructure, while the increased flexural strength of the ZnO-doped samples might be due to the decreased residual stress resulting from a reduction of viscosity. In addition, the structural role of Zn ions is changed under different phase evolutions. For highly crystalline samples with commercial-like composition, Zn ions tend to have spinel-like local environments; while in a simplified composition, Zn ions favor hexagonal ZnO-like surroundings. The appearance of significant multiple scattering peaks in the near edge structure indicates Zn ions usually presented in an ordered local environment in high doping level samples (>1 % ZnO or $ MgF_{2} $). Flexural Strength Glass Matrix MgF2 ZnAl2O4 Zn2SiO4 Hsu, Kuo-Chuan aut Lee, Chih-Hao aut Enthalten in Journal of materials science Springer US, 1966 48(2013), 12 vom: 08. März, Seite 4427-4437 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:48 year:2013 number:12 day:08 month:03 pages:4427-4437 https://doi.org/10.1007/s10853-013-7261-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 48 2013 12 08 03 4427-4437 |
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10.1007/s10853-013-7261-5 doi (DE-627)OLC2046386094 (DE-He213)s10853-013-7261-5-p DE-627 ger DE-627 rakwb eng 670 VZ Wu, Yu-Han verfasserin aut Study of relationships among synthesis, microstructure and mechanical properties of lithium aluminosilicate glass-ceramics containing ZnO and $ MgF_{2} $ by synchrotron XRD and XANES 2013 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2013 Abstract The effect of $ MgF_{2} $ and ZnO as additives on the microstructure evolution of a lithium aluminosilicate glass-ceramic is studied by X-ray powder diffraction and X-ray absorption near edge structure. The changes of main, secondary phase development and morphology under different additive concentrations are responsible for the variation in flexural strength. The decreased flexural strength (>50 %) of $ MgF_{2} $-bearing samples can be attributed to the non-uniform microstructure, while the increased flexural strength of the ZnO-doped samples might be due to the decreased residual stress resulting from a reduction of viscosity. In addition, the structural role of Zn ions is changed under different phase evolutions. For highly crystalline samples with commercial-like composition, Zn ions tend to have spinel-like local environments; while in a simplified composition, Zn ions favor hexagonal ZnO-like surroundings. The appearance of significant multiple scattering peaks in the near edge structure indicates Zn ions usually presented in an ordered local environment in high doping level samples (>1 % ZnO or $ MgF_{2} $). Flexural Strength Glass Matrix MgF2 ZnAl2O4 Zn2SiO4 Hsu, Kuo-Chuan aut Lee, Chih-Hao aut Enthalten in Journal of materials science Springer US, 1966 48(2013), 12 vom: 08. März, Seite 4427-4437 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:48 year:2013 number:12 day:08 month:03 pages:4427-4437 https://doi.org/10.1007/s10853-013-7261-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 48 2013 12 08 03 4427-4437 |
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10.1007/s10853-013-7261-5 doi (DE-627)OLC2046386094 (DE-He213)s10853-013-7261-5-p DE-627 ger DE-627 rakwb eng 670 VZ Wu, Yu-Han verfasserin aut Study of relationships among synthesis, microstructure and mechanical properties of lithium aluminosilicate glass-ceramics containing ZnO and $ MgF_{2} $ by synchrotron XRD and XANES 2013 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2013 Abstract The effect of $ MgF_{2} $ and ZnO as additives on the microstructure evolution of a lithium aluminosilicate glass-ceramic is studied by X-ray powder diffraction and X-ray absorption near edge structure. The changes of main, secondary phase development and morphology under different additive concentrations are responsible for the variation in flexural strength. The decreased flexural strength (>50 %) of $ MgF_{2} $-bearing samples can be attributed to the non-uniform microstructure, while the increased flexural strength of the ZnO-doped samples might be due to the decreased residual stress resulting from a reduction of viscosity. In addition, the structural role of Zn ions is changed under different phase evolutions. For highly crystalline samples with commercial-like composition, Zn ions tend to have spinel-like local environments; while in a simplified composition, Zn ions favor hexagonal ZnO-like surroundings. The appearance of significant multiple scattering peaks in the near edge structure indicates Zn ions usually presented in an ordered local environment in high doping level samples (>1 % ZnO or $ MgF_{2} $). Flexural Strength Glass Matrix MgF2 ZnAl2O4 Zn2SiO4 Hsu, Kuo-Chuan aut Lee, Chih-Hao aut Enthalten in Journal of materials science Springer US, 1966 48(2013), 12 vom: 08. März, Seite 4427-4437 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:48 year:2013 number:12 day:08 month:03 pages:4427-4437 https://doi.org/10.1007/s10853-013-7261-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 48 2013 12 08 03 4427-4437 |
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10.1007/s10853-013-7261-5 doi (DE-627)OLC2046386094 (DE-He213)s10853-013-7261-5-p DE-627 ger DE-627 rakwb eng 670 VZ Wu, Yu-Han verfasserin aut Study of relationships among synthesis, microstructure and mechanical properties of lithium aluminosilicate glass-ceramics containing ZnO and $ MgF_{2} $ by synchrotron XRD and XANES 2013 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2013 Abstract The effect of $ MgF_{2} $ and ZnO as additives on the microstructure evolution of a lithium aluminosilicate glass-ceramic is studied by X-ray powder diffraction and X-ray absorption near edge structure. The changes of main, secondary phase development and morphology under different additive concentrations are responsible for the variation in flexural strength. The decreased flexural strength (>50 %) of $ MgF_{2} $-bearing samples can be attributed to the non-uniform microstructure, while the increased flexural strength of the ZnO-doped samples might be due to the decreased residual stress resulting from a reduction of viscosity. In addition, the structural role of Zn ions is changed under different phase evolutions. For highly crystalline samples with commercial-like composition, Zn ions tend to have spinel-like local environments; while in a simplified composition, Zn ions favor hexagonal ZnO-like surroundings. The appearance of significant multiple scattering peaks in the near edge structure indicates Zn ions usually presented in an ordered local environment in high doping level samples (>1 % ZnO or $ MgF_{2} $). Flexural Strength Glass Matrix MgF2 ZnAl2O4 Zn2SiO4 Hsu, Kuo-Chuan aut Lee, Chih-Hao aut Enthalten in Journal of materials science Springer US, 1966 48(2013), 12 vom: 08. März, Seite 4427-4437 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:48 year:2013 number:12 day:08 month:03 pages:4427-4437 https://doi.org/10.1007/s10853-013-7261-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_20 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 48 2013 12 08 03 4427-4437 |
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Wu, Yu-Han Hsu, Kuo-Chuan Lee, Chih-Hao |
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Wu, Yu-Han |
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10.1007/s10853-013-7261-5 |
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670 |
title_sort |
study of relationships among synthesis, microstructure and mechanical properties of lithium aluminosilicate glass-ceramics containing zno and $ mgf_{2} $ by synchrotron xrd and xanes |
title_auth |
Study of relationships among synthesis, microstructure and mechanical properties of lithium aluminosilicate glass-ceramics containing ZnO and $ MgF_{2} $ by synchrotron XRD and XANES |
abstract |
Abstract The effect of $ MgF_{2} $ and ZnO as additives on the microstructure evolution of a lithium aluminosilicate glass-ceramic is studied by X-ray powder diffraction and X-ray absorption near edge structure. The changes of main, secondary phase development and morphology under different additive concentrations are responsible for the variation in flexural strength. The decreased flexural strength (>50 %) of $ MgF_{2} $-bearing samples can be attributed to the non-uniform microstructure, while the increased flexural strength of the ZnO-doped samples might be due to the decreased residual stress resulting from a reduction of viscosity. In addition, the structural role of Zn ions is changed under different phase evolutions. For highly crystalline samples with commercial-like composition, Zn ions tend to have spinel-like local environments; while in a simplified composition, Zn ions favor hexagonal ZnO-like surroundings. The appearance of significant multiple scattering peaks in the near edge structure indicates Zn ions usually presented in an ordered local environment in high doping level samples (>1 % ZnO or $ MgF_{2} $). © Springer Science+Business Media New York 2013 |
abstractGer |
Abstract The effect of $ MgF_{2} $ and ZnO as additives on the microstructure evolution of a lithium aluminosilicate glass-ceramic is studied by X-ray powder diffraction and X-ray absorption near edge structure. The changes of main, secondary phase development and morphology under different additive concentrations are responsible for the variation in flexural strength. The decreased flexural strength (>50 %) of $ MgF_{2} $-bearing samples can be attributed to the non-uniform microstructure, while the increased flexural strength of the ZnO-doped samples might be due to the decreased residual stress resulting from a reduction of viscosity. In addition, the structural role of Zn ions is changed under different phase evolutions. For highly crystalline samples with commercial-like composition, Zn ions tend to have spinel-like local environments; while in a simplified composition, Zn ions favor hexagonal ZnO-like surroundings. The appearance of significant multiple scattering peaks in the near edge structure indicates Zn ions usually presented in an ordered local environment in high doping level samples (>1 % ZnO or $ MgF_{2} $). © Springer Science+Business Media New York 2013 |
abstract_unstemmed |
Abstract The effect of $ MgF_{2} $ and ZnO as additives on the microstructure evolution of a lithium aluminosilicate glass-ceramic is studied by X-ray powder diffraction and X-ray absorption near edge structure. The changes of main, secondary phase development and morphology under different additive concentrations are responsible for the variation in flexural strength. The decreased flexural strength (>50 %) of $ MgF_{2} $-bearing samples can be attributed to the non-uniform microstructure, while the increased flexural strength of the ZnO-doped samples might be due to the decreased residual stress resulting from a reduction of viscosity. In addition, the structural role of Zn ions is changed under different phase evolutions. For highly crystalline samples with commercial-like composition, Zn ions tend to have spinel-like local environments; while in a simplified composition, Zn ions favor hexagonal ZnO-like surroundings. The appearance of significant multiple scattering peaks in the near edge structure indicates Zn ions usually presented in an ordered local environment in high doping level samples (>1 % ZnO or $ MgF_{2} $). © Springer Science+Business Media New York 2013 |
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container_issue |
12 |
title_short |
Study of relationships among synthesis, microstructure and mechanical properties of lithium aluminosilicate glass-ceramics containing ZnO and $ MgF_{2} $ by synchrotron XRD and XANES |
url |
https://doi.org/10.1007/s10853-013-7261-5 |
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up_date |
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