Reactive infiltration: identifying the role of chemical reactions, capillarity, viscosity and gravity
Abstract A wealth of experimental data indicate that while capillarity-controlled infiltration gives an infiltration length that varies with the square root of time, reactive infiltration is characterized by a linear relationship between the two magnitudes. In addition, the infiltration rate in the...
Ausführliche Beschreibung
Autor*in: |
Louis, E. [verfasserIn] |
---|
Format: |
Artikel |
---|---|
Sprache: |
Englisch |
Erschienen: |
2017 |
---|
Schlagwörter: |
---|
Anmerkung: |
© Springer Science+Business Media New York 2017 |
---|
Übergeordnetes Werk: |
Enthalten in: Journal of materials science - Springer US, 1966, 52(2017), 12 vom: 20. März, Seite 7530-7538 |
---|---|
Übergeordnetes Werk: |
volume:52 ; year:2017 ; number:12 ; day:20 ; month:03 ; pages:7530-7538 |
Links: |
---|
DOI / URN: |
10.1007/s10853-017-0985-x |
---|
Katalog-ID: |
OLC2046423194 |
---|
LEADER | 01000caa a22002652 4500 | ||
---|---|---|---|
001 | OLC2046423194 | ||
003 | DE-627 | ||
005 | 20230503124738.0 | ||
007 | tu | ||
008 | 200820s2017 xx ||||| 00| ||eng c | ||
024 | 7 | |a 10.1007/s10853-017-0985-x |2 doi | |
035 | |a (DE-627)OLC2046423194 | ||
035 | |a (DE-He213)s10853-017-0985-x-p | ||
040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
041 | |a eng | ||
082 | 0 | 4 | |a 670 |q VZ |
100 | 1 | |a Louis, E. |e verfasserin |0 (orcid)0000-0001-8631-0189 |4 aut | |
245 | 1 | 0 | |a Reactive infiltration: identifying the role of chemical reactions, capillarity, viscosity and gravity |
264 | 1 | |c 2017 | |
336 | |a Text |b txt |2 rdacontent | ||
337 | |a ohne Hilfsmittel zu benutzen |b n |2 rdamedia | ||
338 | |a Band |b nc |2 rdacarrier | ||
500 | |a © Springer Science+Business Media New York 2017 | ||
520 | |a Abstract A wealth of experimental data indicate that while capillarity-controlled infiltration gives an infiltration length that varies with the square root of time, reactive infiltration is characterized by a linear relationship between the two magnitudes. In addition, the infiltration rate in the latter is at least two orders of magnitude lower than in the former. This work is addressed to investigate imbibition of a non-wetting, albeit reactive, liquid into a capillary, within the framework of a simple model that includes capillarity effects, viscosity and gravity. The capillary radius is allowed to vary, due to reaction, with both position and time, according to either an interface or a diffusion law. The model allows for capillary closure when reaction kinetics dominates imbibition. At short times, and depending on whether infiltration is capillarity or gravity controlled, the infiltrated length varies either as the square root or linearly with time. This suggests the following track for reactive infiltration: (1) In most cases, the contact angle is initially larger than $$90^\circ $$, (2) after some time, reaction gradually replaces the interface liquid/preform by the liquid/reaction product interface and, concomitantly, the contact angle gets closer to $$90^\circ $$, (3) beyond that time, gravity triggers infiltration (actually the contact angle does not need to be smaller than $$90^\circ $$ for the initiation of infiltration due to the metallostatic pressure exerted by the liquid metal on top of the porous preform) and (4) thereafter, infiltration is controlled by viscosity and gravity, provided that, due to reaction, the contact angle remains close to that at which infiltration was initiated. | ||
650 | 4 | |a Contact Angle | |
650 | 4 | |a Infiltration Rate | |
650 | 4 | |a Capillary Radius | |
650 | 4 | |a Porous Graphite | |
650 | 4 | |a Reactive Infiltration | |
700 | 1 | |a Miralles, J. A. |4 aut | |
700 | 1 | |a Molina, J. M. |4 aut | |
773 | 0 | 8 | |i Enthalten in |t Journal of materials science |d Springer US, 1966 |g 52(2017), 12 vom: 20. März, Seite 7530-7538 |w (DE-627)129546372 |w (DE-600)218324-9 |w (DE-576)014996774 |x 0022-2461 |7 nnns |
773 | 1 | 8 | |g volume:52 |g year:2017 |g number:12 |g day:20 |g month:03 |g pages:7530-7538 |
856 | 4 | 1 | |u https://doi.org/10.1007/s10853-017-0985-x |z lizenzpflichtig |3 Volltext |
912 | |a GBV_USEFLAG_A | ||
912 | |a SYSFLAG_A | ||
912 | |a GBV_OLC | ||
912 | |a SSG-OLC-TEC | ||
912 | |a GBV_ILN_30 | ||
912 | |a GBV_ILN_70 | ||
912 | |a GBV_ILN_2004 | ||
912 | |a GBV_ILN_4046 | ||
912 | |a GBV_ILN_4305 | ||
912 | |a GBV_ILN_4323 | ||
951 | |a AR | ||
952 | |d 52 |j 2017 |e 12 |b 20 |c 03 |h 7530-7538 |
author_variant |
e l el j a m ja jam j m m jm jmm |
---|---|
matchkey_str |
article:00222461:2017----::ecienitaindniynteoefhmclecincpl |
hierarchy_sort_str |
2017 |
publishDate |
2017 |
allfields |
10.1007/s10853-017-0985-x doi (DE-627)OLC2046423194 (DE-He213)s10853-017-0985-x-p DE-627 ger DE-627 rakwb eng 670 VZ Louis, E. verfasserin (orcid)0000-0001-8631-0189 aut Reactive infiltration: identifying the role of chemical reactions, capillarity, viscosity and gravity 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2017 Abstract A wealth of experimental data indicate that while capillarity-controlled infiltration gives an infiltration length that varies with the square root of time, reactive infiltration is characterized by a linear relationship between the two magnitudes. In addition, the infiltration rate in the latter is at least two orders of magnitude lower than in the former. This work is addressed to investigate imbibition of a non-wetting, albeit reactive, liquid into a capillary, within the framework of a simple model that includes capillarity effects, viscosity and gravity. The capillary radius is allowed to vary, due to reaction, with both position and time, according to either an interface or a diffusion law. The model allows for capillary closure when reaction kinetics dominates imbibition. At short times, and depending on whether infiltration is capillarity or gravity controlled, the infiltrated length varies either as the square root or linearly with time. This suggests the following track for reactive infiltration: (1) In most cases, the contact angle is initially larger than $$90^\circ $$, (2) after some time, reaction gradually replaces the interface liquid/preform by the liquid/reaction product interface and, concomitantly, the contact angle gets closer to $$90^\circ $$, (3) beyond that time, gravity triggers infiltration (actually the contact angle does not need to be smaller than $$90^\circ $$ for the initiation of infiltration due to the metallostatic pressure exerted by the liquid metal on top of the porous preform) and (4) thereafter, infiltration is controlled by viscosity and gravity, provided that, due to reaction, the contact angle remains close to that at which infiltration was initiated. Contact Angle Infiltration Rate Capillary Radius Porous Graphite Reactive Infiltration Miralles, J. A. aut Molina, J. M. aut Enthalten in Journal of materials science Springer US, 1966 52(2017), 12 vom: 20. März, Seite 7530-7538 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:52 year:2017 number:12 day:20 month:03 pages:7530-7538 https://doi.org/10.1007/s10853-017-0985-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_30 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 52 2017 12 20 03 7530-7538 |
spelling |
10.1007/s10853-017-0985-x doi (DE-627)OLC2046423194 (DE-He213)s10853-017-0985-x-p DE-627 ger DE-627 rakwb eng 670 VZ Louis, E. verfasserin (orcid)0000-0001-8631-0189 aut Reactive infiltration: identifying the role of chemical reactions, capillarity, viscosity and gravity 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2017 Abstract A wealth of experimental data indicate that while capillarity-controlled infiltration gives an infiltration length that varies with the square root of time, reactive infiltration is characterized by a linear relationship between the two magnitudes. In addition, the infiltration rate in the latter is at least two orders of magnitude lower than in the former. This work is addressed to investigate imbibition of a non-wetting, albeit reactive, liquid into a capillary, within the framework of a simple model that includes capillarity effects, viscosity and gravity. The capillary radius is allowed to vary, due to reaction, with both position and time, according to either an interface or a diffusion law. The model allows for capillary closure when reaction kinetics dominates imbibition. At short times, and depending on whether infiltration is capillarity or gravity controlled, the infiltrated length varies either as the square root or linearly with time. This suggests the following track for reactive infiltration: (1) In most cases, the contact angle is initially larger than $$90^\circ $$, (2) after some time, reaction gradually replaces the interface liquid/preform by the liquid/reaction product interface and, concomitantly, the contact angle gets closer to $$90^\circ $$, (3) beyond that time, gravity triggers infiltration (actually the contact angle does not need to be smaller than $$90^\circ $$ for the initiation of infiltration due to the metallostatic pressure exerted by the liquid metal on top of the porous preform) and (4) thereafter, infiltration is controlled by viscosity and gravity, provided that, due to reaction, the contact angle remains close to that at which infiltration was initiated. Contact Angle Infiltration Rate Capillary Radius Porous Graphite Reactive Infiltration Miralles, J. A. aut Molina, J. M. aut Enthalten in Journal of materials science Springer US, 1966 52(2017), 12 vom: 20. März, Seite 7530-7538 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:52 year:2017 number:12 day:20 month:03 pages:7530-7538 https://doi.org/10.1007/s10853-017-0985-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_30 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 52 2017 12 20 03 7530-7538 |
allfields_unstemmed |
10.1007/s10853-017-0985-x doi (DE-627)OLC2046423194 (DE-He213)s10853-017-0985-x-p DE-627 ger DE-627 rakwb eng 670 VZ Louis, E. verfasserin (orcid)0000-0001-8631-0189 aut Reactive infiltration: identifying the role of chemical reactions, capillarity, viscosity and gravity 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2017 Abstract A wealth of experimental data indicate that while capillarity-controlled infiltration gives an infiltration length that varies with the square root of time, reactive infiltration is characterized by a linear relationship between the two magnitudes. In addition, the infiltration rate in the latter is at least two orders of magnitude lower than in the former. This work is addressed to investigate imbibition of a non-wetting, albeit reactive, liquid into a capillary, within the framework of a simple model that includes capillarity effects, viscosity and gravity. The capillary radius is allowed to vary, due to reaction, with both position and time, according to either an interface or a diffusion law. The model allows for capillary closure when reaction kinetics dominates imbibition. At short times, and depending on whether infiltration is capillarity or gravity controlled, the infiltrated length varies either as the square root or linearly with time. This suggests the following track for reactive infiltration: (1) In most cases, the contact angle is initially larger than $$90^\circ $$, (2) after some time, reaction gradually replaces the interface liquid/preform by the liquid/reaction product interface and, concomitantly, the contact angle gets closer to $$90^\circ $$, (3) beyond that time, gravity triggers infiltration (actually the contact angle does not need to be smaller than $$90^\circ $$ for the initiation of infiltration due to the metallostatic pressure exerted by the liquid metal on top of the porous preform) and (4) thereafter, infiltration is controlled by viscosity and gravity, provided that, due to reaction, the contact angle remains close to that at which infiltration was initiated. Contact Angle Infiltration Rate Capillary Radius Porous Graphite Reactive Infiltration Miralles, J. A. aut Molina, J. M. aut Enthalten in Journal of materials science Springer US, 1966 52(2017), 12 vom: 20. März, Seite 7530-7538 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:52 year:2017 number:12 day:20 month:03 pages:7530-7538 https://doi.org/10.1007/s10853-017-0985-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_30 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 52 2017 12 20 03 7530-7538 |
allfieldsGer |
10.1007/s10853-017-0985-x doi (DE-627)OLC2046423194 (DE-He213)s10853-017-0985-x-p DE-627 ger DE-627 rakwb eng 670 VZ Louis, E. verfasserin (orcid)0000-0001-8631-0189 aut Reactive infiltration: identifying the role of chemical reactions, capillarity, viscosity and gravity 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2017 Abstract A wealth of experimental data indicate that while capillarity-controlled infiltration gives an infiltration length that varies with the square root of time, reactive infiltration is characterized by a linear relationship between the two magnitudes. In addition, the infiltration rate in the latter is at least two orders of magnitude lower than in the former. This work is addressed to investigate imbibition of a non-wetting, albeit reactive, liquid into a capillary, within the framework of a simple model that includes capillarity effects, viscosity and gravity. The capillary radius is allowed to vary, due to reaction, with both position and time, according to either an interface or a diffusion law. The model allows for capillary closure when reaction kinetics dominates imbibition. At short times, and depending on whether infiltration is capillarity or gravity controlled, the infiltrated length varies either as the square root or linearly with time. This suggests the following track for reactive infiltration: (1) In most cases, the contact angle is initially larger than $$90^\circ $$, (2) after some time, reaction gradually replaces the interface liquid/preform by the liquid/reaction product interface and, concomitantly, the contact angle gets closer to $$90^\circ $$, (3) beyond that time, gravity triggers infiltration (actually the contact angle does not need to be smaller than $$90^\circ $$ for the initiation of infiltration due to the metallostatic pressure exerted by the liquid metal on top of the porous preform) and (4) thereafter, infiltration is controlled by viscosity and gravity, provided that, due to reaction, the contact angle remains close to that at which infiltration was initiated. Contact Angle Infiltration Rate Capillary Radius Porous Graphite Reactive Infiltration Miralles, J. A. aut Molina, J. M. aut Enthalten in Journal of materials science Springer US, 1966 52(2017), 12 vom: 20. März, Seite 7530-7538 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:52 year:2017 number:12 day:20 month:03 pages:7530-7538 https://doi.org/10.1007/s10853-017-0985-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_30 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 52 2017 12 20 03 7530-7538 |
allfieldsSound |
10.1007/s10853-017-0985-x doi (DE-627)OLC2046423194 (DE-He213)s10853-017-0985-x-p DE-627 ger DE-627 rakwb eng 670 VZ Louis, E. verfasserin (orcid)0000-0001-8631-0189 aut Reactive infiltration: identifying the role of chemical reactions, capillarity, viscosity and gravity 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2017 Abstract A wealth of experimental data indicate that while capillarity-controlled infiltration gives an infiltration length that varies with the square root of time, reactive infiltration is characterized by a linear relationship between the two magnitudes. In addition, the infiltration rate in the latter is at least two orders of magnitude lower than in the former. This work is addressed to investigate imbibition of a non-wetting, albeit reactive, liquid into a capillary, within the framework of a simple model that includes capillarity effects, viscosity and gravity. The capillary radius is allowed to vary, due to reaction, with both position and time, according to either an interface or a diffusion law. The model allows for capillary closure when reaction kinetics dominates imbibition. At short times, and depending on whether infiltration is capillarity or gravity controlled, the infiltrated length varies either as the square root or linearly with time. This suggests the following track for reactive infiltration: (1) In most cases, the contact angle is initially larger than $$90^\circ $$, (2) after some time, reaction gradually replaces the interface liquid/preform by the liquid/reaction product interface and, concomitantly, the contact angle gets closer to $$90^\circ $$, (3) beyond that time, gravity triggers infiltration (actually the contact angle does not need to be smaller than $$90^\circ $$ for the initiation of infiltration due to the metallostatic pressure exerted by the liquid metal on top of the porous preform) and (4) thereafter, infiltration is controlled by viscosity and gravity, provided that, due to reaction, the contact angle remains close to that at which infiltration was initiated. Contact Angle Infiltration Rate Capillary Radius Porous Graphite Reactive Infiltration Miralles, J. A. aut Molina, J. M. aut Enthalten in Journal of materials science Springer US, 1966 52(2017), 12 vom: 20. März, Seite 7530-7538 (DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 0022-2461 nnns volume:52 year:2017 number:12 day:20 month:03 pages:7530-7538 https://doi.org/10.1007/s10853-017-0985-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_30 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 52 2017 12 20 03 7530-7538 |
language |
English |
source |
Enthalten in Journal of materials science 52(2017), 12 vom: 20. März, Seite 7530-7538 volume:52 year:2017 number:12 day:20 month:03 pages:7530-7538 |
sourceStr |
Enthalten in Journal of materials science 52(2017), 12 vom: 20. März, Seite 7530-7538 volume:52 year:2017 number:12 day:20 month:03 pages:7530-7538 |
format_phy_str_mv |
Article |
institution |
findex.gbv.de |
topic_facet |
Contact Angle Infiltration Rate Capillary Radius Porous Graphite Reactive Infiltration |
dewey-raw |
670 |
isfreeaccess_bool |
false |
container_title |
Journal of materials science |
authorswithroles_txt_mv |
Louis, E. @@aut@@ Miralles, J. A. @@aut@@ Molina, J. M. @@aut@@ |
publishDateDaySort_date |
2017-03-20T00:00:00Z |
hierarchy_top_id |
129546372 |
dewey-sort |
3670 |
id |
OLC2046423194 |
language_de |
englisch |
fullrecord |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">OLC2046423194</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230503124738.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">200820s2017 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10853-017-0985-x</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC2046423194</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-He213)s10853-017-0985-x-p</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">670</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Louis, E.</subfield><subfield code="e">verfasserin</subfield><subfield code="0">(orcid)0000-0001-8631-0189</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Reactive infiltration: identifying the role of chemical reactions, capillarity, viscosity and gravity</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2017</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Springer Science+Business Media New York 2017</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract A wealth of experimental data indicate that while capillarity-controlled infiltration gives an infiltration length that varies with the square root of time, reactive infiltration is characterized by a linear relationship between the two magnitudes. In addition, the infiltration rate in the latter is at least two orders of magnitude lower than in the former. This work is addressed to investigate imbibition of a non-wetting, albeit reactive, liquid into a capillary, within the framework of a simple model that includes capillarity effects, viscosity and gravity. The capillary radius is allowed to vary, due to reaction, with both position and time, according to either an interface or a diffusion law. The model allows for capillary closure when reaction kinetics dominates imbibition. At short times, and depending on whether infiltration is capillarity or gravity controlled, the infiltrated length varies either as the square root or linearly with time. This suggests the following track for reactive infiltration: (1) In most cases, the contact angle is initially larger than $$90^\circ $$, (2) after some time, reaction gradually replaces the interface liquid/preform by the liquid/reaction product interface and, concomitantly, the contact angle gets closer to $$90^\circ $$, (3) beyond that time, gravity triggers infiltration (actually the contact angle does not need to be smaller than $$90^\circ $$ for the initiation of infiltration due to the metallostatic pressure exerted by the liquid metal on top of the porous preform) and (4) thereafter, infiltration is controlled by viscosity and gravity, provided that, due to reaction, the contact angle remains close to that at which infiltration was initiated.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Contact Angle</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Infiltration Rate</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Capillary Radius</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Porous Graphite</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Reactive Infiltration</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Miralles, J. A.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Molina, J. M.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of materials science</subfield><subfield code="d">Springer US, 1966</subfield><subfield code="g">52(2017), 12 vom: 20. März, Seite 7530-7538</subfield><subfield code="w">(DE-627)129546372</subfield><subfield code="w">(DE-600)218324-9</subfield><subfield code="w">(DE-576)014996774</subfield><subfield code="x">0022-2461</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:52</subfield><subfield code="g">year:2017</subfield><subfield code="g">number:12</subfield><subfield code="g">day:20</subfield><subfield code="g">month:03</subfield><subfield code="g">pages:7530-7538</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1007/s10853-017-0985-x</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_30</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4046</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">52</subfield><subfield code="j">2017</subfield><subfield code="e">12</subfield><subfield code="b">20</subfield><subfield code="c">03</subfield><subfield code="h">7530-7538</subfield></datafield></record></collection>
|
author |
Louis, E. |
spellingShingle |
Louis, E. ddc 670 misc Contact Angle misc Infiltration Rate misc Capillary Radius misc Porous Graphite misc Reactive Infiltration Reactive infiltration: identifying the role of chemical reactions, capillarity, viscosity and gravity |
authorStr |
Louis, E. |
ppnlink_with_tag_str_mv |
@@773@@(DE-627)129546372 |
format |
Article |
dewey-ones |
670 - Manufacturing |
delete_txt_mv |
keep |
author_role |
aut aut aut |
collection |
OLC |
remote_str |
false |
illustrated |
Not Illustrated |
issn |
0022-2461 |
topic_title |
670 VZ Reactive infiltration: identifying the role of chemical reactions, capillarity, viscosity and gravity Contact Angle Infiltration Rate Capillary Radius Porous Graphite Reactive Infiltration |
topic |
ddc 670 misc Contact Angle misc Infiltration Rate misc Capillary Radius misc Porous Graphite misc Reactive Infiltration |
topic_unstemmed |
ddc 670 misc Contact Angle misc Infiltration Rate misc Capillary Radius misc Porous Graphite misc Reactive Infiltration |
topic_browse |
ddc 670 misc Contact Angle misc Infiltration Rate misc Capillary Radius misc Porous Graphite misc Reactive Infiltration |
format_facet |
Aufsätze Gedruckte Aufsätze |
format_main_str_mv |
Text Zeitschrift/Artikel |
carriertype_str_mv |
nc |
hierarchy_parent_title |
Journal of materials science |
hierarchy_parent_id |
129546372 |
dewey-tens |
670 - Manufacturing |
hierarchy_top_title |
Journal of materials science |
isfreeaccess_txt |
false |
familylinks_str_mv |
(DE-627)129546372 (DE-600)218324-9 (DE-576)014996774 |
title |
Reactive infiltration: identifying the role of chemical reactions, capillarity, viscosity and gravity |
ctrlnum |
(DE-627)OLC2046423194 (DE-He213)s10853-017-0985-x-p |
title_full |
Reactive infiltration: identifying the role of chemical reactions, capillarity, viscosity and gravity |
author_sort |
Louis, E. |
journal |
Journal of materials science |
journalStr |
Journal of materials science |
lang_code |
eng |
isOA_bool |
false |
dewey-hundreds |
600 - Technology |
recordtype |
marc |
publishDateSort |
2017 |
contenttype_str_mv |
txt |
container_start_page |
7530 |
author_browse |
Louis, E. Miralles, J. A. Molina, J. M. |
container_volume |
52 |
class |
670 VZ |
format_se |
Aufsätze |
author-letter |
Louis, E. |
doi_str_mv |
10.1007/s10853-017-0985-x |
normlink |
(ORCID)0000-0001-8631-0189 |
normlink_prefix_str_mv |
(orcid)0000-0001-8631-0189 |
dewey-full |
670 |
title_sort |
reactive infiltration: identifying the role of chemical reactions, capillarity, viscosity and gravity |
title_auth |
Reactive infiltration: identifying the role of chemical reactions, capillarity, viscosity and gravity |
abstract |
Abstract A wealth of experimental data indicate that while capillarity-controlled infiltration gives an infiltration length that varies with the square root of time, reactive infiltration is characterized by a linear relationship between the two magnitudes. In addition, the infiltration rate in the latter is at least two orders of magnitude lower than in the former. This work is addressed to investigate imbibition of a non-wetting, albeit reactive, liquid into a capillary, within the framework of a simple model that includes capillarity effects, viscosity and gravity. The capillary radius is allowed to vary, due to reaction, with both position and time, according to either an interface or a diffusion law. The model allows for capillary closure when reaction kinetics dominates imbibition. At short times, and depending on whether infiltration is capillarity or gravity controlled, the infiltrated length varies either as the square root or linearly with time. This suggests the following track for reactive infiltration: (1) In most cases, the contact angle is initially larger than $$90^\circ $$, (2) after some time, reaction gradually replaces the interface liquid/preform by the liquid/reaction product interface and, concomitantly, the contact angle gets closer to $$90^\circ $$, (3) beyond that time, gravity triggers infiltration (actually the contact angle does not need to be smaller than $$90^\circ $$ for the initiation of infiltration due to the metallostatic pressure exerted by the liquid metal on top of the porous preform) and (4) thereafter, infiltration is controlled by viscosity and gravity, provided that, due to reaction, the contact angle remains close to that at which infiltration was initiated. © Springer Science+Business Media New York 2017 |
abstractGer |
Abstract A wealth of experimental data indicate that while capillarity-controlled infiltration gives an infiltration length that varies with the square root of time, reactive infiltration is characterized by a linear relationship between the two magnitudes. In addition, the infiltration rate in the latter is at least two orders of magnitude lower than in the former. This work is addressed to investigate imbibition of a non-wetting, albeit reactive, liquid into a capillary, within the framework of a simple model that includes capillarity effects, viscosity and gravity. The capillary radius is allowed to vary, due to reaction, with both position and time, according to either an interface or a diffusion law. The model allows for capillary closure when reaction kinetics dominates imbibition. At short times, and depending on whether infiltration is capillarity or gravity controlled, the infiltrated length varies either as the square root or linearly with time. This suggests the following track for reactive infiltration: (1) In most cases, the contact angle is initially larger than $$90^\circ $$, (2) after some time, reaction gradually replaces the interface liquid/preform by the liquid/reaction product interface and, concomitantly, the contact angle gets closer to $$90^\circ $$, (3) beyond that time, gravity triggers infiltration (actually the contact angle does not need to be smaller than $$90^\circ $$ for the initiation of infiltration due to the metallostatic pressure exerted by the liquid metal on top of the porous preform) and (4) thereafter, infiltration is controlled by viscosity and gravity, provided that, due to reaction, the contact angle remains close to that at which infiltration was initiated. © Springer Science+Business Media New York 2017 |
abstract_unstemmed |
Abstract A wealth of experimental data indicate that while capillarity-controlled infiltration gives an infiltration length that varies with the square root of time, reactive infiltration is characterized by a linear relationship between the two magnitudes. In addition, the infiltration rate in the latter is at least two orders of magnitude lower than in the former. This work is addressed to investigate imbibition of a non-wetting, albeit reactive, liquid into a capillary, within the framework of a simple model that includes capillarity effects, viscosity and gravity. The capillary radius is allowed to vary, due to reaction, with both position and time, according to either an interface or a diffusion law. The model allows for capillary closure when reaction kinetics dominates imbibition. At short times, and depending on whether infiltration is capillarity or gravity controlled, the infiltrated length varies either as the square root or linearly with time. This suggests the following track for reactive infiltration: (1) In most cases, the contact angle is initially larger than $$90^\circ $$, (2) after some time, reaction gradually replaces the interface liquid/preform by the liquid/reaction product interface and, concomitantly, the contact angle gets closer to $$90^\circ $$, (3) beyond that time, gravity triggers infiltration (actually the contact angle does not need to be smaller than $$90^\circ $$ for the initiation of infiltration due to the metallostatic pressure exerted by the liquid metal on top of the porous preform) and (4) thereafter, infiltration is controlled by viscosity and gravity, provided that, due to reaction, the contact angle remains close to that at which infiltration was initiated. © Springer Science+Business Media New York 2017 |
collection_details |
GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_30 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 |
container_issue |
12 |
title_short |
Reactive infiltration: identifying the role of chemical reactions, capillarity, viscosity and gravity |
url |
https://doi.org/10.1007/s10853-017-0985-x |
remote_bool |
false |
author2 |
Miralles, J. A. Molina, J. M. |
author2Str |
Miralles, J. A. Molina, J. M. |
ppnlink |
129546372 |
mediatype_str_mv |
n |
isOA_txt |
false |
hochschulschrift_bool |
false |
doi_str |
10.1007/s10853-017-0985-x |
up_date |
2024-07-04T05:03:36.635Z |
_version_ |
1803623508606976000 |
fullrecord_marcxml |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">OLC2046423194</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230503124738.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">200820s2017 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10853-017-0985-x</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC2046423194</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-He213)s10853-017-0985-x-p</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">670</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Louis, E.</subfield><subfield code="e">verfasserin</subfield><subfield code="0">(orcid)0000-0001-8631-0189</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Reactive infiltration: identifying the role of chemical reactions, capillarity, viscosity and gravity</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2017</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Springer Science+Business Media New York 2017</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract A wealth of experimental data indicate that while capillarity-controlled infiltration gives an infiltration length that varies with the square root of time, reactive infiltration is characterized by a linear relationship between the two magnitudes. In addition, the infiltration rate in the latter is at least two orders of magnitude lower than in the former. This work is addressed to investigate imbibition of a non-wetting, albeit reactive, liquid into a capillary, within the framework of a simple model that includes capillarity effects, viscosity and gravity. The capillary radius is allowed to vary, due to reaction, with both position and time, according to either an interface or a diffusion law. The model allows for capillary closure when reaction kinetics dominates imbibition. At short times, and depending on whether infiltration is capillarity or gravity controlled, the infiltrated length varies either as the square root or linearly with time. This suggests the following track for reactive infiltration: (1) In most cases, the contact angle is initially larger than $$90^\circ $$, (2) after some time, reaction gradually replaces the interface liquid/preform by the liquid/reaction product interface and, concomitantly, the contact angle gets closer to $$90^\circ $$, (3) beyond that time, gravity triggers infiltration (actually the contact angle does not need to be smaller than $$90^\circ $$ for the initiation of infiltration due to the metallostatic pressure exerted by the liquid metal on top of the porous preform) and (4) thereafter, infiltration is controlled by viscosity and gravity, provided that, due to reaction, the contact angle remains close to that at which infiltration was initiated.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Contact Angle</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Infiltration Rate</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Capillary Radius</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Porous Graphite</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Reactive Infiltration</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Miralles, J. A.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Molina, J. M.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of materials science</subfield><subfield code="d">Springer US, 1966</subfield><subfield code="g">52(2017), 12 vom: 20. März, Seite 7530-7538</subfield><subfield code="w">(DE-627)129546372</subfield><subfield code="w">(DE-600)218324-9</subfield><subfield code="w">(DE-576)014996774</subfield><subfield code="x">0022-2461</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:52</subfield><subfield code="g">year:2017</subfield><subfield code="g">number:12</subfield><subfield code="g">day:20</subfield><subfield code="g">month:03</subfield><subfield code="g">pages:7530-7538</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1007/s10853-017-0985-x</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_30</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4046</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">52</subfield><subfield code="j">2017</subfield><subfield code="e">12</subfield><subfield code="b">20</subfield><subfield code="c">03</subfield><subfield code="h">7530-7538</subfield></datafield></record></collection>
|
score |
7.4003057 |