Oxidation of wax in the presence of a soluble catalyst
Summary It has been established that the formation of manganese soaps of a soluble oxidation catalyst in fatty acids proceeds best by the action of an alkali on manganese sulfate, previously mixed with oxidized wax.It is advantageous to prepare the soluble catalyst with a reduced amount of oxidate,...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Rusinov, I. E. [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1967 |
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| Schlagwörter: |
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| Anmerkung: |
© Consultants Bureau 1968 |
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| Übergeordnetes Werk: |
Enthalten in: Chemistry and technology of fuels and oils - Kluwer Academic Publishers-Plenum Publishers, 1966, 3(1967), 9 vom: Sept., Seite 642-645 |
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| Übergeordnetes Werk: |
volume:3 ; year:1967 ; number:9 ; month:09 ; pages:642-645 |
| Links: |
|---|
| DOI / URN: |
10.1007/BF00722368 |
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OLC2049534760 |
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| 520 | |a Summary It has been established that the formation of manganese soaps of a soluble oxidation catalyst in fatty acids proceeds best by the action of an alkali on manganese sulfate, previously mixed with oxidized wax.It is advantageous to prepare the soluble catalyst with a reduced amount of oxidate, basing this on preparation from the saponification value.It has been shown that the losses of manganese with the sulfate waters separated from the manganese soaps are reduced to 3–4% when alkali diluted to 30% is used with an excess of alkali in the precipitated hydrated manganous oxide hydrate up to 30% of the theoretically required amount for the reaction with manganese sulfate.Here the losses of sodium with the sulfate waters are about 5% of the amount of sodium introduced with the excess alkali.It has been established that the oxidation of wax with a soluble catalyst begins without an induction period leading to a reduction of about 10% in the duration of the reaction. This enables the oxidation process to be carried out continuously under low-temperature conditions to give oxidation products of improved quaiity. The rate of wax oxidation involving a soluble catalyst increases as its concentration in the feedstock being oxidized is reduced from 0.13 to 0.07 wt, %, calculated as manganese. | ||
| 650 | 4 | |a Oxidation | |
| 650 | 4 | |a Sodium | |
| 650 | 4 | |a Sulfate | |
| 650 | 4 | |a Hydrate | |
| 650 | 4 | |a Oxide Hydrate | |
| 700 | 1 | |a Solodova, N. I. |4 aut | |
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10.1007/BF00722368 doi (DE-627)OLC2049534760 (DE-He213)BF00722368-p DE-627 ger DE-627 rakwb eng 660 VZ Rusinov, I. E. verfasserin aut Oxidation of wax in the presence of a soluble catalyst 1967 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Consultants Bureau 1968 Summary It has been established that the formation of manganese soaps of a soluble oxidation catalyst in fatty acids proceeds best by the action of an alkali on manganese sulfate, previously mixed with oxidized wax.It is advantageous to prepare the soluble catalyst with a reduced amount of oxidate, basing this on preparation from the saponification value.It has been shown that the losses of manganese with the sulfate waters separated from the manganese soaps are reduced to 3–4% when alkali diluted to 30% is used with an excess of alkali in the precipitated hydrated manganous oxide hydrate up to 30% of the theoretically required amount for the reaction with manganese sulfate.Here the losses of sodium with the sulfate waters are about 5% of the amount of sodium introduced with the excess alkali.It has been established that the oxidation of wax with a soluble catalyst begins without an induction period leading to a reduction of about 10% in the duration of the reaction. This enables the oxidation process to be carried out continuously under low-temperature conditions to give oxidation products of improved quaiity. The rate of wax oxidation involving a soluble catalyst increases as its concentration in the feedstock being oxidized is reduced from 0.13 to 0.07 wt, %, calculated as manganese. Oxidation Sodium Sulfate Hydrate Oxide Hydrate Solodova, N. I. aut Enthalten in Chemistry and technology of fuels and oils Kluwer Academic Publishers-Plenum Publishers, 1966 3(1967), 9 vom: Sept., Seite 642-645 (DE-627)129592196 (DE-600)240238-5 (DE-576)015084906 0009-3092 nnns volume:3 year:1967 number:9 month:09 pages:642-645 https://doi.org/10.1007/BF00722368 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_70 GBV_ILN_2015 AR 3 1967 9 09 642-645 |
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10.1007/BF00722368 doi (DE-627)OLC2049534760 (DE-He213)BF00722368-p DE-627 ger DE-627 rakwb eng 660 VZ Rusinov, I. E. verfasserin aut Oxidation of wax in the presence of a soluble catalyst 1967 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Consultants Bureau 1968 Summary It has been established that the formation of manganese soaps of a soluble oxidation catalyst in fatty acids proceeds best by the action of an alkali on manganese sulfate, previously mixed with oxidized wax.It is advantageous to prepare the soluble catalyst with a reduced amount of oxidate, basing this on preparation from the saponification value.It has been shown that the losses of manganese with the sulfate waters separated from the manganese soaps are reduced to 3–4% when alkali diluted to 30% is used with an excess of alkali in the precipitated hydrated manganous oxide hydrate up to 30% of the theoretically required amount for the reaction with manganese sulfate.Here the losses of sodium with the sulfate waters are about 5% of the amount of sodium introduced with the excess alkali.It has been established that the oxidation of wax with a soluble catalyst begins without an induction period leading to a reduction of about 10% in the duration of the reaction. This enables the oxidation process to be carried out continuously under low-temperature conditions to give oxidation products of improved quaiity. The rate of wax oxidation involving a soluble catalyst increases as its concentration in the feedstock being oxidized is reduced from 0.13 to 0.07 wt, %, calculated as manganese. Oxidation Sodium Sulfate Hydrate Oxide Hydrate Solodova, N. I. aut Enthalten in Chemistry and technology of fuels and oils Kluwer Academic Publishers-Plenum Publishers, 1966 3(1967), 9 vom: Sept., Seite 642-645 (DE-627)129592196 (DE-600)240238-5 (DE-576)015084906 0009-3092 nnns volume:3 year:1967 number:9 month:09 pages:642-645 https://doi.org/10.1007/BF00722368 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_70 GBV_ILN_2015 AR 3 1967 9 09 642-645 |
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10.1007/BF00722368 doi (DE-627)OLC2049534760 (DE-He213)BF00722368-p DE-627 ger DE-627 rakwb eng 660 VZ Rusinov, I. E. verfasserin aut Oxidation of wax in the presence of a soluble catalyst 1967 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Consultants Bureau 1968 Summary It has been established that the formation of manganese soaps of a soluble oxidation catalyst in fatty acids proceeds best by the action of an alkali on manganese sulfate, previously mixed with oxidized wax.It is advantageous to prepare the soluble catalyst with a reduced amount of oxidate, basing this on preparation from the saponification value.It has been shown that the losses of manganese with the sulfate waters separated from the manganese soaps are reduced to 3–4% when alkali diluted to 30% is used with an excess of alkali in the precipitated hydrated manganous oxide hydrate up to 30% of the theoretically required amount for the reaction with manganese sulfate.Here the losses of sodium with the sulfate waters are about 5% of the amount of sodium introduced with the excess alkali.It has been established that the oxidation of wax with a soluble catalyst begins without an induction period leading to a reduction of about 10% in the duration of the reaction. This enables the oxidation process to be carried out continuously under low-temperature conditions to give oxidation products of improved quaiity. The rate of wax oxidation involving a soluble catalyst increases as its concentration in the feedstock being oxidized is reduced from 0.13 to 0.07 wt, %, calculated as manganese. Oxidation Sodium Sulfate Hydrate Oxide Hydrate Solodova, N. I. aut Enthalten in Chemistry and technology of fuels and oils Kluwer Academic Publishers-Plenum Publishers, 1966 3(1967), 9 vom: Sept., Seite 642-645 (DE-627)129592196 (DE-600)240238-5 (DE-576)015084906 0009-3092 nnns volume:3 year:1967 number:9 month:09 pages:642-645 https://doi.org/10.1007/BF00722368 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_70 GBV_ILN_2015 AR 3 1967 9 09 642-645 |
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10.1007/BF00722368 doi (DE-627)OLC2049534760 (DE-He213)BF00722368-p DE-627 ger DE-627 rakwb eng 660 VZ Rusinov, I. E. verfasserin aut Oxidation of wax in the presence of a soluble catalyst 1967 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Consultants Bureau 1968 Summary It has been established that the formation of manganese soaps of a soluble oxidation catalyst in fatty acids proceeds best by the action of an alkali on manganese sulfate, previously mixed with oxidized wax.It is advantageous to prepare the soluble catalyst with a reduced amount of oxidate, basing this on preparation from the saponification value.It has been shown that the losses of manganese with the sulfate waters separated from the manganese soaps are reduced to 3–4% when alkali diluted to 30% is used with an excess of alkali in the precipitated hydrated manganous oxide hydrate up to 30% of the theoretically required amount for the reaction with manganese sulfate.Here the losses of sodium with the sulfate waters are about 5% of the amount of sodium introduced with the excess alkali.It has been established that the oxidation of wax with a soluble catalyst begins without an induction period leading to a reduction of about 10% in the duration of the reaction. This enables the oxidation process to be carried out continuously under low-temperature conditions to give oxidation products of improved quaiity. The rate of wax oxidation involving a soluble catalyst increases as its concentration in the feedstock being oxidized is reduced from 0.13 to 0.07 wt, %, calculated as manganese. Oxidation Sodium Sulfate Hydrate Oxide Hydrate Solodova, N. I. aut Enthalten in Chemistry and technology of fuels and oils Kluwer Academic Publishers-Plenum Publishers, 1966 3(1967), 9 vom: Sept., Seite 642-645 (DE-627)129592196 (DE-600)240238-5 (DE-576)015084906 0009-3092 nnns volume:3 year:1967 number:9 month:09 pages:642-645 https://doi.org/10.1007/BF00722368 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_70 GBV_ILN_2015 AR 3 1967 9 09 642-645 |
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10.1007/BF00722368 doi (DE-627)OLC2049534760 (DE-He213)BF00722368-p DE-627 ger DE-627 rakwb eng 660 VZ Rusinov, I. E. verfasserin aut Oxidation of wax in the presence of a soluble catalyst 1967 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Consultants Bureau 1968 Summary It has been established that the formation of manganese soaps of a soluble oxidation catalyst in fatty acids proceeds best by the action of an alkali on manganese sulfate, previously mixed with oxidized wax.It is advantageous to prepare the soluble catalyst with a reduced amount of oxidate, basing this on preparation from the saponification value.It has been shown that the losses of manganese with the sulfate waters separated from the manganese soaps are reduced to 3–4% when alkali diluted to 30% is used with an excess of alkali in the precipitated hydrated manganous oxide hydrate up to 30% of the theoretically required amount for the reaction with manganese sulfate.Here the losses of sodium with the sulfate waters are about 5% of the amount of sodium introduced with the excess alkali.It has been established that the oxidation of wax with a soluble catalyst begins without an induction period leading to a reduction of about 10% in the duration of the reaction. This enables the oxidation process to be carried out continuously under low-temperature conditions to give oxidation products of improved quaiity. The rate of wax oxidation involving a soluble catalyst increases as its concentration in the feedstock being oxidized is reduced from 0.13 to 0.07 wt, %, calculated as manganese. Oxidation Sodium Sulfate Hydrate Oxide Hydrate Solodova, N. I. aut Enthalten in Chemistry and technology of fuels and oils Kluwer Academic Publishers-Plenum Publishers, 1966 3(1967), 9 vom: Sept., Seite 642-645 (DE-627)129592196 (DE-600)240238-5 (DE-576)015084906 0009-3092 nnns volume:3 year:1967 number:9 month:09 pages:642-645 https://doi.org/10.1007/BF00722368 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_70 GBV_ILN_2015 AR 3 1967 9 09 642-645 |
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660 VZ Oxidation of wax in the presence of a soluble catalyst Oxidation Sodium Sulfate Hydrate Oxide Hydrate |
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oxidation of wax in the presence of a soluble catalyst |
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Oxidation of wax in the presence of a soluble catalyst |
| abstract |
Summary It has been established that the formation of manganese soaps of a soluble oxidation catalyst in fatty acids proceeds best by the action of an alkali on manganese sulfate, previously mixed with oxidized wax.It is advantageous to prepare the soluble catalyst with a reduced amount of oxidate, basing this on preparation from the saponification value.It has been shown that the losses of manganese with the sulfate waters separated from the manganese soaps are reduced to 3–4% when alkali diluted to 30% is used with an excess of alkali in the precipitated hydrated manganous oxide hydrate up to 30% of the theoretically required amount for the reaction with manganese sulfate.Here the losses of sodium with the sulfate waters are about 5% of the amount of sodium introduced with the excess alkali.It has been established that the oxidation of wax with a soluble catalyst begins without an induction period leading to a reduction of about 10% in the duration of the reaction. This enables the oxidation process to be carried out continuously under low-temperature conditions to give oxidation products of improved quaiity. The rate of wax oxidation involving a soluble catalyst increases as its concentration in the feedstock being oxidized is reduced from 0.13 to 0.07 wt, %, calculated as manganese. © Consultants Bureau 1968 |
| abstractGer |
Summary It has been established that the formation of manganese soaps of a soluble oxidation catalyst in fatty acids proceeds best by the action of an alkali on manganese sulfate, previously mixed with oxidized wax.It is advantageous to prepare the soluble catalyst with a reduced amount of oxidate, basing this on preparation from the saponification value.It has been shown that the losses of manganese with the sulfate waters separated from the manganese soaps are reduced to 3–4% when alkali diluted to 30% is used with an excess of alkali in the precipitated hydrated manganous oxide hydrate up to 30% of the theoretically required amount for the reaction with manganese sulfate.Here the losses of sodium with the sulfate waters are about 5% of the amount of sodium introduced with the excess alkali.It has been established that the oxidation of wax with a soluble catalyst begins without an induction period leading to a reduction of about 10% in the duration of the reaction. This enables the oxidation process to be carried out continuously under low-temperature conditions to give oxidation products of improved quaiity. The rate of wax oxidation involving a soluble catalyst increases as its concentration in the feedstock being oxidized is reduced from 0.13 to 0.07 wt, %, calculated as manganese. © Consultants Bureau 1968 |
| abstract_unstemmed |
Summary It has been established that the formation of manganese soaps of a soluble oxidation catalyst in fatty acids proceeds best by the action of an alkali on manganese sulfate, previously mixed with oxidized wax.It is advantageous to prepare the soluble catalyst with a reduced amount of oxidate, basing this on preparation from the saponification value.It has been shown that the losses of manganese with the sulfate waters separated from the manganese soaps are reduced to 3–4% when alkali diluted to 30% is used with an excess of alkali in the precipitated hydrated manganous oxide hydrate up to 30% of the theoretically required amount for the reaction with manganese sulfate.Here the losses of sodium with the sulfate waters are about 5% of the amount of sodium introduced with the excess alkali.It has been established that the oxidation of wax with a soluble catalyst begins without an induction period leading to a reduction of about 10% in the duration of the reaction. This enables the oxidation process to be carried out continuously under low-temperature conditions to give oxidation products of improved quaiity. The rate of wax oxidation involving a soluble catalyst increases as its concentration in the feedstock being oxidized is reduced from 0.13 to 0.07 wt, %, calculated as manganese. © Consultants Bureau 1968 |
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9 |
| title_short |
Oxidation of wax in the presence of a soluble catalyst |
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Solodova, N. I. |
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