Role of solid acceptors in the oxidative dehydrogenation of hydrocarbons with iodine
Conclusions It is shown that at small iodine feeds the dehydrogenation indices both for isopentane and for n-butane are significantly inferior, in the reactor filled with solid acceptor, to the corresponding indices in the reactor filled with the quartz filler alone or the reactor filled with a comb...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Adel'son, S. V. [verfasserIn] |
|---|
| Format: |
Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
1969 |
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| Schlagwörter: |
|---|
| Anmerkung: |
© Consultants Bureau 1969 |
|---|
| Übergeordnetes Werk: |
Enthalten in: Chemistry and technology of fuels and oils - Kluwer Academic Publishers-Plenum Publishers, 1966, 5(1969), 6 vom: Juni, Seite 395-399 |
|---|---|
| Übergeordnetes Werk: |
volume:5 ; year:1969 ; number:6 ; month:06 ; pages:395-399 |
| Links: |
|---|
| DOI / URN: |
10.1007/BF00722483 |
|---|
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OLC2049538871 |
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| 520 | |a Conclusions It is shown that at small iodine feeds the dehydrogenation indices both for isopentane and for n-butane are significantly inferior, in the reactor filled with solid acceptor, to the corresponding indices in the reactor filled with the quartz filler alone or the reactor filled with a combination of quartz filler and acceptor.The iodination indices for the iodinated acceptor and the quartz filler are identical.It is established that the role of the solid acceptor consists only in the absorption of HI with the formation of an iodide which is not oxidized during the time of the reaction cycle.The oxidation of the iodide to iodine takes place only during the acceptor regeneration cycle when the raw material is not being fed to the reactor. | ||
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10.1007/BF00722483 doi (DE-627)OLC2049538871 (DE-He213)BF00722483-p DE-627 ger DE-627 rakwb eng 660 VZ Adel'son, S. V. verfasserin aut Role of solid acceptors in the oxidative dehydrogenation of hydrocarbons with iodine 1969 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Consultants Bureau 1969 Conclusions It is shown that at small iodine feeds the dehydrogenation indices both for isopentane and for n-butane are significantly inferior, in the reactor filled with solid acceptor, to the corresponding indices in the reactor filled with the quartz filler alone or the reactor filled with a combination of quartz filler and acceptor.The iodination indices for the iodinated acceptor and the quartz filler are identical.It is established that the role of the solid acceptor consists only in the absorption of HI with the formation of an iodide which is not oxidized during the time of the reaction cycle.The oxidation of the iodide to iodine takes place only during the acceptor regeneration cycle when the raw material is not being fed to the reactor. Oxidation Quartz Iodine Hydrocarbon Iodide Nikonova, M. M. aut Enthalten in Chemistry and technology of fuels and oils Kluwer Academic Publishers-Plenum Publishers, 1966 5(1969), 6 vom: Juni, Seite 395-399 (DE-627)129592196 (DE-600)240238-5 (DE-576)015084906 0009-3092 nnns volume:5 year:1969 number:6 month:06 pages:395-399 https://doi.org/10.1007/BF00722483 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_70 GBV_ILN_2015 GBV_ILN_4307 AR 5 1969 6 06 395-399 |
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10.1007/BF00722483 doi (DE-627)OLC2049538871 (DE-He213)BF00722483-p DE-627 ger DE-627 rakwb eng 660 VZ Adel'son, S. V. verfasserin aut Role of solid acceptors in the oxidative dehydrogenation of hydrocarbons with iodine 1969 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Consultants Bureau 1969 Conclusions It is shown that at small iodine feeds the dehydrogenation indices both for isopentane and for n-butane are significantly inferior, in the reactor filled with solid acceptor, to the corresponding indices in the reactor filled with the quartz filler alone or the reactor filled with a combination of quartz filler and acceptor.The iodination indices for the iodinated acceptor and the quartz filler are identical.It is established that the role of the solid acceptor consists only in the absorption of HI with the formation of an iodide which is not oxidized during the time of the reaction cycle.The oxidation of the iodide to iodine takes place only during the acceptor regeneration cycle when the raw material is not being fed to the reactor. Oxidation Quartz Iodine Hydrocarbon Iodide Nikonova, M. M. aut Enthalten in Chemistry and technology of fuels and oils Kluwer Academic Publishers-Plenum Publishers, 1966 5(1969), 6 vom: Juni, Seite 395-399 (DE-627)129592196 (DE-600)240238-5 (DE-576)015084906 0009-3092 nnns volume:5 year:1969 number:6 month:06 pages:395-399 https://doi.org/10.1007/BF00722483 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_70 GBV_ILN_2015 GBV_ILN_4307 AR 5 1969 6 06 395-399 |
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10.1007/BF00722483 doi (DE-627)OLC2049538871 (DE-He213)BF00722483-p DE-627 ger DE-627 rakwb eng 660 VZ Adel'son, S. V. verfasserin aut Role of solid acceptors in the oxidative dehydrogenation of hydrocarbons with iodine 1969 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Consultants Bureau 1969 Conclusions It is shown that at small iodine feeds the dehydrogenation indices both for isopentane and for n-butane are significantly inferior, in the reactor filled with solid acceptor, to the corresponding indices in the reactor filled with the quartz filler alone or the reactor filled with a combination of quartz filler and acceptor.The iodination indices for the iodinated acceptor and the quartz filler are identical.It is established that the role of the solid acceptor consists only in the absorption of HI with the formation of an iodide which is not oxidized during the time of the reaction cycle.The oxidation of the iodide to iodine takes place only during the acceptor regeneration cycle when the raw material is not being fed to the reactor. Oxidation Quartz Iodine Hydrocarbon Iodide Nikonova, M. M. aut Enthalten in Chemistry and technology of fuels and oils Kluwer Academic Publishers-Plenum Publishers, 1966 5(1969), 6 vom: Juni, Seite 395-399 (DE-627)129592196 (DE-600)240238-5 (DE-576)015084906 0009-3092 nnns volume:5 year:1969 number:6 month:06 pages:395-399 https://doi.org/10.1007/BF00722483 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_70 GBV_ILN_2015 GBV_ILN_4307 AR 5 1969 6 06 395-399 |
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10.1007/BF00722483 doi (DE-627)OLC2049538871 (DE-He213)BF00722483-p DE-627 ger DE-627 rakwb eng 660 VZ Adel'son, S. V. verfasserin aut Role of solid acceptors in the oxidative dehydrogenation of hydrocarbons with iodine 1969 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Consultants Bureau 1969 Conclusions It is shown that at small iodine feeds the dehydrogenation indices both for isopentane and for n-butane are significantly inferior, in the reactor filled with solid acceptor, to the corresponding indices in the reactor filled with the quartz filler alone or the reactor filled with a combination of quartz filler and acceptor.The iodination indices for the iodinated acceptor and the quartz filler are identical.It is established that the role of the solid acceptor consists only in the absorption of HI with the formation of an iodide which is not oxidized during the time of the reaction cycle.The oxidation of the iodide to iodine takes place only during the acceptor regeneration cycle when the raw material is not being fed to the reactor. Oxidation Quartz Iodine Hydrocarbon Iodide Nikonova, M. M. aut Enthalten in Chemistry and technology of fuels and oils Kluwer Academic Publishers-Plenum Publishers, 1966 5(1969), 6 vom: Juni, Seite 395-399 (DE-627)129592196 (DE-600)240238-5 (DE-576)015084906 0009-3092 nnns volume:5 year:1969 number:6 month:06 pages:395-399 https://doi.org/10.1007/BF00722483 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_70 GBV_ILN_2015 GBV_ILN_4307 AR 5 1969 6 06 395-399 |
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10.1007/BF00722483 doi (DE-627)OLC2049538871 (DE-He213)BF00722483-p DE-627 ger DE-627 rakwb eng 660 VZ Adel'son, S. V. verfasserin aut Role of solid acceptors in the oxidative dehydrogenation of hydrocarbons with iodine 1969 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Consultants Bureau 1969 Conclusions It is shown that at small iodine feeds the dehydrogenation indices both for isopentane and for n-butane are significantly inferior, in the reactor filled with solid acceptor, to the corresponding indices in the reactor filled with the quartz filler alone or the reactor filled with a combination of quartz filler and acceptor.The iodination indices for the iodinated acceptor and the quartz filler are identical.It is established that the role of the solid acceptor consists only in the absorption of HI with the formation of an iodide which is not oxidized during the time of the reaction cycle.The oxidation of the iodide to iodine takes place only during the acceptor regeneration cycle when the raw material is not being fed to the reactor. Oxidation Quartz Iodine Hydrocarbon Iodide Nikonova, M. M. aut Enthalten in Chemistry and technology of fuels and oils Kluwer Academic Publishers-Plenum Publishers, 1966 5(1969), 6 vom: Juni, Seite 395-399 (DE-627)129592196 (DE-600)240238-5 (DE-576)015084906 0009-3092 nnns volume:5 year:1969 number:6 month:06 pages:395-399 https://doi.org/10.1007/BF00722483 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_70 GBV_ILN_2015 GBV_ILN_4307 AR 5 1969 6 06 395-399 |
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Enthalten in Chemistry and technology of fuels and oils 5(1969), 6 vom: Juni, Seite 395-399 volume:5 year:1969 number:6 month:06 pages:395-399 |
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660 VZ Role of solid acceptors in the oxidative dehydrogenation of hydrocarbons with iodine Oxidation Quartz Iodine Hydrocarbon Iodide |
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role of solid acceptors in the oxidative dehydrogenation of hydrocarbons with iodine |
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Role of solid acceptors in the oxidative dehydrogenation of hydrocarbons with iodine |
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Conclusions It is shown that at small iodine feeds the dehydrogenation indices both for isopentane and for n-butane are significantly inferior, in the reactor filled with solid acceptor, to the corresponding indices in the reactor filled with the quartz filler alone or the reactor filled with a combination of quartz filler and acceptor.The iodination indices for the iodinated acceptor and the quartz filler are identical.It is established that the role of the solid acceptor consists only in the absorption of HI with the formation of an iodide which is not oxidized during the time of the reaction cycle.The oxidation of the iodide to iodine takes place only during the acceptor regeneration cycle when the raw material is not being fed to the reactor. © Consultants Bureau 1969 |
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Conclusions It is shown that at small iodine feeds the dehydrogenation indices both for isopentane and for n-butane are significantly inferior, in the reactor filled with solid acceptor, to the corresponding indices in the reactor filled with the quartz filler alone or the reactor filled with a combination of quartz filler and acceptor.The iodination indices for the iodinated acceptor and the quartz filler are identical.It is established that the role of the solid acceptor consists only in the absorption of HI with the formation of an iodide which is not oxidized during the time of the reaction cycle.The oxidation of the iodide to iodine takes place only during the acceptor regeneration cycle when the raw material is not being fed to the reactor. © Consultants Bureau 1969 |
| abstract_unstemmed |
Conclusions It is shown that at small iodine feeds the dehydrogenation indices both for isopentane and for n-butane are significantly inferior, in the reactor filled with solid acceptor, to the corresponding indices in the reactor filled with the quartz filler alone or the reactor filled with a combination of quartz filler and acceptor.The iodination indices for the iodinated acceptor and the quartz filler are identical.It is established that the role of the solid acceptor consists only in the absorption of HI with the formation of an iodide which is not oxidized during the time of the reaction cycle.The oxidation of the iodide to iodine takes place only during the acceptor regeneration cycle when the raw material is not being fed to the reactor. © Consultants Bureau 1969 |
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V.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Role of solid acceptors in the oxidative dehydrogenation of hydrocarbons with iodine</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">1969</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Consultants Bureau 1969</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Conclusions It is shown that at small iodine feeds the dehydrogenation indices both for isopentane and for n-butane are significantly inferior, in the reactor filled with solid acceptor, to the corresponding indices in the reactor filled with the quartz filler alone or the reactor filled with a combination of quartz filler and acceptor.The iodination indices for the iodinated acceptor and the quartz filler are identical.It is established that the role of the solid acceptor consists only in the absorption of HI with the formation of an iodide which is not oxidized during the time of the reaction cycle.The oxidation of the iodide to iodine takes place only during the acceptor regeneration cycle when the raw material is not being fed to the reactor.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Oxidation</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Quartz</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Iodine</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Hydrocarbon</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Iodide</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Nikonova, M. M.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Chemistry and technology of fuels and oils</subfield><subfield code="d">Kluwer Academic Publishers-Plenum Publishers, 1966</subfield><subfield code="g">5(1969), 6 vom: Juni, Seite 395-399</subfield><subfield code="w">(DE-627)129592196</subfield><subfield code="w">(DE-600)240238-5</subfield><subfield code="w">(DE-576)015084906</subfield><subfield code="x">0009-3092</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:5</subfield><subfield code="g">year:1969</subfield><subfield code="g">number:6</subfield><subfield code="g">month:06</subfield><subfield code="g">pages:395-399</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1007/BF00722483</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-CHE</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-DE-84</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_11</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4307</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">5</subfield><subfield code="j">1969</subfield><subfield code="e">6</subfield><subfield code="c">06</subfield><subfield code="h">395-399</subfield></datafield></record></collection>
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