Dehydrogenation of isopentenes by iodine
Summary A study was made of the oxidative dehydrogenation of isopentenes by iodine in the presence of a solid soda acceptor. It was shown that the process occurs with a high yield of isoprene and high selectivity (75.5 and 94.2 wt.%, respectively) at molar ratios of iodine: oxygen: water vapor: isop...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Adel'son, S. V. [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1970 |
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| Schlagwörter: |
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| Anmerkung: |
© Consultants Bureau 1970 |
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| Übergeordnetes Werk: |
Enthalten in: Chemistry and technology of fuels and oils - Kluwer Academic Publishers-Plenum Publishers, 1966, 6(1970), 1 vom: Jan., Seite 10-14 |
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| Übergeordnetes Werk: |
volume:6 ; year:1970 ; number:1 ; month:01 ; pages:10-14 |
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|---|
| DOI / URN: |
10.1007/BF00729729 |
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OLC2049540183 |
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| 245 | 1 | 0 | |a Dehydrogenation of isopentenes by iodine |
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| 520 | |a Summary A study was made of the oxidative dehydrogenation of isopentenes by iodine in the presence of a solid soda acceptor. It was shown that the process occurs with a high yield of isoprene and high selectivity (75.5 and 94.2 wt.%, respectively) at molar ratios of iodine: oxygen: water vapor: isopentenes = 0.05∶1.0∶12.4∶1.0, temperature 520°C, and contact time 1.3 sec.It was shown that in the dehydrogenation of isopentenes the yield of isoprene and the selectivity are commensurable in reactors filled with a solid acceptor or a quartz packing.It has been established that the reaction rate for the dehydrogenation of isopentenes by iodine is significantly greater than that for the dehydrogenation of isopentane.The products arising from extensive oxidation and decomposition during the dehydrogenation of isopentane are formed predominantly by side reactions of the original feedstock, and only in insignificant amounts from the intermediate product, isopentene. | ||
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| 650 | 4 | |a Iodine | |
| 700 | 1 | |a Nikonova, M. M. |4 aut | |
| 700 | 1 | |a Nikonov, V. I. |4 aut | |
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10.1007/BF00729729 doi (DE-627)OLC2049540183 (DE-He213)BF00729729-p DE-627 ger DE-627 rakwb eng 660 VZ Adel'son, S. V. verfasserin aut Dehydrogenation of isopentenes by iodine 1970 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Consultants Bureau 1970 Summary A study was made of the oxidative dehydrogenation of isopentenes by iodine in the presence of a solid soda acceptor. It was shown that the process occurs with a high yield of isoprene and high selectivity (75.5 and 94.2 wt.%, respectively) at molar ratios of iodine: oxygen: water vapor: isopentenes = 0.05∶1.0∶12.4∶1.0, temperature 520°C, and contact time 1.3 sec.It was shown that in the dehydrogenation of isopentenes the yield of isoprene and the selectivity are commensurable in reactors filled with a solid acceptor or a quartz packing.It has been established that the reaction rate for the dehydrogenation of isopentenes by iodine is significantly greater than that for the dehydrogenation of isopentane.The products arising from extensive oxidation and decomposition during the dehydrogenation of isopentane are formed predominantly by side reactions of the original feedstock, and only in insignificant amounts from the intermediate product, isopentene. Oxidation Oxygen Soda Quartz Iodine Nikonova, M. M. aut Nikonov, V. I. aut Enthalten in Chemistry and technology of fuels and oils Kluwer Academic Publishers-Plenum Publishers, 1966 6(1970), 1 vom: Jan., Seite 10-14 (DE-627)129592196 (DE-600)240238-5 (DE-576)015084906 0009-3092 nnns volume:6 year:1970 number:1 month:01 pages:10-14 https://doi.org/10.1007/BF00729729 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_70 GBV_ILN_2015 GBV_ILN_4307 AR 6 1970 1 01 10-14 |
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10.1007/BF00729729 doi (DE-627)OLC2049540183 (DE-He213)BF00729729-p DE-627 ger DE-627 rakwb eng 660 VZ Adel'son, S. V. verfasserin aut Dehydrogenation of isopentenes by iodine 1970 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Consultants Bureau 1970 Summary A study was made of the oxidative dehydrogenation of isopentenes by iodine in the presence of a solid soda acceptor. It was shown that the process occurs with a high yield of isoprene and high selectivity (75.5 and 94.2 wt.%, respectively) at molar ratios of iodine: oxygen: water vapor: isopentenes = 0.05∶1.0∶12.4∶1.0, temperature 520°C, and contact time 1.3 sec.It was shown that in the dehydrogenation of isopentenes the yield of isoprene and the selectivity are commensurable in reactors filled with a solid acceptor or a quartz packing.It has been established that the reaction rate for the dehydrogenation of isopentenes by iodine is significantly greater than that for the dehydrogenation of isopentane.The products arising from extensive oxidation and decomposition during the dehydrogenation of isopentane are formed predominantly by side reactions of the original feedstock, and only in insignificant amounts from the intermediate product, isopentene. Oxidation Oxygen Soda Quartz Iodine Nikonova, M. M. aut Nikonov, V. I. aut Enthalten in Chemistry and technology of fuels and oils Kluwer Academic Publishers-Plenum Publishers, 1966 6(1970), 1 vom: Jan., Seite 10-14 (DE-627)129592196 (DE-600)240238-5 (DE-576)015084906 0009-3092 nnns volume:6 year:1970 number:1 month:01 pages:10-14 https://doi.org/10.1007/BF00729729 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_70 GBV_ILN_2015 GBV_ILN_4307 AR 6 1970 1 01 10-14 |
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10.1007/BF00729729 doi (DE-627)OLC2049540183 (DE-He213)BF00729729-p DE-627 ger DE-627 rakwb eng 660 VZ Adel'son, S. V. verfasserin aut Dehydrogenation of isopentenes by iodine 1970 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Consultants Bureau 1970 Summary A study was made of the oxidative dehydrogenation of isopentenes by iodine in the presence of a solid soda acceptor. It was shown that the process occurs with a high yield of isoprene and high selectivity (75.5 and 94.2 wt.%, respectively) at molar ratios of iodine: oxygen: water vapor: isopentenes = 0.05∶1.0∶12.4∶1.0, temperature 520°C, and contact time 1.3 sec.It was shown that in the dehydrogenation of isopentenes the yield of isoprene and the selectivity are commensurable in reactors filled with a solid acceptor or a quartz packing.It has been established that the reaction rate for the dehydrogenation of isopentenes by iodine is significantly greater than that for the dehydrogenation of isopentane.The products arising from extensive oxidation and decomposition during the dehydrogenation of isopentane are formed predominantly by side reactions of the original feedstock, and only in insignificant amounts from the intermediate product, isopentene. Oxidation Oxygen Soda Quartz Iodine Nikonova, M. M. aut Nikonov, V. I. aut Enthalten in Chemistry and technology of fuels and oils Kluwer Academic Publishers-Plenum Publishers, 1966 6(1970), 1 vom: Jan., Seite 10-14 (DE-627)129592196 (DE-600)240238-5 (DE-576)015084906 0009-3092 nnns volume:6 year:1970 number:1 month:01 pages:10-14 https://doi.org/10.1007/BF00729729 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_70 GBV_ILN_2015 GBV_ILN_4307 AR 6 1970 1 01 10-14 |
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10.1007/BF00729729 doi (DE-627)OLC2049540183 (DE-He213)BF00729729-p DE-627 ger DE-627 rakwb eng 660 VZ Adel'son, S. V. verfasserin aut Dehydrogenation of isopentenes by iodine 1970 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Consultants Bureau 1970 Summary A study was made of the oxidative dehydrogenation of isopentenes by iodine in the presence of a solid soda acceptor. It was shown that the process occurs with a high yield of isoprene and high selectivity (75.5 and 94.2 wt.%, respectively) at molar ratios of iodine: oxygen: water vapor: isopentenes = 0.05∶1.0∶12.4∶1.0, temperature 520°C, and contact time 1.3 sec.It was shown that in the dehydrogenation of isopentenes the yield of isoprene and the selectivity are commensurable in reactors filled with a solid acceptor or a quartz packing.It has been established that the reaction rate for the dehydrogenation of isopentenes by iodine is significantly greater than that for the dehydrogenation of isopentane.The products arising from extensive oxidation and decomposition during the dehydrogenation of isopentane are formed predominantly by side reactions of the original feedstock, and only in insignificant amounts from the intermediate product, isopentene. Oxidation Oxygen Soda Quartz Iodine Nikonova, M. M. aut Nikonov, V. I. aut Enthalten in Chemistry and technology of fuels and oils Kluwer Academic Publishers-Plenum Publishers, 1966 6(1970), 1 vom: Jan., Seite 10-14 (DE-627)129592196 (DE-600)240238-5 (DE-576)015084906 0009-3092 nnns volume:6 year:1970 number:1 month:01 pages:10-14 https://doi.org/10.1007/BF00729729 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_70 GBV_ILN_2015 GBV_ILN_4307 AR 6 1970 1 01 10-14 |
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10.1007/BF00729729 doi (DE-627)OLC2049540183 (DE-He213)BF00729729-p DE-627 ger DE-627 rakwb eng 660 VZ Adel'son, S. V. verfasserin aut Dehydrogenation of isopentenes by iodine 1970 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Consultants Bureau 1970 Summary A study was made of the oxidative dehydrogenation of isopentenes by iodine in the presence of a solid soda acceptor. It was shown that the process occurs with a high yield of isoprene and high selectivity (75.5 and 94.2 wt.%, respectively) at molar ratios of iodine: oxygen: water vapor: isopentenes = 0.05∶1.0∶12.4∶1.0, temperature 520°C, and contact time 1.3 sec.It was shown that in the dehydrogenation of isopentenes the yield of isoprene and the selectivity are commensurable in reactors filled with a solid acceptor or a quartz packing.It has been established that the reaction rate for the dehydrogenation of isopentenes by iodine is significantly greater than that for the dehydrogenation of isopentane.The products arising from extensive oxidation and decomposition during the dehydrogenation of isopentane are formed predominantly by side reactions of the original feedstock, and only in insignificant amounts from the intermediate product, isopentene. Oxidation Oxygen Soda Quartz Iodine Nikonova, M. M. aut Nikonov, V. I. aut Enthalten in Chemistry and technology of fuels and oils Kluwer Academic Publishers-Plenum Publishers, 1966 6(1970), 1 vom: Jan., Seite 10-14 (DE-627)129592196 (DE-600)240238-5 (DE-576)015084906 0009-3092 nnns volume:6 year:1970 number:1 month:01 pages:10-14 https://doi.org/10.1007/BF00729729 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_70 GBV_ILN_2015 GBV_ILN_4307 AR 6 1970 1 01 10-14 |
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Dehydrogenation of isopentenes by iodine |
| abstract |
Summary A study was made of the oxidative dehydrogenation of isopentenes by iodine in the presence of a solid soda acceptor. It was shown that the process occurs with a high yield of isoprene and high selectivity (75.5 and 94.2 wt.%, respectively) at molar ratios of iodine: oxygen: water vapor: isopentenes = 0.05∶1.0∶12.4∶1.0, temperature 520°C, and contact time 1.3 sec.It was shown that in the dehydrogenation of isopentenes the yield of isoprene and the selectivity are commensurable in reactors filled with a solid acceptor or a quartz packing.It has been established that the reaction rate for the dehydrogenation of isopentenes by iodine is significantly greater than that for the dehydrogenation of isopentane.The products arising from extensive oxidation and decomposition during the dehydrogenation of isopentane are formed predominantly by side reactions of the original feedstock, and only in insignificant amounts from the intermediate product, isopentene. © Consultants Bureau 1970 |
| abstractGer |
Summary A study was made of the oxidative dehydrogenation of isopentenes by iodine in the presence of a solid soda acceptor. It was shown that the process occurs with a high yield of isoprene and high selectivity (75.5 and 94.2 wt.%, respectively) at molar ratios of iodine: oxygen: water vapor: isopentenes = 0.05∶1.0∶12.4∶1.0, temperature 520°C, and contact time 1.3 sec.It was shown that in the dehydrogenation of isopentenes the yield of isoprene and the selectivity are commensurable in reactors filled with a solid acceptor or a quartz packing.It has been established that the reaction rate for the dehydrogenation of isopentenes by iodine is significantly greater than that for the dehydrogenation of isopentane.The products arising from extensive oxidation and decomposition during the dehydrogenation of isopentane are formed predominantly by side reactions of the original feedstock, and only in insignificant amounts from the intermediate product, isopentene. © Consultants Bureau 1970 |
| abstract_unstemmed |
Summary A study was made of the oxidative dehydrogenation of isopentenes by iodine in the presence of a solid soda acceptor. It was shown that the process occurs with a high yield of isoprene and high selectivity (75.5 and 94.2 wt.%, respectively) at molar ratios of iodine: oxygen: water vapor: isopentenes = 0.05∶1.0∶12.4∶1.0, temperature 520°C, and contact time 1.3 sec.It was shown that in the dehydrogenation of isopentenes the yield of isoprene and the selectivity are commensurable in reactors filled with a solid acceptor or a quartz packing.It has been established that the reaction rate for the dehydrogenation of isopentenes by iodine is significantly greater than that for the dehydrogenation of isopentane.The products arising from extensive oxidation and decomposition during the dehydrogenation of isopentane are formed predominantly by side reactions of the original feedstock, and only in insignificant amounts from the intermediate product, isopentene. © Consultants Bureau 1970 |
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Dehydrogenation of isopentenes by iodine |
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Nikonova, M. M. Nikonov, V. I. |
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