Change in the Hydrocarbon and Component Compositions of Heavy Crude Ashalchinsk Oil Upon Catalytic Aquathermolysis
A physical model has been developed for the aquathermolysis of heavy crude oil from the Ashalchinsk oil field at 250°, 300°, and 350°C. Nickel and cobalt carboxylates were used as oil-soluble catalyst precursors. In the presence of a hydrogen proton donor at 300°C, the oil content was found to rise...
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| Autor*in: |
Foss, L. E. [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2017 |
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| Anmerkung: |
© Springer Science+Business Media, LLC 2017 |
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| Übergeordnetes Werk: |
Enthalten in: Chemistry and technology of fuels and oils - Springer US, 1966, 53(2017), 2 vom: Mai, Seite 173-180 |
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| Übergeordnetes Werk: |
volume:53 ; year:2017 ; number:2 ; month:05 ; pages:173-180 |
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| DOI / URN: |
10.1007/s10553-017-0793-7 |
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| 520 | |a A physical model has been developed for the aquathermolysis of heavy crude oil from the Ashalchinsk oil field at 250°, 300°, and 350°C. Nickel and cobalt carboxylates were used as oil-soluble catalyst precursors. In the presence of a hydrogen proton donor at 300°C, the oil content was found to rise considerably and the resin content was found to decrease by a factor of 1.8, which leads to a decrease in crude oil viscosity by 91% and a decrease in density from 960 to 933 kg/$ m^{3} $. The hydrocarbon composition of the liquid aquathermolysis products was studied by chromate-mass spectrometry. The average molecular weight of the asphaltenes was determined by matrix-assisted laser desorption/ionization (MALDI) spectrometry. The maximum disproportionation of the hydrocarbons into n-alkanes, alkylcyclohexanes, and alkylbenzenes occurs at 300° and 350°C. The composition of the hydrogen proton donor (tetralin) conversion products at these aquathermolysis temperatures was determined. | ||
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| 700 | 1 | |a Nikolaev, V. F. |4 aut | |
| 700 | 1 | |a Romanov, G. V. |4 aut | |
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10.1007/s10553-017-0793-7 doi (DE-627)OLC2049610475 (DE-He213)s10553-017-0793-7-p DE-627 ger DE-627 rakwb eng 660 VZ Foss, L. E. verfasserin aut Change in the Hydrocarbon and Component Compositions of Heavy Crude Ashalchinsk Oil Upon Catalytic Aquathermolysis 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2017 A physical model has been developed for the aquathermolysis of heavy crude oil from the Ashalchinsk oil field at 250°, 300°, and 350°C. Nickel and cobalt carboxylates were used as oil-soluble catalyst precursors. In the presence of a hydrogen proton donor at 300°C, the oil content was found to rise considerably and the resin content was found to decrease by a factor of 1.8, which leads to a decrease in crude oil viscosity by 91% and a decrease in density from 960 to 933 kg/$ m^{3} $. The hydrocarbon composition of the liquid aquathermolysis products was studied by chromate-mass spectrometry. The average molecular weight of the asphaltenes was determined by matrix-assisted laser desorption/ionization (MALDI) spectrometry. The maximum disproportionation of the hydrocarbons into n-alkanes, alkylcyclohexanes, and alkylbenzenes occurs at 300° and 350°C. The composition of the hydrogen proton donor (tetralin) conversion products at these aquathermolysis temperatures was determined. Kayukova, G. P. aut Tumanyan, B. P. aut Petrukhina, N. N. aut Nikolaev, V. F. aut Romanov, G. V. aut Enthalten in Chemistry and technology of fuels and oils Springer US, 1966 53(2017), 2 vom: Mai, Seite 173-180 (DE-627)129592196 (DE-600)240238-5 (DE-576)015084906 0009-3092 nnns volume:53 year:2017 number:2 month:05 pages:173-180 https://doi.org/10.1007/s10553-017-0793-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 53 2017 2 05 173-180 |
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10.1007/s10553-017-0793-7 doi (DE-627)OLC2049610475 (DE-He213)s10553-017-0793-7-p DE-627 ger DE-627 rakwb eng 660 VZ Foss, L. E. verfasserin aut Change in the Hydrocarbon and Component Compositions of Heavy Crude Ashalchinsk Oil Upon Catalytic Aquathermolysis 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2017 A physical model has been developed for the aquathermolysis of heavy crude oil from the Ashalchinsk oil field at 250°, 300°, and 350°C. Nickel and cobalt carboxylates were used as oil-soluble catalyst precursors. In the presence of a hydrogen proton donor at 300°C, the oil content was found to rise considerably and the resin content was found to decrease by a factor of 1.8, which leads to a decrease in crude oil viscosity by 91% and a decrease in density from 960 to 933 kg/$ m^{3} $. The hydrocarbon composition of the liquid aquathermolysis products was studied by chromate-mass spectrometry. The average molecular weight of the asphaltenes was determined by matrix-assisted laser desorption/ionization (MALDI) spectrometry. The maximum disproportionation of the hydrocarbons into n-alkanes, alkylcyclohexanes, and alkylbenzenes occurs at 300° and 350°C. The composition of the hydrogen proton donor (tetralin) conversion products at these aquathermolysis temperatures was determined. Kayukova, G. P. aut Tumanyan, B. P. aut Petrukhina, N. N. aut Nikolaev, V. F. aut Romanov, G. V. aut Enthalten in Chemistry and technology of fuels and oils Springer US, 1966 53(2017), 2 vom: Mai, Seite 173-180 (DE-627)129592196 (DE-600)240238-5 (DE-576)015084906 0009-3092 nnns volume:53 year:2017 number:2 month:05 pages:173-180 https://doi.org/10.1007/s10553-017-0793-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 53 2017 2 05 173-180 |
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10.1007/s10553-017-0793-7 doi (DE-627)OLC2049610475 (DE-He213)s10553-017-0793-7-p DE-627 ger DE-627 rakwb eng 660 VZ Foss, L. E. verfasserin aut Change in the Hydrocarbon and Component Compositions of Heavy Crude Ashalchinsk Oil Upon Catalytic Aquathermolysis 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2017 A physical model has been developed for the aquathermolysis of heavy crude oil from the Ashalchinsk oil field at 250°, 300°, and 350°C. Nickel and cobalt carboxylates were used as oil-soluble catalyst precursors. In the presence of a hydrogen proton donor at 300°C, the oil content was found to rise considerably and the resin content was found to decrease by a factor of 1.8, which leads to a decrease in crude oil viscosity by 91% and a decrease in density from 960 to 933 kg/$ m^{3} $. The hydrocarbon composition of the liquid aquathermolysis products was studied by chromate-mass spectrometry. The average molecular weight of the asphaltenes was determined by matrix-assisted laser desorption/ionization (MALDI) spectrometry. The maximum disproportionation of the hydrocarbons into n-alkanes, alkylcyclohexanes, and alkylbenzenes occurs at 300° and 350°C. The composition of the hydrogen proton donor (tetralin) conversion products at these aquathermolysis temperatures was determined. Kayukova, G. P. aut Tumanyan, B. P. aut Petrukhina, N. N. aut Nikolaev, V. F. aut Romanov, G. V. aut Enthalten in Chemistry and technology of fuels and oils Springer US, 1966 53(2017), 2 vom: Mai, Seite 173-180 (DE-627)129592196 (DE-600)240238-5 (DE-576)015084906 0009-3092 nnns volume:53 year:2017 number:2 month:05 pages:173-180 https://doi.org/10.1007/s10553-017-0793-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 53 2017 2 05 173-180 |
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10.1007/s10553-017-0793-7 doi (DE-627)OLC2049610475 (DE-He213)s10553-017-0793-7-p DE-627 ger DE-627 rakwb eng 660 VZ Foss, L. E. verfasserin aut Change in the Hydrocarbon and Component Compositions of Heavy Crude Ashalchinsk Oil Upon Catalytic Aquathermolysis 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2017 A physical model has been developed for the aquathermolysis of heavy crude oil from the Ashalchinsk oil field at 250°, 300°, and 350°C. Nickel and cobalt carboxylates were used as oil-soluble catalyst precursors. In the presence of a hydrogen proton donor at 300°C, the oil content was found to rise considerably and the resin content was found to decrease by a factor of 1.8, which leads to a decrease in crude oil viscosity by 91% and a decrease in density from 960 to 933 kg/$ m^{3} $. The hydrocarbon composition of the liquid aquathermolysis products was studied by chromate-mass spectrometry. The average molecular weight of the asphaltenes was determined by matrix-assisted laser desorption/ionization (MALDI) spectrometry. The maximum disproportionation of the hydrocarbons into n-alkanes, alkylcyclohexanes, and alkylbenzenes occurs at 300° and 350°C. The composition of the hydrogen proton donor (tetralin) conversion products at these aquathermolysis temperatures was determined. Kayukova, G. P. aut Tumanyan, B. P. aut Petrukhina, N. N. aut Nikolaev, V. F. aut Romanov, G. V. aut Enthalten in Chemistry and technology of fuels and oils Springer US, 1966 53(2017), 2 vom: Mai, Seite 173-180 (DE-627)129592196 (DE-600)240238-5 (DE-576)015084906 0009-3092 nnns volume:53 year:2017 number:2 month:05 pages:173-180 https://doi.org/10.1007/s10553-017-0793-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 53 2017 2 05 173-180 |
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10.1007/s10553-017-0793-7 doi (DE-627)OLC2049610475 (DE-He213)s10553-017-0793-7-p DE-627 ger DE-627 rakwb eng 660 VZ Foss, L. E. verfasserin aut Change in the Hydrocarbon and Component Compositions of Heavy Crude Ashalchinsk Oil Upon Catalytic Aquathermolysis 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2017 A physical model has been developed for the aquathermolysis of heavy crude oil from the Ashalchinsk oil field at 250°, 300°, and 350°C. Nickel and cobalt carboxylates were used as oil-soluble catalyst precursors. In the presence of a hydrogen proton donor at 300°C, the oil content was found to rise considerably and the resin content was found to decrease by a factor of 1.8, which leads to a decrease in crude oil viscosity by 91% and a decrease in density from 960 to 933 kg/$ m^{3} $. The hydrocarbon composition of the liquid aquathermolysis products was studied by chromate-mass spectrometry. The average molecular weight of the asphaltenes was determined by matrix-assisted laser desorption/ionization (MALDI) spectrometry. The maximum disproportionation of the hydrocarbons into n-alkanes, alkylcyclohexanes, and alkylbenzenes occurs at 300° and 350°C. The composition of the hydrogen proton donor (tetralin) conversion products at these aquathermolysis temperatures was determined. Kayukova, G. P. aut Tumanyan, B. P. aut Petrukhina, N. N. aut Nikolaev, V. F. aut Romanov, G. V. aut Enthalten in Chemistry and technology of fuels and oils Springer US, 1966 53(2017), 2 vom: Mai, Seite 173-180 (DE-627)129592196 (DE-600)240238-5 (DE-576)015084906 0009-3092 nnns volume:53 year:2017 number:2 month:05 pages:173-180 https://doi.org/10.1007/s10553-017-0793-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 53 2017 2 05 173-180 |
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change in the hydrocarbon and component compositions of heavy crude ashalchinsk oil upon catalytic aquathermolysis |
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Change in the Hydrocarbon and Component Compositions of Heavy Crude Ashalchinsk Oil Upon Catalytic Aquathermolysis |
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A physical model has been developed for the aquathermolysis of heavy crude oil from the Ashalchinsk oil field at 250°, 300°, and 350°C. Nickel and cobalt carboxylates were used as oil-soluble catalyst precursors. In the presence of a hydrogen proton donor at 300°C, the oil content was found to rise considerably and the resin content was found to decrease by a factor of 1.8, which leads to a decrease in crude oil viscosity by 91% and a decrease in density from 960 to 933 kg/$ m^{3} $. The hydrocarbon composition of the liquid aquathermolysis products was studied by chromate-mass spectrometry. The average molecular weight of the asphaltenes was determined by matrix-assisted laser desorption/ionization (MALDI) spectrometry. The maximum disproportionation of the hydrocarbons into n-alkanes, alkylcyclohexanes, and alkylbenzenes occurs at 300° and 350°C. The composition of the hydrogen proton donor (tetralin) conversion products at these aquathermolysis temperatures was determined. © Springer Science+Business Media, LLC 2017 |
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A physical model has been developed for the aquathermolysis of heavy crude oil from the Ashalchinsk oil field at 250°, 300°, and 350°C. Nickel and cobalt carboxylates were used as oil-soluble catalyst precursors. In the presence of a hydrogen proton donor at 300°C, the oil content was found to rise considerably and the resin content was found to decrease by a factor of 1.8, which leads to a decrease in crude oil viscosity by 91% and a decrease in density from 960 to 933 kg/$ m^{3} $. The hydrocarbon composition of the liquid aquathermolysis products was studied by chromate-mass spectrometry. The average molecular weight of the asphaltenes was determined by matrix-assisted laser desorption/ionization (MALDI) spectrometry. The maximum disproportionation of the hydrocarbons into n-alkanes, alkylcyclohexanes, and alkylbenzenes occurs at 300° and 350°C. The composition of the hydrogen proton donor (tetralin) conversion products at these aquathermolysis temperatures was determined. © Springer Science+Business Media, LLC 2017 |
| abstract_unstemmed |
A physical model has been developed for the aquathermolysis of heavy crude oil from the Ashalchinsk oil field at 250°, 300°, and 350°C. Nickel and cobalt carboxylates were used as oil-soluble catalyst precursors. In the presence of a hydrogen proton donor at 300°C, the oil content was found to rise considerably and the resin content was found to decrease by a factor of 1.8, which leads to a decrease in crude oil viscosity by 91% and a decrease in density from 960 to 933 kg/$ m^{3} $. The hydrocarbon composition of the liquid aquathermolysis products was studied by chromate-mass spectrometry. The average molecular weight of the asphaltenes was determined by matrix-assisted laser desorption/ionization (MALDI) spectrometry. The maximum disproportionation of the hydrocarbons into n-alkanes, alkylcyclohexanes, and alkylbenzenes occurs at 300° and 350°C. The composition of the hydrogen proton donor (tetralin) conversion products at these aquathermolysis temperatures was determined. © Springer Science+Business Media, LLC 2017 |
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Change in the Hydrocarbon and Component Compositions of Heavy Crude Ashalchinsk Oil Upon Catalytic Aquathermolysis |
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Kayukova, G. P. Tumanyan, B. P. Petrukhina, N. N. Nikolaev, V. F. Romanov, G. V. |
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