Effect of $ LaF_{3} $ admixture on thermal stability of borosilicate glasses
Abstract Oxyfluoride glass-ceramics based on the aluminosilicate glass-matrix with the nano-phase of fluoride is an interesting material for optoelectronics. A new glass from the $ SiO_{2} $–$ B_{2} $$ O_{3} $–$ Na_{2} $O–$ LaF_{3} $ system in which nanocrystallization of $ LaF_{3} $ could be obtain...
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| Autor*in: |
Środa, M. [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2007 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer-Verlag 2007 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of thermal analysis and calorimetry - Kluwer Academic Publishers, 1998, 88(2007), 1 vom: Apr., Seite 245-249 |
|---|---|
| Übergeordnetes Werk: |
volume:88 ; year:2007 ; number:1 ; month:04 ; pages:245-249 |
| Links: |
|---|
| DOI / URN: |
10.1007/s10973-006-8137-6 |
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OLC2049783965 |
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| 520 | |a Abstract Oxyfluoride glass-ceramics based on the aluminosilicate glass-matrix with the nano-phase of fluoride is an interesting material for optoelectronics. A new glass from the $ SiO_{2} $–$ B_{2} $$ O_{3} $–$ Na_{2} $O–$ LaF_{3} $ system in which nanocrystallization of $ LaF_{3} $ could be obtained as well is presented. Thermal stability of glass and the crystalline phases formed upon heat treatment were determined by DTA/DSC and XRD methods, respectively. The effect of the glass composition on thermal stability was investigated by the SEM method. It has been found that the addition of $ LaF_{3} $ increases the tendency to decomposition of the borosilicate glass. In glasses with the ratio $ B_{2} $$ O_{3} $/($ Na_{2} $O+$ 3La_{2} $$ F_{6} $)<1 it is possible to obtain the immersed crystallization of $ LaF_{3} $ in transparent glassy matrix. The process is preceded by LaOF formation. Glasses with the composition $ B_{2} $$ O_{3} $/($ Na_{2} $O+$ 3La_{2} $$ F_{6} $)≥1 revealed the tendency to La($ BSiO_{5} $) crystallization. | ||
| 650 | 4 | |a borosilicate glass | |
| 650 | 4 | |a lanthanum fluoride | |
| 650 | 4 | |a oxyfluoride glass | |
| 650 | 4 | |a thermal analysis | |
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10.1007/s10973-006-8137-6 doi (DE-627)OLC2049783965 (DE-He213)s10973-006-8137-6-p DE-627 ger DE-627 rakwb eng 660 VZ Środa, M. verfasserin aut Effect of $ LaF_{3} $ admixture on thermal stability of borosilicate glasses 2007 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 2007 Abstract Oxyfluoride glass-ceramics based on the aluminosilicate glass-matrix with the nano-phase of fluoride is an interesting material for optoelectronics. A new glass from the $ SiO_{2} $–$ B_{2} $$ O_{3} $–$ Na_{2} $O–$ LaF_{3} $ system in which nanocrystallization of $ LaF_{3} $ could be obtained as well is presented. Thermal stability of glass and the crystalline phases formed upon heat treatment were determined by DTA/DSC and XRD methods, respectively. The effect of the glass composition on thermal stability was investigated by the SEM method. It has been found that the addition of $ LaF_{3} $ increases the tendency to decomposition of the borosilicate glass. In glasses with the ratio $ B_{2} $$ O_{3} $/($ Na_{2} $O+$ 3La_{2} $$ F_{6} $)<1 it is possible to obtain the immersed crystallization of $ LaF_{3} $ in transparent glassy matrix. The process is preceded by LaOF formation. Glasses with the composition $ B_{2} $$ O_{3} $/($ Na_{2} $O+$ 3La_{2} $$ F_{6} $)≥1 revealed the tendency to La($ BSiO_{5} $) crystallization. borosilicate glass lanthanum fluoride oxyfluoride glass thermal analysis Enthalten in Journal of thermal analysis and calorimetry Kluwer Academic Publishers, 1998 88(2007), 1 vom: Apr., Seite 245-249 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:88 year:2007 number:1 month:04 pages:245-249 https://doi.org/10.1007/s10973-006-8137-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 88 2007 1 04 245-249 |
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10.1007/s10973-006-8137-6 doi (DE-627)OLC2049783965 (DE-He213)s10973-006-8137-6-p DE-627 ger DE-627 rakwb eng 660 VZ Środa, M. verfasserin aut Effect of $ LaF_{3} $ admixture on thermal stability of borosilicate glasses 2007 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 2007 Abstract Oxyfluoride glass-ceramics based on the aluminosilicate glass-matrix with the nano-phase of fluoride is an interesting material for optoelectronics. A new glass from the $ SiO_{2} $–$ B_{2} $$ O_{3} $–$ Na_{2} $O–$ LaF_{3} $ system in which nanocrystallization of $ LaF_{3} $ could be obtained as well is presented. Thermal stability of glass and the crystalline phases formed upon heat treatment were determined by DTA/DSC and XRD methods, respectively. The effect of the glass composition on thermal stability was investigated by the SEM method. It has been found that the addition of $ LaF_{3} $ increases the tendency to decomposition of the borosilicate glass. In glasses with the ratio $ B_{2} $$ O_{3} $/($ Na_{2} $O+$ 3La_{2} $$ F_{6} $)<1 it is possible to obtain the immersed crystallization of $ LaF_{3} $ in transparent glassy matrix. The process is preceded by LaOF formation. Glasses with the composition $ B_{2} $$ O_{3} $/($ Na_{2} $O+$ 3La_{2} $$ F_{6} $)≥1 revealed the tendency to La($ BSiO_{5} $) crystallization. borosilicate glass lanthanum fluoride oxyfluoride glass thermal analysis Enthalten in Journal of thermal analysis and calorimetry Kluwer Academic Publishers, 1998 88(2007), 1 vom: Apr., Seite 245-249 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:88 year:2007 number:1 month:04 pages:245-249 https://doi.org/10.1007/s10973-006-8137-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 88 2007 1 04 245-249 |
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10.1007/s10973-006-8137-6 doi (DE-627)OLC2049783965 (DE-He213)s10973-006-8137-6-p DE-627 ger DE-627 rakwb eng 660 VZ Środa, M. verfasserin aut Effect of $ LaF_{3} $ admixture on thermal stability of borosilicate glasses 2007 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 2007 Abstract Oxyfluoride glass-ceramics based on the aluminosilicate glass-matrix with the nano-phase of fluoride is an interesting material for optoelectronics. A new glass from the $ SiO_{2} $–$ B_{2} $$ O_{3} $–$ Na_{2} $O–$ LaF_{3} $ system in which nanocrystallization of $ LaF_{3} $ could be obtained as well is presented. Thermal stability of glass and the crystalline phases formed upon heat treatment were determined by DTA/DSC and XRD methods, respectively. The effect of the glass composition on thermal stability was investigated by the SEM method. It has been found that the addition of $ LaF_{3} $ increases the tendency to decomposition of the borosilicate glass. In glasses with the ratio $ B_{2} $$ O_{3} $/($ Na_{2} $O+$ 3La_{2} $$ F_{6} $)<1 it is possible to obtain the immersed crystallization of $ LaF_{3} $ in transparent glassy matrix. The process is preceded by LaOF formation. Glasses with the composition $ B_{2} $$ O_{3} $/($ Na_{2} $O+$ 3La_{2} $$ F_{6} $)≥1 revealed the tendency to La($ BSiO_{5} $) crystallization. borosilicate glass lanthanum fluoride oxyfluoride glass thermal analysis Enthalten in Journal of thermal analysis and calorimetry Kluwer Academic Publishers, 1998 88(2007), 1 vom: Apr., Seite 245-249 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:88 year:2007 number:1 month:04 pages:245-249 https://doi.org/10.1007/s10973-006-8137-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 88 2007 1 04 245-249 |
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10.1007/s10973-006-8137-6 doi (DE-627)OLC2049783965 (DE-He213)s10973-006-8137-6-p DE-627 ger DE-627 rakwb eng 660 VZ Środa, M. verfasserin aut Effect of $ LaF_{3} $ admixture on thermal stability of borosilicate glasses 2007 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 2007 Abstract Oxyfluoride glass-ceramics based on the aluminosilicate glass-matrix with the nano-phase of fluoride is an interesting material for optoelectronics. A new glass from the $ SiO_{2} $–$ B_{2} $$ O_{3} $–$ Na_{2} $O–$ LaF_{3} $ system in which nanocrystallization of $ LaF_{3} $ could be obtained as well is presented. Thermal stability of glass and the crystalline phases formed upon heat treatment were determined by DTA/DSC and XRD methods, respectively. The effect of the glass composition on thermal stability was investigated by the SEM method. It has been found that the addition of $ LaF_{3} $ increases the tendency to decomposition of the borosilicate glass. In glasses with the ratio $ B_{2} $$ O_{3} $/($ Na_{2} $O+$ 3La_{2} $$ F_{6} $)<1 it is possible to obtain the immersed crystallization of $ LaF_{3} $ in transparent glassy matrix. The process is preceded by LaOF formation. Glasses with the composition $ B_{2} $$ O_{3} $/($ Na_{2} $O+$ 3La_{2} $$ F_{6} $)≥1 revealed the tendency to La($ BSiO_{5} $) crystallization. borosilicate glass lanthanum fluoride oxyfluoride glass thermal analysis Enthalten in Journal of thermal analysis and calorimetry Kluwer Academic Publishers, 1998 88(2007), 1 vom: Apr., Seite 245-249 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:88 year:2007 number:1 month:04 pages:245-249 https://doi.org/10.1007/s10973-006-8137-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 88 2007 1 04 245-249 |
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10.1007/s10973-006-8137-6 doi (DE-627)OLC2049783965 (DE-He213)s10973-006-8137-6-p DE-627 ger DE-627 rakwb eng 660 VZ Środa, M. verfasserin aut Effect of $ LaF_{3} $ admixture on thermal stability of borosilicate glasses 2007 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer-Verlag 2007 Abstract Oxyfluoride glass-ceramics based on the aluminosilicate glass-matrix with the nano-phase of fluoride is an interesting material for optoelectronics. A new glass from the $ SiO_{2} $–$ B_{2} $$ O_{3} $–$ Na_{2} $O–$ LaF_{3} $ system in which nanocrystallization of $ LaF_{3} $ could be obtained as well is presented. Thermal stability of glass and the crystalline phases formed upon heat treatment were determined by DTA/DSC and XRD methods, respectively. The effect of the glass composition on thermal stability was investigated by the SEM method. It has been found that the addition of $ LaF_{3} $ increases the tendency to decomposition of the borosilicate glass. In glasses with the ratio $ B_{2} $$ O_{3} $/($ Na_{2} $O+$ 3La_{2} $$ F_{6} $)<1 it is possible to obtain the immersed crystallization of $ LaF_{3} $ in transparent glassy matrix. The process is preceded by LaOF formation. Glasses with the composition $ B_{2} $$ O_{3} $/($ Na_{2} $O+$ 3La_{2} $$ F_{6} $)≥1 revealed the tendency to La($ BSiO_{5} $) crystallization. borosilicate glass lanthanum fluoride oxyfluoride glass thermal analysis Enthalten in Journal of thermal analysis and calorimetry Kluwer Academic Publishers, 1998 88(2007), 1 vom: Apr., Seite 245-249 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:88 year:2007 number:1 month:04 pages:245-249 https://doi.org/10.1007/s10973-006-8137-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 88 2007 1 04 245-249 |
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effect of $ laf_{3} $ admixture on thermal stability of borosilicate glasses |
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Effect of $ LaF_{3} $ admixture on thermal stability of borosilicate glasses |
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Abstract Oxyfluoride glass-ceramics based on the aluminosilicate glass-matrix with the nano-phase of fluoride is an interesting material for optoelectronics. A new glass from the $ SiO_{2} $–$ B_{2} $$ O_{3} $–$ Na_{2} $O–$ LaF_{3} $ system in which nanocrystallization of $ LaF_{3} $ could be obtained as well is presented. Thermal stability of glass and the crystalline phases formed upon heat treatment were determined by DTA/DSC and XRD methods, respectively. The effect of the glass composition on thermal stability was investigated by the SEM method. It has been found that the addition of $ LaF_{3} $ increases the tendency to decomposition of the borosilicate glass. In glasses with the ratio $ B_{2} $$ O_{3} $/($ Na_{2} $O+$ 3La_{2} $$ F_{6} $)<1 it is possible to obtain the immersed crystallization of $ LaF_{3} $ in transparent glassy matrix. The process is preceded by LaOF formation. Glasses with the composition $ B_{2} $$ O_{3} $/($ Na_{2} $O+$ 3La_{2} $$ F_{6} $)≥1 revealed the tendency to La($ BSiO_{5} $) crystallization. © Springer-Verlag 2007 |
| abstractGer |
Abstract Oxyfluoride glass-ceramics based on the aluminosilicate glass-matrix with the nano-phase of fluoride is an interesting material for optoelectronics. A new glass from the $ SiO_{2} $–$ B_{2} $$ O_{3} $–$ Na_{2} $O–$ LaF_{3} $ system in which nanocrystallization of $ LaF_{3} $ could be obtained as well is presented. Thermal stability of glass and the crystalline phases formed upon heat treatment were determined by DTA/DSC and XRD methods, respectively. The effect of the glass composition on thermal stability was investigated by the SEM method. It has been found that the addition of $ LaF_{3} $ increases the tendency to decomposition of the borosilicate glass. In glasses with the ratio $ B_{2} $$ O_{3} $/($ Na_{2} $O+$ 3La_{2} $$ F_{6} $)<1 it is possible to obtain the immersed crystallization of $ LaF_{3} $ in transparent glassy matrix. The process is preceded by LaOF formation. Glasses with the composition $ B_{2} $$ O_{3} $/($ Na_{2} $O+$ 3La_{2} $$ F_{6} $)≥1 revealed the tendency to La($ BSiO_{5} $) crystallization. © Springer-Verlag 2007 |
| abstract_unstemmed |
Abstract Oxyfluoride glass-ceramics based on the aluminosilicate glass-matrix with the nano-phase of fluoride is an interesting material for optoelectronics. A new glass from the $ SiO_{2} $–$ B_{2} $$ O_{3} $–$ Na_{2} $O–$ LaF_{3} $ system in which nanocrystallization of $ LaF_{3} $ could be obtained as well is presented. Thermal stability of glass and the crystalline phases formed upon heat treatment were determined by DTA/DSC and XRD methods, respectively. The effect of the glass composition on thermal stability was investigated by the SEM method. It has been found that the addition of $ LaF_{3} $ increases the tendency to decomposition of the borosilicate glass. In glasses with the ratio $ B_{2} $$ O_{3} $/($ Na_{2} $O+$ 3La_{2} $$ F_{6} $)<1 it is possible to obtain the immersed crystallization of $ LaF_{3} $ in transparent glassy matrix. The process is preceded by LaOF formation. Glasses with the composition $ B_{2} $$ O_{3} $/($ Na_{2} $O+$ 3La_{2} $$ F_{6} $)≥1 revealed the tendency to La($ BSiO_{5} $) crystallization. © Springer-Verlag 2007 |
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Effect of $ LaF_{3} $ admixture on thermal stability of borosilicate glasses |
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