[$ Cu_{2} $(μ-(3,4,5-meo-ba)2bn)(μ-I)2]n, a new 1D polymeric copper(I) chain
Abstract New 1D-chain copper(I) complex [$ Cu_{2} $(μ-(3,4,5-MeO-ba)2bn)(μ-I)2]n (1), where (3,4,5-MeO-ba)2bn = N,N′-bis(3,4-dimethoxybenzylidene)-butane-1,4-diamine, involving a new bidentate Schiff-base containing a flexible spacer (=N–C–C–C–C–N=) has been synthesized and characterized by elementa...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Khalaji, Aliakbar Dehno [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2010 |
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| Schlagwörter: |
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| Anmerkung: |
© Akadémiai Kiadó, Budapest, Hungary 2010 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of thermal analysis and calorimetry - Springer Netherlands, 1998, 103(2010), 3 vom: 26. Okt., Seite 779-783 |
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| Übergeordnetes Werk: |
volume:103 ; year:2010 ; number:3 ; day:26 ; month:10 ; pages:779-783 |
| Links: |
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| DOI / URN: |
10.1007/s10973-010-1102-4 |
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OLC2049804555 |
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| 520 | |a Abstract New 1D-chain copper(I) complex [$ Cu_{2} $(μ-(3,4,5-MeO-ba)2bn)(μ-I)2]n (1), where (3,4,5-MeO-ba)2bn = N,N′-bis(3,4-dimethoxybenzylidene)-butane-1,4-diamine, involving a new bidentate Schiff-base containing a flexible spacer (=N–C–C–C–C–N=) has been synthesized and characterized by elemental analyses (CHN) and FT-IR spectroscopy. The crystal structure of 1 was determined from single-crystal X-ray diffraction analyses and shows the (3,4,5-MeO-ba)2en acts as a bridging ligand with the nitrogen atoms of the two imine functions and leading to the dinuclear [$ Cu_{2} $((μ-(3,4,5-MeO-ba)2en)] groups. Such dinuclear [$ Cu_{2} $((μ-(3,4,5-MeO-ba)2en)] groups are bridged by two iodine anions [(μ-I)2] to form a neutral 1D-chain copper(I) iodide coordination polymer. The coordination polyhedron about the copper(I) center in 1 is best described as a distorted trigonal planar. Thermogravimetric analyses reveal the thermal stability and decomposition pattern of 1. | ||
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10.1007/s10973-010-1102-4 doi (DE-627)OLC2049804555 (DE-He213)s10973-010-1102-4-p DE-627 ger DE-627 rakwb eng 660 VZ Khalaji, Aliakbar Dehno verfasserin aut [$ Cu_{2} $(μ-(3,4,5-meo-ba)2bn)(μ-I)2]n, a new 1D polymeric copper(I) chain 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2010 Abstract New 1D-chain copper(I) complex [$ Cu_{2} $(μ-(3,4,5-MeO-ba)2bn)(μ-I)2]n (1), where (3,4,5-MeO-ba)2bn = N,N′-bis(3,4-dimethoxybenzylidene)-butane-1,4-diamine, involving a new bidentate Schiff-base containing a flexible spacer (=N–C–C–C–C–N=) has been synthesized and characterized by elemental analyses (CHN) and FT-IR spectroscopy. The crystal structure of 1 was determined from single-crystal X-ray diffraction analyses and shows the (3,4,5-MeO-ba)2en acts as a bridging ligand with the nitrogen atoms of the two imine functions and leading to the dinuclear [$ Cu_{2} $((μ-(3,4,5-MeO-ba)2en)] groups. Such dinuclear [$ Cu_{2} $((μ-(3,4,5-MeO-ba)2en)] groups are bridged by two iodine anions [(μ-I)2] to form a neutral 1D-chain copper(I) iodide coordination polymer. The coordination polyhedron about the copper(I) center in 1 is best described as a distorted trigonal planar. Thermogravimetric analyses reveal the thermal stability and decomposition pattern of 1. Schiff-base 1D-chain Flexible spacer Copper(I) iodide coordination polymer Triki, Smail aut Das, Debasis aut Enthalten in Journal of thermal analysis and calorimetry Springer Netherlands, 1998 103(2010), 3 vom: 26. Okt., Seite 779-783 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:103 year:2010 number:3 day:26 month:10 pages:779-783 https://doi.org/10.1007/s10973-010-1102-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 103 2010 3 26 10 779-783 |
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10.1007/s10973-010-1102-4 doi (DE-627)OLC2049804555 (DE-He213)s10973-010-1102-4-p DE-627 ger DE-627 rakwb eng 660 VZ Khalaji, Aliakbar Dehno verfasserin aut [$ Cu_{2} $(μ-(3,4,5-meo-ba)2bn)(μ-I)2]n, a new 1D polymeric copper(I) chain 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2010 Abstract New 1D-chain copper(I) complex [$ Cu_{2} $(μ-(3,4,5-MeO-ba)2bn)(μ-I)2]n (1), where (3,4,5-MeO-ba)2bn = N,N′-bis(3,4-dimethoxybenzylidene)-butane-1,4-diamine, involving a new bidentate Schiff-base containing a flexible spacer (=N–C–C–C–C–N=) has been synthesized and characterized by elemental analyses (CHN) and FT-IR spectroscopy. The crystal structure of 1 was determined from single-crystal X-ray diffraction analyses and shows the (3,4,5-MeO-ba)2en acts as a bridging ligand with the nitrogen atoms of the two imine functions and leading to the dinuclear [$ Cu_{2} $((μ-(3,4,5-MeO-ba)2en)] groups. Such dinuclear [$ Cu_{2} $((μ-(3,4,5-MeO-ba)2en)] groups are bridged by two iodine anions [(μ-I)2] to form a neutral 1D-chain copper(I) iodide coordination polymer. The coordination polyhedron about the copper(I) center in 1 is best described as a distorted trigonal planar. Thermogravimetric analyses reveal the thermal stability and decomposition pattern of 1. Schiff-base 1D-chain Flexible spacer Copper(I) iodide coordination polymer Triki, Smail aut Das, Debasis aut Enthalten in Journal of thermal analysis and calorimetry Springer Netherlands, 1998 103(2010), 3 vom: 26. Okt., Seite 779-783 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:103 year:2010 number:3 day:26 month:10 pages:779-783 https://doi.org/10.1007/s10973-010-1102-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 103 2010 3 26 10 779-783 |
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10.1007/s10973-010-1102-4 doi (DE-627)OLC2049804555 (DE-He213)s10973-010-1102-4-p DE-627 ger DE-627 rakwb eng 660 VZ Khalaji, Aliakbar Dehno verfasserin aut [$ Cu_{2} $(μ-(3,4,5-meo-ba)2bn)(μ-I)2]n, a new 1D polymeric copper(I) chain 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2010 Abstract New 1D-chain copper(I) complex [$ Cu_{2} $(μ-(3,4,5-MeO-ba)2bn)(μ-I)2]n (1), where (3,4,5-MeO-ba)2bn = N,N′-bis(3,4-dimethoxybenzylidene)-butane-1,4-diamine, involving a new bidentate Schiff-base containing a flexible spacer (=N–C–C–C–C–N=) has been synthesized and characterized by elemental analyses (CHN) and FT-IR spectroscopy. The crystal structure of 1 was determined from single-crystal X-ray diffraction analyses and shows the (3,4,5-MeO-ba)2en acts as a bridging ligand with the nitrogen atoms of the two imine functions and leading to the dinuclear [$ Cu_{2} $((μ-(3,4,5-MeO-ba)2en)] groups. Such dinuclear [$ Cu_{2} $((μ-(3,4,5-MeO-ba)2en)] groups are bridged by two iodine anions [(μ-I)2] to form a neutral 1D-chain copper(I) iodide coordination polymer. The coordination polyhedron about the copper(I) center in 1 is best described as a distorted trigonal planar. Thermogravimetric analyses reveal the thermal stability and decomposition pattern of 1. Schiff-base 1D-chain Flexible spacer Copper(I) iodide coordination polymer Triki, Smail aut Das, Debasis aut Enthalten in Journal of thermal analysis and calorimetry Springer Netherlands, 1998 103(2010), 3 vom: 26. Okt., Seite 779-783 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:103 year:2010 number:3 day:26 month:10 pages:779-783 https://doi.org/10.1007/s10973-010-1102-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 103 2010 3 26 10 779-783 |
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10.1007/s10973-010-1102-4 doi (DE-627)OLC2049804555 (DE-He213)s10973-010-1102-4-p DE-627 ger DE-627 rakwb eng 660 VZ Khalaji, Aliakbar Dehno verfasserin aut [$ Cu_{2} $(μ-(3,4,5-meo-ba)2bn)(μ-I)2]n, a new 1D polymeric copper(I) chain 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2010 Abstract New 1D-chain copper(I) complex [$ Cu_{2} $(μ-(3,4,5-MeO-ba)2bn)(μ-I)2]n (1), where (3,4,5-MeO-ba)2bn = N,N′-bis(3,4-dimethoxybenzylidene)-butane-1,4-diamine, involving a new bidentate Schiff-base containing a flexible spacer (=N–C–C–C–C–N=) has been synthesized and characterized by elemental analyses (CHN) and FT-IR spectroscopy. The crystal structure of 1 was determined from single-crystal X-ray diffraction analyses and shows the (3,4,5-MeO-ba)2en acts as a bridging ligand with the nitrogen atoms of the two imine functions and leading to the dinuclear [$ Cu_{2} $((μ-(3,4,5-MeO-ba)2en)] groups. Such dinuclear [$ Cu_{2} $((μ-(3,4,5-MeO-ba)2en)] groups are bridged by two iodine anions [(μ-I)2] to form a neutral 1D-chain copper(I) iodide coordination polymer. The coordination polyhedron about the copper(I) center in 1 is best described as a distorted trigonal planar. Thermogravimetric analyses reveal the thermal stability and decomposition pattern of 1. Schiff-base 1D-chain Flexible spacer Copper(I) iodide coordination polymer Triki, Smail aut Das, Debasis aut Enthalten in Journal of thermal analysis and calorimetry Springer Netherlands, 1998 103(2010), 3 vom: 26. Okt., Seite 779-783 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:103 year:2010 number:3 day:26 month:10 pages:779-783 https://doi.org/10.1007/s10973-010-1102-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 103 2010 3 26 10 779-783 |
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10.1007/s10973-010-1102-4 doi (DE-627)OLC2049804555 (DE-He213)s10973-010-1102-4-p DE-627 ger DE-627 rakwb eng 660 VZ Khalaji, Aliakbar Dehno verfasserin aut [$ Cu_{2} $(μ-(3,4,5-meo-ba)2bn)(μ-I)2]n, a new 1D polymeric copper(I) chain 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2010 Abstract New 1D-chain copper(I) complex [$ Cu_{2} $(μ-(3,4,5-MeO-ba)2bn)(μ-I)2]n (1), where (3,4,5-MeO-ba)2bn = N,N′-bis(3,4-dimethoxybenzylidene)-butane-1,4-diamine, involving a new bidentate Schiff-base containing a flexible spacer (=N–C–C–C–C–N=) has been synthesized and characterized by elemental analyses (CHN) and FT-IR spectroscopy. The crystal structure of 1 was determined from single-crystal X-ray diffraction analyses and shows the (3,4,5-MeO-ba)2en acts as a bridging ligand with the nitrogen atoms of the two imine functions and leading to the dinuclear [$ Cu_{2} $((μ-(3,4,5-MeO-ba)2en)] groups. Such dinuclear [$ Cu_{2} $((μ-(3,4,5-MeO-ba)2en)] groups are bridged by two iodine anions [(μ-I)2] to form a neutral 1D-chain copper(I) iodide coordination polymer. The coordination polyhedron about the copper(I) center in 1 is best described as a distorted trigonal planar. Thermogravimetric analyses reveal the thermal stability and decomposition pattern of 1. Schiff-base 1D-chain Flexible spacer Copper(I) iodide coordination polymer Triki, Smail aut Das, Debasis aut Enthalten in Journal of thermal analysis and calorimetry Springer Netherlands, 1998 103(2010), 3 vom: 26. Okt., Seite 779-783 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:103 year:2010 number:3 day:26 month:10 pages:779-783 https://doi.org/10.1007/s10973-010-1102-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 103 2010 3 26 10 779-783 |
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[$ Cu_{2} $(μ-(3,4,5-meo-ba)2bn)(μ-I)2]n, a new 1D polymeric copper(I) chain |
| author_sort |
Khalaji, Aliakbar Dehno |
| journal |
Journal of thermal analysis and calorimetry |
| journalStr |
Journal of thermal analysis and calorimetry |
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eng |
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| dewey-hundreds |
600 - Technology |
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marc |
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2010 |
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txt |
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779 |
| author_browse |
Khalaji, Aliakbar Dehno Triki, Smail Das, Debasis |
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103 |
| class |
660 VZ |
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Aufsätze |
| author-letter |
Khalaji, Aliakbar Dehno |
| doi_str_mv |
10.1007/s10973-010-1102-4 |
| dewey-full |
660 |
| title_sort |
[$ cu_{2} $(μ-(3,4,5-meo-ba)2bn)(μ-i)2]n, a new 1d polymeric copper(i) chain |
| title_auth |
[$ Cu_{2} $(μ-(3,4,5-meo-ba)2bn)(μ-I)2]n, a new 1D polymeric copper(I) chain |
| abstract |
Abstract New 1D-chain copper(I) complex [$ Cu_{2} $(μ-(3,4,5-MeO-ba)2bn)(μ-I)2]n (1), where (3,4,5-MeO-ba)2bn = N,N′-bis(3,4-dimethoxybenzylidene)-butane-1,4-diamine, involving a new bidentate Schiff-base containing a flexible spacer (=N–C–C–C–C–N=) has been synthesized and characterized by elemental analyses (CHN) and FT-IR spectroscopy. The crystal structure of 1 was determined from single-crystal X-ray diffraction analyses and shows the (3,4,5-MeO-ba)2en acts as a bridging ligand with the nitrogen atoms of the two imine functions and leading to the dinuclear [$ Cu_{2} $((μ-(3,4,5-MeO-ba)2en)] groups. Such dinuclear [$ Cu_{2} $((μ-(3,4,5-MeO-ba)2en)] groups are bridged by two iodine anions [(μ-I)2] to form a neutral 1D-chain copper(I) iodide coordination polymer. The coordination polyhedron about the copper(I) center in 1 is best described as a distorted trigonal planar. Thermogravimetric analyses reveal the thermal stability and decomposition pattern of 1. © Akadémiai Kiadó, Budapest, Hungary 2010 |
| abstractGer |
Abstract New 1D-chain copper(I) complex [$ Cu_{2} $(μ-(3,4,5-MeO-ba)2bn)(μ-I)2]n (1), where (3,4,5-MeO-ba)2bn = N,N′-bis(3,4-dimethoxybenzylidene)-butane-1,4-diamine, involving a new bidentate Schiff-base containing a flexible spacer (=N–C–C–C–C–N=) has been synthesized and characterized by elemental analyses (CHN) and FT-IR spectroscopy. The crystal structure of 1 was determined from single-crystal X-ray diffraction analyses and shows the (3,4,5-MeO-ba)2en acts as a bridging ligand with the nitrogen atoms of the two imine functions and leading to the dinuclear [$ Cu_{2} $((μ-(3,4,5-MeO-ba)2en)] groups. Such dinuclear [$ Cu_{2} $((μ-(3,4,5-MeO-ba)2en)] groups are bridged by two iodine anions [(μ-I)2] to form a neutral 1D-chain copper(I) iodide coordination polymer. The coordination polyhedron about the copper(I) center in 1 is best described as a distorted trigonal planar. Thermogravimetric analyses reveal the thermal stability and decomposition pattern of 1. © Akadémiai Kiadó, Budapest, Hungary 2010 |
| abstract_unstemmed |
Abstract New 1D-chain copper(I) complex [$ Cu_{2} $(μ-(3,4,5-MeO-ba)2bn)(μ-I)2]n (1), where (3,4,5-MeO-ba)2bn = N,N′-bis(3,4-dimethoxybenzylidene)-butane-1,4-diamine, involving a new bidentate Schiff-base containing a flexible spacer (=N–C–C–C–C–N=) has been synthesized and characterized by elemental analyses (CHN) and FT-IR spectroscopy. The crystal structure of 1 was determined from single-crystal X-ray diffraction analyses and shows the (3,4,5-MeO-ba)2en acts as a bridging ligand with the nitrogen atoms of the two imine functions and leading to the dinuclear [$ Cu_{2} $((μ-(3,4,5-MeO-ba)2en)] groups. Such dinuclear [$ Cu_{2} $((μ-(3,4,5-MeO-ba)2en)] groups are bridged by two iodine anions [(μ-I)2] to form a neutral 1D-chain copper(I) iodide coordination polymer. The coordination polyhedron about the copper(I) center in 1 is best described as a distorted trigonal planar. Thermogravimetric analyses reveal the thermal stability and decomposition pattern of 1. © Akadémiai Kiadó, Budapest, Hungary 2010 |
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GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 |
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3 |
| title_short |
[$ Cu_{2} $(μ-(3,4,5-meo-ba)2bn)(μ-I)2]n, a new 1D polymeric copper(I) chain |
| url |
https://doi.org/10.1007/s10973-010-1102-4 |
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Triki, Smail Das, Debasis |
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Triki, Smail Das, Debasis |
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| doi_str |
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| up_date |
2024-07-04T00:05:01.235Z |
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