The desorption of moisture from wool
Abstract We have carried out a DSC investigation under nitrogen flow of moisture desorption from wool equilibrated with various amounts of water. The recorded data have been used to calculate the kinetic parameters of the desorption process assuming a single process and within the framework of the r...
Ausführliche Beschreibung
Autor*in: |
Popescu, C. [verfasserIn] |
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Format: |
Artikel |
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Sprache: |
Englisch |
Erschienen: |
2014 |
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Schlagwörter: |
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Anmerkung: |
© Akadémiai Kiadó, Budapest, Hungary 2014 |
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Übergeordnetes Werk: |
Enthalten in: Journal of thermal analysis and calorimetry - Springer Netherlands, 1998, 120(2014), 1 vom: 04. Dez., Seite 113-117 |
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Übergeordnetes Werk: |
volume:120 ; year:2014 ; number:1 ; day:04 ; month:12 ; pages:113-117 |
Links: |
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DOI / URN: |
10.1007/s10973-014-4317-y |
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Katalog-ID: |
OLC2049837186 |
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520 | |a Abstract We have carried out a DSC investigation under nitrogen flow of moisture desorption from wool equilibrated with various amounts of water. The recorded data have been used to calculate the kinetic parameters of the desorption process assuming a single process and within the framework of the reaction order. We found that while the reaction order and the peak temperature change with the equilibrium water content (e.w.c.) which wool fibre had at the beginning of the desorption experiment, the activation energy and the pre-exponential factor remain fairly constant. The overall reaction rate shows that, due to the change of the kinetics of wool-water system with the change of the initial moisture content, higher the initial water content of the fibre is, faster the desorption occurs. The results point out clearly that any study of moisture desorption from keratins should specify the initial value of the equilibrium water content. | ||
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10.1007/s10973-014-4317-y doi (DE-627)OLC2049837186 (DE-He213)s10973-014-4317-y-p DE-627 ger DE-627 rakwb eng 660 VZ Popescu, C. verfasserin aut The desorption of moisture from wool 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2014 Abstract We have carried out a DSC investigation under nitrogen flow of moisture desorption from wool equilibrated with various amounts of water. The recorded data have been used to calculate the kinetic parameters of the desorption process assuming a single process and within the framework of the reaction order. We found that while the reaction order and the peak temperature change with the equilibrium water content (e.w.c.) which wool fibre had at the beginning of the desorption experiment, the activation energy and the pre-exponential factor remain fairly constant. The overall reaction rate shows that, due to the change of the kinetics of wool-water system with the change of the initial moisture content, higher the initial water content of the fibre is, faster the desorption occurs. The results point out clearly that any study of moisture desorption from keratins should specify the initial value of the equilibrium water content. Keratin fibres DSC Desorption kinetics Kinetic parameters Augustin, P. aut Wortmann, F. J. aut Enthalten in Journal of thermal analysis and calorimetry Springer Netherlands, 1998 120(2014), 1 vom: 04. Dez., Seite 113-117 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:120 year:2014 number:1 day:04 month:12 pages:113-117 https://doi.org/10.1007/s10973-014-4317-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 120 2014 1 04 12 113-117 |
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10.1007/s10973-014-4317-y doi (DE-627)OLC2049837186 (DE-He213)s10973-014-4317-y-p DE-627 ger DE-627 rakwb eng 660 VZ Popescu, C. verfasserin aut The desorption of moisture from wool 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2014 Abstract We have carried out a DSC investigation under nitrogen flow of moisture desorption from wool equilibrated with various amounts of water. The recorded data have been used to calculate the kinetic parameters of the desorption process assuming a single process and within the framework of the reaction order. We found that while the reaction order and the peak temperature change with the equilibrium water content (e.w.c.) which wool fibre had at the beginning of the desorption experiment, the activation energy and the pre-exponential factor remain fairly constant. The overall reaction rate shows that, due to the change of the kinetics of wool-water system with the change of the initial moisture content, higher the initial water content of the fibre is, faster the desorption occurs. The results point out clearly that any study of moisture desorption from keratins should specify the initial value of the equilibrium water content. Keratin fibres DSC Desorption kinetics Kinetic parameters Augustin, P. aut Wortmann, F. J. aut Enthalten in Journal of thermal analysis and calorimetry Springer Netherlands, 1998 120(2014), 1 vom: 04. Dez., Seite 113-117 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:120 year:2014 number:1 day:04 month:12 pages:113-117 https://doi.org/10.1007/s10973-014-4317-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 120 2014 1 04 12 113-117 |
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10.1007/s10973-014-4317-y doi (DE-627)OLC2049837186 (DE-He213)s10973-014-4317-y-p DE-627 ger DE-627 rakwb eng 660 VZ Popescu, C. verfasserin aut The desorption of moisture from wool 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2014 Abstract We have carried out a DSC investigation under nitrogen flow of moisture desorption from wool equilibrated with various amounts of water. The recorded data have been used to calculate the kinetic parameters of the desorption process assuming a single process and within the framework of the reaction order. We found that while the reaction order and the peak temperature change with the equilibrium water content (e.w.c.) which wool fibre had at the beginning of the desorption experiment, the activation energy and the pre-exponential factor remain fairly constant. The overall reaction rate shows that, due to the change of the kinetics of wool-water system with the change of the initial moisture content, higher the initial water content of the fibre is, faster the desorption occurs. The results point out clearly that any study of moisture desorption from keratins should specify the initial value of the equilibrium water content. Keratin fibres DSC Desorption kinetics Kinetic parameters Augustin, P. aut Wortmann, F. J. aut Enthalten in Journal of thermal analysis and calorimetry Springer Netherlands, 1998 120(2014), 1 vom: 04. Dez., Seite 113-117 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:120 year:2014 number:1 day:04 month:12 pages:113-117 https://doi.org/10.1007/s10973-014-4317-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 120 2014 1 04 12 113-117 |
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10.1007/s10973-014-4317-y doi (DE-627)OLC2049837186 (DE-He213)s10973-014-4317-y-p DE-627 ger DE-627 rakwb eng 660 VZ Popescu, C. verfasserin aut The desorption of moisture from wool 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2014 Abstract We have carried out a DSC investigation under nitrogen flow of moisture desorption from wool equilibrated with various amounts of water. The recorded data have been used to calculate the kinetic parameters of the desorption process assuming a single process and within the framework of the reaction order. We found that while the reaction order and the peak temperature change with the equilibrium water content (e.w.c.) which wool fibre had at the beginning of the desorption experiment, the activation energy and the pre-exponential factor remain fairly constant. The overall reaction rate shows that, due to the change of the kinetics of wool-water system with the change of the initial moisture content, higher the initial water content of the fibre is, faster the desorption occurs. The results point out clearly that any study of moisture desorption from keratins should specify the initial value of the equilibrium water content. Keratin fibres DSC Desorption kinetics Kinetic parameters Augustin, P. aut Wortmann, F. J. aut Enthalten in Journal of thermal analysis and calorimetry Springer Netherlands, 1998 120(2014), 1 vom: 04. Dez., Seite 113-117 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:120 year:2014 number:1 day:04 month:12 pages:113-117 https://doi.org/10.1007/s10973-014-4317-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 120 2014 1 04 12 113-117 |
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10.1007/s10973-014-4317-y doi (DE-627)OLC2049837186 (DE-He213)s10973-014-4317-y-p DE-627 ger DE-627 rakwb eng 660 VZ Popescu, C. verfasserin aut The desorption of moisture from wool 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2014 Abstract We have carried out a DSC investigation under nitrogen flow of moisture desorption from wool equilibrated with various amounts of water. The recorded data have been used to calculate the kinetic parameters of the desorption process assuming a single process and within the framework of the reaction order. We found that while the reaction order and the peak temperature change with the equilibrium water content (e.w.c.) which wool fibre had at the beginning of the desorption experiment, the activation energy and the pre-exponential factor remain fairly constant. The overall reaction rate shows that, due to the change of the kinetics of wool-water system with the change of the initial moisture content, higher the initial water content of the fibre is, faster the desorption occurs. The results point out clearly that any study of moisture desorption from keratins should specify the initial value of the equilibrium water content. Keratin fibres DSC Desorption kinetics Kinetic parameters Augustin, P. aut Wortmann, F. J. aut Enthalten in Journal of thermal analysis and calorimetry Springer Netherlands, 1998 120(2014), 1 vom: 04. Dez., Seite 113-117 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:120 year:2014 number:1 day:04 month:12 pages:113-117 https://doi.org/10.1007/s10973-014-4317-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 120 2014 1 04 12 113-117 |
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Abstract We have carried out a DSC investigation under nitrogen flow of moisture desorption from wool equilibrated with various amounts of water. The recorded data have been used to calculate the kinetic parameters of the desorption process assuming a single process and within the framework of the reaction order. We found that while the reaction order and the peak temperature change with the equilibrium water content (e.w.c.) which wool fibre had at the beginning of the desorption experiment, the activation energy and the pre-exponential factor remain fairly constant. The overall reaction rate shows that, due to the change of the kinetics of wool-water system with the change of the initial moisture content, higher the initial water content of the fibre is, faster the desorption occurs. The results point out clearly that any study of moisture desorption from keratins should specify the initial value of the equilibrium water content. © Akadémiai Kiadó, Budapest, Hungary 2014 |
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Abstract We have carried out a DSC investigation under nitrogen flow of moisture desorption from wool equilibrated with various amounts of water. The recorded data have been used to calculate the kinetic parameters of the desorption process assuming a single process and within the framework of the reaction order. We found that while the reaction order and the peak temperature change with the equilibrium water content (e.w.c.) which wool fibre had at the beginning of the desorption experiment, the activation energy and the pre-exponential factor remain fairly constant. The overall reaction rate shows that, due to the change of the kinetics of wool-water system with the change of the initial moisture content, higher the initial water content of the fibre is, faster the desorption occurs. The results point out clearly that any study of moisture desorption from keratins should specify the initial value of the equilibrium water content. © Akadémiai Kiadó, Budapest, Hungary 2014 |
abstract_unstemmed |
Abstract We have carried out a DSC investigation under nitrogen flow of moisture desorption from wool equilibrated with various amounts of water. The recorded data have been used to calculate the kinetic parameters of the desorption process assuming a single process and within the framework of the reaction order. We found that while the reaction order and the peak temperature change with the equilibrium water content (e.w.c.) which wool fibre had at the beginning of the desorption experiment, the activation energy and the pre-exponential factor remain fairly constant. The overall reaction rate shows that, due to the change of the kinetics of wool-water system with the change of the initial moisture content, higher the initial water content of the fibre is, faster the desorption occurs. The results point out clearly that any study of moisture desorption from keratins should specify the initial value of the equilibrium water content. © Akadémiai Kiadó, Budapest, Hungary 2014 |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">OLC2049837186</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230503170039.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">200820s2014 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10973-014-4317-y</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC2049837186</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-He213)s10973-014-4317-y-p</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">660</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Popescu, C.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">The desorption of moisture from wool</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2014</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Akadémiai Kiadó, Budapest, Hungary 2014</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract We have carried out a DSC investigation under nitrogen flow of moisture desorption from wool equilibrated with various amounts of water. The recorded data have been used to calculate the kinetic parameters of the desorption process assuming a single process and within the framework of the reaction order. We found that while the reaction order and the peak temperature change with the equilibrium water content (e.w.c.) which wool fibre had at the beginning of the desorption experiment, the activation energy and the pre-exponential factor remain fairly constant. The overall reaction rate shows that, due to the change of the kinetics of wool-water system with the change of the initial moisture content, higher the initial water content of the fibre is, faster the desorption occurs. The results point out clearly that any study of moisture desorption from keratins should specify the initial value of the equilibrium water content.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Keratin fibres</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">DSC</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Desorption kinetics</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Kinetic parameters</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Augustin, P.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wortmann, F. J.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of thermal analysis and calorimetry</subfield><subfield code="d">Springer Netherlands, 1998</subfield><subfield code="g">120(2014), 1 vom: 04. Dez., Seite 113-117</subfield><subfield code="w">(DE-627)244148767</subfield><subfield code="w">(DE-600)1429493-X</subfield><subfield code="w">(DE-576)066397693</subfield><subfield code="x">1388-6150</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:120</subfield><subfield code="g">year:2014</subfield><subfield code="g">number:1</subfield><subfield code="g">day:04</subfield><subfield code="g">month:12</subfield><subfield code="g">pages:113-117</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1007/s10973-014-4317-y</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-CHE</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">120</subfield><subfield code="j">2014</subfield><subfield code="e">1</subfield><subfield code="b">04</subfield><subfield code="c">12</subfield><subfield code="h">113-117</subfield></datafield></record></collection>
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