Using TG-FTIR and XPS to understand thermal degradation and flame-retardant mechanism of flexible poly(vinyl chloride) filled with metallic ferrites
Abstract The effect of three metallic ferrites, $ LaFeO_{3} $, $ ZnFe_{2} $$ O_{4} $, and $ BiFeO_{3} $, on the thermal degradation and flame retardancy of flexible poly(vinyl chloride) (PVC) was investigated using thermogravimetric analysis (TG), differential thermal analysis, and TG coupled with F...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Qi, Yanxia [verfasserIn] |
|---|
| Format: |
Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
2015 |
|---|
| Schlagwörter: |
|---|
| Anmerkung: |
© Akadémiai Kiadó, Budapest, Hungary 2015 |
|---|
| Übergeordnetes Werk: |
Enthalten in: Journal of thermal analysis and calorimetry - Springer Netherlands, 1998, 123(2015), 2 vom: 13. Okt., Seite 1263-1271 |
|---|---|
| Übergeordnetes Werk: |
volume:123 ; year:2015 ; number:2 ; day:13 ; month:10 ; pages:1263-1271 |
| Links: |
|---|
| DOI / URN: |
10.1007/s10973-015-5084-0 |
|---|
| Katalog-ID: |
OLC2049843011 |
|---|
| LEADER | 01000caa a22002652 4500 | ||
|---|---|---|---|
| 001 | OLC2049843011 | ||
| 003 | DE-627 | ||
| 005 | 20230503170118.0 | ||
| 007 | tu | ||
| 008 | 200820s2015 xx ||||| 00| ||eng c | ||
| 024 | 7 | |a 10.1007/s10973-015-5084-0 |2 doi | |
| 035 | |a (DE-627)OLC2049843011 | ||
| 035 | |a (DE-He213)s10973-015-5084-0-p | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
| 041 | |a eng | ||
| 082 | 0 | 4 | |a 660 |q VZ |
| 100 | 1 | |a Qi, Yanxia |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Using TG-FTIR and XPS to understand thermal degradation and flame-retardant mechanism of flexible poly(vinyl chloride) filled with metallic ferrites |
| 264 | 1 | |c 2015 | |
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a ohne Hilfsmittel zu benutzen |b n |2 rdamedia | ||
| 338 | |a Band |b nc |2 rdacarrier | ||
| 500 | |a © Akadémiai Kiadó, Budapest, Hungary 2015 | ||
| 520 | |a Abstract The effect of three metallic ferrites, $ LaFeO_{3} $, $ ZnFe_{2} $$ O_{4} $, and $ BiFeO_{3} $, on the thermal degradation and flame retardancy of flexible poly(vinyl chloride) (PVC) was investigated using thermogravimetric analysis (TG), differential thermal analysis, and TG coupled with Fourier transform infrared spectrometry. In combination with X-ray photoelectron spectroscopy techniques, the charring and flame-retardant mechanism has been obtained. The results show that compared with $ LaFeO_{3} $ and $ ZnFe_{2} $$ O_{4} $, $ BiFeO_{3} $ promoted the dehydrochlorination reaction of PVC more effectively and generated a large amount of stable char residue in a condensed phase. In the char residue of PVC/$ BiFeO_{3} $, the Fe2p spectra are assigned to $ FeCl_{2} $ and FeOCl, which acts as effective catalysts for the ionic dehydrochlorination of PVC owing to their strong Lewis acidity. Bi exists as BiOCl, which has a lower melting point and boiling point and can more easily decompose to form $ BiCl_{3} $ gas at the flame temperature. The results demonstrated that $ BiFeO_{3} $ can not only effectively inhibit the production of smoke from PVC during combustion, but it also has an effect similar to that of $ Sb_{2} $$ O_{3} $ in flame-retardant PVC. | ||
| 650 | 4 | |a Ferrites | |
| 650 | 4 | |a PVC | |
| 650 | 4 | |a Flame retardancy | |
| 650 | 4 | |a TG-FTIR | |
| 650 | 4 | |a XPS | |
| 700 | 1 | |a Wu, Weihong |4 aut | |
| 700 | 1 | |a Han, Lijing |4 aut | |
| 700 | 1 | |a Qu, Hongqiang |4 aut | |
| 700 | 1 | |a Han, Xing |4 aut | |
| 700 | 1 | |a Wang, Aiqing |4 aut | |
| 700 | 1 | |a Xu, Jianzhong |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Journal of thermal analysis and calorimetry |d Springer Netherlands, 1998 |g 123(2015), 2 vom: 13. Okt., Seite 1263-1271 |w (DE-627)244148767 |w (DE-600)1429493-X |w (DE-576)066397693 |x 1388-6150 |7 nnns |
| 773 | 1 | 8 | |g volume:123 |g year:2015 |g number:2 |g day:13 |g month:10 |g pages:1263-1271 |
| 856 | 4 | 1 | |u https://doi.org/10.1007/s10973-015-5084-0 |z lizenzpflichtig |3 Volltext |
| 912 | |a GBV_USEFLAG_A | ||
| 912 | |a SYSFLAG_A | ||
| 912 | |a GBV_OLC | ||
| 912 | |a SSG-OLC-TEC | ||
| 912 | |a SSG-OLC-CHE | ||
| 912 | |a GBV_ILN_70 | ||
| 951 | |a AR | ||
| 952 | |d 123 |j 2015 |e 2 |b 13 |c 10 |h 1263-1271 | ||
| author_variant |
y q yq w w ww l h lh h q hq x h xh a w aw j x jx |
|---|---|
| matchkey_str |
article:13886150:2015----::sntfiadptudrtntemlerdtoadlmrtratehnsofeilplvnl |
| hierarchy_sort_str |
2015 |
| publishDate |
2015 |
| allfields |
10.1007/s10973-015-5084-0 doi (DE-627)OLC2049843011 (DE-He213)s10973-015-5084-0-p DE-627 ger DE-627 rakwb eng 660 VZ Qi, Yanxia verfasserin aut Using TG-FTIR and XPS to understand thermal degradation and flame-retardant mechanism of flexible poly(vinyl chloride) filled with metallic ferrites 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2015 Abstract The effect of three metallic ferrites, $ LaFeO_{3} $, $ ZnFe_{2} $$ O_{4} $, and $ BiFeO_{3} $, on the thermal degradation and flame retardancy of flexible poly(vinyl chloride) (PVC) was investigated using thermogravimetric analysis (TG), differential thermal analysis, and TG coupled with Fourier transform infrared spectrometry. In combination with X-ray photoelectron spectroscopy techniques, the charring and flame-retardant mechanism has been obtained. The results show that compared with $ LaFeO_{3} $ and $ ZnFe_{2} $$ O_{4} $, $ BiFeO_{3} $ promoted the dehydrochlorination reaction of PVC more effectively and generated a large amount of stable char residue in a condensed phase. In the char residue of PVC/$ BiFeO_{3} $, the Fe2p spectra are assigned to $ FeCl_{2} $ and FeOCl, which acts as effective catalysts for the ionic dehydrochlorination of PVC owing to their strong Lewis acidity. Bi exists as BiOCl, which has a lower melting point and boiling point and can more easily decompose to form $ BiCl_{3} $ gas at the flame temperature. The results demonstrated that $ BiFeO_{3} $ can not only effectively inhibit the production of smoke from PVC during combustion, but it also has an effect similar to that of $ Sb_{2} $$ O_{3} $ in flame-retardant PVC. Ferrites PVC Flame retardancy TG-FTIR XPS Wu, Weihong aut Han, Lijing aut Qu, Hongqiang aut Han, Xing aut Wang, Aiqing aut Xu, Jianzhong aut Enthalten in Journal of thermal analysis and calorimetry Springer Netherlands, 1998 123(2015), 2 vom: 13. Okt., Seite 1263-1271 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:123 year:2015 number:2 day:13 month:10 pages:1263-1271 https://doi.org/10.1007/s10973-015-5084-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 123 2015 2 13 10 1263-1271 |
| spelling |
10.1007/s10973-015-5084-0 doi (DE-627)OLC2049843011 (DE-He213)s10973-015-5084-0-p DE-627 ger DE-627 rakwb eng 660 VZ Qi, Yanxia verfasserin aut Using TG-FTIR and XPS to understand thermal degradation and flame-retardant mechanism of flexible poly(vinyl chloride) filled with metallic ferrites 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2015 Abstract The effect of three metallic ferrites, $ LaFeO_{3} $, $ ZnFe_{2} $$ O_{4} $, and $ BiFeO_{3} $, on the thermal degradation and flame retardancy of flexible poly(vinyl chloride) (PVC) was investigated using thermogravimetric analysis (TG), differential thermal analysis, and TG coupled with Fourier transform infrared spectrometry. In combination with X-ray photoelectron spectroscopy techniques, the charring and flame-retardant mechanism has been obtained. The results show that compared with $ LaFeO_{3} $ and $ ZnFe_{2} $$ O_{4} $, $ BiFeO_{3} $ promoted the dehydrochlorination reaction of PVC more effectively and generated a large amount of stable char residue in a condensed phase. In the char residue of PVC/$ BiFeO_{3} $, the Fe2p spectra are assigned to $ FeCl_{2} $ and FeOCl, which acts as effective catalysts for the ionic dehydrochlorination of PVC owing to their strong Lewis acidity. Bi exists as BiOCl, which has a lower melting point and boiling point and can more easily decompose to form $ BiCl_{3} $ gas at the flame temperature. The results demonstrated that $ BiFeO_{3} $ can not only effectively inhibit the production of smoke from PVC during combustion, but it also has an effect similar to that of $ Sb_{2} $$ O_{3} $ in flame-retardant PVC. Ferrites PVC Flame retardancy TG-FTIR XPS Wu, Weihong aut Han, Lijing aut Qu, Hongqiang aut Han, Xing aut Wang, Aiqing aut Xu, Jianzhong aut Enthalten in Journal of thermal analysis and calorimetry Springer Netherlands, 1998 123(2015), 2 vom: 13. Okt., Seite 1263-1271 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:123 year:2015 number:2 day:13 month:10 pages:1263-1271 https://doi.org/10.1007/s10973-015-5084-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 123 2015 2 13 10 1263-1271 |
| allfields_unstemmed |
10.1007/s10973-015-5084-0 doi (DE-627)OLC2049843011 (DE-He213)s10973-015-5084-0-p DE-627 ger DE-627 rakwb eng 660 VZ Qi, Yanxia verfasserin aut Using TG-FTIR and XPS to understand thermal degradation and flame-retardant mechanism of flexible poly(vinyl chloride) filled with metallic ferrites 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2015 Abstract The effect of three metallic ferrites, $ LaFeO_{3} $, $ ZnFe_{2} $$ O_{4} $, and $ BiFeO_{3} $, on the thermal degradation and flame retardancy of flexible poly(vinyl chloride) (PVC) was investigated using thermogravimetric analysis (TG), differential thermal analysis, and TG coupled with Fourier transform infrared spectrometry. In combination with X-ray photoelectron spectroscopy techniques, the charring and flame-retardant mechanism has been obtained. The results show that compared with $ LaFeO_{3} $ and $ ZnFe_{2} $$ O_{4} $, $ BiFeO_{3} $ promoted the dehydrochlorination reaction of PVC more effectively and generated a large amount of stable char residue in a condensed phase. In the char residue of PVC/$ BiFeO_{3} $, the Fe2p spectra are assigned to $ FeCl_{2} $ and FeOCl, which acts as effective catalysts for the ionic dehydrochlorination of PVC owing to their strong Lewis acidity. Bi exists as BiOCl, which has a lower melting point and boiling point and can more easily decompose to form $ BiCl_{3} $ gas at the flame temperature. The results demonstrated that $ BiFeO_{3} $ can not only effectively inhibit the production of smoke from PVC during combustion, but it also has an effect similar to that of $ Sb_{2} $$ O_{3} $ in flame-retardant PVC. Ferrites PVC Flame retardancy TG-FTIR XPS Wu, Weihong aut Han, Lijing aut Qu, Hongqiang aut Han, Xing aut Wang, Aiqing aut Xu, Jianzhong aut Enthalten in Journal of thermal analysis and calorimetry Springer Netherlands, 1998 123(2015), 2 vom: 13. Okt., Seite 1263-1271 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:123 year:2015 number:2 day:13 month:10 pages:1263-1271 https://doi.org/10.1007/s10973-015-5084-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 123 2015 2 13 10 1263-1271 |
| allfieldsGer |
10.1007/s10973-015-5084-0 doi (DE-627)OLC2049843011 (DE-He213)s10973-015-5084-0-p DE-627 ger DE-627 rakwb eng 660 VZ Qi, Yanxia verfasserin aut Using TG-FTIR and XPS to understand thermal degradation and flame-retardant mechanism of flexible poly(vinyl chloride) filled with metallic ferrites 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2015 Abstract The effect of three metallic ferrites, $ LaFeO_{3} $, $ ZnFe_{2} $$ O_{4} $, and $ BiFeO_{3} $, on the thermal degradation and flame retardancy of flexible poly(vinyl chloride) (PVC) was investigated using thermogravimetric analysis (TG), differential thermal analysis, and TG coupled with Fourier transform infrared spectrometry. In combination with X-ray photoelectron spectroscopy techniques, the charring and flame-retardant mechanism has been obtained. The results show that compared with $ LaFeO_{3} $ and $ ZnFe_{2} $$ O_{4} $, $ BiFeO_{3} $ promoted the dehydrochlorination reaction of PVC more effectively and generated a large amount of stable char residue in a condensed phase. In the char residue of PVC/$ BiFeO_{3} $, the Fe2p spectra are assigned to $ FeCl_{2} $ and FeOCl, which acts as effective catalysts for the ionic dehydrochlorination of PVC owing to their strong Lewis acidity. Bi exists as BiOCl, which has a lower melting point and boiling point and can more easily decompose to form $ BiCl_{3} $ gas at the flame temperature. The results demonstrated that $ BiFeO_{3} $ can not only effectively inhibit the production of smoke from PVC during combustion, but it also has an effect similar to that of $ Sb_{2} $$ O_{3} $ in flame-retardant PVC. Ferrites PVC Flame retardancy TG-FTIR XPS Wu, Weihong aut Han, Lijing aut Qu, Hongqiang aut Han, Xing aut Wang, Aiqing aut Xu, Jianzhong aut Enthalten in Journal of thermal analysis and calorimetry Springer Netherlands, 1998 123(2015), 2 vom: 13. Okt., Seite 1263-1271 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:123 year:2015 number:2 day:13 month:10 pages:1263-1271 https://doi.org/10.1007/s10973-015-5084-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 123 2015 2 13 10 1263-1271 |
| allfieldsSound |
10.1007/s10973-015-5084-0 doi (DE-627)OLC2049843011 (DE-He213)s10973-015-5084-0-p DE-627 ger DE-627 rakwb eng 660 VZ Qi, Yanxia verfasserin aut Using TG-FTIR and XPS to understand thermal degradation and flame-retardant mechanism of flexible poly(vinyl chloride) filled with metallic ferrites 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2015 Abstract The effect of three metallic ferrites, $ LaFeO_{3} $, $ ZnFe_{2} $$ O_{4} $, and $ BiFeO_{3} $, on the thermal degradation and flame retardancy of flexible poly(vinyl chloride) (PVC) was investigated using thermogravimetric analysis (TG), differential thermal analysis, and TG coupled with Fourier transform infrared spectrometry. In combination with X-ray photoelectron spectroscopy techniques, the charring and flame-retardant mechanism has been obtained. The results show that compared with $ LaFeO_{3} $ and $ ZnFe_{2} $$ O_{4} $, $ BiFeO_{3} $ promoted the dehydrochlorination reaction of PVC more effectively and generated a large amount of stable char residue in a condensed phase. In the char residue of PVC/$ BiFeO_{3} $, the Fe2p spectra are assigned to $ FeCl_{2} $ and FeOCl, which acts as effective catalysts for the ionic dehydrochlorination of PVC owing to their strong Lewis acidity. Bi exists as BiOCl, which has a lower melting point and boiling point and can more easily decompose to form $ BiCl_{3} $ gas at the flame temperature. The results demonstrated that $ BiFeO_{3} $ can not only effectively inhibit the production of smoke from PVC during combustion, but it also has an effect similar to that of $ Sb_{2} $$ O_{3} $ in flame-retardant PVC. Ferrites PVC Flame retardancy TG-FTIR XPS Wu, Weihong aut Han, Lijing aut Qu, Hongqiang aut Han, Xing aut Wang, Aiqing aut Xu, Jianzhong aut Enthalten in Journal of thermal analysis and calorimetry Springer Netherlands, 1998 123(2015), 2 vom: 13. Okt., Seite 1263-1271 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:123 year:2015 number:2 day:13 month:10 pages:1263-1271 https://doi.org/10.1007/s10973-015-5084-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 123 2015 2 13 10 1263-1271 |
| language |
English |
| source |
Enthalten in Journal of thermal analysis and calorimetry 123(2015), 2 vom: 13. Okt., Seite 1263-1271 volume:123 year:2015 number:2 day:13 month:10 pages:1263-1271 |
| sourceStr |
Enthalten in Journal of thermal analysis and calorimetry 123(2015), 2 vom: 13. Okt., Seite 1263-1271 volume:123 year:2015 number:2 day:13 month:10 pages:1263-1271 |
| format_phy_str_mv |
Article |
| institution |
findex.gbv.de |
| topic_facet |
Ferrites PVC Flame retardancy TG-FTIR XPS |
| dewey-raw |
660 |
| isfreeaccess_bool |
false |
| container_title |
Journal of thermal analysis and calorimetry |
| authorswithroles_txt_mv |
Qi, Yanxia @@aut@@ Wu, Weihong @@aut@@ Han, Lijing @@aut@@ Qu, Hongqiang @@aut@@ Han, Xing @@aut@@ Wang, Aiqing @@aut@@ Xu, Jianzhong @@aut@@ |
| publishDateDaySort_date |
2015-10-13T00:00:00Z |
| hierarchy_top_id |
244148767 |
| dewey-sort |
3660 |
| id |
OLC2049843011 |
| language_de |
englisch |
| fullrecord |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">OLC2049843011</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230503170118.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">200820s2015 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10973-015-5084-0</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC2049843011</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-He213)s10973-015-5084-0-p</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">660</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Qi, Yanxia</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Using TG-FTIR and XPS to understand thermal degradation and flame-retardant mechanism of flexible poly(vinyl chloride) filled with metallic ferrites</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2015</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Akadémiai Kiadó, Budapest, Hungary 2015</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract The effect of three metallic ferrites, $ LaFeO_{3} $, $ ZnFe_{2} $$ O_{4} $, and $ BiFeO_{3} $, on the thermal degradation and flame retardancy of flexible poly(vinyl chloride) (PVC) was investigated using thermogravimetric analysis (TG), differential thermal analysis, and TG coupled with Fourier transform infrared spectrometry. In combination with X-ray photoelectron spectroscopy techniques, the charring and flame-retardant mechanism has been obtained. The results show that compared with $ LaFeO_{3} $ and $ ZnFe_{2} $$ O_{4} $, $ BiFeO_{3} $ promoted the dehydrochlorination reaction of PVC more effectively and generated a large amount of stable char residue in a condensed phase. In the char residue of PVC/$ BiFeO_{3} $, the Fe2p spectra are assigned to $ FeCl_{2} $ and FeOCl, which acts as effective catalysts for the ionic dehydrochlorination of PVC owing to their strong Lewis acidity. Bi exists as BiOCl, which has a lower melting point and boiling point and can more easily decompose to form $ BiCl_{3} $ gas at the flame temperature. The results demonstrated that $ BiFeO_{3} $ can not only effectively inhibit the production of smoke from PVC during combustion, but it also has an effect similar to that of $ Sb_{2} $$ O_{3} $ in flame-retardant PVC.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Ferrites</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">PVC</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Flame retardancy</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">TG-FTIR</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">XPS</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wu, Weihong</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Han, Lijing</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Qu, Hongqiang</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Han, Xing</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wang, Aiqing</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Xu, Jianzhong</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of thermal analysis and calorimetry</subfield><subfield code="d">Springer Netherlands, 1998</subfield><subfield code="g">123(2015), 2 vom: 13. Okt., Seite 1263-1271</subfield><subfield code="w">(DE-627)244148767</subfield><subfield code="w">(DE-600)1429493-X</subfield><subfield code="w">(DE-576)066397693</subfield><subfield code="x">1388-6150</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:123</subfield><subfield code="g">year:2015</subfield><subfield code="g">number:2</subfield><subfield code="g">day:13</subfield><subfield code="g">month:10</subfield><subfield code="g">pages:1263-1271</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1007/s10973-015-5084-0</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-CHE</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">123</subfield><subfield code="j">2015</subfield><subfield code="e">2</subfield><subfield code="b">13</subfield><subfield code="c">10</subfield><subfield code="h">1263-1271</subfield></datafield></record></collection>
|
| author |
Qi, Yanxia |
| spellingShingle |
Qi, Yanxia ddc 660 misc Ferrites misc PVC misc Flame retardancy misc TG-FTIR misc XPS Using TG-FTIR and XPS to understand thermal degradation and flame-retardant mechanism of flexible poly(vinyl chloride) filled with metallic ferrites |
| authorStr |
Qi, Yanxia |
| ppnlink_with_tag_str_mv |
@@773@@(DE-627)244148767 |
| format |
Article |
| dewey-ones |
660 - Chemical engineering |
| delete_txt_mv |
keep |
| author_role |
aut aut aut aut aut aut aut |
| collection |
OLC |
| remote_str |
false |
| illustrated |
Not Illustrated |
| issn |
1388-6150 |
| topic_title |
660 VZ Using TG-FTIR and XPS to understand thermal degradation and flame-retardant mechanism of flexible poly(vinyl chloride) filled with metallic ferrites Ferrites PVC Flame retardancy TG-FTIR XPS |
| topic |
ddc 660 misc Ferrites misc PVC misc Flame retardancy misc TG-FTIR misc XPS |
| topic_unstemmed |
ddc 660 misc Ferrites misc PVC misc Flame retardancy misc TG-FTIR misc XPS |
| topic_browse |
ddc 660 misc Ferrites misc PVC misc Flame retardancy misc TG-FTIR misc XPS |
| format_facet |
Aufsätze Gedruckte Aufsätze |
| format_main_str_mv |
Text Zeitschrift/Artikel |
| carriertype_str_mv |
nc |
| hierarchy_parent_title |
Journal of thermal analysis and calorimetry |
| hierarchy_parent_id |
244148767 |
| dewey-tens |
660 - Chemical engineering |
| hierarchy_top_title |
Journal of thermal analysis and calorimetry |
| isfreeaccess_txt |
false |
| familylinks_str_mv |
(DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 |
| title |
Using TG-FTIR and XPS to understand thermal degradation and flame-retardant mechanism of flexible poly(vinyl chloride) filled with metallic ferrites |
| ctrlnum |
(DE-627)OLC2049843011 (DE-He213)s10973-015-5084-0-p |
| title_full |
Using TG-FTIR and XPS to understand thermal degradation and flame-retardant mechanism of flexible poly(vinyl chloride) filled with metallic ferrites |
| author_sort |
Qi, Yanxia |
| journal |
Journal of thermal analysis and calorimetry |
| journalStr |
Journal of thermal analysis and calorimetry |
| lang_code |
eng |
| isOA_bool |
false |
| dewey-hundreds |
600 - Technology |
| recordtype |
marc |
| publishDateSort |
2015 |
| contenttype_str_mv |
txt |
| container_start_page |
1263 |
| author_browse |
Qi, Yanxia Wu, Weihong Han, Lijing Qu, Hongqiang Han, Xing Wang, Aiqing Xu, Jianzhong |
| container_volume |
123 |
| class |
660 VZ |
| format_se |
Aufsätze |
| author-letter |
Qi, Yanxia |
| doi_str_mv |
10.1007/s10973-015-5084-0 |
| dewey-full |
660 |
| title_sort |
using tg-ftir and xps to understand thermal degradation and flame-retardant mechanism of flexible poly(vinyl chloride) filled with metallic ferrites |
| title_auth |
Using TG-FTIR and XPS to understand thermal degradation and flame-retardant mechanism of flexible poly(vinyl chloride) filled with metallic ferrites |
| abstract |
Abstract The effect of three metallic ferrites, $ LaFeO_{3} $, $ ZnFe_{2} $$ O_{4} $, and $ BiFeO_{3} $, on the thermal degradation and flame retardancy of flexible poly(vinyl chloride) (PVC) was investigated using thermogravimetric analysis (TG), differential thermal analysis, and TG coupled with Fourier transform infrared spectrometry. In combination with X-ray photoelectron spectroscopy techniques, the charring and flame-retardant mechanism has been obtained. The results show that compared with $ LaFeO_{3} $ and $ ZnFe_{2} $$ O_{4} $, $ BiFeO_{3} $ promoted the dehydrochlorination reaction of PVC more effectively and generated a large amount of stable char residue in a condensed phase. In the char residue of PVC/$ BiFeO_{3} $, the Fe2p spectra are assigned to $ FeCl_{2} $ and FeOCl, which acts as effective catalysts for the ionic dehydrochlorination of PVC owing to their strong Lewis acidity. Bi exists as BiOCl, which has a lower melting point and boiling point and can more easily decompose to form $ BiCl_{3} $ gas at the flame temperature. The results demonstrated that $ BiFeO_{3} $ can not only effectively inhibit the production of smoke from PVC during combustion, but it also has an effect similar to that of $ Sb_{2} $$ O_{3} $ in flame-retardant PVC. © Akadémiai Kiadó, Budapest, Hungary 2015 |
| abstractGer |
Abstract The effect of three metallic ferrites, $ LaFeO_{3} $, $ ZnFe_{2} $$ O_{4} $, and $ BiFeO_{3} $, on the thermal degradation and flame retardancy of flexible poly(vinyl chloride) (PVC) was investigated using thermogravimetric analysis (TG), differential thermal analysis, and TG coupled with Fourier transform infrared spectrometry. In combination with X-ray photoelectron spectroscopy techniques, the charring and flame-retardant mechanism has been obtained. The results show that compared with $ LaFeO_{3} $ and $ ZnFe_{2} $$ O_{4} $, $ BiFeO_{3} $ promoted the dehydrochlorination reaction of PVC more effectively and generated a large amount of stable char residue in a condensed phase. In the char residue of PVC/$ BiFeO_{3} $, the Fe2p spectra are assigned to $ FeCl_{2} $ and FeOCl, which acts as effective catalysts for the ionic dehydrochlorination of PVC owing to their strong Lewis acidity. Bi exists as BiOCl, which has a lower melting point and boiling point and can more easily decompose to form $ BiCl_{3} $ gas at the flame temperature. The results demonstrated that $ BiFeO_{3} $ can not only effectively inhibit the production of smoke from PVC during combustion, but it also has an effect similar to that of $ Sb_{2} $$ O_{3} $ in flame-retardant PVC. © Akadémiai Kiadó, Budapest, Hungary 2015 |
| abstract_unstemmed |
Abstract The effect of three metallic ferrites, $ LaFeO_{3} $, $ ZnFe_{2} $$ O_{4} $, and $ BiFeO_{3} $, on the thermal degradation and flame retardancy of flexible poly(vinyl chloride) (PVC) was investigated using thermogravimetric analysis (TG), differential thermal analysis, and TG coupled with Fourier transform infrared spectrometry. In combination with X-ray photoelectron spectroscopy techniques, the charring and flame-retardant mechanism has been obtained. The results show that compared with $ LaFeO_{3} $ and $ ZnFe_{2} $$ O_{4} $, $ BiFeO_{3} $ promoted the dehydrochlorination reaction of PVC more effectively and generated a large amount of stable char residue in a condensed phase. In the char residue of PVC/$ BiFeO_{3} $, the Fe2p spectra are assigned to $ FeCl_{2} $ and FeOCl, which acts as effective catalysts for the ionic dehydrochlorination of PVC owing to their strong Lewis acidity. Bi exists as BiOCl, which has a lower melting point and boiling point and can more easily decompose to form $ BiCl_{3} $ gas at the flame temperature. The results demonstrated that $ BiFeO_{3} $ can not only effectively inhibit the production of smoke from PVC during combustion, but it also has an effect similar to that of $ Sb_{2} $$ O_{3} $ in flame-retardant PVC. © Akadémiai Kiadó, Budapest, Hungary 2015 |
| collection_details |
GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 |
| container_issue |
2 |
| title_short |
Using TG-FTIR and XPS to understand thermal degradation and flame-retardant mechanism of flexible poly(vinyl chloride) filled with metallic ferrites |
| url |
https://doi.org/10.1007/s10973-015-5084-0 |
| remote_bool |
false |
| author2 |
Wu, Weihong Han, Lijing Qu, Hongqiang Han, Xing Wang, Aiqing Xu, Jianzhong |
| author2Str |
Wu, Weihong Han, Lijing Qu, Hongqiang Han, Xing Wang, Aiqing Xu, Jianzhong |
| ppnlink |
244148767 |
| mediatype_str_mv |
n |
| isOA_txt |
false |
| hochschulschrift_bool |
false |
| doi_str |
10.1007/s10973-015-5084-0 |
| up_date |
2024-07-04T00:13:44.755Z |
| _version_ |
1803605271910547456 |
| fullrecord_marcxml |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">OLC2049843011</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230503170118.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">200820s2015 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10973-015-5084-0</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC2049843011</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-He213)s10973-015-5084-0-p</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">660</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Qi, Yanxia</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Using TG-FTIR and XPS to understand thermal degradation and flame-retardant mechanism of flexible poly(vinyl chloride) filled with metallic ferrites</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2015</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Akadémiai Kiadó, Budapest, Hungary 2015</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract The effect of three metallic ferrites, $ LaFeO_{3} $, $ ZnFe_{2} $$ O_{4} $, and $ BiFeO_{3} $, on the thermal degradation and flame retardancy of flexible poly(vinyl chloride) (PVC) was investigated using thermogravimetric analysis (TG), differential thermal analysis, and TG coupled with Fourier transform infrared spectrometry. In combination with X-ray photoelectron spectroscopy techniques, the charring and flame-retardant mechanism has been obtained. The results show that compared with $ LaFeO_{3} $ and $ ZnFe_{2} $$ O_{4} $, $ BiFeO_{3} $ promoted the dehydrochlorination reaction of PVC more effectively and generated a large amount of stable char residue in a condensed phase. In the char residue of PVC/$ BiFeO_{3} $, the Fe2p spectra are assigned to $ FeCl_{2} $ and FeOCl, which acts as effective catalysts for the ionic dehydrochlorination of PVC owing to their strong Lewis acidity. Bi exists as BiOCl, which has a lower melting point and boiling point and can more easily decompose to form $ BiCl_{3} $ gas at the flame temperature. The results demonstrated that $ BiFeO_{3} $ can not only effectively inhibit the production of smoke from PVC during combustion, but it also has an effect similar to that of $ Sb_{2} $$ O_{3} $ in flame-retardant PVC.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Ferrites</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">PVC</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Flame retardancy</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">TG-FTIR</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">XPS</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wu, Weihong</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Han, Lijing</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Qu, Hongqiang</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Han, Xing</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wang, Aiqing</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Xu, Jianzhong</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of thermal analysis and calorimetry</subfield><subfield code="d">Springer Netherlands, 1998</subfield><subfield code="g">123(2015), 2 vom: 13. Okt., Seite 1263-1271</subfield><subfield code="w">(DE-627)244148767</subfield><subfield code="w">(DE-600)1429493-X</subfield><subfield code="w">(DE-576)066397693</subfield><subfield code="x">1388-6150</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:123</subfield><subfield code="g">year:2015</subfield><subfield code="g">number:2</subfield><subfield code="g">day:13</subfield><subfield code="g">month:10</subfield><subfield code="g">pages:1263-1271</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1007/s10973-015-5084-0</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-CHE</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">123</subfield><subfield code="j">2015</subfield><subfield code="e">2</subfield><subfield code="b">13</subfield><subfield code="c">10</subfield><subfield code="h">1263-1271</subfield></datafield></record></collection>
|
| score |
7.3996267 |