Thermal decomposition characteristics of expired single-based propellant using a lab-scale tube furnace and a thermo-gravimetric analysis reactor
Abstract The Republic of Korea has a plan to construct an incineration facility for expired propellant from munitions including 155, 105 mm, and 8 in. howitzer shells. It is important to understand thermal characteristics of the propellant before designing the incineration facility. In this study, t...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Park, Sang Shin [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2016 |
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| Schlagwörter: |
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| Anmerkung: |
© Akadémiai Kiadó, Budapest, Hungary 2016 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of thermal analysis and calorimetry - Springer Netherlands, 1998, 124(2016), 2 vom: 18. Jan., Seite 657-665 |
|---|---|
| Übergeordnetes Werk: |
volume:124 ; year:2016 ; number:2 ; day:18 ; month:01 ; pages:657-665 |
| Links: |
|---|
| DOI / URN: |
10.1007/s10973-015-5231-7 |
|---|
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OLC2049845189 |
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| 520 | |a Abstract The Republic of Korea has a plan to construct an incineration facility for expired propellant from munitions including 155, 105 mm, and 8 in. howitzer shells. It is important to understand thermal characteristics of the propellant before designing the incineration facility. In this study, the ingredients of a propellant sample were analyzed using liquid chromatography–mass spectrometry, and the temporal mass loss of the sample was measured using thermo-gravimetric analysis in an argon atmosphere up to a temperature of 350 °C at different heating rates of 10, 20, and 30 °C $ min^{−1} $. The mass of the sample started decreasing at a temperature of about 180 °C and was fully decomposed when the temperature reached about 210 °C. Using a first-order model to describe the reaction kinetics, we obtained a pre-exponential factor of 2.09 × $ 10^{39} $ $ min^{−1} $ and an activation energy of 335.77 kJ $ mol^{−1} $ for the sample. In order to understand product gas compositions, another thermal decomposition experiment was carried out using a lab-scale tube furnace under an argon atmosphere up to a temperature of 350 °C. Gas compositions were analyzed using gas chromatography and gas detecting tubes. Residual ash compounds were analyzed using X-ray fluorescence. | ||
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10.1007/s10973-015-5231-7 doi (DE-627)OLC2049845189 (DE-He213)s10973-015-5231-7-p DE-627 ger DE-627 rakwb eng 660 VZ Park, Sang Shin verfasserin aut Thermal decomposition characteristics of expired single-based propellant using a lab-scale tube furnace and a thermo-gravimetric analysis reactor 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2016 Abstract The Republic of Korea has a plan to construct an incineration facility for expired propellant from munitions including 155, 105 mm, and 8 in. howitzer shells. It is important to understand thermal characteristics of the propellant before designing the incineration facility. In this study, the ingredients of a propellant sample were analyzed using liquid chromatography–mass spectrometry, and the temporal mass loss of the sample was measured using thermo-gravimetric analysis in an argon atmosphere up to a temperature of 350 °C at different heating rates of 10, 20, and 30 °C $ min^{−1} $. The mass of the sample started decreasing at a temperature of about 180 °C and was fully decomposed when the temperature reached about 210 °C. Using a first-order model to describe the reaction kinetics, we obtained a pre-exponential factor of 2.09 × $ 10^{39} $ $ min^{−1} $ and an activation energy of 335.77 kJ $ mol^{−1} $ for the sample. In order to understand product gas compositions, another thermal decomposition experiment was carried out using a lab-scale tube furnace under an argon atmosphere up to a temperature of 350 °C. Gas compositions were analyzed using gas chromatography and gas detecting tubes. Residual ash compounds were analyzed using X-ray fluorescence. Thermal decomposition Single-based solid propellant TG Reactivity Kinetic constant Nitrocellulose Hwang, In Sik aut Kang, Myung Soo aut Jeong, Hyo Jae aut Hwang, Jungho aut Enthalten in Journal of thermal analysis and calorimetry Springer Netherlands, 1998 124(2016), 2 vom: 18. Jan., Seite 657-665 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:124 year:2016 number:2 day:18 month:01 pages:657-665 https://doi.org/10.1007/s10973-015-5231-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 124 2016 2 18 01 657-665 |
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10.1007/s10973-015-5231-7 doi (DE-627)OLC2049845189 (DE-He213)s10973-015-5231-7-p DE-627 ger DE-627 rakwb eng 660 VZ Park, Sang Shin verfasserin aut Thermal decomposition characteristics of expired single-based propellant using a lab-scale tube furnace and a thermo-gravimetric analysis reactor 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2016 Abstract The Republic of Korea has a plan to construct an incineration facility for expired propellant from munitions including 155, 105 mm, and 8 in. howitzer shells. It is important to understand thermal characteristics of the propellant before designing the incineration facility. In this study, the ingredients of a propellant sample were analyzed using liquid chromatography–mass spectrometry, and the temporal mass loss of the sample was measured using thermo-gravimetric analysis in an argon atmosphere up to a temperature of 350 °C at different heating rates of 10, 20, and 30 °C $ min^{−1} $. The mass of the sample started decreasing at a temperature of about 180 °C and was fully decomposed when the temperature reached about 210 °C. Using a first-order model to describe the reaction kinetics, we obtained a pre-exponential factor of 2.09 × $ 10^{39} $ $ min^{−1} $ and an activation energy of 335.77 kJ $ mol^{−1} $ for the sample. In order to understand product gas compositions, another thermal decomposition experiment was carried out using a lab-scale tube furnace under an argon atmosphere up to a temperature of 350 °C. Gas compositions were analyzed using gas chromatography and gas detecting tubes. Residual ash compounds were analyzed using X-ray fluorescence. Thermal decomposition Single-based solid propellant TG Reactivity Kinetic constant Nitrocellulose Hwang, In Sik aut Kang, Myung Soo aut Jeong, Hyo Jae aut Hwang, Jungho aut Enthalten in Journal of thermal analysis and calorimetry Springer Netherlands, 1998 124(2016), 2 vom: 18. Jan., Seite 657-665 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:124 year:2016 number:2 day:18 month:01 pages:657-665 https://doi.org/10.1007/s10973-015-5231-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 124 2016 2 18 01 657-665 |
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10.1007/s10973-015-5231-7 doi (DE-627)OLC2049845189 (DE-He213)s10973-015-5231-7-p DE-627 ger DE-627 rakwb eng 660 VZ Park, Sang Shin verfasserin aut Thermal decomposition characteristics of expired single-based propellant using a lab-scale tube furnace and a thermo-gravimetric analysis reactor 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2016 Abstract The Republic of Korea has a plan to construct an incineration facility for expired propellant from munitions including 155, 105 mm, and 8 in. howitzer shells. It is important to understand thermal characteristics of the propellant before designing the incineration facility. In this study, the ingredients of a propellant sample were analyzed using liquid chromatography–mass spectrometry, and the temporal mass loss of the sample was measured using thermo-gravimetric analysis in an argon atmosphere up to a temperature of 350 °C at different heating rates of 10, 20, and 30 °C $ min^{−1} $. The mass of the sample started decreasing at a temperature of about 180 °C and was fully decomposed when the temperature reached about 210 °C. Using a first-order model to describe the reaction kinetics, we obtained a pre-exponential factor of 2.09 × $ 10^{39} $ $ min^{−1} $ and an activation energy of 335.77 kJ $ mol^{−1} $ for the sample. In order to understand product gas compositions, another thermal decomposition experiment was carried out using a lab-scale tube furnace under an argon atmosphere up to a temperature of 350 °C. Gas compositions were analyzed using gas chromatography and gas detecting tubes. Residual ash compounds were analyzed using X-ray fluorescence. Thermal decomposition Single-based solid propellant TG Reactivity Kinetic constant Nitrocellulose Hwang, In Sik aut Kang, Myung Soo aut Jeong, Hyo Jae aut Hwang, Jungho aut Enthalten in Journal of thermal analysis and calorimetry Springer Netherlands, 1998 124(2016), 2 vom: 18. Jan., Seite 657-665 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:124 year:2016 number:2 day:18 month:01 pages:657-665 https://doi.org/10.1007/s10973-015-5231-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 124 2016 2 18 01 657-665 |
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10.1007/s10973-015-5231-7 doi (DE-627)OLC2049845189 (DE-He213)s10973-015-5231-7-p DE-627 ger DE-627 rakwb eng 660 VZ Park, Sang Shin verfasserin aut Thermal decomposition characteristics of expired single-based propellant using a lab-scale tube furnace and a thermo-gravimetric analysis reactor 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2016 Abstract The Republic of Korea has a plan to construct an incineration facility for expired propellant from munitions including 155, 105 mm, and 8 in. howitzer shells. It is important to understand thermal characteristics of the propellant before designing the incineration facility. In this study, the ingredients of a propellant sample were analyzed using liquid chromatography–mass spectrometry, and the temporal mass loss of the sample was measured using thermo-gravimetric analysis in an argon atmosphere up to a temperature of 350 °C at different heating rates of 10, 20, and 30 °C $ min^{−1} $. The mass of the sample started decreasing at a temperature of about 180 °C and was fully decomposed when the temperature reached about 210 °C. Using a first-order model to describe the reaction kinetics, we obtained a pre-exponential factor of 2.09 × $ 10^{39} $ $ min^{−1} $ and an activation energy of 335.77 kJ $ mol^{−1} $ for the sample. In order to understand product gas compositions, another thermal decomposition experiment was carried out using a lab-scale tube furnace under an argon atmosphere up to a temperature of 350 °C. Gas compositions were analyzed using gas chromatography and gas detecting tubes. Residual ash compounds were analyzed using X-ray fluorescence. Thermal decomposition Single-based solid propellant TG Reactivity Kinetic constant Nitrocellulose Hwang, In Sik aut Kang, Myung Soo aut Jeong, Hyo Jae aut Hwang, Jungho aut Enthalten in Journal of thermal analysis and calorimetry Springer Netherlands, 1998 124(2016), 2 vom: 18. Jan., Seite 657-665 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:124 year:2016 number:2 day:18 month:01 pages:657-665 https://doi.org/10.1007/s10973-015-5231-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 124 2016 2 18 01 657-665 |
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10.1007/s10973-015-5231-7 doi (DE-627)OLC2049845189 (DE-He213)s10973-015-5231-7-p DE-627 ger DE-627 rakwb eng 660 VZ Park, Sang Shin verfasserin aut Thermal decomposition characteristics of expired single-based propellant using a lab-scale tube furnace and a thermo-gravimetric analysis reactor 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2016 Abstract The Republic of Korea has a plan to construct an incineration facility for expired propellant from munitions including 155, 105 mm, and 8 in. howitzer shells. It is important to understand thermal characteristics of the propellant before designing the incineration facility. In this study, the ingredients of a propellant sample were analyzed using liquid chromatography–mass spectrometry, and the temporal mass loss of the sample was measured using thermo-gravimetric analysis in an argon atmosphere up to a temperature of 350 °C at different heating rates of 10, 20, and 30 °C $ min^{−1} $. The mass of the sample started decreasing at a temperature of about 180 °C and was fully decomposed when the temperature reached about 210 °C. Using a first-order model to describe the reaction kinetics, we obtained a pre-exponential factor of 2.09 × $ 10^{39} $ $ min^{−1} $ and an activation energy of 335.77 kJ $ mol^{−1} $ for the sample. In order to understand product gas compositions, another thermal decomposition experiment was carried out using a lab-scale tube furnace under an argon atmosphere up to a temperature of 350 °C. Gas compositions were analyzed using gas chromatography and gas detecting tubes. Residual ash compounds were analyzed using X-ray fluorescence. Thermal decomposition Single-based solid propellant TG Reactivity Kinetic constant Nitrocellulose Hwang, In Sik aut Kang, Myung Soo aut Jeong, Hyo Jae aut Hwang, Jungho aut Enthalten in Journal of thermal analysis and calorimetry Springer Netherlands, 1998 124(2016), 2 vom: 18. Jan., Seite 657-665 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:124 year:2016 number:2 day:18 month:01 pages:657-665 https://doi.org/10.1007/s10973-015-5231-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 124 2016 2 18 01 657-665 |
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thermal decomposition characteristics of expired single-based propellant using a lab-scale tube furnace and a thermo-gravimetric analysis reactor |
| title_auth |
Thermal decomposition characteristics of expired single-based propellant using a lab-scale tube furnace and a thermo-gravimetric analysis reactor |
| abstract |
Abstract The Republic of Korea has a plan to construct an incineration facility for expired propellant from munitions including 155, 105 mm, and 8 in. howitzer shells. It is important to understand thermal characteristics of the propellant before designing the incineration facility. In this study, the ingredients of a propellant sample were analyzed using liquid chromatography–mass spectrometry, and the temporal mass loss of the sample was measured using thermo-gravimetric analysis in an argon atmosphere up to a temperature of 350 °C at different heating rates of 10, 20, and 30 °C $ min^{−1} $. The mass of the sample started decreasing at a temperature of about 180 °C and was fully decomposed when the temperature reached about 210 °C. Using a first-order model to describe the reaction kinetics, we obtained a pre-exponential factor of 2.09 × $ 10^{39} $ $ min^{−1} $ and an activation energy of 335.77 kJ $ mol^{−1} $ for the sample. In order to understand product gas compositions, another thermal decomposition experiment was carried out using a lab-scale tube furnace under an argon atmosphere up to a temperature of 350 °C. Gas compositions were analyzed using gas chromatography and gas detecting tubes. Residual ash compounds were analyzed using X-ray fluorescence. © Akadémiai Kiadó, Budapest, Hungary 2016 |
| abstractGer |
Abstract The Republic of Korea has a plan to construct an incineration facility for expired propellant from munitions including 155, 105 mm, and 8 in. howitzer shells. It is important to understand thermal characteristics of the propellant before designing the incineration facility. In this study, the ingredients of a propellant sample were analyzed using liquid chromatography–mass spectrometry, and the temporal mass loss of the sample was measured using thermo-gravimetric analysis in an argon atmosphere up to a temperature of 350 °C at different heating rates of 10, 20, and 30 °C $ min^{−1} $. The mass of the sample started decreasing at a temperature of about 180 °C and was fully decomposed when the temperature reached about 210 °C. Using a first-order model to describe the reaction kinetics, we obtained a pre-exponential factor of 2.09 × $ 10^{39} $ $ min^{−1} $ and an activation energy of 335.77 kJ $ mol^{−1} $ for the sample. In order to understand product gas compositions, another thermal decomposition experiment was carried out using a lab-scale tube furnace under an argon atmosphere up to a temperature of 350 °C. Gas compositions were analyzed using gas chromatography and gas detecting tubes. Residual ash compounds were analyzed using X-ray fluorescence. © Akadémiai Kiadó, Budapest, Hungary 2016 |
| abstract_unstemmed |
Abstract The Republic of Korea has a plan to construct an incineration facility for expired propellant from munitions including 155, 105 mm, and 8 in. howitzer shells. It is important to understand thermal characteristics of the propellant before designing the incineration facility. In this study, the ingredients of a propellant sample were analyzed using liquid chromatography–mass spectrometry, and the temporal mass loss of the sample was measured using thermo-gravimetric analysis in an argon atmosphere up to a temperature of 350 °C at different heating rates of 10, 20, and 30 °C $ min^{−1} $. The mass of the sample started decreasing at a temperature of about 180 °C and was fully decomposed when the temperature reached about 210 °C. Using a first-order model to describe the reaction kinetics, we obtained a pre-exponential factor of 2.09 × $ 10^{39} $ $ min^{−1} $ and an activation energy of 335.77 kJ $ mol^{−1} $ for the sample. In order to understand product gas compositions, another thermal decomposition experiment was carried out using a lab-scale tube furnace under an argon atmosphere up to a temperature of 350 °C. Gas compositions were analyzed using gas chromatography and gas detecting tubes. Residual ash compounds were analyzed using X-ray fluorescence. © Akadémiai Kiadó, Budapest, Hungary 2016 |
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Thermal decomposition characteristics of expired single-based propellant using a lab-scale tube furnace and a thermo-gravimetric analysis reactor |
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