Volume properties of the molten systems MF–$ K_{2} $$ TaF_{7} $ (MF = LiF, NaF and KF)
Abstract Based on experimental density measurements, molar volumes, excess molar volumes and partial molar volumes were calculated for the systems MF–$ K_{2} $$ TaF_{7} $ (MF = LiF, NaF and KF) at 1273 K. Excess partial molar volumes of $ K_{2} $$ TaF_{7} $ and MF at infinite dissolution were also c...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Mlynáriková, Jarmila [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2017 |
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| Schlagwörter: |
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| Anmerkung: |
© Akadémiai Kiadó, Budapest, Hungary 2017 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of thermal analysis and calorimetry - Springer Netherlands, 1998, 129(2017), 1 vom: 15. Feb., Seite 475-486 |
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| Übergeordnetes Werk: |
volume:129 ; year:2017 ; number:1 ; day:15 ; month:02 ; pages:475-486 |
| Links: |
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| DOI / URN: |
10.1007/s10973-017-6137-3 |
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OLC2049854102 |
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| 520 | |a Abstract Based on experimental density measurements, molar volumes, excess molar volumes and partial molar volumes were calculated for the systems MF–$ K_{2} $$ TaF_{7} $ (MF = LiF, NaF and KF) at 1273 K. Excess partial molar volumes of $ K_{2} $$ TaF_{7} $ and MF at infinite dissolution were also calculated. Based on these values, the overall volume contraction was identified. This volume contraction consists of two contributions: a volume contraction induced by the association reaction of [$ TaF_{7} $]2− and $ F^{−} $ anions, and cationic volume contraction. | ||
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| 650 | 4 | |a Excess molar volume | |
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| 650 | 4 | |a Tantalates | |
| 650 | 4 | |a Molten salts | |
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| 700 | 1 | |a Mikšíková, Eva |4 aut | |
| 700 | 1 | |a Netriová, Zuzana |4 aut | |
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10.1007/s10973-017-6137-3 doi (DE-627)OLC2049854102 (DE-He213)s10973-017-6137-3-p DE-627 ger DE-627 rakwb eng 660 VZ Mlynáriková, Jarmila verfasserin (orcid)0000-0002-8002-5907 aut Volume properties of the molten systems MF–$ K_{2} $$ TaF_{7} $ (MF = LiF, NaF and KF) 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2017 Abstract Based on experimental density measurements, molar volumes, excess molar volumes and partial molar volumes were calculated for the systems MF–$ K_{2} $$ TaF_{7} $ (MF = LiF, NaF and KF) at 1273 K. Excess partial molar volumes of $ K_{2} $$ TaF_{7} $ and MF at infinite dissolution were also calculated. Based on these values, the overall volume contraction was identified. This volume contraction consists of two contributions: a volume contraction induced by the association reaction of [$ TaF_{7} $]2− and $ F^{−} $ anions, and cationic volume contraction. Density Molar volume Excess molar volume Partial molar volume Excess partial molar volume Tantalates Molten salts Fluorides Boča, Miroslav aut Mikšíková, Eva aut Netriová, Zuzana aut Enthalten in Journal of thermal analysis and calorimetry Springer Netherlands, 1998 129(2017), 1 vom: 15. Feb., Seite 475-486 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:129 year:2017 number:1 day:15 month:02 pages:475-486 https://doi.org/10.1007/s10973-017-6137-3 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 129 2017 1 15 02 475-486 |
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10.1007/s10973-017-6137-3 doi (DE-627)OLC2049854102 (DE-He213)s10973-017-6137-3-p DE-627 ger DE-627 rakwb eng 660 VZ Mlynáriková, Jarmila verfasserin (orcid)0000-0002-8002-5907 aut Volume properties of the molten systems MF–$ K_{2} $$ TaF_{7} $ (MF = LiF, NaF and KF) 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2017 Abstract Based on experimental density measurements, molar volumes, excess molar volumes and partial molar volumes were calculated for the systems MF–$ K_{2} $$ TaF_{7} $ (MF = LiF, NaF and KF) at 1273 K. Excess partial molar volumes of $ K_{2} $$ TaF_{7} $ and MF at infinite dissolution were also calculated. Based on these values, the overall volume contraction was identified. This volume contraction consists of two contributions: a volume contraction induced by the association reaction of [$ TaF_{7} $]2− and $ F^{−} $ anions, and cationic volume contraction. Density Molar volume Excess molar volume Partial molar volume Excess partial molar volume Tantalates Molten salts Fluorides Boča, Miroslav aut Mikšíková, Eva aut Netriová, Zuzana aut Enthalten in Journal of thermal analysis and calorimetry Springer Netherlands, 1998 129(2017), 1 vom: 15. Feb., Seite 475-486 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:129 year:2017 number:1 day:15 month:02 pages:475-486 https://doi.org/10.1007/s10973-017-6137-3 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 129 2017 1 15 02 475-486 |
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10.1007/s10973-017-6137-3 doi (DE-627)OLC2049854102 (DE-He213)s10973-017-6137-3-p DE-627 ger DE-627 rakwb eng 660 VZ Mlynáriková, Jarmila verfasserin (orcid)0000-0002-8002-5907 aut Volume properties of the molten systems MF–$ K_{2} $$ TaF_{7} $ (MF = LiF, NaF and KF) 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2017 Abstract Based on experimental density measurements, molar volumes, excess molar volumes and partial molar volumes were calculated for the systems MF–$ K_{2} $$ TaF_{7} $ (MF = LiF, NaF and KF) at 1273 K. Excess partial molar volumes of $ K_{2} $$ TaF_{7} $ and MF at infinite dissolution were also calculated. Based on these values, the overall volume contraction was identified. This volume contraction consists of two contributions: a volume contraction induced by the association reaction of [$ TaF_{7} $]2− and $ F^{−} $ anions, and cationic volume contraction. Density Molar volume Excess molar volume Partial molar volume Excess partial molar volume Tantalates Molten salts Fluorides Boča, Miroslav aut Mikšíková, Eva aut Netriová, Zuzana aut Enthalten in Journal of thermal analysis and calorimetry Springer Netherlands, 1998 129(2017), 1 vom: 15. Feb., Seite 475-486 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:129 year:2017 number:1 day:15 month:02 pages:475-486 https://doi.org/10.1007/s10973-017-6137-3 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 129 2017 1 15 02 475-486 |
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10.1007/s10973-017-6137-3 doi (DE-627)OLC2049854102 (DE-He213)s10973-017-6137-3-p DE-627 ger DE-627 rakwb eng 660 VZ Mlynáriková, Jarmila verfasserin (orcid)0000-0002-8002-5907 aut Volume properties of the molten systems MF–$ K_{2} $$ TaF_{7} $ (MF = LiF, NaF and KF) 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2017 Abstract Based on experimental density measurements, molar volumes, excess molar volumes and partial molar volumes were calculated for the systems MF–$ K_{2} $$ TaF_{7} $ (MF = LiF, NaF and KF) at 1273 K. Excess partial molar volumes of $ K_{2} $$ TaF_{7} $ and MF at infinite dissolution were also calculated. Based on these values, the overall volume contraction was identified. This volume contraction consists of two contributions: a volume contraction induced by the association reaction of [$ TaF_{7} $]2− and $ F^{−} $ anions, and cationic volume contraction. Density Molar volume Excess molar volume Partial molar volume Excess partial molar volume Tantalates Molten salts Fluorides Boča, Miroslav aut Mikšíková, Eva aut Netriová, Zuzana aut Enthalten in Journal of thermal analysis and calorimetry Springer Netherlands, 1998 129(2017), 1 vom: 15. Feb., Seite 475-486 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:129 year:2017 number:1 day:15 month:02 pages:475-486 https://doi.org/10.1007/s10973-017-6137-3 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 129 2017 1 15 02 475-486 |
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Volume properties of the molten systems MF–$ K_{2} $$ TaF_{7} $ (MF = LiF, NaF and KF) |
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Abstract Based on experimental density measurements, molar volumes, excess molar volumes and partial molar volumes were calculated for the systems MF–$ K_{2} $$ TaF_{7} $ (MF = LiF, NaF and KF) at 1273 K. Excess partial molar volumes of $ K_{2} $$ TaF_{7} $ and MF at infinite dissolution were also calculated. Based on these values, the overall volume contraction was identified. This volume contraction consists of two contributions: a volume contraction induced by the association reaction of [$ TaF_{7} $]2− and $ F^{−} $ anions, and cationic volume contraction. © Akadémiai Kiadó, Budapest, Hungary 2017 |
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Abstract Based on experimental density measurements, molar volumes, excess molar volumes and partial molar volumes were calculated for the systems MF–$ K_{2} $$ TaF_{7} $ (MF = LiF, NaF and KF) at 1273 K. Excess partial molar volumes of $ K_{2} $$ TaF_{7} $ and MF at infinite dissolution were also calculated. Based on these values, the overall volume contraction was identified. This volume contraction consists of two contributions: a volume contraction induced by the association reaction of [$ TaF_{7} $]2− and $ F^{−} $ anions, and cationic volume contraction. © Akadémiai Kiadó, Budapest, Hungary 2017 |
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Abstract Based on experimental density measurements, molar volumes, excess molar volumes and partial molar volumes were calculated for the systems MF–$ K_{2} $$ TaF_{7} $ (MF = LiF, NaF and KF) at 1273 K. Excess partial molar volumes of $ K_{2} $$ TaF_{7} $ and MF at infinite dissolution were also calculated. Based on these values, the overall volume contraction was identified. This volume contraction consists of two contributions: a volume contraction induced by the association reaction of [$ TaF_{7} $]2− and $ F^{−} $ anions, and cationic volume contraction. © Akadémiai Kiadó, Budapest, Hungary 2017 |
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Volume properties of the molten systems MF–$ K_{2} $$ TaF_{7} $ (MF = LiF, NaF and KF) |
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https://doi.org/10.1007/s10973-017-6137-3 |
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Boča, Miroslav Mikšíková, Eva Netriová, Zuzana |
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Boča, Miroslav Mikšíková, Eva Netriová, Zuzana |
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10.1007/s10973-017-6137-3 |
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2024-07-04T00:16:21.179Z |
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