The mechanism study on the cooperative flame resistance effect between HMP and NP in ABS by TG–FTIR
Abstract Thermogravimetry (TG) coupled with Fourier transform infrared spectroscopy (FTIR) (TG–FTIR) is an effective tool on studying the mechanism of the flame retardant. The mechanism on the cooperative effect between hydroquinone bis(di-2-methylphenyl phosphate) (HMP), which is an effective flame...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Yang, Zhiyi [verfasserIn] |
|---|
| Format: |
Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
2017 |
|---|
| Schlagwörter: |
|---|
| Anmerkung: |
© Akadémiai Kiadó, Budapest, Hungary 2017 |
|---|
| Übergeordnetes Werk: |
Enthalten in: Journal of thermal analysis and calorimetry - Springer Netherlands, 1998, 129(2017), 1 vom: 04. Feb., Seite 303-314 |
|---|---|
| Übergeordnetes Werk: |
volume:129 ; year:2017 ; number:1 ; day:04 ; month:02 ; pages:303-314 |
| Links: |
|---|
| DOI / URN: |
10.1007/s10973-017-6111-0 |
|---|
| Katalog-ID: |
OLC2049854269 |
|---|
| LEADER | 01000caa a22002652 4500 | ||
|---|---|---|---|
| 001 | OLC2049854269 | ||
| 003 | DE-627 | ||
| 005 | 20230503170231.0 | ||
| 007 | tu | ||
| 008 | 200820s2017 xx ||||| 00| ||eng c | ||
| 024 | 7 | |a 10.1007/s10973-017-6111-0 |2 doi | |
| 035 | |a (DE-627)OLC2049854269 | ||
| 035 | |a (DE-He213)s10973-017-6111-0-p | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
| 041 | |a eng | ||
| 082 | 0 | 4 | |a 660 |q VZ |
| 100 | 1 | |a Yang, Zhiyi |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a The mechanism study on the cooperative flame resistance effect between HMP and NP in ABS by TG–FTIR |
| 264 | 1 | |c 2017 | |
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a ohne Hilfsmittel zu benutzen |b n |2 rdamedia | ||
| 338 | |a Band |b nc |2 rdacarrier | ||
| 500 | |a © Akadémiai Kiadó, Budapest, Hungary 2017 | ||
| 520 | |a Abstract Thermogravimetry (TG) coupled with Fourier transform infrared spectroscopy (FTIR) (TG–FTIR) is an effective tool on studying the mechanism of the flame retardant. The mechanism on the cooperative effect between hydroquinone bis(di-2-methylphenyl phosphate) (HMP), which is an effective flame retardant, and novolac phenol (NP) in acrylonitrile–butadiene–styrene (ABS) is investigated by TG–FTIR under air in this study. The TG–FTIR of ABS/HMP, ABS/HMP/NP and ABS/NP are discussed carefully as well as their semi-quantitative analyses. The semi-quantitative analysis results of TG–FTIR show that ABS/HMP, ABS/HMP/NP and ABS/NP decompose in a two-step process. The first step is mainly the process of thermal degradation, macromolecules being decomposed into micromolecules containing many functional groups such as $ C_{Ar} $–H, –$ CH_{2} $–, –OH, P–O–$ C_{Ar} $. The second step is mainly the process of combustion, the layer of carbon being further oxidized into carbon dioxide, water and alkyne. The residue of ABS/HMP/NP is the highest as well as its temperature at which the maximum of mass loss rate occurs. Furthermore, the comparison of their semi-quantitative analyses indicates that NP could absorb parts of micromolecules containing the functional groups of –OH, $ CH_{2} $– and $ C_{Ar} $–H, contributing to the formation of carbon layer, and HMP slows down the degradation of the carbon layer, achieving the cooperative effect. | ||
| 650 | 4 | |a TG–FTIR | |
| 650 | 4 | |a Mechanism | |
| 650 | 4 | |a Cooperative flame | |
| 700 | 1 | |a Gu, Zhanyong |4 aut | |
| 700 | 1 | |a Yang, Xiushan |4 aut | |
| 700 | 1 | |a Zhang, Zhiye |4 aut | |
| 700 | 1 | |a Wang, Xinlong |4 aut | |
| 700 | 1 | |a Chen, Xiaodong |4 aut | |
| 700 | 1 | |a Yang, Lin |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Journal of thermal analysis and calorimetry |d Springer Netherlands, 1998 |g 129(2017), 1 vom: 04. Feb., Seite 303-314 |w (DE-627)244148767 |w (DE-600)1429493-X |w (DE-576)066397693 |x 1388-6150 |7 nnns |
| 773 | 1 | 8 | |g volume:129 |g year:2017 |g number:1 |g day:04 |g month:02 |g pages:303-314 |
| 856 | 4 | 1 | |u https://doi.org/10.1007/s10973-017-6111-0 |z lizenzpflichtig |3 Volltext |
| 912 | |a GBV_USEFLAG_A | ||
| 912 | |a SYSFLAG_A | ||
| 912 | |a GBV_OLC | ||
| 912 | |a SSG-OLC-TEC | ||
| 912 | |a SSG-OLC-CHE | ||
| 912 | |a GBV_ILN_70 | ||
| 951 | |a AR | ||
| 952 | |d 129 |j 2017 |e 1 |b 04 |c 02 |h 303-314 | ||
| author_variant |
z y zy z g zg x y xy z z zz x w xw x c xc l y ly |
|---|---|
| matchkey_str |
article:13886150:2017----::hmcaimtdoteoprtvfaeeitnefetewe |
| hierarchy_sort_str |
2017 |
| publishDate |
2017 |
| allfields |
10.1007/s10973-017-6111-0 doi (DE-627)OLC2049854269 (DE-He213)s10973-017-6111-0-p DE-627 ger DE-627 rakwb eng 660 VZ Yang, Zhiyi verfasserin aut The mechanism study on the cooperative flame resistance effect between HMP and NP in ABS by TG–FTIR 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2017 Abstract Thermogravimetry (TG) coupled with Fourier transform infrared spectroscopy (FTIR) (TG–FTIR) is an effective tool on studying the mechanism of the flame retardant. The mechanism on the cooperative effect between hydroquinone bis(di-2-methylphenyl phosphate) (HMP), which is an effective flame retardant, and novolac phenol (NP) in acrylonitrile–butadiene–styrene (ABS) is investigated by TG–FTIR under air in this study. The TG–FTIR of ABS/HMP, ABS/HMP/NP and ABS/NP are discussed carefully as well as their semi-quantitative analyses. The semi-quantitative analysis results of TG–FTIR show that ABS/HMP, ABS/HMP/NP and ABS/NP decompose in a two-step process. The first step is mainly the process of thermal degradation, macromolecules being decomposed into micromolecules containing many functional groups such as $ C_{Ar} $–H, –$ CH_{2} $–, –OH, P–O–$ C_{Ar} $. The second step is mainly the process of combustion, the layer of carbon being further oxidized into carbon dioxide, water and alkyne. The residue of ABS/HMP/NP is the highest as well as its temperature at which the maximum of mass loss rate occurs. Furthermore, the comparison of their semi-quantitative analyses indicates that NP could absorb parts of micromolecules containing the functional groups of –OH, $ CH_{2} $– and $ C_{Ar} $–H, contributing to the formation of carbon layer, and HMP slows down the degradation of the carbon layer, achieving the cooperative effect. TG–FTIR Mechanism Cooperative flame Gu, Zhanyong aut Yang, Xiushan aut Zhang, Zhiye aut Wang, Xinlong aut Chen, Xiaodong aut Yang, Lin aut Enthalten in Journal of thermal analysis and calorimetry Springer Netherlands, 1998 129(2017), 1 vom: 04. Feb., Seite 303-314 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:129 year:2017 number:1 day:04 month:02 pages:303-314 https://doi.org/10.1007/s10973-017-6111-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 129 2017 1 04 02 303-314 |
| spelling |
10.1007/s10973-017-6111-0 doi (DE-627)OLC2049854269 (DE-He213)s10973-017-6111-0-p DE-627 ger DE-627 rakwb eng 660 VZ Yang, Zhiyi verfasserin aut The mechanism study on the cooperative flame resistance effect between HMP and NP in ABS by TG–FTIR 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2017 Abstract Thermogravimetry (TG) coupled with Fourier transform infrared spectroscopy (FTIR) (TG–FTIR) is an effective tool on studying the mechanism of the flame retardant. The mechanism on the cooperative effect between hydroquinone bis(di-2-methylphenyl phosphate) (HMP), which is an effective flame retardant, and novolac phenol (NP) in acrylonitrile–butadiene–styrene (ABS) is investigated by TG–FTIR under air in this study. The TG–FTIR of ABS/HMP, ABS/HMP/NP and ABS/NP are discussed carefully as well as their semi-quantitative analyses. The semi-quantitative analysis results of TG–FTIR show that ABS/HMP, ABS/HMP/NP and ABS/NP decompose in a two-step process. The first step is mainly the process of thermal degradation, macromolecules being decomposed into micromolecules containing many functional groups such as $ C_{Ar} $–H, –$ CH_{2} $–, –OH, P–O–$ C_{Ar} $. The second step is mainly the process of combustion, the layer of carbon being further oxidized into carbon dioxide, water and alkyne. The residue of ABS/HMP/NP is the highest as well as its temperature at which the maximum of mass loss rate occurs. Furthermore, the comparison of their semi-quantitative analyses indicates that NP could absorb parts of micromolecules containing the functional groups of –OH, $ CH_{2} $– and $ C_{Ar} $–H, contributing to the formation of carbon layer, and HMP slows down the degradation of the carbon layer, achieving the cooperative effect. TG–FTIR Mechanism Cooperative flame Gu, Zhanyong aut Yang, Xiushan aut Zhang, Zhiye aut Wang, Xinlong aut Chen, Xiaodong aut Yang, Lin aut Enthalten in Journal of thermal analysis and calorimetry Springer Netherlands, 1998 129(2017), 1 vom: 04. Feb., Seite 303-314 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:129 year:2017 number:1 day:04 month:02 pages:303-314 https://doi.org/10.1007/s10973-017-6111-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 129 2017 1 04 02 303-314 |
| allfields_unstemmed |
10.1007/s10973-017-6111-0 doi (DE-627)OLC2049854269 (DE-He213)s10973-017-6111-0-p DE-627 ger DE-627 rakwb eng 660 VZ Yang, Zhiyi verfasserin aut The mechanism study on the cooperative flame resistance effect between HMP and NP in ABS by TG–FTIR 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2017 Abstract Thermogravimetry (TG) coupled with Fourier transform infrared spectroscopy (FTIR) (TG–FTIR) is an effective tool on studying the mechanism of the flame retardant. The mechanism on the cooperative effect between hydroquinone bis(di-2-methylphenyl phosphate) (HMP), which is an effective flame retardant, and novolac phenol (NP) in acrylonitrile–butadiene–styrene (ABS) is investigated by TG–FTIR under air in this study. The TG–FTIR of ABS/HMP, ABS/HMP/NP and ABS/NP are discussed carefully as well as their semi-quantitative analyses. The semi-quantitative analysis results of TG–FTIR show that ABS/HMP, ABS/HMP/NP and ABS/NP decompose in a two-step process. The first step is mainly the process of thermal degradation, macromolecules being decomposed into micromolecules containing many functional groups such as $ C_{Ar} $–H, –$ CH_{2} $–, –OH, P–O–$ C_{Ar} $. The second step is mainly the process of combustion, the layer of carbon being further oxidized into carbon dioxide, water and alkyne. The residue of ABS/HMP/NP is the highest as well as its temperature at which the maximum of mass loss rate occurs. Furthermore, the comparison of their semi-quantitative analyses indicates that NP could absorb parts of micromolecules containing the functional groups of –OH, $ CH_{2} $– and $ C_{Ar} $–H, contributing to the formation of carbon layer, and HMP slows down the degradation of the carbon layer, achieving the cooperative effect. TG–FTIR Mechanism Cooperative flame Gu, Zhanyong aut Yang, Xiushan aut Zhang, Zhiye aut Wang, Xinlong aut Chen, Xiaodong aut Yang, Lin aut Enthalten in Journal of thermal analysis and calorimetry Springer Netherlands, 1998 129(2017), 1 vom: 04. Feb., Seite 303-314 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:129 year:2017 number:1 day:04 month:02 pages:303-314 https://doi.org/10.1007/s10973-017-6111-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 129 2017 1 04 02 303-314 |
| allfieldsGer |
10.1007/s10973-017-6111-0 doi (DE-627)OLC2049854269 (DE-He213)s10973-017-6111-0-p DE-627 ger DE-627 rakwb eng 660 VZ Yang, Zhiyi verfasserin aut The mechanism study on the cooperative flame resistance effect between HMP and NP in ABS by TG–FTIR 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2017 Abstract Thermogravimetry (TG) coupled with Fourier transform infrared spectroscopy (FTIR) (TG–FTIR) is an effective tool on studying the mechanism of the flame retardant. The mechanism on the cooperative effect between hydroquinone bis(di-2-methylphenyl phosphate) (HMP), which is an effective flame retardant, and novolac phenol (NP) in acrylonitrile–butadiene–styrene (ABS) is investigated by TG–FTIR under air in this study. The TG–FTIR of ABS/HMP, ABS/HMP/NP and ABS/NP are discussed carefully as well as their semi-quantitative analyses. The semi-quantitative analysis results of TG–FTIR show that ABS/HMP, ABS/HMP/NP and ABS/NP decompose in a two-step process. The first step is mainly the process of thermal degradation, macromolecules being decomposed into micromolecules containing many functional groups such as $ C_{Ar} $–H, –$ CH_{2} $–, –OH, P–O–$ C_{Ar} $. The second step is mainly the process of combustion, the layer of carbon being further oxidized into carbon dioxide, water and alkyne. The residue of ABS/HMP/NP is the highest as well as its temperature at which the maximum of mass loss rate occurs. Furthermore, the comparison of their semi-quantitative analyses indicates that NP could absorb parts of micromolecules containing the functional groups of –OH, $ CH_{2} $– and $ C_{Ar} $–H, contributing to the formation of carbon layer, and HMP slows down the degradation of the carbon layer, achieving the cooperative effect. TG–FTIR Mechanism Cooperative flame Gu, Zhanyong aut Yang, Xiushan aut Zhang, Zhiye aut Wang, Xinlong aut Chen, Xiaodong aut Yang, Lin aut Enthalten in Journal of thermal analysis and calorimetry Springer Netherlands, 1998 129(2017), 1 vom: 04. Feb., Seite 303-314 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:129 year:2017 number:1 day:04 month:02 pages:303-314 https://doi.org/10.1007/s10973-017-6111-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 129 2017 1 04 02 303-314 |
| allfieldsSound |
10.1007/s10973-017-6111-0 doi (DE-627)OLC2049854269 (DE-He213)s10973-017-6111-0-p DE-627 ger DE-627 rakwb eng 660 VZ Yang, Zhiyi verfasserin aut The mechanism study on the cooperative flame resistance effect between HMP and NP in ABS by TG–FTIR 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Akadémiai Kiadó, Budapest, Hungary 2017 Abstract Thermogravimetry (TG) coupled with Fourier transform infrared spectroscopy (FTIR) (TG–FTIR) is an effective tool on studying the mechanism of the flame retardant. The mechanism on the cooperative effect between hydroquinone bis(di-2-methylphenyl phosphate) (HMP), which is an effective flame retardant, and novolac phenol (NP) in acrylonitrile–butadiene–styrene (ABS) is investigated by TG–FTIR under air in this study. The TG–FTIR of ABS/HMP, ABS/HMP/NP and ABS/NP are discussed carefully as well as their semi-quantitative analyses. The semi-quantitative analysis results of TG–FTIR show that ABS/HMP, ABS/HMP/NP and ABS/NP decompose in a two-step process. The first step is mainly the process of thermal degradation, macromolecules being decomposed into micromolecules containing many functional groups such as $ C_{Ar} $–H, –$ CH_{2} $–, –OH, P–O–$ C_{Ar} $. The second step is mainly the process of combustion, the layer of carbon being further oxidized into carbon dioxide, water and alkyne. The residue of ABS/HMP/NP is the highest as well as its temperature at which the maximum of mass loss rate occurs. Furthermore, the comparison of their semi-quantitative analyses indicates that NP could absorb parts of micromolecules containing the functional groups of –OH, $ CH_{2} $– and $ C_{Ar} $–H, contributing to the formation of carbon layer, and HMP slows down the degradation of the carbon layer, achieving the cooperative effect. TG–FTIR Mechanism Cooperative flame Gu, Zhanyong aut Yang, Xiushan aut Zhang, Zhiye aut Wang, Xinlong aut Chen, Xiaodong aut Yang, Lin aut Enthalten in Journal of thermal analysis and calorimetry Springer Netherlands, 1998 129(2017), 1 vom: 04. Feb., Seite 303-314 (DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 1388-6150 nnns volume:129 year:2017 number:1 day:04 month:02 pages:303-314 https://doi.org/10.1007/s10973-017-6111-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 AR 129 2017 1 04 02 303-314 |
| language |
English |
| source |
Enthalten in Journal of thermal analysis and calorimetry 129(2017), 1 vom: 04. Feb., Seite 303-314 volume:129 year:2017 number:1 day:04 month:02 pages:303-314 |
| sourceStr |
Enthalten in Journal of thermal analysis and calorimetry 129(2017), 1 vom: 04. Feb., Seite 303-314 volume:129 year:2017 number:1 day:04 month:02 pages:303-314 |
| format_phy_str_mv |
Article |
| institution |
findex.gbv.de |
| topic_facet |
TG–FTIR Mechanism Cooperative flame |
| dewey-raw |
660 |
| isfreeaccess_bool |
false |
| container_title |
Journal of thermal analysis and calorimetry |
| authorswithroles_txt_mv |
Yang, Zhiyi @@aut@@ Gu, Zhanyong @@aut@@ Yang, Xiushan @@aut@@ Zhang, Zhiye @@aut@@ Wang, Xinlong @@aut@@ Chen, Xiaodong @@aut@@ Yang, Lin @@aut@@ |
| publishDateDaySort_date |
2017-02-04T00:00:00Z |
| hierarchy_top_id |
244148767 |
| dewey-sort |
3660 |
| id |
OLC2049854269 |
| language_de |
englisch |
| fullrecord |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">OLC2049854269</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230503170231.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">200820s2017 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10973-017-6111-0</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC2049854269</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-He213)s10973-017-6111-0-p</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">660</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Yang, Zhiyi</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">The mechanism study on the cooperative flame resistance effect between HMP and NP in ABS by TG–FTIR</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2017</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Akadémiai Kiadó, Budapest, Hungary 2017</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Thermogravimetry (TG) coupled with Fourier transform infrared spectroscopy (FTIR) (TG–FTIR) is an effective tool on studying the mechanism of the flame retardant. The mechanism on the cooperative effect between hydroquinone bis(di-2-methylphenyl phosphate) (HMP), which is an effective flame retardant, and novolac phenol (NP) in acrylonitrile–butadiene–styrene (ABS) is investigated by TG–FTIR under air in this study. The TG–FTIR of ABS/HMP, ABS/HMP/NP and ABS/NP are discussed carefully as well as their semi-quantitative analyses. The semi-quantitative analysis results of TG–FTIR show that ABS/HMP, ABS/HMP/NP and ABS/NP decompose in a two-step process. The first step is mainly the process of thermal degradation, macromolecules being decomposed into micromolecules containing many functional groups such as $ C_{Ar} $–H, –$ CH_{2} $–, –OH, P–O–$ C_{Ar} $. The second step is mainly the process of combustion, the layer of carbon being further oxidized into carbon dioxide, water and alkyne. The residue of ABS/HMP/NP is the highest as well as its temperature at which the maximum of mass loss rate occurs. Furthermore, the comparison of their semi-quantitative analyses indicates that NP could absorb parts of micromolecules containing the functional groups of –OH, $ CH_{2} $– and $ C_{Ar} $–H, contributing to the formation of carbon layer, and HMP slows down the degradation of the carbon layer, achieving the cooperative effect.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">TG–FTIR</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Mechanism</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Cooperative flame</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Gu, Zhanyong</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Yang, Xiushan</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhang, Zhiye</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wang, Xinlong</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Chen, Xiaodong</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Yang, Lin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of thermal analysis and calorimetry</subfield><subfield code="d">Springer Netherlands, 1998</subfield><subfield code="g">129(2017), 1 vom: 04. Feb., Seite 303-314</subfield><subfield code="w">(DE-627)244148767</subfield><subfield code="w">(DE-600)1429493-X</subfield><subfield code="w">(DE-576)066397693</subfield><subfield code="x">1388-6150</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:129</subfield><subfield code="g">year:2017</subfield><subfield code="g">number:1</subfield><subfield code="g">day:04</subfield><subfield code="g">month:02</subfield><subfield code="g">pages:303-314</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1007/s10973-017-6111-0</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-CHE</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">129</subfield><subfield code="j">2017</subfield><subfield code="e">1</subfield><subfield code="b">04</subfield><subfield code="c">02</subfield><subfield code="h">303-314</subfield></datafield></record></collection>
|
| author |
Yang, Zhiyi |
| spellingShingle |
Yang, Zhiyi ddc 660 misc TG–FTIR misc Mechanism misc Cooperative flame The mechanism study on the cooperative flame resistance effect between HMP and NP in ABS by TG–FTIR |
| authorStr |
Yang, Zhiyi |
| ppnlink_with_tag_str_mv |
@@773@@(DE-627)244148767 |
| format |
Article |
| dewey-ones |
660 - Chemical engineering |
| delete_txt_mv |
keep |
| author_role |
aut aut aut aut aut aut aut |
| collection |
OLC |
| remote_str |
false |
| illustrated |
Not Illustrated |
| issn |
1388-6150 |
| topic_title |
660 VZ The mechanism study on the cooperative flame resistance effect between HMP and NP in ABS by TG–FTIR TG–FTIR Mechanism Cooperative flame |
| topic |
ddc 660 misc TG–FTIR misc Mechanism misc Cooperative flame |
| topic_unstemmed |
ddc 660 misc TG–FTIR misc Mechanism misc Cooperative flame |
| topic_browse |
ddc 660 misc TG–FTIR misc Mechanism misc Cooperative flame |
| format_facet |
Aufsätze Gedruckte Aufsätze |
| format_main_str_mv |
Text Zeitschrift/Artikel |
| carriertype_str_mv |
nc |
| hierarchy_parent_title |
Journal of thermal analysis and calorimetry |
| hierarchy_parent_id |
244148767 |
| dewey-tens |
660 - Chemical engineering |
| hierarchy_top_title |
Journal of thermal analysis and calorimetry |
| isfreeaccess_txt |
false |
| familylinks_str_mv |
(DE-627)244148767 (DE-600)1429493-X (DE-576)066397693 |
| title |
The mechanism study on the cooperative flame resistance effect between HMP and NP in ABS by TG–FTIR |
| ctrlnum |
(DE-627)OLC2049854269 (DE-He213)s10973-017-6111-0-p |
| title_full |
The mechanism study on the cooperative flame resistance effect between HMP and NP in ABS by TG–FTIR |
| author_sort |
Yang, Zhiyi |
| journal |
Journal of thermal analysis and calorimetry |
| journalStr |
Journal of thermal analysis and calorimetry |
| lang_code |
eng |
| isOA_bool |
false |
| dewey-hundreds |
600 - Technology |
| recordtype |
marc |
| publishDateSort |
2017 |
| contenttype_str_mv |
txt |
| container_start_page |
303 |
| author_browse |
Yang, Zhiyi Gu, Zhanyong Yang, Xiushan Zhang, Zhiye Wang, Xinlong Chen, Xiaodong Yang, Lin |
| container_volume |
129 |
| class |
660 VZ |
| format_se |
Aufsätze |
| author-letter |
Yang, Zhiyi |
| doi_str_mv |
10.1007/s10973-017-6111-0 |
| dewey-full |
660 |
| title_sort |
the mechanism study on the cooperative flame resistance effect between hmp and np in abs by tg–ftir |
| title_auth |
The mechanism study on the cooperative flame resistance effect between HMP and NP in ABS by TG–FTIR |
| abstract |
Abstract Thermogravimetry (TG) coupled with Fourier transform infrared spectroscopy (FTIR) (TG–FTIR) is an effective tool on studying the mechanism of the flame retardant. The mechanism on the cooperative effect between hydroquinone bis(di-2-methylphenyl phosphate) (HMP), which is an effective flame retardant, and novolac phenol (NP) in acrylonitrile–butadiene–styrene (ABS) is investigated by TG–FTIR under air in this study. The TG–FTIR of ABS/HMP, ABS/HMP/NP and ABS/NP are discussed carefully as well as their semi-quantitative analyses. The semi-quantitative analysis results of TG–FTIR show that ABS/HMP, ABS/HMP/NP and ABS/NP decompose in a two-step process. The first step is mainly the process of thermal degradation, macromolecules being decomposed into micromolecules containing many functional groups such as $ C_{Ar} $–H, –$ CH_{2} $–, –OH, P–O–$ C_{Ar} $. The second step is mainly the process of combustion, the layer of carbon being further oxidized into carbon dioxide, water and alkyne. The residue of ABS/HMP/NP is the highest as well as its temperature at which the maximum of mass loss rate occurs. Furthermore, the comparison of their semi-quantitative analyses indicates that NP could absorb parts of micromolecules containing the functional groups of –OH, $ CH_{2} $– and $ C_{Ar} $–H, contributing to the formation of carbon layer, and HMP slows down the degradation of the carbon layer, achieving the cooperative effect. © Akadémiai Kiadó, Budapest, Hungary 2017 |
| abstractGer |
Abstract Thermogravimetry (TG) coupled with Fourier transform infrared spectroscopy (FTIR) (TG–FTIR) is an effective tool on studying the mechanism of the flame retardant. The mechanism on the cooperative effect between hydroquinone bis(di-2-methylphenyl phosphate) (HMP), which is an effective flame retardant, and novolac phenol (NP) in acrylonitrile–butadiene–styrene (ABS) is investigated by TG–FTIR under air in this study. The TG–FTIR of ABS/HMP, ABS/HMP/NP and ABS/NP are discussed carefully as well as their semi-quantitative analyses. The semi-quantitative analysis results of TG–FTIR show that ABS/HMP, ABS/HMP/NP and ABS/NP decompose in a two-step process. The first step is mainly the process of thermal degradation, macromolecules being decomposed into micromolecules containing many functional groups such as $ C_{Ar} $–H, –$ CH_{2} $–, –OH, P–O–$ C_{Ar} $. The second step is mainly the process of combustion, the layer of carbon being further oxidized into carbon dioxide, water and alkyne. The residue of ABS/HMP/NP is the highest as well as its temperature at which the maximum of mass loss rate occurs. Furthermore, the comparison of their semi-quantitative analyses indicates that NP could absorb parts of micromolecules containing the functional groups of –OH, $ CH_{2} $– and $ C_{Ar} $–H, contributing to the formation of carbon layer, and HMP slows down the degradation of the carbon layer, achieving the cooperative effect. © Akadémiai Kiadó, Budapest, Hungary 2017 |
| abstract_unstemmed |
Abstract Thermogravimetry (TG) coupled with Fourier transform infrared spectroscopy (FTIR) (TG–FTIR) is an effective tool on studying the mechanism of the flame retardant. The mechanism on the cooperative effect between hydroquinone bis(di-2-methylphenyl phosphate) (HMP), which is an effective flame retardant, and novolac phenol (NP) in acrylonitrile–butadiene–styrene (ABS) is investigated by TG–FTIR under air in this study. The TG–FTIR of ABS/HMP, ABS/HMP/NP and ABS/NP are discussed carefully as well as their semi-quantitative analyses. The semi-quantitative analysis results of TG–FTIR show that ABS/HMP, ABS/HMP/NP and ABS/NP decompose in a two-step process. The first step is mainly the process of thermal degradation, macromolecules being decomposed into micromolecules containing many functional groups such as $ C_{Ar} $–H, –$ CH_{2} $–, –OH, P–O–$ C_{Ar} $. The second step is mainly the process of combustion, the layer of carbon being further oxidized into carbon dioxide, water and alkyne. The residue of ABS/HMP/NP is the highest as well as its temperature at which the maximum of mass loss rate occurs. Furthermore, the comparison of their semi-quantitative analyses indicates that NP could absorb parts of micromolecules containing the functional groups of –OH, $ CH_{2} $– and $ C_{Ar} $–H, contributing to the formation of carbon layer, and HMP slows down the degradation of the carbon layer, achieving the cooperative effect. © Akadémiai Kiadó, Budapest, Hungary 2017 |
| collection_details |
GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 |
| container_issue |
1 |
| title_short |
The mechanism study on the cooperative flame resistance effect between HMP and NP in ABS by TG–FTIR |
| url |
https://doi.org/10.1007/s10973-017-6111-0 |
| remote_bool |
false |
| author2 |
Gu, Zhanyong Yang, Xiushan Zhang, Zhiye Wang, Xinlong Chen, Xiaodong Yang, Lin |
| author2Str |
Gu, Zhanyong Yang, Xiushan Zhang, Zhiye Wang, Xinlong Chen, Xiaodong Yang, Lin |
| ppnlink |
244148767 |
| mediatype_str_mv |
n |
| isOA_txt |
false |
| hochschulschrift_bool |
false |
| doi_str |
10.1007/s10973-017-6111-0 |
| up_date |
2024-07-04T00:16:23.386Z |
| _version_ |
1803605438248255488 |
| fullrecord_marcxml |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">OLC2049854269</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230503170231.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">200820s2017 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10973-017-6111-0</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC2049854269</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-He213)s10973-017-6111-0-p</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">660</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Yang, Zhiyi</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">The mechanism study on the cooperative flame resistance effect between HMP and NP in ABS by TG–FTIR</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2017</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Akadémiai Kiadó, Budapest, Hungary 2017</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Thermogravimetry (TG) coupled with Fourier transform infrared spectroscopy (FTIR) (TG–FTIR) is an effective tool on studying the mechanism of the flame retardant. The mechanism on the cooperative effect between hydroquinone bis(di-2-methylphenyl phosphate) (HMP), which is an effective flame retardant, and novolac phenol (NP) in acrylonitrile–butadiene–styrene (ABS) is investigated by TG–FTIR under air in this study. The TG–FTIR of ABS/HMP, ABS/HMP/NP and ABS/NP are discussed carefully as well as their semi-quantitative analyses. The semi-quantitative analysis results of TG–FTIR show that ABS/HMP, ABS/HMP/NP and ABS/NP decompose in a two-step process. The first step is mainly the process of thermal degradation, macromolecules being decomposed into micromolecules containing many functional groups such as $ C_{Ar} $–H, –$ CH_{2} $–, –OH, P–O–$ C_{Ar} $. The second step is mainly the process of combustion, the layer of carbon being further oxidized into carbon dioxide, water and alkyne. The residue of ABS/HMP/NP is the highest as well as its temperature at which the maximum of mass loss rate occurs. Furthermore, the comparison of their semi-quantitative analyses indicates that NP could absorb parts of micromolecules containing the functional groups of –OH, $ CH_{2} $– and $ C_{Ar} $–H, contributing to the formation of carbon layer, and HMP slows down the degradation of the carbon layer, achieving the cooperative effect.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">TG–FTIR</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Mechanism</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Cooperative flame</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Gu, Zhanyong</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Yang, Xiushan</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhang, Zhiye</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wang, Xinlong</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Chen, Xiaodong</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Yang, Lin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of thermal analysis and calorimetry</subfield><subfield code="d">Springer Netherlands, 1998</subfield><subfield code="g">129(2017), 1 vom: 04. Feb., Seite 303-314</subfield><subfield code="w">(DE-627)244148767</subfield><subfield code="w">(DE-600)1429493-X</subfield><subfield code="w">(DE-576)066397693</subfield><subfield code="x">1388-6150</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:129</subfield><subfield code="g">year:2017</subfield><subfield code="g">number:1</subfield><subfield code="g">day:04</subfield><subfield code="g">month:02</subfield><subfield code="g">pages:303-314</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1007/s10973-017-6111-0</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-CHE</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">129</subfield><subfield code="j">2017</subfield><subfield code="e">1</subfield><subfield code="b">04</subfield><subfield code="c">02</subfield><subfield code="h">303-314</subfield></datafield></record></collection>
|
| score |
7.401078 |