Thermodynamic stability of palladium alloys: Part I: The palladium-niobium system
Abstract The palladium activities of 12 palladium-niobium alloys (compositions from 60Pd40Nb to 97Pd3Nb) have been determined experimentally with a twin-chamber Knudsen cell mass spectrometer between 1450 and 1750 K. From the measured $ a_{Pd} $ data, other relevant thermo-dynamic properties are cal...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Stickney, M. J. [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1991 |
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| Schlagwörter: |
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| Anmerkung: |
© The Minerals, Metals and Materials Society, and ASM International 1991 |
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| Übergeordnetes Werk: |
Enthalten in: Metallurgical transactions. A, Physical metallurgy and materials science - Springer-Verlag, 1975, 22(1991), 9 vom: Sept., Seite 1937-1943 |
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| Übergeordnetes Werk: |
volume:22 ; year:1991 ; number:9 ; month:09 ; pages:1937-1943 |
| Links: |
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| DOI / URN: |
10.1007/BF02669861 |
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| Katalog-ID: |
OLC2053972866 |
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| 520 | |a Abstract The palladium activities of 12 palladium-niobium alloys (compositions from 60Pd40Nb to 97Pd3Nb) have been determined experimentally with a twin-chamber Knudsen cell mass spectrometer between 1450 and 1750 K. From the measured $ a_{Pd} $ data, other relevant thermo-dynamic properties are calculated. The $ ΔG_{f} $o and $ ΔH_{f} $o of Pd-Nb alloys thus obtained are com-pared with the published values estimated on the basis of empirical models. The results of the present work show a strong attractive interaction in the solid state between the palladium atoms and the niobium atoms. The measured palladium activities show a strong negative deviation from the ideal solution behavior. | ||
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10.1007/BF02669861 doi (DE-627)OLC2053972866 (DE-He213)BF02669861-p DE-627 ger DE-627 rakwb eng 670 530 VZ Stickney, M. J. verfasserin aut Thermodynamic stability of palladium alloys: Part I: The palladium-niobium system 1991 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Minerals, Metals and Materials Society, and ASM International 1991 Abstract The palladium activities of 12 palladium-niobium alloys (compositions from 60Pd40Nb to 97Pd3Nb) have been determined experimentally with a twin-chamber Knudsen cell mass spectrometer between 1450 and 1750 K. From the measured $ a_{Pd} $ data, other relevant thermo-dynamic properties are calculated. The $ ΔG_{f} $o and $ ΔH_{f} $o of Pd-Nb alloys thus obtained are com-pared with the published values estimated on the basis of empirical models. The results of the present work show a strong attractive interaction in the solid state between the palladium atoms and the niobium atoms. The measured palladium activities show a strong negative deviation from the ideal solution behavior. Palladium Metallurgical Transaction Alloy Sample Palladium Alloy Surface Depletion Chandrasekharaiah, M. S. aut Gingerich, K. A. aut Speed, J. A. aut Enthalten in Metallurgical transactions. A, Physical metallurgy and materials science Springer-Verlag, 1975 22(1991), 9 vom: Sept., Seite 1937-1943 (DE-627)129429058 (DE-600)192156-3 (DE-576)01480204X 0026-086X nnns volume:22 year:1991 number:9 month:09 pages:1937-1943 https://doi.org/10.1007/BF02669861 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_11 GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_62 GBV_ILN_70 GBV_ILN_602 GBV_ILN_2004 GBV_ILN_2015 GBV_ILN_2016 GBV_ILN_2020 GBV_ILN_2027 GBV_ILN_4035 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4319 GBV_ILN_4323 GBV_ILN_4700 AR 22 1991 9 09 1937-1943 |
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10.1007/BF02669861 doi (DE-627)OLC2053972866 (DE-He213)BF02669861-p DE-627 ger DE-627 rakwb eng 670 530 VZ Stickney, M. J. verfasserin aut Thermodynamic stability of palladium alloys: Part I: The palladium-niobium system 1991 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Minerals, Metals and Materials Society, and ASM International 1991 Abstract The palladium activities of 12 palladium-niobium alloys (compositions from 60Pd40Nb to 97Pd3Nb) have been determined experimentally with a twin-chamber Knudsen cell mass spectrometer between 1450 and 1750 K. From the measured $ a_{Pd} $ data, other relevant thermo-dynamic properties are calculated. The $ ΔG_{f} $o and $ ΔH_{f} $o of Pd-Nb alloys thus obtained are com-pared with the published values estimated on the basis of empirical models. The results of the present work show a strong attractive interaction in the solid state between the palladium atoms and the niobium atoms. The measured palladium activities show a strong negative deviation from the ideal solution behavior. Palladium Metallurgical Transaction Alloy Sample Palladium Alloy Surface Depletion Chandrasekharaiah, M. S. aut Gingerich, K. A. aut Speed, J. A. aut Enthalten in Metallurgical transactions. A, Physical metallurgy and materials science Springer-Verlag, 1975 22(1991), 9 vom: Sept., Seite 1937-1943 (DE-627)129429058 (DE-600)192156-3 (DE-576)01480204X 0026-086X nnns volume:22 year:1991 number:9 month:09 pages:1937-1943 https://doi.org/10.1007/BF02669861 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_11 GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_62 GBV_ILN_70 GBV_ILN_602 GBV_ILN_2004 GBV_ILN_2015 GBV_ILN_2016 GBV_ILN_2020 GBV_ILN_2027 GBV_ILN_4035 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4319 GBV_ILN_4323 GBV_ILN_4700 AR 22 1991 9 09 1937-1943 |
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10.1007/BF02669861 doi (DE-627)OLC2053972866 (DE-He213)BF02669861-p DE-627 ger DE-627 rakwb eng 670 530 VZ Stickney, M. J. verfasserin aut Thermodynamic stability of palladium alloys: Part I: The palladium-niobium system 1991 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Minerals, Metals and Materials Society, and ASM International 1991 Abstract The palladium activities of 12 palladium-niobium alloys (compositions from 60Pd40Nb to 97Pd3Nb) have been determined experimentally with a twin-chamber Knudsen cell mass spectrometer between 1450 and 1750 K. From the measured $ a_{Pd} $ data, other relevant thermo-dynamic properties are calculated. The $ ΔG_{f} $o and $ ΔH_{f} $o of Pd-Nb alloys thus obtained are com-pared with the published values estimated on the basis of empirical models. The results of the present work show a strong attractive interaction in the solid state between the palladium atoms and the niobium atoms. The measured palladium activities show a strong negative deviation from the ideal solution behavior. Palladium Metallurgical Transaction Alloy Sample Palladium Alloy Surface Depletion Chandrasekharaiah, M. S. aut Gingerich, K. A. aut Speed, J. A. aut Enthalten in Metallurgical transactions. A, Physical metallurgy and materials science Springer-Verlag, 1975 22(1991), 9 vom: Sept., Seite 1937-1943 (DE-627)129429058 (DE-600)192156-3 (DE-576)01480204X 0026-086X nnns volume:22 year:1991 number:9 month:09 pages:1937-1943 https://doi.org/10.1007/BF02669861 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_11 GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_62 GBV_ILN_70 GBV_ILN_602 GBV_ILN_2004 GBV_ILN_2015 GBV_ILN_2016 GBV_ILN_2020 GBV_ILN_2027 GBV_ILN_4035 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4319 GBV_ILN_4323 GBV_ILN_4700 AR 22 1991 9 09 1937-1943 |
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10.1007/BF02669861 doi (DE-627)OLC2053972866 (DE-He213)BF02669861-p DE-627 ger DE-627 rakwb eng 670 530 VZ Stickney, M. J. verfasserin aut Thermodynamic stability of palladium alloys: Part I: The palladium-niobium system 1991 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Minerals, Metals and Materials Society, and ASM International 1991 Abstract The palladium activities of 12 palladium-niobium alloys (compositions from 60Pd40Nb to 97Pd3Nb) have been determined experimentally with a twin-chamber Knudsen cell mass spectrometer between 1450 and 1750 K. From the measured $ a_{Pd} $ data, other relevant thermo-dynamic properties are calculated. The $ ΔG_{f} $o and $ ΔH_{f} $o of Pd-Nb alloys thus obtained are com-pared with the published values estimated on the basis of empirical models. The results of the present work show a strong attractive interaction in the solid state between the palladium atoms and the niobium atoms. The measured palladium activities show a strong negative deviation from the ideal solution behavior. Palladium Metallurgical Transaction Alloy Sample Palladium Alloy Surface Depletion Chandrasekharaiah, M. S. aut Gingerich, K. A. aut Speed, J. A. aut Enthalten in Metallurgical transactions. A, Physical metallurgy and materials science Springer-Verlag, 1975 22(1991), 9 vom: Sept., Seite 1937-1943 (DE-627)129429058 (DE-600)192156-3 (DE-576)01480204X 0026-086X nnns volume:22 year:1991 number:9 month:09 pages:1937-1943 https://doi.org/10.1007/BF02669861 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_11 GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_62 GBV_ILN_70 GBV_ILN_602 GBV_ILN_2004 GBV_ILN_2015 GBV_ILN_2016 GBV_ILN_2020 GBV_ILN_2027 GBV_ILN_4035 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4319 GBV_ILN_4323 GBV_ILN_4700 AR 22 1991 9 09 1937-1943 |
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10.1007/BF02669861 doi (DE-627)OLC2053972866 (DE-He213)BF02669861-p DE-627 ger DE-627 rakwb eng 670 530 VZ Stickney, M. J. verfasserin aut Thermodynamic stability of palladium alloys: Part I: The palladium-niobium system 1991 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Minerals, Metals and Materials Society, and ASM International 1991 Abstract The palladium activities of 12 palladium-niobium alloys (compositions from 60Pd40Nb to 97Pd3Nb) have been determined experimentally with a twin-chamber Knudsen cell mass spectrometer between 1450 and 1750 K. From the measured $ a_{Pd} $ data, other relevant thermo-dynamic properties are calculated. The $ ΔG_{f} $o and $ ΔH_{f} $o of Pd-Nb alloys thus obtained are com-pared with the published values estimated on the basis of empirical models. The results of the present work show a strong attractive interaction in the solid state between the palladium atoms and the niobium atoms. The measured palladium activities show a strong negative deviation from the ideal solution behavior. Palladium Metallurgical Transaction Alloy Sample Palladium Alloy Surface Depletion Chandrasekharaiah, M. S. aut Gingerich, K. A. aut Speed, J. A. aut Enthalten in Metallurgical transactions. A, Physical metallurgy and materials science Springer-Verlag, 1975 22(1991), 9 vom: Sept., Seite 1937-1943 (DE-627)129429058 (DE-600)192156-3 (DE-576)01480204X 0026-086X nnns volume:22 year:1991 number:9 month:09 pages:1937-1943 https://doi.org/10.1007/BF02669861 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_11 GBV_ILN_20 GBV_ILN_21 GBV_ILN_23 GBV_ILN_30 GBV_ILN_62 GBV_ILN_70 GBV_ILN_602 GBV_ILN_2004 GBV_ILN_2015 GBV_ILN_2016 GBV_ILN_2020 GBV_ILN_2027 GBV_ILN_4035 GBV_ILN_4046 GBV_ILN_4082 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4319 GBV_ILN_4323 GBV_ILN_4700 AR 22 1991 9 09 1937-1943 |
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Stickney, M. J. |
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670 530 VZ Thermodynamic stability of palladium alloys: Part I: The palladium-niobium system Palladium Metallurgical Transaction Alloy Sample Palladium Alloy Surface Depletion |
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Thermodynamic stability of palladium alloys: Part I: The palladium-niobium system |
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Thermodynamic stability of palladium alloys: Part I: The palladium-niobium system |
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Metallurgical transactions. A, Physical metallurgy and materials science |
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Stickney, M. J. Chandrasekharaiah, M. S. Gingerich, K. A. Speed, J. A. |
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thermodynamic stability of palladium alloys: part i: the palladium-niobium system |
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Thermodynamic stability of palladium alloys: Part I: The palladium-niobium system |
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Abstract The palladium activities of 12 palladium-niobium alloys (compositions from 60Pd40Nb to 97Pd3Nb) have been determined experimentally with a twin-chamber Knudsen cell mass spectrometer between 1450 and 1750 K. From the measured $ a_{Pd} $ data, other relevant thermo-dynamic properties are calculated. The $ ΔG_{f} $o and $ ΔH_{f} $o of Pd-Nb alloys thus obtained are com-pared with the published values estimated on the basis of empirical models. The results of the present work show a strong attractive interaction in the solid state between the palladium atoms and the niobium atoms. The measured palladium activities show a strong negative deviation from the ideal solution behavior. © The Minerals, Metals and Materials Society, and ASM International 1991 |
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Abstract The palladium activities of 12 palladium-niobium alloys (compositions from 60Pd40Nb to 97Pd3Nb) have been determined experimentally with a twin-chamber Knudsen cell mass spectrometer between 1450 and 1750 K. From the measured $ a_{Pd} $ data, other relevant thermo-dynamic properties are calculated. The $ ΔG_{f} $o and $ ΔH_{f} $o of Pd-Nb alloys thus obtained are com-pared with the published values estimated on the basis of empirical models. The results of the present work show a strong attractive interaction in the solid state between the palladium atoms and the niobium atoms. The measured palladium activities show a strong negative deviation from the ideal solution behavior. © The Minerals, Metals and Materials Society, and ASM International 1991 |
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Abstract The palladium activities of 12 palladium-niobium alloys (compositions from 60Pd40Nb to 97Pd3Nb) have been determined experimentally with a twin-chamber Knudsen cell mass spectrometer between 1450 and 1750 K. From the measured $ a_{Pd} $ data, other relevant thermo-dynamic properties are calculated. The $ ΔG_{f} $o and $ ΔH_{f} $o of Pd-Nb alloys thus obtained are com-pared with the published values estimated on the basis of empirical models. The results of the present work show a strong attractive interaction in the solid state between the palladium atoms and the niobium atoms. The measured palladium activities show a strong negative deviation from the ideal solution behavior. © The Minerals, Metals and Materials Society, and ASM International 1991 |
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