Case reviews on the effect of microstructure on the corrosion behavior of austenitic alloys for processing and storage of nuclear waste
Abstract This article describes the corrosion behavior of special austenitic alloys for waste management applications. The special stainless steels have controlled levels of alloying and impurity elements and inclusion levels. It is shown that “active” inclusions and segregation of chromium along fl...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Kain, V. [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2005 |
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| Schlagwörter: |
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| Anmerkung: |
© ASM International & TMS-The Minerals, Metals and Materials Society 2005 |
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| Übergeordnetes Werk: |
Enthalten in: Metallurgical and materials transactions / A - Springer-Verlag, 1994, 36(2005), 5 vom: Mai, Seite 1075-1084 |
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| Übergeordnetes Werk: |
volume:36 ; year:2005 ; number:5 ; month:05 ; pages:1075-1084 |
| Links: |
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| DOI / URN: |
10.1007/s11661-005-0201-5 |
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OLC2054019291 |
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| 520 | |a Abstract This article describes the corrosion behavior of special austenitic alloys for waste management applications. The special stainless steels have controlled levels of alloying and impurity elements and inclusion levels. It is shown that “active” inclusions and segregation of chromium along flow lines accelerated IGC of nonsensitized stainless steels. Concentration of $ Cr^{+6} $ ions in the grooves of dissolved inclusions increased the potential to the transpassive region of the material, leading to accelerated attack. It is shown that a combination of cold working and controlled solution annealing resulted in a microstructure that resisted corrosion even after a sensitization heat treatment. This imparted extra resistance to corrosion by increasing the fraction of “random” grain boundaries above a threshold value. Randomization of grain boundaries made the stainless steels resistant to sensitization, IGC, and intergranular stress corrosion cracking (IGSCC) in even hot chloride environments. The increased corrosion resistance has been attributed to connectivity of random grain boundaries. The reaction mechanism between the molten glass and the material for process pot, alloy 690, during the vitrification process has been shown to result in depletion of chromium from the reacting surfaces. A comparison is drawn between the electrochemical behavior of alloys 33 and 22 in 1 M HCl at 65 °C. It is shown that a secondary phase formed during welding of alloy 33 impaired corrosion properties in the HCl environment. | ||
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10.1007/s11661-005-0201-5 doi (DE-627)OLC2054019291 (DE-He213)s11661-005-0201-5-p DE-627 ger DE-627 rakwb eng 670 530 VZ 19,1 ssgn Kain, V. verfasserin aut Case reviews on the effect of microstructure on the corrosion behavior of austenitic alloys for processing and storage of nuclear waste 2005 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © ASM International & TMS-The Minerals, Metals and Materials Society 2005 Abstract This article describes the corrosion behavior of special austenitic alloys for waste management applications. The special stainless steels have controlled levels of alloying and impurity elements and inclusion levels. It is shown that “active” inclusions and segregation of chromium along flow lines accelerated IGC of nonsensitized stainless steels. Concentration of $ Cr^{+6} $ ions in the grooves of dissolved inclusions increased the potential to the transpassive region of the material, leading to accelerated attack. It is shown that a combination of cold working and controlled solution annealing resulted in a microstructure that resisted corrosion even after a sensitization heat treatment. This imparted extra resistance to corrosion by increasing the fraction of “random” grain boundaries above a threshold value. Randomization of grain boundaries made the stainless steels resistant to sensitization, IGC, and intergranular stress corrosion cracking (IGSCC) in even hot chloride environments. The increased corrosion resistance has been attributed to connectivity of random grain boundaries. The reaction mechanism between the molten glass and the material for process pot, alloy 690, during the vitrification process has been shown to result in depletion of chromium from the reacting surfaces. A comparison is drawn between the electrochemical behavior of alloys 33 and 22 in 1 M HCl at 65 °C. It is shown that a secondary phase formed during welding of alloy 33 impaired corrosion properties in the HCl environment. Material Transaction Flow Line Chromium Carbide Molten Glass Orientation Imaging Microscopy Sengupta, P. aut De, P. K. aut Banerjee, S. aut Enthalten in Metallurgical and materials transactions / A Springer-Verlag, 1994 36(2005), 5 vom: Mai, Seite 1075-1084 (DE-627)171342011 (DE-600)1179415-X (DE-576)038876930 1073-5623 nnns volume:36 year:2005 number:5 month:05 pages:1075-1084 https://doi.org/10.1007/s11661-005-0201-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_20 GBV_ILN_23 GBV_ILN_30 GBV_ILN_62 GBV_ILN_70 GBV_ILN_602 GBV_ILN_2006 GBV_ILN_2020 GBV_ILN_2027 GBV_ILN_4116 GBV_ILN_4313 GBV_ILN_4316 GBV_ILN_4319 GBV_ILN_4700 AR 36 2005 5 05 1075-1084 |
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10.1007/s11661-005-0201-5 doi (DE-627)OLC2054019291 (DE-He213)s11661-005-0201-5-p DE-627 ger DE-627 rakwb eng 670 530 VZ 19,1 ssgn Kain, V. verfasserin aut Case reviews on the effect of microstructure on the corrosion behavior of austenitic alloys for processing and storage of nuclear waste 2005 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © ASM International & TMS-The Minerals, Metals and Materials Society 2005 Abstract This article describes the corrosion behavior of special austenitic alloys for waste management applications. The special stainless steels have controlled levels of alloying and impurity elements and inclusion levels. It is shown that “active” inclusions and segregation of chromium along flow lines accelerated IGC of nonsensitized stainless steels. Concentration of $ Cr^{+6} $ ions in the grooves of dissolved inclusions increased the potential to the transpassive region of the material, leading to accelerated attack. It is shown that a combination of cold working and controlled solution annealing resulted in a microstructure that resisted corrosion even after a sensitization heat treatment. This imparted extra resistance to corrosion by increasing the fraction of “random” grain boundaries above a threshold value. Randomization of grain boundaries made the stainless steels resistant to sensitization, IGC, and intergranular stress corrosion cracking (IGSCC) in even hot chloride environments. The increased corrosion resistance has been attributed to connectivity of random grain boundaries. The reaction mechanism between the molten glass and the material for process pot, alloy 690, during the vitrification process has been shown to result in depletion of chromium from the reacting surfaces. A comparison is drawn between the electrochemical behavior of alloys 33 and 22 in 1 M HCl at 65 °C. It is shown that a secondary phase formed during welding of alloy 33 impaired corrosion properties in the HCl environment. Material Transaction Flow Line Chromium Carbide Molten Glass Orientation Imaging Microscopy Sengupta, P. aut De, P. K. aut Banerjee, S. aut Enthalten in Metallurgical and materials transactions / A Springer-Verlag, 1994 36(2005), 5 vom: Mai, Seite 1075-1084 (DE-627)171342011 (DE-600)1179415-X (DE-576)038876930 1073-5623 nnns volume:36 year:2005 number:5 month:05 pages:1075-1084 https://doi.org/10.1007/s11661-005-0201-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_20 GBV_ILN_23 GBV_ILN_30 GBV_ILN_62 GBV_ILN_70 GBV_ILN_602 GBV_ILN_2006 GBV_ILN_2020 GBV_ILN_2027 GBV_ILN_4116 GBV_ILN_4313 GBV_ILN_4316 GBV_ILN_4319 GBV_ILN_4700 AR 36 2005 5 05 1075-1084 |
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10.1007/s11661-005-0201-5 doi (DE-627)OLC2054019291 (DE-He213)s11661-005-0201-5-p DE-627 ger DE-627 rakwb eng 670 530 VZ 19,1 ssgn Kain, V. verfasserin aut Case reviews on the effect of microstructure on the corrosion behavior of austenitic alloys for processing and storage of nuclear waste 2005 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © ASM International & TMS-The Minerals, Metals and Materials Society 2005 Abstract This article describes the corrosion behavior of special austenitic alloys for waste management applications. The special stainless steels have controlled levels of alloying and impurity elements and inclusion levels. It is shown that “active” inclusions and segregation of chromium along flow lines accelerated IGC of nonsensitized stainless steels. Concentration of $ Cr^{+6} $ ions in the grooves of dissolved inclusions increased the potential to the transpassive region of the material, leading to accelerated attack. It is shown that a combination of cold working and controlled solution annealing resulted in a microstructure that resisted corrosion even after a sensitization heat treatment. This imparted extra resistance to corrosion by increasing the fraction of “random” grain boundaries above a threshold value. Randomization of grain boundaries made the stainless steels resistant to sensitization, IGC, and intergranular stress corrosion cracking (IGSCC) in even hot chloride environments. The increased corrosion resistance has been attributed to connectivity of random grain boundaries. The reaction mechanism between the molten glass and the material for process pot, alloy 690, during the vitrification process has been shown to result in depletion of chromium from the reacting surfaces. A comparison is drawn between the electrochemical behavior of alloys 33 and 22 in 1 M HCl at 65 °C. It is shown that a secondary phase formed during welding of alloy 33 impaired corrosion properties in the HCl environment. Material Transaction Flow Line Chromium Carbide Molten Glass Orientation Imaging Microscopy Sengupta, P. aut De, P. K. aut Banerjee, S. aut Enthalten in Metallurgical and materials transactions / A Springer-Verlag, 1994 36(2005), 5 vom: Mai, Seite 1075-1084 (DE-627)171342011 (DE-600)1179415-X (DE-576)038876930 1073-5623 nnns volume:36 year:2005 number:5 month:05 pages:1075-1084 https://doi.org/10.1007/s11661-005-0201-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_20 GBV_ILN_23 GBV_ILN_30 GBV_ILN_62 GBV_ILN_70 GBV_ILN_602 GBV_ILN_2006 GBV_ILN_2020 GBV_ILN_2027 GBV_ILN_4116 GBV_ILN_4313 GBV_ILN_4316 GBV_ILN_4319 GBV_ILN_4700 AR 36 2005 5 05 1075-1084 |
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10.1007/s11661-005-0201-5 doi (DE-627)OLC2054019291 (DE-He213)s11661-005-0201-5-p DE-627 ger DE-627 rakwb eng 670 530 VZ 19,1 ssgn Kain, V. verfasserin aut Case reviews on the effect of microstructure on the corrosion behavior of austenitic alloys for processing and storage of nuclear waste 2005 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © ASM International & TMS-The Minerals, Metals and Materials Society 2005 Abstract This article describes the corrosion behavior of special austenitic alloys for waste management applications. The special stainless steels have controlled levels of alloying and impurity elements and inclusion levels. It is shown that “active” inclusions and segregation of chromium along flow lines accelerated IGC of nonsensitized stainless steels. Concentration of $ Cr^{+6} $ ions in the grooves of dissolved inclusions increased the potential to the transpassive region of the material, leading to accelerated attack. It is shown that a combination of cold working and controlled solution annealing resulted in a microstructure that resisted corrosion even after a sensitization heat treatment. This imparted extra resistance to corrosion by increasing the fraction of “random” grain boundaries above a threshold value. Randomization of grain boundaries made the stainless steels resistant to sensitization, IGC, and intergranular stress corrosion cracking (IGSCC) in even hot chloride environments. The increased corrosion resistance has been attributed to connectivity of random grain boundaries. The reaction mechanism between the molten glass and the material for process pot, alloy 690, during the vitrification process has been shown to result in depletion of chromium from the reacting surfaces. A comparison is drawn between the electrochemical behavior of alloys 33 and 22 in 1 M HCl at 65 °C. It is shown that a secondary phase formed during welding of alloy 33 impaired corrosion properties in the HCl environment. Material Transaction Flow Line Chromium Carbide Molten Glass Orientation Imaging Microscopy Sengupta, P. aut De, P. K. aut Banerjee, S. aut Enthalten in Metallurgical and materials transactions / A Springer-Verlag, 1994 36(2005), 5 vom: Mai, Seite 1075-1084 (DE-627)171342011 (DE-600)1179415-X (DE-576)038876930 1073-5623 nnns volume:36 year:2005 number:5 month:05 pages:1075-1084 https://doi.org/10.1007/s11661-005-0201-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_20 GBV_ILN_23 GBV_ILN_30 GBV_ILN_62 GBV_ILN_70 GBV_ILN_602 GBV_ILN_2006 GBV_ILN_2020 GBV_ILN_2027 GBV_ILN_4116 GBV_ILN_4313 GBV_ILN_4316 GBV_ILN_4319 GBV_ILN_4700 AR 36 2005 5 05 1075-1084 |
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10.1007/s11661-005-0201-5 doi (DE-627)OLC2054019291 (DE-He213)s11661-005-0201-5-p DE-627 ger DE-627 rakwb eng 670 530 VZ 19,1 ssgn Kain, V. verfasserin aut Case reviews on the effect of microstructure on the corrosion behavior of austenitic alloys for processing and storage of nuclear waste 2005 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © ASM International & TMS-The Minerals, Metals and Materials Society 2005 Abstract This article describes the corrosion behavior of special austenitic alloys for waste management applications. The special stainless steels have controlled levels of alloying and impurity elements and inclusion levels. It is shown that “active” inclusions and segregation of chromium along flow lines accelerated IGC of nonsensitized stainless steels. Concentration of $ Cr^{+6} $ ions in the grooves of dissolved inclusions increased the potential to the transpassive region of the material, leading to accelerated attack. It is shown that a combination of cold working and controlled solution annealing resulted in a microstructure that resisted corrosion even after a sensitization heat treatment. This imparted extra resistance to corrosion by increasing the fraction of “random” grain boundaries above a threshold value. Randomization of grain boundaries made the stainless steels resistant to sensitization, IGC, and intergranular stress corrosion cracking (IGSCC) in even hot chloride environments. The increased corrosion resistance has been attributed to connectivity of random grain boundaries. The reaction mechanism between the molten glass and the material for process pot, alloy 690, during the vitrification process has been shown to result in depletion of chromium from the reacting surfaces. A comparison is drawn between the electrochemical behavior of alloys 33 and 22 in 1 M HCl at 65 °C. It is shown that a secondary phase formed during welding of alloy 33 impaired corrosion properties in the HCl environment. Material Transaction Flow Line Chromium Carbide Molten Glass Orientation Imaging Microscopy Sengupta, P. aut De, P. K. aut Banerjee, S. aut Enthalten in Metallurgical and materials transactions / A Springer-Verlag, 1994 36(2005), 5 vom: Mai, Seite 1075-1084 (DE-627)171342011 (DE-600)1179415-X (DE-576)038876930 1073-5623 nnns volume:36 year:2005 number:5 month:05 pages:1075-1084 https://doi.org/10.1007/s11661-005-0201-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_20 GBV_ILN_23 GBV_ILN_30 GBV_ILN_62 GBV_ILN_70 GBV_ILN_602 GBV_ILN_2006 GBV_ILN_2020 GBV_ILN_2027 GBV_ILN_4116 GBV_ILN_4313 GBV_ILN_4316 GBV_ILN_4319 GBV_ILN_4700 AR 36 2005 5 05 1075-1084 |
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case reviews on the effect of microstructure on the corrosion behavior of austenitic alloys for processing and storage of nuclear waste |
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Case reviews on the effect of microstructure on the corrosion behavior of austenitic alloys for processing and storage of nuclear waste |
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Abstract This article describes the corrosion behavior of special austenitic alloys for waste management applications. The special stainless steels have controlled levels of alloying and impurity elements and inclusion levels. It is shown that “active” inclusions and segregation of chromium along flow lines accelerated IGC of nonsensitized stainless steels. Concentration of $ Cr^{+6} $ ions in the grooves of dissolved inclusions increased the potential to the transpassive region of the material, leading to accelerated attack. It is shown that a combination of cold working and controlled solution annealing resulted in a microstructure that resisted corrosion even after a sensitization heat treatment. This imparted extra resistance to corrosion by increasing the fraction of “random” grain boundaries above a threshold value. Randomization of grain boundaries made the stainless steels resistant to sensitization, IGC, and intergranular stress corrosion cracking (IGSCC) in even hot chloride environments. The increased corrosion resistance has been attributed to connectivity of random grain boundaries. The reaction mechanism between the molten glass and the material for process pot, alloy 690, during the vitrification process has been shown to result in depletion of chromium from the reacting surfaces. A comparison is drawn between the electrochemical behavior of alloys 33 and 22 in 1 M HCl at 65 °C. It is shown that a secondary phase formed during welding of alloy 33 impaired corrosion properties in the HCl environment. © ASM International & TMS-The Minerals, Metals and Materials Society 2005 |
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Abstract This article describes the corrosion behavior of special austenitic alloys for waste management applications. The special stainless steels have controlled levels of alloying and impurity elements and inclusion levels. It is shown that “active” inclusions and segregation of chromium along flow lines accelerated IGC of nonsensitized stainless steels. Concentration of $ Cr^{+6} $ ions in the grooves of dissolved inclusions increased the potential to the transpassive region of the material, leading to accelerated attack. It is shown that a combination of cold working and controlled solution annealing resulted in a microstructure that resisted corrosion even after a sensitization heat treatment. This imparted extra resistance to corrosion by increasing the fraction of “random” grain boundaries above a threshold value. Randomization of grain boundaries made the stainless steels resistant to sensitization, IGC, and intergranular stress corrosion cracking (IGSCC) in even hot chloride environments. The increased corrosion resistance has been attributed to connectivity of random grain boundaries. The reaction mechanism between the molten glass and the material for process pot, alloy 690, during the vitrification process has been shown to result in depletion of chromium from the reacting surfaces. A comparison is drawn between the electrochemical behavior of alloys 33 and 22 in 1 M HCl at 65 °C. It is shown that a secondary phase formed during welding of alloy 33 impaired corrosion properties in the HCl environment. © ASM International & TMS-The Minerals, Metals and Materials Society 2005 |
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Abstract This article describes the corrosion behavior of special austenitic alloys for waste management applications. The special stainless steels have controlled levels of alloying and impurity elements and inclusion levels. It is shown that “active” inclusions and segregation of chromium along flow lines accelerated IGC of nonsensitized stainless steels. Concentration of $ Cr^{+6} $ ions in the grooves of dissolved inclusions increased the potential to the transpassive region of the material, leading to accelerated attack. It is shown that a combination of cold working and controlled solution annealing resulted in a microstructure that resisted corrosion even after a sensitization heat treatment. This imparted extra resistance to corrosion by increasing the fraction of “random” grain boundaries above a threshold value. Randomization of grain boundaries made the stainless steels resistant to sensitization, IGC, and intergranular stress corrosion cracking (IGSCC) in even hot chloride environments. The increased corrosion resistance has been attributed to connectivity of random grain boundaries. The reaction mechanism between the molten glass and the material for process pot, alloy 690, during the vitrification process has been shown to result in depletion of chromium from the reacting surfaces. A comparison is drawn between the electrochemical behavior of alloys 33 and 22 in 1 M HCl at 65 °C. It is shown that a secondary phase formed during welding of alloy 33 impaired corrosion properties in the HCl environment. © ASM International & TMS-The Minerals, Metals and Materials Society 2005 |
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