Determination of Chlorinated Solvent Sorption by Porous Material—Application to Trichloroethene Vapor on Cement Mortar
Abstract Experiments have been performed to investigate the sorption of trichloroethene (TCE) vapor by concrete material or, more specifically, the cement mortar component. Gas-flow experiments were conducted using columns packed with small pieces of cement mortar obtained from the grinding of typic...
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Gespeichert in:
| Autor*in: |
Musielak, Marion [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2014 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer Science+Business Media Dordrecht 2014 |
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| Übergeordnetes Werk: |
Enthalten in: Transport in porous media - Springer Netherlands, 1986, 104(2014), 1 vom: 18. Mai, Seite 77-90 |
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| Übergeordnetes Werk: |
volume:104 ; year:2014 ; number:1 ; day:18 ; month:05 ; pages:77-90 |
| Links: |
|---|
| DOI / URN: |
10.1007/s11242-014-0321-8 |
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OLC2054388335 |
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| 520 | |a Abstract Experiments have been performed to investigate the sorption of trichloroethene (TCE) vapor by concrete material or, more specifically, the cement mortar component. Gas-flow experiments were conducted using columns packed with small pieces of cement mortar obtained from the grinding of typical concrete material. Transport and retardation of TCE at high vapor concentrations (500 mg L$$^{-1})$$ was compared to that of a non-reactive gas tracer (Sulfur Hexafluoride, SF$$_{6})$$. The results show a large magnitude of retardation (retardation factor $$=$$ 23) and sorption (sorption coefficient $$=$$ 10.6 cm$$^{3}$$ g$$^{-1})$$ for TCE, compared to negligible sorption for SF$$_{6}$$. This magnitude of sorption obtained with pollutant vapor is much bigger than the one obtained for aqueous-flow experiments conducted for water-saturated systems. The considerable sorption exhibited for TCE under vapor-flow conditions is attributed to some combination of accumulation at the air-water interface and vapor-phase adsorption, both of which are anticipated to be significant for this system given the large surface area associated with the cement mortar. Transport of both SF$$_{6}$$ and TCE was simulated successfully with a two-region physical non-equilibrium model, consistent with the dual-medium structure of the crushed cement mortar. This work emphasizes the importance of taking into account sorption phenomena when modeling transport of volatile organic compounds through concrete material, especially in regard to assessing vapor intrusion. | ||
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10.1007/s11242-014-0321-8 doi (DE-627)OLC2054388335 (DE-He213)s11242-014-0321-8-p DE-627 ger DE-627 rakwb eng 530 VZ Musielak, Marion verfasserin aut Determination of Chlorinated Solvent Sorption by Porous Material—Application to Trichloroethene Vapor on Cement Mortar 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media Dordrecht 2014 Abstract Experiments have been performed to investigate the sorption of trichloroethene (TCE) vapor by concrete material or, more specifically, the cement mortar component. Gas-flow experiments were conducted using columns packed with small pieces of cement mortar obtained from the grinding of typical concrete material. Transport and retardation of TCE at high vapor concentrations (500 mg L$$^{-1})$$ was compared to that of a non-reactive gas tracer (Sulfur Hexafluoride, SF$$_{6})$$. The results show a large magnitude of retardation (retardation factor $$=$$ 23) and sorption (sorption coefficient $$=$$ 10.6 cm$$^{3}$$ g$$^{-1})$$ for TCE, compared to negligible sorption for SF$$_{6}$$. This magnitude of sorption obtained with pollutant vapor is much bigger than the one obtained for aqueous-flow experiments conducted for water-saturated systems. The considerable sorption exhibited for TCE under vapor-flow conditions is attributed to some combination of accumulation at the air-water interface and vapor-phase adsorption, both of which are anticipated to be significant for this system given the large surface area associated with the cement mortar. Transport of both SF$$_{6}$$ and TCE was simulated successfully with a two-region physical non-equilibrium model, consistent with the dual-medium structure of the crushed cement mortar. This work emphasizes the importance of taking into account sorption phenomena when modeling transport of volatile organic compounds through concrete material, especially in regard to assessing vapor intrusion. Vapor intrusion NAPL Sorption Concrete Effective diffusion Brusseau, Mark L. aut Marcoux, Manuel aut Morrison, Candice aut Quintard, Michel aut Enthalten in Transport in porous media Springer Netherlands, 1986 104(2014), 1 vom: 18. Mai, Seite 77-90 (DE-627)129206105 (DE-600)54858-3 (DE-576)014457431 0169-3913 nnns volume:104 year:2014 number:1 day:18 month:05 pages:77-90 https://doi.org/10.1007/s11242-014-0321-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_70 AR 104 2014 1 18 05 77-90 |
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10.1007/s11242-014-0321-8 doi (DE-627)OLC2054388335 (DE-He213)s11242-014-0321-8-p DE-627 ger DE-627 rakwb eng 530 VZ Musielak, Marion verfasserin aut Determination of Chlorinated Solvent Sorption by Porous Material—Application to Trichloroethene Vapor on Cement Mortar 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media Dordrecht 2014 Abstract Experiments have been performed to investigate the sorption of trichloroethene (TCE) vapor by concrete material or, more specifically, the cement mortar component. Gas-flow experiments were conducted using columns packed with small pieces of cement mortar obtained from the grinding of typical concrete material. Transport and retardation of TCE at high vapor concentrations (500 mg L$$^{-1})$$ was compared to that of a non-reactive gas tracer (Sulfur Hexafluoride, SF$$_{6})$$. The results show a large magnitude of retardation (retardation factor $$=$$ 23) and sorption (sorption coefficient $$=$$ 10.6 cm$$^{3}$$ g$$^{-1})$$ for TCE, compared to negligible sorption for SF$$_{6}$$. This magnitude of sorption obtained with pollutant vapor is much bigger than the one obtained for aqueous-flow experiments conducted for water-saturated systems. The considerable sorption exhibited for TCE under vapor-flow conditions is attributed to some combination of accumulation at the air-water interface and vapor-phase adsorption, both of which are anticipated to be significant for this system given the large surface area associated with the cement mortar. Transport of both SF$$_{6}$$ and TCE was simulated successfully with a two-region physical non-equilibrium model, consistent with the dual-medium structure of the crushed cement mortar. This work emphasizes the importance of taking into account sorption phenomena when modeling transport of volatile organic compounds through concrete material, especially in regard to assessing vapor intrusion. Vapor intrusion NAPL Sorption Concrete Effective diffusion Brusseau, Mark L. aut Marcoux, Manuel aut Morrison, Candice aut Quintard, Michel aut Enthalten in Transport in porous media Springer Netherlands, 1986 104(2014), 1 vom: 18. Mai, Seite 77-90 (DE-627)129206105 (DE-600)54858-3 (DE-576)014457431 0169-3913 nnns volume:104 year:2014 number:1 day:18 month:05 pages:77-90 https://doi.org/10.1007/s11242-014-0321-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_70 AR 104 2014 1 18 05 77-90 |
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10.1007/s11242-014-0321-8 doi (DE-627)OLC2054388335 (DE-He213)s11242-014-0321-8-p DE-627 ger DE-627 rakwb eng 530 VZ Musielak, Marion verfasserin aut Determination of Chlorinated Solvent Sorption by Porous Material—Application to Trichloroethene Vapor on Cement Mortar 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media Dordrecht 2014 Abstract Experiments have been performed to investigate the sorption of trichloroethene (TCE) vapor by concrete material or, more specifically, the cement mortar component. Gas-flow experiments were conducted using columns packed with small pieces of cement mortar obtained from the grinding of typical concrete material. Transport and retardation of TCE at high vapor concentrations (500 mg L$$^{-1})$$ was compared to that of a non-reactive gas tracer (Sulfur Hexafluoride, SF$$_{6})$$. The results show a large magnitude of retardation (retardation factor $$=$$ 23) and sorption (sorption coefficient $$=$$ 10.6 cm$$^{3}$$ g$$^{-1})$$ for TCE, compared to negligible sorption for SF$$_{6}$$. This magnitude of sorption obtained with pollutant vapor is much bigger than the one obtained for aqueous-flow experiments conducted for water-saturated systems. The considerable sorption exhibited for TCE under vapor-flow conditions is attributed to some combination of accumulation at the air-water interface and vapor-phase adsorption, both of which are anticipated to be significant for this system given the large surface area associated with the cement mortar. Transport of both SF$$_{6}$$ and TCE was simulated successfully with a two-region physical non-equilibrium model, consistent with the dual-medium structure of the crushed cement mortar. This work emphasizes the importance of taking into account sorption phenomena when modeling transport of volatile organic compounds through concrete material, especially in regard to assessing vapor intrusion. Vapor intrusion NAPL Sorption Concrete Effective diffusion Brusseau, Mark L. aut Marcoux, Manuel aut Morrison, Candice aut Quintard, Michel aut Enthalten in Transport in porous media Springer Netherlands, 1986 104(2014), 1 vom: 18. Mai, Seite 77-90 (DE-627)129206105 (DE-600)54858-3 (DE-576)014457431 0169-3913 nnns volume:104 year:2014 number:1 day:18 month:05 pages:77-90 https://doi.org/10.1007/s11242-014-0321-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_70 AR 104 2014 1 18 05 77-90 |
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10.1007/s11242-014-0321-8 doi (DE-627)OLC2054388335 (DE-He213)s11242-014-0321-8-p DE-627 ger DE-627 rakwb eng 530 VZ Musielak, Marion verfasserin aut Determination of Chlorinated Solvent Sorption by Porous Material—Application to Trichloroethene Vapor on Cement Mortar 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media Dordrecht 2014 Abstract Experiments have been performed to investigate the sorption of trichloroethene (TCE) vapor by concrete material or, more specifically, the cement mortar component. Gas-flow experiments were conducted using columns packed with small pieces of cement mortar obtained from the grinding of typical concrete material. Transport and retardation of TCE at high vapor concentrations (500 mg L$$^{-1})$$ was compared to that of a non-reactive gas tracer (Sulfur Hexafluoride, SF$$_{6})$$. The results show a large magnitude of retardation (retardation factor $$=$$ 23) and sorption (sorption coefficient $$=$$ 10.6 cm$$^{3}$$ g$$^{-1})$$ for TCE, compared to negligible sorption for SF$$_{6}$$. This magnitude of sorption obtained with pollutant vapor is much bigger than the one obtained for aqueous-flow experiments conducted for water-saturated systems. The considerable sorption exhibited for TCE under vapor-flow conditions is attributed to some combination of accumulation at the air-water interface and vapor-phase adsorption, both of which are anticipated to be significant for this system given the large surface area associated with the cement mortar. Transport of both SF$$_{6}$$ and TCE was simulated successfully with a two-region physical non-equilibrium model, consistent with the dual-medium structure of the crushed cement mortar. This work emphasizes the importance of taking into account sorption phenomena when modeling transport of volatile organic compounds through concrete material, especially in regard to assessing vapor intrusion. Vapor intrusion NAPL Sorption Concrete Effective diffusion Brusseau, Mark L. aut Marcoux, Manuel aut Morrison, Candice aut Quintard, Michel aut Enthalten in Transport in porous media Springer Netherlands, 1986 104(2014), 1 vom: 18. Mai, Seite 77-90 (DE-627)129206105 (DE-600)54858-3 (DE-576)014457431 0169-3913 nnns volume:104 year:2014 number:1 day:18 month:05 pages:77-90 https://doi.org/10.1007/s11242-014-0321-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_70 AR 104 2014 1 18 05 77-90 |
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10.1007/s11242-014-0321-8 doi (DE-627)OLC2054388335 (DE-He213)s11242-014-0321-8-p DE-627 ger DE-627 rakwb eng 530 VZ Musielak, Marion verfasserin aut Determination of Chlorinated Solvent Sorption by Porous Material—Application to Trichloroethene Vapor on Cement Mortar 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media Dordrecht 2014 Abstract Experiments have been performed to investigate the sorption of trichloroethene (TCE) vapor by concrete material or, more specifically, the cement mortar component. Gas-flow experiments were conducted using columns packed with small pieces of cement mortar obtained from the grinding of typical concrete material. Transport and retardation of TCE at high vapor concentrations (500 mg L$$^{-1})$$ was compared to that of a non-reactive gas tracer (Sulfur Hexafluoride, SF$$_{6})$$. The results show a large magnitude of retardation (retardation factor $$=$$ 23) and sorption (sorption coefficient $$=$$ 10.6 cm$$^{3}$$ g$$^{-1})$$ for TCE, compared to negligible sorption for SF$$_{6}$$. This magnitude of sorption obtained with pollutant vapor is much bigger than the one obtained for aqueous-flow experiments conducted for water-saturated systems. The considerable sorption exhibited for TCE under vapor-flow conditions is attributed to some combination of accumulation at the air-water interface and vapor-phase adsorption, both of which are anticipated to be significant for this system given the large surface area associated with the cement mortar. Transport of both SF$$_{6}$$ and TCE was simulated successfully with a two-region physical non-equilibrium model, consistent with the dual-medium structure of the crushed cement mortar. This work emphasizes the importance of taking into account sorption phenomena when modeling transport of volatile organic compounds through concrete material, especially in regard to assessing vapor intrusion. Vapor intrusion NAPL Sorption Concrete Effective diffusion Brusseau, Mark L. aut Marcoux, Manuel aut Morrison, Candice aut Quintard, Michel aut Enthalten in Transport in porous media Springer Netherlands, 1986 104(2014), 1 vom: 18. Mai, Seite 77-90 (DE-627)129206105 (DE-600)54858-3 (DE-576)014457431 0169-3913 nnns volume:104 year:2014 number:1 day:18 month:05 pages:77-90 https://doi.org/10.1007/s11242-014-0321-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_70 AR 104 2014 1 18 05 77-90 |
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Musielak, Marion Brusseau, Mark L. Marcoux, Manuel Morrison, Candice Quintard, Michel |
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Musielak, Marion |
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10.1007/s11242-014-0321-8 |
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530 |
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determination of chlorinated solvent sorption by porous material—application to trichloroethene vapor on cement mortar |
| title_auth |
Determination of Chlorinated Solvent Sorption by Porous Material—Application to Trichloroethene Vapor on Cement Mortar |
| abstract |
Abstract Experiments have been performed to investigate the sorption of trichloroethene (TCE) vapor by concrete material or, more specifically, the cement mortar component. Gas-flow experiments were conducted using columns packed with small pieces of cement mortar obtained from the grinding of typical concrete material. Transport and retardation of TCE at high vapor concentrations (500 mg L$$^{-1})$$ was compared to that of a non-reactive gas tracer (Sulfur Hexafluoride, SF$$_{6})$$. The results show a large magnitude of retardation (retardation factor $$=$$ 23) and sorption (sorption coefficient $$=$$ 10.6 cm$$^{3}$$ g$$^{-1})$$ for TCE, compared to negligible sorption for SF$$_{6}$$. This magnitude of sorption obtained with pollutant vapor is much bigger than the one obtained for aqueous-flow experiments conducted for water-saturated systems. The considerable sorption exhibited for TCE under vapor-flow conditions is attributed to some combination of accumulation at the air-water interface and vapor-phase adsorption, both of which are anticipated to be significant for this system given the large surface area associated with the cement mortar. Transport of both SF$$_{6}$$ and TCE was simulated successfully with a two-region physical non-equilibrium model, consistent with the dual-medium structure of the crushed cement mortar. This work emphasizes the importance of taking into account sorption phenomena when modeling transport of volatile organic compounds through concrete material, especially in regard to assessing vapor intrusion. © Springer Science+Business Media Dordrecht 2014 |
| abstractGer |
Abstract Experiments have been performed to investigate the sorption of trichloroethene (TCE) vapor by concrete material or, more specifically, the cement mortar component. Gas-flow experiments were conducted using columns packed with small pieces of cement mortar obtained from the grinding of typical concrete material. Transport and retardation of TCE at high vapor concentrations (500 mg L$$^{-1})$$ was compared to that of a non-reactive gas tracer (Sulfur Hexafluoride, SF$$_{6})$$. The results show a large magnitude of retardation (retardation factor $$=$$ 23) and sorption (sorption coefficient $$=$$ 10.6 cm$$^{3}$$ g$$^{-1})$$ for TCE, compared to negligible sorption for SF$$_{6}$$. This magnitude of sorption obtained with pollutant vapor is much bigger than the one obtained for aqueous-flow experiments conducted for water-saturated systems. The considerable sorption exhibited for TCE under vapor-flow conditions is attributed to some combination of accumulation at the air-water interface and vapor-phase adsorption, both of which are anticipated to be significant for this system given the large surface area associated with the cement mortar. Transport of both SF$$_{6}$$ and TCE was simulated successfully with a two-region physical non-equilibrium model, consistent with the dual-medium structure of the crushed cement mortar. This work emphasizes the importance of taking into account sorption phenomena when modeling transport of volatile organic compounds through concrete material, especially in regard to assessing vapor intrusion. © Springer Science+Business Media Dordrecht 2014 |
| abstract_unstemmed |
Abstract Experiments have been performed to investigate the sorption of trichloroethene (TCE) vapor by concrete material or, more specifically, the cement mortar component. Gas-flow experiments were conducted using columns packed with small pieces of cement mortar obtained from the grinding of typical concrete material. Transport and retardation of TCE at high vapor concentrations (500 mg L$$^{-1})$$ was compared to that of a non-reactive gas tracer (Sulfur Hexafluoride, SF$$_{6})$$. The results show a large magnitude of retardation (retardation factor $$=$$ 23) and sorption (sorption coefficient $$=$$ 10.6 cm$$^{3}$$ g$$^{-1})$$ for TCE, compared to negligible sorption for SF$$_{6}$$. This magnitude of sorption obtained with pollutant vapor is much bigger than the one obtained for aqueous-flow experiments conducted for water-saturated systems. The considerable sorption exhibited for TCE under vapor-flow conditions is attributed to some combination of accumulation at the air-water interface and vapor-phase adsorption, both of which are anticipated to be significant for this system given the large surface area associated with the cement mortar. Transport of both SF$$_{6}$$ and TCE was simulated successfully with a two-region physical non-equilibrium model, consistent with the dual-medium structure of the crushed cement mortar. This work emphasizes the importance of taking into account sorption phenomena when modeling transport of volatile organic compounds through concrete material, especially in regard to assessing vapor intrusion. © Springer Science+Business Media Dordrecht 2014 |
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Determination of Chlorinated Solvent Sorption by Porous Material—Application to Trichloroethene Vapor on Cement Mortar |
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