The Tribological Chemistry of the Oil Blends of Zinc Dialkyldithiophosphate with 2-Mercaptobenzothiazole Derivatives
Abstract X-ray absorption near-edge spectroscopy at the phosphorous and sulfur edges was used to identify the chemical species in thermal films and antiwear films on the macroscale. For the thermal films, it was found that the introduction of the additive MBTT/MBTA to the base oil, zinc dialkyldithi...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Wu, Hua [verfasserIn] |
|---|
| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2009 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer Science+Business Media, LLC 2009 |
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| Übergeordnetes Werk: |
Enthalten in: Tribology letters - Springer US, 1995, 35(2009), 3 vom: 12. Mai, Seite 171-179 |
|---|---|
| Übergeordnetes Werk: |
volume:35 ; year:2009 ; number:3 ; day:12 ; month:05 ; pages:171-179 |
| Links: |
|---|
| DOI / URN: |
10.1007/s11249-009-9446-2 |
|---|
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OLC2054475432 |
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| 520 | |a Abstract X-ray absorption near-edge spectroscopy at the phosphorous and sulfur edges was used to identify the chemical species in thermal films and antiwear films on the macroscale. For the thermal films, it was found that the introduction of the additive MBTT/MBTA to the base oil, zinc dialkyldithiophosphate (ZDDP), tended to retard the formation of the polyphosphate, and has no effect on the thickness of the films. The topmost surface thermal films may be mainly comprised of some new compounds generated from the interaction of ZDDP with the antiwear additives MBTT/MBTA, along with a small amount of unchanged ZDDP, the sub-surface, and the bulk were mainly comprised of Zn phosphate, along with an amount of ZnS. For the antiwear films, the introduction of the additive MBTT/MBTA to the base oil, ZDDP, reduces the chain length of polyphosphate, which the N-containing decomposed products of 2-mercaptobenzothiazole derivatives are responsible for. It is very clear that MBTT or MBTA has indeed interacted with ZDDP to form new phosphate in the overall antiwear films. The topmost surface antiwear films were mainly comprised of short-chain polyphosphate, the sub-surface and the bulk may be mainly comprised of Zn phosphate and ZnS. | ||
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| 700 | 1 | |a Zuo, Guangzhi |4 aut | |
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10.1007/s11249-009-9446-2 doi (DE-627)OLC2054475432 (DE-He213)s11249-009-9446-2-p DE-627 ger DE-627 rakwb eng 670 VZ Wu, Hua verfasserin aut The Tribological Chemistry of the Oil Blends of Zinc Dialkyldithiophosphate with 2-Mercaptobenzothiazole Derivatives 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2009 Abstract X-ray absorption near-edge spectroscopy at the phosphorous and sulfur edges was used to identify the chemical species in thermal films and antiwear films on the macroscale. For the thermal films, it was found that the introduction of the additive MBTT/MBTA to the base oil, zinc dialkyldithiophosphate (ZDDP), tended to retard the formation of the polyphosphate, and has no effect on the thickness of the films. The topmost surface thermal films may be mainly comprised of some new compounds generated from the interaction of ZDDP with the antiwear additives MBTT/MBTA, along with a small amount of unchanged ZDDP, the sub-surface, and the bulk were mainly comprised of Zn phosphate, along with an amount of ZnS. For the antiwear films, the introduction of the additive MBTT/MBTA to the base oil, ZDDP, reduces the chain length of polyphosphate, which the N-containing decomposed products of 2-mercaptobenzothiazole derivatives are responsible for. It is very clear that MBTT or MBTA has indeed interacted with ZDDP to form new phosphate in the overall antiwear films. The topmost surface antiwear films were mainly comprised of short-chain polyphosphate, the sub-surface and the bulk may be mainly comprised of Zn phosphate and ZnS. Antiwear additives Wear Wear mechanisms X-ray absorption near-edge spectroscopy (XANES) Ren, Tianhui aut Zuo, Guangzhi aut Enthalten in Tribology letters Springer US, 1995 35(2009), 3 vom: 12. Mai, Seite 171-179 (DE-627)221187790 (DE-600)1355921-7 (DE-576)06488354X 1023-8883 nnns volume:35 year:2009 number:3 day:12 month:05 pages:171-179 https://doi.org/10.1007/s11249-009-9446-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_70 AR 35 2009 3 12 05 171-179 |
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10.1007/s11249-009-9446-2 doi (DE-627)OLC2054475432 (DE-He213)s11249-009-9446-2-p DE-627 ger DE-627 rakwb eng 670 VZ Wu, Hua verfasserin aut The Tribological Chemistry of the Oil Blends of Zinc Dialkyldithiophosphate with 2-Mercaptobenzothiazole Derivatives 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2009 Abstract X-ray absorption near-edge spectroscopy at the phosphorous and sulfur edges was used to identify the chemical species in thermal films and antiwear films on the macroscale. For the thermal films, it was found that the introduction of the additive MBTT/MBTA to the base oil, zinc dialkyldithiophosphate (ZDDP), tended to retard the formation of the polyphosphate, and has no effect on the thickness of the films. The topmost surface thermal films may be mainly comprised of some new compounds generated from the interaction of ZDDP with the antiwear additives MBTT/MBTA, along with a small amount of unchanged ZDDP, the sub-surface, and the bulk were mainly comprised of Zn phosphate, along with an amount of ZnS. For the antiwear films, the introduction of the additive MBTT/MBTA to the base oil, ZDDP, reduces the chain length of polyphosphate, which the N-containing decomposed products of 2-mercaptobenzothiazole derivatives are responsible for. It is very clear that MBTT or MBTA has indeed interacted with ZDDP to form new phosphate in the overall antiwear films. The topmost surface antiwear films were mainly comprised of short-chain polyphosphate, the sub-surface and the bulk may be mainly comprised of Zn phosphate and ZnS. Antiwear additives Wear Wear mechanisms X-ray absorption near-edge spectroscopy (XANES) Ren, Tianhui aut Zuo, Guangzhi aut Enthalten in Tribology letters Springer US, 1995 35(2009), 3 vom: 12. Mai, Seite 171-179 (DE-627)221187790 (DE-600)1355921-7 (DE-576)06488354X 1023-8883 nnns volume:35 year:2009 number:3 day:12 month:05 pages:171-179 https://doi.org/10.1007/s11249-009-9446-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_70 AR 35 2009 3 12 05 171-179 |
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10.1007/s11249-009-9446-2 doi (DE-627)OLC2054475432 (DE-He213)s11249-009-9446-2-p DE-627 ger DE-627 rakwb eng 670 VZ Wu, Hua verfasserin aut The Tribological Chemistry of the Oil Blends of Zinc Dialkyldithiophosphate with 2-Mercaptobenzothiazole Derivatives 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2009 Abstract X-ray absorption near-edge spectroscopy at the phosphorous and sulfur edges was used to identify the chemical species in thermal films and antiwear films on the macroscale. For the thermal films, it was found that the introduction of the additive MBTT/MBTA to the base oil, zinc dialkyldithiophosphate (ZDDP), tended to retard the formation of the polyphosphate, and has no effect on the thickness of the films. The topmost surface thermal films may be mainly comprised of some new compounds generated from the interaction of ZDDP with the antiwear additives MBTT/MBTA, along with a small amount of unchanged ZDDP, the sub-surface, and the bulk were mainly comprised of Zn phosphate, along with an amount of ZnS. For the antiwear films, the introduction of the additive MBTT/MBTA to the base oil, ZDDP, reduces the chain length of polyphosphate, which the N-containing decomposed products of 2-mercaptobenzothiazole derivatives are responsible for. It is very clear that MBTT or MBTA has indeed interacted with ZDDP to form new phosphate in the overall antiwear films. The topmost surface antiwear films were mainly comprised of short-chain polyphosphate, the sub-surface and the bulk may be mainly comprised of Zn phosphate and ZnS. Antiwear additives Wear Wear mechanisms X-ray absorption near-edge spectroscopy (XANES) Ren, Tianhui aut Zuo, Guangzhi aut Enthalten in Tribology letters Springer US, 1995 35(2009), 3 vom: 12. Mai, Seite 171-179 (DE-627)221187790 (DE-600)1355921-7 (DE-576)06488354X 1023-8883 nnns volume:35 year:2009 number:3 day:12 month:05 pages:171-179 https://doi.org/10.1007/s11249-009-9446-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_70 AR 35 2009 3 12 05 171-179 |
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10.1007/s11249-009-9446-2 doi (DE-627)OLC2054475432 (DE-He213)s11249-009-9446-2-p DE-627 ger DE-627 rakwb eng 670 VZ Wu, Hua verfasserin aut The Tribological Chemistry of the Oil Blends of Zinc Dialkyldithiophosphate with 2-Mercaptobenzothiazole Derivatives 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2009 Abstract X-ray absorption near-edge spectroscopy at the phosphorous and sulfur edges was used to identify the chemical species in thermal films and antiwear films on the macroscale. For the thermal films, it was found that the introduction of the additive MBTT/MBTA to the base oil, zinc dialkyldithiophosphate (ZDDP), tended to retard the formation of the polyphosphate, and has no effect on the thickness of the films. The topmost surface thermal films may be mainly comprised of some new compounds generated from the interaction of ZDDP with the antiwear additives MBTT/MBTA, along with a small amount of unchanged ZDDP, the sub-surface, and the bulk were mainly comprised of Zn phosphate, along with an amount of ZnS. For the antiwear films, the introduction of the additive MBTT/MBTA to the base oil, ZDDP, reduces the chain length of polyphosphate, which the N-containing decomposed products of 2-mercaptobenzothiazole derivatives are responsible for. It is very clear that MBTT or MBTA has indeed interacted with ZDDP to form new phosphate in the overall antiwear films. The topmost surface antiwear films were mainly comprised of short-chain polyphosphate, the sub-surface and the bulk may be mainly comprised of Zn phosphate and ZnS. Antiwear additives Wear Wear mechanisms X-ray absorption near-edge spectroscopy (XANES) Ren, Tianhui aut Zuo, Guangzhi aut Enthalten in Tribology letters Springer US, 1995 35(2009), 3 vom: 12. Mai, Seite 171-179 (DE-627)221187790 (DE-600)1355921-7 (DE-576)06488354X 1023-8883 nnns volume:35 year:2009 number:3 day:12 month:05 pages:171-179 https://doi.org/10.1007/s11249-009-9446-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_70 AR 35 2009 3 12 05 171-179 |
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10.1007/s11249-009-9446-2 doi (DE-627)OLC2054475432 (DE-He213)s11249-009-9446-2-p DE-627 ger DE-627 rakwb eng 670 VZ Wu, Hua verfasserin aut The Tribological Chemistry of the Oil Blends of Zinc Dialkyldithiophosphate with 2-Mercaptobenzothiazole Derivatives 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2009 Abstract X-ray absorption near-edge spectroscopy at the phosphorous and sulfur edges was used to identify the chemical species in thermal films and antiwear films on the macroscale. For the thermal films, it was found that the introduction of the additive MBTT/MBTA to the base oil, zinc dialkyldithiophosphate (ZDDP), tended to retard the formation of the polyphosphate, and has no effect on the thickness of the films. The topmost surface thermal films may be mainly comprised of some new compounds generated from the interaction of ZDDP with the antiwear additives MBTT/MBTA, along with a small amount of unchanged ZDDP, the sub-surface, and the bulk were mainly comprised of Zn phosphate, along with an amount of ZnS. For the antiwear films, the introduction of the additive MBTT/MBTA to the base oil, ZDDP, reduces the chain length of polyphosphate, which the N-containing decomposed products of 2-mercaptobenzothiazole derivatives are responsible for. It is very clear that MBTT or MBTA has indeed interacted with ZDDP to form new phosphate in the overall antiwear films. The topmost surface antiwear films were mainly comprised of short-chain polyphosphate, the sub-surface and the bulk may be mainly comprised of Zn phosphate and ZnS. Antiwear additives Wear Wear mechanisms X-ray absorption near-edge spectroscopy (XANES) Ren, Tianhui aut Zuo, Guangzhi aut Enthalten in Tribology letters Springer US, 1995 35(2009), 3 vom: 12. Mai, Seite 171-179 (DE-627)221187790 (DE-600)1355921-7 (DE-576)06488354X 1023-8883 nnns volume:35 year:2009 number:3 day:12 month:05 pages:171-179 https://doi.org/10.1007/s11249-009-9446-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_70 AR 35 2009 3 12 05 171-179 |
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The Tribological Chemistry of the Oil Blends of Zinc Dialkyldithiophosphate with 2-Mercaptobenzothiazole Derivatives |
| abstract |
Abstract X-ray absorption near-edge spectroscopy at the phosphorous and sulfur edges was used to identify the chemical species in thermal films and antiwear films on the macroscale. For the thermal films, it was found that the introduction of the additive MBTT/MBTA to the base oil, zinc dialkyldithiophosphate (ZDDP), tended to retard the formation of the polyphosphate, and has no effect on the thickness of the films. The topmost surface thermal films may be mainly comprised of some new compounds generated from the interaction of ZDDP with the antiwear additives MBTT/MBTA, along with a small amount of unchanged ZDDP, the sub-surface, and the bulk were mainly comprised of Zn phosphate, along with an amount of ZnS. For the antiwear films, the introduction of the additive MBTT/MBTA to the base oil, ZDDP, reduces the chain length of polyphosphate, which the N-containing decomposed products of 2-mercaptobenzothiazole derivatives are responsible for. It is very clear that MBTT or MBTA has indeed interacted with ZDDP to form new phosphate in the overall antiwear films. The topmost surface antiwear films were mainly comprised of short-chain polyphosphate, the sub-surface and the bulk may be mainly comprised of Zn phosphate and ZnS. © Springer Science+Business Media, LLC 2009 |
| abstractGer |
Abstract X-ray absorption near-edge spectroscopy at the phosphorous and sulfur edges was used to identify the chemical species in thermal films and antiwear films on the macroscale. For the thermal films, it was found that the introduction of the additive MBTT/MBTA to the base oil, zinc dialkyldithiophosphate (ZDDP), tended to retard the formation of the polyphosphate, and has no effect on the thickness of the films. The topmost surface thermal films may be mainly comprised of some new compounds generated from the interaction of ZDDP with the antiwear additives MBTT/MBTA, along with a small amount of unchanged ZDDP, the sub-surface, and the bulk were mainly comprised of Zn phosphate, along with an amount of ZnS. For the antiwear films, the introduction of the additive MBTT/MBTA to the base oil, ZDDP, reduces the chain length of polyphosphate, which the N-containing decomposed products of 2-mercaptobenzothiazole derivatives are responsible for. It is very clear that MBTT or MBTA has indeed interacted with ZDDP to form new phosphate in the overall antiwear films. The topmost surface antiwear films were mainly comprised of short-chain polyphosphate, the sub-surface and the bulk may be mainly comprised of Zn phosphate and ZnS. © Springer Science+Business Media, LLC 2009 |
| abstract_unstemmed |
Abstract X-ray absorption near-edge spectroscopy at the phosphorous and sulfur edges was used to identify the chemical species in thermal films and antiwear films on the macroscale. For the thermal films, it was found that the introduction of the additive MBTT/MBTA to the base oil, zinc dialkyldithiophosphate (ZDDP), tended to retard the formation of the polyphosphate, and has no effect on the thickness of the films. The topmost surface thermal films may be mainly comprised of some new compounds generated from the interaction of ZDDP with the antiwear additives MBTT/MBTA, along with a small amount of unchanged ZDDP, the sub-surface, and the bulk were mainly comprised of Zn phosphate, along with an amount of ZnS. For the antiwear films, the introduction of the additive MBTT/MBTA to the base oil, ZDDP, reduces the chain length of polyphosphate, which the N-containing decomposed products of 2-mercaptobenzothiazole derivatives are responsible for. It is very clear that MBTT or MBTA has indeed interacted with ZDDP to form new phosphate in the overall antiwear films. The topmost surface antiwear films were mainly comprised of short-chain polyphosphate, the sub-surface and the bulk may be mainly comprised of Zn phosphate and ZnS. © Springer Science+Business Media, LLC 2009 |
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| container_issue |
3 |
| title_short |
The Tribological Chemistry of the Oil Blends of Zinc Dialkyldithiophosphate with 2-Mercaptobenzothiazole Derivatives |
| url |
https://doi.org/10.1007/s11249-009-9446-2 |
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| author2 |
Ren, Tianhui Zuo, Guangzhi |
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Ren, Tianhui Zuo, Guangzhi |
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| doi_str |
10.1007/s11249-009-9446-2 |
| up_date |
2024-07-03T23:17:39.281Z |
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7.401101 |