The Role of Functional End Groups of Perfluoropolyether (Z-dol and Z-03) Lubricants in Augmenting the Tribology of SU-8 Composites
Abstract In an earlier work, we demonstrated the development of SU-8 composites using perfluoropolyether (PFPE) as lubricant filler which reduced friction coefficient by ~7 times and enhanced wear life of SU-8 by more than four orders of magnitude. In this work, we have investigated the role of chem...
Ausführliche Beschreibung
Autor*in: |
Prabakaran, Saravanan [verfasserIn] |
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Format: |
Artikel |
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Sprache: |
Englisch |
Erschienen: |
2014 |
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Schlagwörter: |
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Anmerkung: |
© Springer Science+Business Media New York 2014 |
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Übergeordnetes Werk: |
Enthalten in: Tribology letters - Springer US, 1995, 56(2014), 3 vom: 14. Okt., Seite 423-434 |
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Übergeordnetes Werk: |
volume:56 ; year:2014 ; number:3 ; day:14 ; month:10 ; pages:423-434 |
Links: |
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DOI / URN: |
10.1007/s11249-014-0419-8 |
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Katalog-ID: |
OLC2054484539 |
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520 | |a Abstract In an earlier work, we demonstrated the development of SU-8 composites using perfluoropolyether (PFPE) as lubricant filler which reduced friction coefficient by ~7 times and enhanced wear life of SU-8 by more than four orders of magnitude. In this work, we have investigated the role of chemical bonding between SU-8 and PFPE molecules using two types of PFPE lubricants (i.e., $ Fomblin^{®} $ Z-dol and Z-03) in improving the tribological properties of the composite. Z-dol has polar (–OH) end groups whereas Z-03 has non-polar ($ CF_{3} $) end groups. SU-8 with Z-dol (SU-8 + Z-dol) films yielded ~8 times greater wear life than SU-8 with Z-03 (SU-8 + Z-03) films and more by four orders of magnitude than pure SU-8. The nature of the films was analyzed in detail by chemical and physical characterization techniques like X-ray photoelectron spectroscopy, water contact angle and thermo-gravimetric analysis. The results validated the role of polar end functional group of Z-dol in covalent binding with SU-8 upon UV plasma treatment that resulted in improved tribological properties. | ||
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10.1007/s11249-014-0419-8 doi (DE-627)OLC2054484539 (DE-He213)s11249-014-0419-8-p DE-627 ger DE-627 rakwb eng 670 VZ Prabakaran, Saravanan verfasserin aut The Role of Functional End Groups of Perfluoropolyether (Z-dol and Z-03) Lubricants in Augmenting the Tribology of SU-8 Composites 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2014 Abstract In an earlier work, we demonstrated the development of SU-8 composites using perfluoropolyether (PFPE) as lubricant filler which reduced friction coefficient by ~7 times and enhanced wear life of SU-8 by more than four orders of magnitude. In this work, we have investigated the role of chemical bonding between SU-8 and PFPE molecules using two types of PFPE lubricants (i.e., $ Fomblin^{®} $ Z-dol and Z-03) in improving the tribological properties of the composite. Z-dol has polar (–OH) end groups whereas Z-03 has non-polar ($ CF_{3} $) end groups. SU-8 with Z-dol (SU-8 + Z-dol) films yielded ~8 times greater wear life than SU-8 with Z-03 (SU-8 + Z-03) films and more by four orders of magnitude than pure SU-8. The nature of the films was analyzed in detail by chemical and physical characterization techniques like X-ray photoelectron spectroscopy, water contact angle and thermo-gravimetric analysis. The results validated the role of polar end functional group of Z-dol in covalent binding with SU-8 upon UV plasma treatment that resulted in improved tribological properties. Polymer tribology SU-8 composite PFPE Jayaraman, Sundaramurthy aut Minh, Duong Hai aut Sinha, Sujeet K. aut Enthalten in Tribology letters Springer US, 1995 56(2014), 3 vom: 14. Okt., Seite 423-434 (DE-627)221187790 (DE-600)1355921-7 (DE-576)06488354X 1023-8883 nnns volume:56 year:2014 number:3 day:14 month:10 pages:423-434 https://doi.org/10.1007/s11249-014-0419-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_70 AR 56 2014 3 14 10 423-434 |
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10.1007/s11249-014-0419-8 doi (DE-627)OLC2054484539 (DE-He213)s11249-014-0419-8-p DE-627 ger DE-627 rakwb eng 670 VZ Prabakaran, Saravanan verfasserin aut The Role of Functional End Groups of Perfluoropolyether (Z-dol and Z-03) Lubricants in Augmenting the Tribology of SU-8 Composites 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2014 Abstract In an earlier work, we demonstrated the development of SU-8 composites using perfluoropolyether (PFPE) as lubricant filler which reduced friction coefficient by ~7 times and enhanced wear life of SU-8 by more than four orders of magnitude. In this work, we have investigated the role of chemical bonding between SU-8 and PFPE molecules using two types of PFPE lubricants (i.e., $ Fomblin^{®} $ Z-dol and Z-03) in improving the tribological properties of the composite. Z-dol has polar (–OH) end groups whereas Z-03 has non-polar ($ CF_{3} $) end groups. SU-8 with Z-dol (SU-8 + Z-dol) films yielded ~8 times greater wear life than SU-8 with Z-03 (SU-8 + Z-03) films and more by four orders of magnitude than pure SU-8. The nature of the films was analyzed in detail by chemical and physical characterization techniques like X-ray photoelectron spectroscopy, water contact angle and thermo-gravimetric analysis. The results validated the role of polar end functional group of Z-dol in covalent binding with SU-8 upon UV plasma treatment that resulted in improved tribological properties. Polymer tribology SU-8 composite PFPE Jayaraman, Sundaramurthy aut Minh, Duong Hai aut Sinha, Sujeet K. aut Enthalten in Tribology letters Springer US, 1995 56(2014), 3 vom: 14. Okt., Seite 423-434 (DE-627)221187790 (DE-600)1355921-7 (DE-576)06488354X 1023-8883 nnns volume:56 year:2014 number:3 day:14 month:10 pages:423-434 https://doi.org/10.1007/s11249-014-0419-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_70 AR 56 2014 3 14 10 423-434 |
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10.1007/s11249-014-0419-8 doi (DE-627)OLC2054484539 (DE-He213)s11249-014-0419-8-p DE-627 ger DE-627 rakwb eng 670 VZ Prabakaran, Saravanan verfasserin aut The Role of Functional End Groups of Perfluoropolyether (Z-dol and Z-03) Lubricants in Augmenting the Tribology of SU-8 Composites 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2014 Abstract In an earlier work, we demonstrated the development of SU-8 composites using perfluoropolyether (PFPE) as lubricant filler which reduced friction coefficient by ~7 times and enhanced wear life of SU-8 by more than four orders of magnitude. In this work, we have investigated the role of chemical bonding between SU-8 and PFPE molecules using two types of PFPE lubricants (i.e., $ Fomblin^{®} $ Z-dol and Z-03) in improving the tribological properties of the composite. Z-dol has polar (–OH) end groups whereas Z-03 has non-polar ($ CF_{3} $) end groups. SU-8 with Z-dol (SU-8 + Z-dol) films yielded ~8 times greater wear life than SU-8 with Z-03 (SU-8 + Z-03) films and more by four orders of magnitude than pure SU-8. The nature of the films was analyzed in detail by chemical and physical characterization techniques like X-ray photoelectron spectroscopy, water contact angle and thermo-gravimetric analysis. The results validated the role of polar end functional group of Z-dol in covalent binding with SU-8 upon UV plasma treatment that resulted in improved tribological properties. Polymer tribology SU-8 composite PFPE Jayaraman, Sundaramurthy aut Minh, Duong Hai aut Sinha, Sujeet K. aut Enthalten in Tribology letters Springer US, 1995 56(2014), 3 vom: 14. Okt., Seite 423-434 (DE-627)221187790 (DE-600)1355921-7 (DE-576)06488354X 1023-8883 nnns volume:56 year:2014 number:3 day:14 month:10 pages:423-434 https://doi.org/10.1007/s11249-014-0419-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_70 AR 56 2014 3 14 10 423-434 |
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10.1007/s11249-014-0419-8 doi (DE-627)OLC2054484539 (DE-He213)s11249-014-0419-8-p DE-627 ger DE-627 rakwb eng 670 VZ Prabakaran, Saravanan verfasserin aut The Role of Functional End Groups of Perfluoropolyether (Z-dol and Z-03) Lubricants in Augmenting the Tribology of SU-8 Composites 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2014 Abstract In an earlier work, we demonstrated the development of SU-8 composites using perfluoropolyether (PFPE) as lubricant filler which reduced friction coefficient by ~7 times and enhanced wear life of SU-8 by more than four orders of magnitude. In this work, we have investigated the role of chemical bonding between SU-8 and PFPE molecules using two types of PFPE lubricants (i.e., $ Fomblin^{®} $ Z-dol and Z-03) in improving the tribological properties of the composite. Z-dol has polar (–OH) end groups whereas Z-03 has non-polar ($ CF_{3} $) end groups. SU-8 with Z-dol (SU-8 + Z-dol) films yielded ~8 times greater wear life than SU-8 with Z-03 (SU-8 + Z-03) films and more by four orders of magnitude than pure SU-8. The nature of the films was analyzed in detail by chemical and physical characterization techniques like X-ray photoelectron spectroscopy, water contact angle and thermo-gravimetric analysis. The results validated the role of polar end functional group of Z-dol in covalent binding with SU-8 upon UV plasma treatment that resulted in improved tribological properties. Polymer tribology SU-8 composite PFPE Jayaraman, Sundaramurthy aut Minh, Duong Hai aut Sinha, Sujeet K. aut Enthalten in Tribology letters Springer US, 1995 56(2014), 3 vom: 14. Okt., Seite 423-434 (DE-627)221187790 (DE-600)1355921-7 (DE-576)06488354X 1023-8883 nnns volume:56 year:2014 number:3 day:14 month:10 pages:423-434 https://doi.org/10.1007/s11249-014-0419-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_70 AR 56 2014 3 14 10 423-434 |
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10.1007/s11249-014-0419-8 doi (DE-627)OLC2054484539 (DE-He213)s11249-014-0419-8-p DE-627 ger DE-627 rakwb eng 670 VZ Prabakaran, Saravanan verfasserin aut The Role of Functional End Groups of Perfluoropolyether (Z-dol and Z-03) Lubricants in Augmenting the Tribology of SU-8 Composites 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2014 Abstract In an earlier work, we demonstrated the development of SU-8 composites using perfluoropolyether (PFPE) as lubricant filler which reduced friction coefficient by ~7 times and enhanced wear life of SU-8 by more than four orders of magnitude. In this work, we have investigated the role of chemical bonding between SU-8 and PFPE molecules using two types of PFPE lubricants (i.e., $ Fomblin^{®} $ Z-dol and Z-03) in improving the tribological properties of the composite. Z-dol has polar (–OH) end groups whereas Z-03 has non-polar ($ CF_{3} $) end groups. SU-8 with Z-dol (SU-8 + Z-dol) films yielded ~8 times greater wear life than SU-8 with Z-03 (SU-8 + Z-03) films and more by four orders of magnitude than pure SU-8. The nature of the films was analyzed in detail by chemical and physical characterization techniques like X-ray photoelectron spectroscopy, water contact angle and thermo-gravimetric analysis. The results validated the role of polar end functional group of Z-dol in covalent binding with SU-8 upon UV plasma treatment that resulted in improved tribological properties. Polymer tribology SU-8 composite PFPE Jayaraman, Sundaramurthy aut Minh, Duong Hai aut Sinha, Sujeet K. aut Enthalten in Tribology letters Springer US, 1995 56(2014), 3 vom: 14. Okt., Seite 423-434 (DE-627)221187790 (DE-600)1355921-7 (DE-576)06488354X 1023-8883 nnns volume:56 year:2014 number:3 day:14 month:10 pages:423-434 https://doi.org/10.1007/s11249-014-0419-8 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_70 AR 56 2014 3 14 10 423-434 |
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The Role of Functional End Groups of Perfluoropolyether (Z-dol and Z-03) Lubricants in Augmenting the Tribology of SU-8 Composites |
abstract |
Abstract In an earlier work, we demonstrated the development of SU-8 composites using perfluoropolyether (PFPE) as lubricant filler which reduced friction coefficient by ~7 times and enhanced wear life of SU-8 by more than four orders of magnitude. In this work, we have investigated the role of chemical bonding between SU-8 and PFPE molecules using two types of PFPE lubricants (i.e., $ Fomblin^{®} $ Z-dol and Z-03) in improving the tribological properties of the composite. Z-dol has polar (–OH) end groups whereas Z-03 has non-polar ($ CF_{3} $) end groups. SU-8 with Z-dol (SU-8 + Z-dol) films yielded ~8 times greater wear life than SU-8 with Z-03 (SU-8 + Z-03) films and more by four orders of magnitude than pure SU-8. The nature of the films was analyzed in detail by chemical and physical characterization techniques like X-ray photoelectron spectroscopy, water contact angle and thermo-gravimetric analysis. The results validated the role of polar end functional group of Z-dol in covalent binding with SU-8 upon UV plasma treatment that resulted in improved tribological properties. © Springer Science+Business Media New York 2014 |
abstractGer |
Abstract In an earlier work, we demonstrated the development of SU-8 composites using perfluoropolyether (PFPE) as lubricant filler which reduced friction coefficient by ~7 times and enhanced wear life of SU-8 by more than four orders of magnitude. In this work, we have investigated the role of chemical bonding between SU-8 and PFPE molecules using two types of PFPE lubricants (i.e., $ Fomblin^{®} $ Z-dol and Z-03) in improving the tribological properties of the composite. Z-dol has polar (–OH) end groups whereas Z-03 has non-polar ($ CF_{3} $) end groups. SU-8 with Z-dol (SU-8 + Z-dol) films yielded ~8 times greater wear life than SU-8 with Z-03 (SU-8 + Z-03) films and more by four orders of magnitude than pure SU-8. The nature of the films was analyzed in detail by chemical and physical characterization techniques like X-ray photoelectron spectroscopy, water contact angle and thermo-gravimetric analysis. The results validated the role of polar end functional group of Z-dol in covalent binding with SU-8 upon UV plasma treatment that resulted in improved tribological properties. © Springer Science+Business Media New York 2014 |
abstract_unstemmed |
Abstract In an earlier work, we demonstrated the development of SU-8 composites using perfluoropolyether (PFPE) as lubricant filler which reduced friction coefficient by ~7 times and enhanced wear life of SU-8 by more than four orders of magnitude. In this work, we have investigated the role of chemical bonding between SU-8 and PFPE molecules using two types of PFPE lubricants (i.e., $ Fomblin^{®} $ Z-dol and Z-03) in improving the tribological properties of the composite. Z-dol has polar (–OH) end groups whereas Z-03 has non-polar ($ CF_{3} $) end groups. SU-8 with Z-dol (SU-8 + Z-dol) films yielded ~8 times greater wear life than SU-8 with Z-03 (SU-8 + Z-03) films and more by four orders of magnitude than pure SU-8. The nature of the films was analyzed in detail by chemical and physical characterization techniques like X-ray photoelectron spectroscopy, water contact angle and thermo-gravimetric analysis. The results validated the role of polar end functional group of Z-dol in covalent binding with SU-8 upon UV plasma treatment that resulted in improved tribological properties. © Springer Science+Business Media New York 2014 |
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title_short |
The Role of Functional End Groups of Perfluoropolyether (Z-dol and Z-03) Lubricants in Augmenting the Tribology of SU-8 Composites |
url |
https://doi.org/10.1007/s11249-014-0419-8 |
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author2 |
Jayaraman, Sundaramurthy Minh, Duong Hai Sinha, Sujeet K. |
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Jayaraman, Sundaramurthy Minh, Duong Hai Sinha, Sujeet K. |
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doi_str |
10.1007/s11249-014-0419-8 |
up_date |
2024-07-03T23:19:58.697Z |
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