Non-covalent chiral fibres in aqueous gels and their functionalization
Abstract The fully reversible synthesis of noncovalent assemblies which are held together by directed bonds is called synkinesis. Micellar fibres with a distinct stereochemistry and gels are formed by amphiphiles forming strong hydrogen bonds between chiral head groups. The 3D-crystallization of suc...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Fuhrhop, Jürgen-Hinrich [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1999 |
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| Schlagwörter: |
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| Anmerkung: |
© Indian Academy of Sciences 1999 |
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| Übergeordnetes Werk: |
Enthalten in: Bulletin of materials science - Springer India, 1979, 22(1999), 3 vom: Mai, Seite 307-312 |
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| Übergeordnetes Werk: |
volume:22 ; year:1999 ; number:3 ; month:05 ; pages:307-312 |
| Links: |
|---|
| DOI / URN: |
10.1007/BF02749936 |
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OLC2055190334 |
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| 520 | |a Abstract The fully reversible synthesis of noncovalent assemblies which are held together by directed bonds is called synkinesis. Micellar fibres with a distinct stereochemistry and gels are formed by amphiphiles forming strong hydrogen bonds between chiral head groups. The 3D-crystallization of such molecular assemblies, without dominating repulsive hydration forces, is prevented by the curvature of the fibres. Curvature might perhaps be directly connected with chirality. Addition of enantiomers often leads to an irreversible destruction of gels. Recent developments relating to ‘hydrophobic water’ in Ångström-wide membrane gaps are also shortly discussed. | ||
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| 700 | 1 | |a Zimmermann, Jörg |4 aut | |
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10.1007/BF02749936 doi (DE-627)OLC2055190334 (DE-He213)BF02749936-p DE-627 ger DE-627 rakwb eng 600 VZ Fuhrhop, Jürgen-Hinrich verfasserin aut Non-covalent chiral fibres in aqueous gels and their functionalization 1999 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Indian Academy of Sciences 1999 Abstract The fully reversible synthesis of noncovalent assemblies which are held together by directed bonds is called synkinesis. Micellar fibres with a distinct stereochemistry and gels are formed by amphiphiles forming strong hydrogen bonds between chiral head groups. The 3D-crystallization of such molecular assemblies, without dominating repulsive hydration forces, is prevented by the curvature of the fibres. Curvature might perhaps be directly connected with chirality. Addition of enantiomers often leads to an irreversible destruction of gels. Recent developments relating to ‘hydrophobic water’ in Ångström-wide membrane gaps are also shortly discussed. Micellar fibres porphyrin assemblies aqueous gels Svenson, Sönke aut Böttcher, Christoph aut Träger, Otto aut Demoulin, Corinna aut Schnieder, Peter aut Messerschmidt, Christian aut Ruhlmann, Laurent aut Zimmermann, Jörg aut Enthalten in Bulletin of materials science Springer India, 1979 22(1999), 3 vom: Mai, Seite 307-312 (DE-627)130547476 (DE-600)781668-6 (DE-576)9130547474 0250-4707 nnns volume:22 year:1999 number:3 month:05 pages:307-312 https://doi.org/10.1007/BF02749936 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_70 AR 22 1999 3 05 307-312 |
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10.1007/BF02749936 doi (DE-627)OLC2055190334 (DE-He213)BF02749936-p DE-627 ger DE-627 rakwb eng 600 VZ Fuhrhop, Jürgen-Hinrich verfasserin aut Non-covalent chiral fibres in aqueous gels and their functionalization 1999 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Indian Academy of Sciences 1999 Abstract The fully reversible synthesis of noncovalent assemblies which are held together by directed bonds is called synkinesis. Micellar fibres with a distinct stereochemistry and gels are formed by amphiphiles forming strong hydrogen bonds between chiral head groups. The 3D-crystallization of such molecular assemblies, without dominating repulsive hydration forces, is prevented by the curvature of the fibres. Curvature might perhaps be directly connected with chirality. Addition of enantiomers often leads to an irreversible destruction of gels. Recent developments relating to ‘hydrophobic water’ in Ångström-wide membrane gaps are also shortly discussed. Micellar fibres porphyrin assemblies aqueous gels Svenson, Sönke aut Böttcher, Christoph aut Träger, Otto aut Demoulin, Corinna aut Schnieder, Peter aut Messerschmidt, Christian aut Ruhlmann, Laurent aut Zimmermann, Jörg aut Enthalten in Bulletin of materials science Springer India, 1979 22(1999), 3 vom: Mai, Seite 307-312 (DE-627)130547476 (DE-600)781668-6 (DE-576)9130547474 0250-4707 nnns volume:22 year:1999 number:3 month:05 pages:307-312 https://doi.org/10.1007/BF02749936 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_70 AR 22 1999 3 05 307-312 |
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10.1007/BF02749936 doi (DE-627)OLC2055190334 (DE-He213)BF02749936-p DE-627 ger DE-627 rakwb eng 600 VZ Fuhrhop, Jürgen-Hinrich verfasserin aut Non-covalent chiral fibres in aqueous gels and their functionalization 1999 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Indian Academy of Sciences 1999 Abstract The fully reversible synthesis of noncovalent assemblies which are held together by directed bonds is called synkinesis. Micellar fibres with a distinct stereochemistry and gels are formed by amphiphiles forming strong hydrogen bonds between chiral head groups. The 3D-crystallization of such molecular assemblies, without dominating repulsive hydration forces, is prevented by the curvature of the fibres. Curvature might perhaps be directly connected with chirality. Addition of enantiomers often leads to an irreversible destruction of gels. Recent developments relating to ‘hydrophobic water’ in Ångström-wide membrane gaps are also shortly discussed. Micellar fibres porphyrin assemblies aqueous gels Svenson, Sönke aut Böttcher, Christoph aut Träger, Otto aut Demoulin, Corinna aut Schnieder, Peter aut Messerschmidt, Christian aut Ruhlmann, Laurent aut Zimmermann, Jörg aut Enthalten in Bulletin of materials science Springer India, 1979 22(1999), 3 vom: Mai, Seite 307-312 (DE-627)130547476 (DE-600)781668-6 (DE-576)9130547474 0250-4707 nnns volume:22 year:1999 number:3 month:05 pages:307-312 https://doi.org/10.1007/BF02749936 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_70 AR 22 1999 3 05 307-312 |
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10.1007/BF02749936 doi (DE-627)OLC2055190334 (DE-He213)BF02749936-p DE-627 ger DE-627 rakwb eng 600 VZ Fuhrhop, Jürgen-Hinrich verfasserin aut Non-covalent chiral fibres in aqueous gels and their functionalization 1999 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Indian Academy of Sciences 1999 Abstract The fully reversible synthesis of noncovalent assemblies which are held together by directed bonds is called synkinesis. Micellar fibres with a distinct stereochemistry and gels are formed by amphiphiles forming strong hydrogen bonds between chiral head groups. The 3D-crystallization of such molecular assemblies, without dominating repulsive hydration forces, is prevented by the curvature of the fibres. Curvature might perhaps be directly connected with chirality. Addition of enantiomers often leads to an irreversible destruction of gels. Recent developments relating to ‘hydrophobic water’ in Ångström-wide membrane gaps are also shortly discussed. Micellar fibres porphyrin assemblies aqueous gels Svenson, Sönke aut Böttcher, Christoph aut Träger, Otto aut Demoulin, Corinna aut Schnieder, Peter aut Messerschmidt, Christian aut Ruhlmann, Laurent aut Zimmermann, Jörg aut Enthalten in Bulletin of materials science Springer India, 1979 22(1999), 3 vom: Mai, Seite 307-312 (DE-627)130547476 (DE-600)781668-6 (DE-576)9130547474 0250-4707 nnns volume:22 year:1999 number:3 month:05 pages:307-312 https://doi.org/10.1007/BF02749936 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_70 AR 22 1999 3 05 307-312 |
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Abstract The fully reversible synthesis of noncovalent assemblies which are held together by directed bonds is called synkinesis. Micellar fibres with a distinct stereochemistry and gels are formed by amphiphiles forming strong hydrogen bonds between chiral head groups. The 3D-crystallization of such molecular assemblies, without dominating repulsive hydration forces, is prevented by the curvature of the fibres. Curvature might perhaps be directly connected with chirality. Addition of enantiomers often leads to an irreversible destruction of gels. Recent developments relating to ‘hydrophobic water’ in Ångström-wide membrane gaps are also shortly discussed. © Indian Academy of Sciences 1999 |
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Abstract The fully reversible synthesis of noncovalent assemblies which are held together by directed bonds is called synkinesis. Micellar fibres with a distinct stereochemistry and gels are formed by amphiphiles forming strong hydrogen bonds between chiral head groups. The 3D-crystallization of such molecular assemblies, without dominating repulsive hydration forces, is prevented by the curvature of the fibres. Curvature might perhaps be directly connected with chirality. Addition of enantiomers often leads to an irreversible destruction of gels. Recent developments relating to ‘hydrophobic water’ in Ångström-wide membrane gaps are also shortly discussed. © Indian Academy of Sciences 1999 |
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Abstract The fully reversible synthesis of noncovalent assemblies which are held together by directed bonds is called synkinesis. Micellar fibres with a distinct stereochemistry and gels are formed by amphiphiles forming strong hydrogen bonds between chiral head groups. The 3D-crystallization of such molecular assemblies, without dominating repulsive hydration forces, is prevented by the curvature of the fibres. Curvature might perhaps be directly connected with chirality. Addition of enantiomers often leads to an irreversible destruction of gels. Recent developments relating to ‘hydrophobic water’ in Ångström-wide membrane gaps are also shortly discussed. © Indian Academy of Sciences 1999 |
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