Nonlinear rheology for threadlike micelles of tetraethylammonium perfluorooctyl sulfonate
Abstract Nonlinear rheological features were investigated for an aqueous solution of tetraethylammonium perfluorooctyl sulfonate ($ C_{8} $$ F_{17} $$ SO_{3} $–$ N^{+} $($ C_{2} $$ H_{5} $)4; abbreviated as FOSTEA). In the solution (c=0.045 mol/l; 28.3 g/l), spherical micelles of FOSTEA were connect...
Ausführliche Beschreibung
Autor*in: |
Watanabe, H. [verfasserIn] |
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Format: |
Artikel |
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Sprache: |
Englisch |
Erschienen: |
1998 |
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Anmerkung: |
© Steinkopff Verlag 1998 |
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Übergeordnetes Werk: |
Enthalten in: Rheologica acta - Steinkopff Verlag, 1961, 37(1998), 5 vom: Nov., Seite 470-485 |
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Übergeordnetes Werk: |
volume:37 ; year:1998 ; number:5 ; month:11 ; pages:470-485 |
Links: |
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DOI / URN: |
10.1007/s003970050134 |
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Katalog-ID: |
OLC205600433X |
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245 | 1 | 0 | |a Nonlinear rheology for threadlike micelles of tetraethylammonium perfluorooctyl sulfonate |
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520 | |a Abstract Nonlinear rheological features were investigated for an aqueous solution of tetraethylammonium perfluorooctyl sulfonate ($ C_{8} $$ F_{17} $$ SO_{3} $–$ N^{+} $($ C_{2} $$ H_{5} $)4; abbreviated as FOSTEA). In the solution (c=0.045 mol/l; 28.3 g/l), spherical micelles of FOSTEA were connected with each other to form threads of pearl-necklace shape. These threads were further organized into a transient network to exhibit linear relaxation characteristic of living polymers, single-mode terminal relaxation widely separated from faster relaxation processes. Nonlinear relaxation experiments against large step-strains γ(≤8) revealed that the terminal relaxation mode had a γ-insensitive relaxation time but its relaxation intensity exhibited significant damping (much stronger than that for entangled polymers). In contrast, the relaxation time and intensity for the fast relaxation modes first increased and then decreased with increasing γ. Under shear flow, the FOSTEA threads exhibited strong thinning of the viscosity. These nonlinear features of the FOSTEA threads were compared with those of other threadlike micelles, analyzed on the basis of an empirically introduced constitutive equation, and discussed in relation to strain/low-induced scission of the living threads. | ||
700 | 1 | |a Osaki, Kunihiro |4 aut | |
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700 | 1 | |a Bossev, Dobrin P. |4 aut | |
700 | 1 | |a McNamee, Cathy E. |4 aut | |
700 | 1 | |a Nakahara, Masaru |4 aut | |
700 | 1 | |a Yao, Ming-Long |4 aut | |
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10.1007/s003970050134 doi (DE-627)OLC205600433X (DE-He213)s003970050134-p DE-627 ger DE-627 rakwb eng 540 660 VZ 530 VZ Watanabe, H. verfasserin aut Nonlinear rheology for threadlike micelles of tetraethylammonium perfluorooctyl sulfonate 1998 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Steinkopff Verlag 1998 Abstract Nonlinear rheological features were investigated for an aqueous solution of tetraethylammonium perfluorooctyl sulfonate ($ C_{8} $$ F_{17} $$ SO_{3} $–$ N^{+} $($ C_{2} $$ H_{5} $)4; abbreviated as FOSTEA). In the solution (c=0.045 mol/l; 28.3 g/l), spherical micelles of FOSTEA were connected with each other to form threads of pearl-necklace shape. These threads were further organized into a transient network to exhibit linear relaxation characteristic of living polymers, single-mode terminal relaxation widely separated from faster relaxation processes. Nonlinear relaxation experiments against large step-strains γ(≤8) revealed that the terminal relaxation mode had a γ-insensitive relaxation time but its relaxation intensity exhibited significant damping (much stronger than that for entangled polymers). In contrast, the relaxation time and intensity for the fast relaxation modes first increased and then decreased with increasing γ. Under shear flow, the FOSTEA threads exhibited strong thinning of the viscosity. These nonlinear features of the FOSTEA threads were compared with those of other threadlike micelles, analyzed on the basis of an empirically introduced constitutive equation, and discussed in relation to strain/low-induced scission of the living threads. Osaki, Kunihiro aut Matsumoto, Mutsuo aut Bossev, Dobrin P. aut McNamee, Cathy E. aut Nakahara, Masaru aut Yao, Ming-Long aut Enthalten in Rheologica acta Steinkopff Verlag, 1961 37(1998), 5 vom: Nov., Seite 470-485 (DE-627)129512052 (DE-600)210407-6 (DE-576)014919613 0035-4511 nnns volume:37 year:1998 number:5 month:11 pages:470-485 https://doi.org/10.1007/s003970050134 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY SSG-OPC-GEO SSG-OPC-GGO GBV_ILN_11 GBV_ILN_21 GBV_ILN_30 GBV_ILN_40 GBV_ILN_65 GBV_ILN_70 GBV_ILN_95 GBV_ILN_170 GBV_ILN_2016 GBV_ILN_2020 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4307 GBV_ILN_4323 AR 37 1998 5 11 470-485 |
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10.1007/s003970050134 doi (DE-627)OLC205600433X (DE-He213)s003970050134-p DE-627 ger DE-627 rakwb eng 540 660 VZ 530 VZ Watanabe, H. verfasserin aut Nonlinear rheology for threadlike micelles of tetraethylammonium perfluorooctyl sulfonate 1998 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Steinkopff Verlag 1998 Abstract Nonlinear rheological features were investigated for an aqueous solution of tetraethylammonium perfluorooctyl sulfonate ($ C_{8} $$ F_{17} $$ SO_{3} $–$ N^{+} $($ C_{2} $$ H_{5} $)4; abbreviated as FOSTEA). In the solution (c=0.045 mol/l; 28.3 g/l), spherical micelles of FOSTEA were connected with each other to form threads of pearl-necklace shape. These threads were further organized into a transient network to exhibit linear relaxation characteristic of living polymers, single-mode terminal relaxation widely separated from faster relaxation processes. Nonlinear relaxation experiments against large step-strains γ(≤8) revealed that the terminal relaxation mode had a γ-insensitive relaxation time but its relaxation intensity exhibited significant damping (much stronger than that for entangled polymers). In contrast, the relaxation time and intensity for the fast relaxation modes first increased and then decreased with increasing γ. Under shear flow, the FOSTEA threads exhibited strong thinning of the viscosity. These nonlinear features of the FOSTEA threads were compared with those of other threadlike micelles, analyzed on the basis of an empirically introduced constitutive equation, and discussed in relation to strain/low-induced scission of the living threads. Osaki, Kunihiro aut Matsumoto, Mutsuo aut Bossev, Dobrin P. aut McNamee, Cathy E. aut Nakahara, Masaru aut Yao, Ming-Long aut Enthalten in Rheologica acta Steinkopff Verlag, 1961 37(1998), 5 vom: Nov., Seite 470-485 (DE-627)129512052 (DE-600)210407-6 (DE-576)014919613 0035-4511 nnns volume:37 year:1998 number:5 month:11 pages:470-485 https://doi.org/10.1007/s003970050134 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY SSG-OPC-GEO SSG-OPC-GGO GBV_ILN_11 GBV_ILN_21 GBV_ILN_30 GBV_ILN_40 GBV_ILN_65 GBV_ILN_70 GBV_ILN_95 GBV_ILN_170 GBV_ILN_2016 GBV_ILN_2020 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4307 GBV_ILN_4323 AR 37 1998 5 11 470-485 |
allfields_unstemmed |
10.1007/s003970050134 doi (DE-627)OLC205600433X (DE-He213)s003970050134-p DE-627 ger DE-627 rakwb eng 540 660 VZ 530 VZ Watanabe, H. verfasserin aut Nonlinear rheology for threadlike micelles of tetraethylammonium perfluorooctyl sulfonate 1998 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Steinkopff Verlag 1998 Abstract Nonlinear rheological features were investigated for an aqueous solution of tetraethylammonium perfluorooctyl sulfonate ($ C_{8} $$ F_{17} $$ SO_{3} $–$ N^{+} $($ C_{2} $$ H_{5} $)4; abbreviated as FOSTEA). In the solution (c=0.045 mol/l; 28.3 g/l), spherical micelles of FOSTEA were connected with each other to form threads of pearl-necklace shape. These threads were further organized into a transient network to exhibit linear relaxation characteristic of living polymers, single-mode terminal relaxation widely separated from faster relaxation processes. Nonlinear relaxation experiments against large step-strains γ(≤8) revealed that the terminal relaxation mode had a γ-insensitive relaxation time but its relaxation intensity exhibited significant damping (much stronger than that for entangled polymers). In contrast, the relaxation time and intensity for the fast relaxation modes first increased and then decreased with increasing γ. Under shear flow, the FOSTEA threads exhibited strong thinning of the viscosity. These nonlinear features of the FOSTEA threads were compared with those of other threadlike micelles, analyzed on the basis of an empirically introduced constitutive equation, and discussed in relation to strain/low-induced scission of the living threads. Osaki, Kunihiro aut Matsumoto, Mutsuo aut Bossev, Dobrin P. aut McNamee, Cathy E. aut Nakahara, Masaru aut Yao, Ming-Long aut Enthalten in Rheologica acta Steinkopff Verlag, 1961 37(1998), 5 vom: Nov., Seite 470-485 (DE-627)129512052 (DE-600)210407-6 (DE-576)014919613 0035-4511 nnns volume:37 year:1998 number:5 month:11 pages:470-485 https://doi.org/10.1007/s003970050134 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY SSG-OPC-GEO SSG-OPC-GGO GBV_ILN_11 GBV_ILN_21 GBV_ILN_30 GBV_ILN_40 GBV_ILN_65 GBV_ILN_70 GBV_ILN_95 GBV_ILN_170 GBV_ILN_2016 GBV_ILN_2020 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4307 GBV_ILN_4323 AR 37 1998 5 11 470-485 |
allfieldsGer |
10.1007/s003970050134 doi (DE-627)OLC205600433X (DE-He213)s003970050134-p DE-627 ger DE-627 rakwb eng 540 660 VZ 530 VZ Watanabe, H. verfasserin aut Nonlinear rheology for threadlike micelles of tetraethylammonium perfluorooctyl sulfonate 1998 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Steinkopff Verlag 1998 Abstract Nonlinear rheological features were investigated for an aqueous solution of tetraethylammonium perfluorooctyl sulfonate ($ C_{8} $$ F_{17} $$ SO_{3} $–$ N^{+} $($ C_{2} $$ H_{5} $)4; abbreviated as FOSTEA). In the solution (c=0.045 mol/l; 28.3 g/l), spherical micelles of FOSTEA were connected with each other to form threads of pearl-necklace shape. These threads were further organized into a transient network to exhibit linear relaxation characteristic of living polymers, single-mode terminal relaxation widely separated from faster relaxation processes. Nonlinear relaxation experiments against large step-strains γ(≤8) revealed that the terminal relaxation mode had a γ-insensitive relaxation time but its relaxation intensity exhibited significant damping (much stronger than that for entangled polymers). In contrast, the relaxation time and intensity for the fast relaxation modes first increased and then decreased with increasing γ. Under shear flow, the FOSTEA threads exhibited strong thinning of the viscosity. These nonlinear features of the FOSTEA threads were compared with those of other threadlike micelles, analyzed on the basis of an empirically introduced constitutive equation, and discussed in relation to strain/low-induced scission of the living threads. Osaki, Kunihiro aut Matsumoto, Mutsuo aut Bossev, Dobrin P. aut McNamee, Cathy E. aut Nakahara, Masaru aut Yao, Ming-Long aut Enthalten in Rheologica acta Steinkopff Verlag, 1961 37(1998), 5 vom: Nov., Seite 470-485 (DE-627)129512052 (DE-600)210407-6 (DE-576)014919613 0035-4511 nnns volume:37 year:1998 number:5 month:11 pages:470-485 https://doi.org/10.1007/s003970050134 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY SSG-OPC-GEO SSG-OPC-GGO GBV_ILN_11 GBV_ILN_21 GBV_ILN_30 GBV_ILN_40 GBV_ILN_65 GBV_ILN_70 GBV_ILN_95 GBV_ILN_170 GBV_ILN_2016 GBV_ILN_2020 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4307 GBV_ILN_4323 AR 37 1998 5 11 470-485 |
allfieldsSound |
10.1007/s003970050134 doi (DE-627)OLC205600433X (DE-He213)s003970050134-p DE-627 ger DE-627 rakwb eng 540 660 VZ 530 VZ Watanabe, H. verfasserin aut Nonlinear rheology for threadlike micelles of tetraethylammonium perfluorooctyl sulfonate 1998 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Steinkopff Verlag 1998 Abstract Nonlinear rheological features were investigated for an aqueous solution of tetraethylammonium perfluorooctyl sulfonate ($ C_{8} $$ F_{17} $$ SO_{3} $–$ N^{+} $($ C_{2} $$ H_{5} $)4; abbreviated as FOSTEA). In the solution (c=0.045 mol/l; 28.3 g/l), spherical micelles of FOSTEA were connected with each other to form threads of pearl-necklace shape. These threads were further organized into a transient network to exhibit linear relaxation characteristic of living polymers, single-mode terminal relaxation widely separated from faster relaxation processes. Nonlinear relaxation experiments against large step-strains γ(≤8) revealed that the terminal relaxation mode had a γ-insensitive relaxation time but its relaxation intensity exhibited significant damping (much stronger than that for entangled polymers). In contrast, the relaxation time and intensity for the fast relaxation modes first increased and then decreased with increasing γ. Under shear flow, the FOSTEA threads exhibited strong thinning of the viscosity. These nonlinear features of the FOSTEA threads were compared with those of other threadlike micelles, analyzed on the basis of an empirically introduced constitutive equation, and discussed in relation to strain/low-induced scission of the living threads. Osaki, Kunihiro aut Matsumoto, Mutsuo aut Bossev, Dobrin P. aut McNamee, Cathy E. aut Nakahara, Masaru aut Yao, Ming-Long aut Enthalten in Rheologica acta Steinkopff Verlag, 1961 37(1998), 5 vom: Nov., Seite 470-485 (DE-627)129512052 (DE-600)210407-6 (DE-576)014919613 0035-4511 nnns volume:37 year:1998 number:5 month:11 pages:470-485 https://doi.org/10.1007/s003970050134 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY SSG-OPC-GEO SSG-OPC-GGO GBV_ILN_11 GBV_ILN_21 GBV_ILN_30 GBV_ILN_40 GBV_ILN_65 GBV_ILN_70 GBV_ILN_95 GBV_ILN_170 GBV_ILN_2016 GBV_ILN_2020 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4307 GBV_ILN_4323 AR 37 1998 5 11 470-485 |
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Watanabe, H. @@aut@@ Osaki, Kunihiro @@aut@@ Matsumoto, Mutsuo @@aut@@ Bossev, Dobrin P. @@aut@@ McNamee, Cathy E. @@aut@@ Nakahara, Masaru @@aut@@ Yao, Ming-Long @@aut@@ |
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nonlinear rheology for threadlike micelles of tetraethylammonium perfluorooctyl sulfonate |
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Nonlinear rheology for threadlike micelles of tetraethylammonium perfluorooctyl sulfonate |
abstract |
Abstract Nonlinear rheological features were investigated for an aqueous solution of tetraethylammonium perfluorooctyl sulfonate ($ C_{8} $$ F_{17} $$ SO_{3} $–$ N^{+} $($ C_{2} $$ H_{5} $)4; abbreviated as FOSTEA). In the solution (c=0.045 mol/l; 28.3 g/l), spherical micelles of FOSTEA were connected with each other to form threads of pearl-necklace shape. These threads were further organized into a transient network to exhibit linear relaxation characteristic of living polymers, single-mode terminal relaxation widely separated from faster relaxation processes. Nonlinear relaxation experiments against large step-strains γ(≤8) revealed that the terminal relaxation mode had a γ-insensitive relaxation time but its relaxation intensity exhibited significant damping (much stronger than that for entangled polymers). In contrast, the relaxation time and intensity for the fast relaxation modes first increased and then decreased with increasing γ. Under shear flow, the FOSTEA threads exhibited strong thinning of the viscosity. These nonlinear features of the FOSTEA threads were compared with those of other threadlike micelles, analyzed on the basis of an empirically introduced constitutive equation, and discussed in relation to strain/low-induced scission of the living threads. © Steinkopff Verlag 1998 |
abstractGer |
Abstract Nonlinear rheological features were investigated for an aqueous solution of tetraethylammonium perfluorooctyl sulfonate ($ C_{8} $$ F_{17} $$ SO_{3} $–$ N^{+} $($ C_{2} $$ H_{5} $)4; abbreviated as FOSTEA). In the solution (c=0.045 mol/l; 28.3 g/l), spherical micelles of FOSTEA were connected with each other to form threads of pearl-necklace shape. These threads were further organized into a transient network to exhibit linear relaxation characteristic of living polymers, single-mode terminal relaxation widely separated from faster relaxation processes. Nonlinear relaxation experiments against large step-strains γ(≤8) revealed that the terminal relaxation mode had a γ-insensitive relaxation time but its relaxation intensity exhibited significant damping (much stronger than that for entangled polymers). In contrast, the relaxation time and intensity for the fast relaxation modes first increased and then decreased with increasing γ. Under shear flow, the FOSTEA threads exhibited strong thinning of the viscosity. These nonlinear features of the FOSTEA threads were compared with those of other threadlike micelles, analyzed on the basis of an empirically introduced constitutive equation, and discussed in relation to strain/low-induced scission of the living threads. © Steinkopff Verlag 1998 |
abstract_unstemmed |
Abstract Nonlinear rheological features were investigated for an aqueous solution of tetraethylammonium perfluorooctyl sulfonate ($ C_{8} $$ F_{17} $$ SO_{3} $–$ N^{+} $($ C_{2} $$ H_{5} $)4; abbreviated as FOSTEA). In the solution (c=0.045 mol/l; 28.3 g/l), spherical micelles of FOSTEA were connected with each other to form threads of pearl-necklace shape. These threads were further organized into a transient network to exhibit linear relaxation characteristic of living polymers, single-mode terminal relaxation widely separated from faster relaxation processes. Nonlinear relaxation experiments against large step-strains γ(≤8) revealed that the terminal relaxation mode had a γ-insensitive relaxation time but its relaxation intensity exhibited significant damping (much stronger than that for entangled polymers). In contrast, the relaxation time and intensity for the fast relaxation modes first increased and then decreased with increasing γ. Under shear flow, the FOSTEA threads exhibited strong thinning of the viscosity. These nonlinear features of the FOSTEA threads were compared with those of other threadlike micelles, analyzed on the basis of an empirically introduced constitutive equation, and discussed in relation to strain/low-induced scission of the living threads. © Steinkopff Verlag 1998 |
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