Nonlinear rheology for threadlike micelles of tetraethylammonium perfluorooctyl sulfonate

Abstract Nonlinear rheological features were investigated for an aqueous solution of tetraethylammonium perfluorooctyl sulfonate ($ C_{8} $$ F_{17} $$ SO_{3} $–$ N^{+} $($ C_{2} $$ H_{5} $)4; abbreviated as FOSTEA). In the solution (c=0.045 mol/l; 28.3 g/l), spherical micelles of FOSTEA were connect...
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Autor*in:	Watanabe, H. [verfasserIn] Osaki, Kunihiro Matsumoto, Mutsuo Bossev, Dobrin P. McNamee, Cathy E. Nakahara, Masaru Yao, Ming-Long

Format:	Artikel
Sprache:	Englisch

Erschienen:	1998

Anmerkung:	© Steinkopff Verlag 1998

Übergeordnetes Werk:	Enthalten in: Rheologica acta - Steinkopff Verlag, 1961, 37(1998), 5 vom: Nov., Seite 470-485
Übergeordnetes Werk:	volume:37 ; year:1998 ; number:5 ; month:11 ; pages:470-485

Links:	Volltext

DOI / URN:	10.1007/s003970050134

Katalog-ID:	OLC205600433X

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520			\|a Abstract Nonlinear rheological features were investigated for an aqueous solution of tetraethylammonium perfluorooctyl sulfonate ($ C_{8} $$ F_{17} $$ SO_{3} $–$ N^{+} $($ C_{2} $$ H_{5} $)4; abbreviated as FOSTEA). In the solution (c=0.045 mol/l; 28.3 g/l), spherical micelles of FOSTEA were connected with each other to form threads of pearl-necklace shape. These threads were further organized into a transient network to exhibit linear relaxation characteristic of living polymers, single-mode terminal relaxation widely separated from faster relaxation processes. Nonlinear relaxation experiments against large step-strains γ(≤8) revealed that the terminal relaxation mode had a γ-insensitive relaxation time but its relaxation intensity exhibited significant damping (much stronger than that for entangled polymers). In contrast, the relaxation time and intensity for the fast relaxation modes first increased and then decreased with increasing γ. Under shear flow, the FOSTEA threads exhibited strong thinning of the viscosity. These nonlinear features of the FOSTEA threads were compared with those of other threadlike micelles, analyzed on the basis of an empirically introduced constitutive equation, and discussed in relation to strain/low-induced scission of the living threads.
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allfields	10.1007/s003970050134 doi (DE-627)OLC205600433X (DE-He213)s003970050134-p DE-627 ger DE-627 rakwb eng 540 660 VZ 530 VZ Watanabe, H. verfasserin aut Nonlinear rheology for threadlike micelles of tetraethylammonium perfluorooctyl sulfonate 1998 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Steinkopff Verlag 1998 Abstract Nonlinear rheological features were investigated for an aqueous solution of tetraethylammonium perfluorooctyl sulfonate ($ C_{8} $$ F_{17} $$ SO_{3} $–$ N^{+} $($ C_{2} $$ H_{5} $)4; abbreviated as FOSTEA). In the solution (c=0.045 mol/l; 28.3 g/l), spherical micelles of FOSTEA were connected with each other to form threads of pearl-necklace shape. These threads were further organized into a transient network to exhibit linear relaxation characteristic of living polymers, single-mode terminal relaxation widely separated from faster relaxation processes. Nonlinear relaxation experiments against large step-strains γ(≤8) revealed that the terminal relaxation mode had a γ-insensitive relaxation time but its relaxation intensity exhibited significant damping (much stronger than that for entangled polymers). In contrast, the relaxation time and intensity for the fast relaxation modes first increased and then decreased with increasing γ. Under shear flow, the FOSTEA threads exhibited strong thinning of the viscosity. These nonlinear features of the FOSTEA threads were compared with those of other threadlike micelles, analyzed on the basis of an empirically introduced constitutive equation, and discussed in relation to strain/low-induced scission of the living threads. Osaki, Kunihiro aut Matsumoto, Mutsuo aut Bossev, Dobrin P. aut McNamee, Cathy E. aut Nakahara, Masaru aut Yao, Ming-Long aut Enthalten in Rheologica acta Steinkopff Verlag, 1961 37(1998), 5 vom: Nov., Seite 470-485 (DE-627)129512052 (DE-600)210407-6 (DE-576)014919613 0035-4511 nnns volume:37 year:1998 number:5 month:11 pages:470-485 https://doi.org/10.1007/s003970050134 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY SSG-OPC-GEO SSG-OPC-GGO GBV_ILN_11 GBV_ILN_21 GBV_ILN_30 GBV_ILN_40 GBV_ILN_65 GBV_ILN_70 GBV_ILN_95 GBV_ILN_170 GBV_ILN_2016 GBV_ILN_2020 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4307 GBV_ILN_4323 AR 37 1998 5 11 470-485
spelling	10.1007/s003970050134 doi (DE-627)OLC205600433X (DE-He213)s003970050134-p DE-627 ger DE-627 rakwb eng 540 660 VZ 530 VZ Watanabe, H. verfasserin aut Nonlinear rheology for threadlike micelles of tetraethylammonium perfluorooctyl sulfonate 1998 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Steinkopff Verlag 1998 Abstract Nonlinear rheological features were investigated for an aqueous solution of tetraethylammonium perfluorooctyl sulfonate ($ C_{8} $$ F_{17} $$ SO_{3} $–$ N^{+} $($ C_{2} $$ H_{5} $)4; abbreviated as FOSTEA). In the solution (c=0.045 mol/l; 28.3 g/l), spherical micelles of FOSTEA were connected with each other to form threads of pearl-necklace shape. These threads were further organized into a transient network to exhibit linear relaxation characteristic of living polymers, single-mode terminal relaxation widely separated from faster relaxation processes. Nonlinear relaxation experiments against large step-strains γ(≤8) revealed that the terminal relaxation mode had a γ-insensitive relaxation time but its relaxation intensity exhibited significant damping (much stronger than that for entangled polymers). In contrast, the relaxation time and intensity for the fast relaxation modes first increased and then decreased with increasing γ. Under shear flow, the FOSTEA threads exhibited strong thinning of the viscosity. These nonlinear features of the FOSTEA threads were compared with those of other threadlike micelles, analyzed on the basis of an empirically introduced constitutive equation, and discussed in relation to strain/low-induced scission of the living threads. Osaki, Kunihiro aut Matsumoto, Mutsuo aut Bossev, Dobrin P. aut McNamee, Cathy E. aut Nakahara, Masaru aut Yao, Ming-Long aut Enthalten in Rheologica acta Steinkopff Verlag, 1961 37(1998), 5 vom: Nov., Seite 470-485 (DE-627)129512052 (DE-600)210407-6 (DE-576)014919613 0035-4511 nnns volume:37 year:1998 number:5 month:11 pages:470-485 https://doi.org/10.1007/s003970050134 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY SSG-OPC-GEO SSG-OPC-GGO GBV_ILN_11 GBV_ILN_21 GBV_ILN_30 GBV_ILN_40 GBV_ILN_65 GBV_ILN_70 GBV_ILN_95 GBV_ILN_170 GBV_ILN_2016 GBV_ILN_2020 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4307 GBV_ILN_4323 AR 37 1998 5 11 470-485
allfields_unstemmed	10.1007/s003970050134 doi (DE-627)OLC205600433X (DE-He213)s003970050134-p DE-627 ger DE-627 rakwb eng 540 660 VZ 530 VZ Watanabe, H. verfasserin aut Nonlinear rheology for threadlike micelles of tetraethylammonium perfluorooctyl sulfonate 1998 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Steinkopff Verlag 1998 Abstract Nonlinear rheological features were investigated for an aqueous solution of tetraethylammonium perfluorooctyl sulfonate ($ C_{8} $$ F_{17} $$ SO_{3} $–$ N^{+} $($ C_{2} $$ H_{5} $)4; abbreviated as FOSTEA). In the solution (c=0.045 mol/l; 28.3 g/l), spherical micelles of FOSTEA were connected with each other to form threads of pearl-necklace shape. These threads were further organized into a transient network to exhibit linear relaxation characteristic of living polymers, single-mode terminal relaxation widely separated from faster relaxation processes. Nonlinear relaxation experiments against large step-strains γ(≤8) revealed that the terminal relaxation mode had a γ-insensitive relaxation time but its relaxation intensity exhibited significant damping (much stronger than that for entangled polymers). In contrast, the relaxation time and intensity for the fast relaxation modes first increased and then decreased with increasing γ. Under shear flow, the FOSTEA threads exhibited strong thinning of the viscosity. These nonlinear features of the FOSTEA threads were compared with those of other threadlike micelles, analyzed on the basis of an empirically introduced constitutive equation, and discussed in relation to strain/low-induced scission of the living threads. Osaki, Kunihiro aut Matsumoto, Mutsuo aut Bossev, Dobrin P. aut McNamee, Cathy E. aut Nakahara, Masaru aut Yao, Ming-Long aut Enthalten in Rheologica acta Steinkopff Verlag, 1961 37(1998), 5 vom: Nov., Seite 470-485 (DE-627)129512052 (DE-600)210407-6 (DE-576)014919613 0035-4511 nnns volume:37 year:1998 number:5 month:11 pages:470-485 https://doi.org/10.1007/s003970050134 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY SSG-OPC-GEO SSG-OPC-GGO GBV_ILN_11 GBV_ILN_21 GBV_ILN_30 GBV_ILN_40 GBV_ILN_65 GBV_ILN_70 GBV_ILN_95 GBV_ILN_170 GBV_ILN_2016 GBV_ILN_2020 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4307 GBV_ILN_4323 AR 37 1998 5 11 470-485
allfieldsGer	10.1007/s003970050134 doi (DE-627)OLC205600433X (DE-He213)s003970050134-p DE-627 ger DE-627 rakwb eng 540 660 VZ 530 VZ Watanabe, H. verfasserin aut Nonlinear rheology for threadlike micelles of tetraethylammonium perfluorooctyl sulfonate 1998 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Steinkopff Verlag 1998 Abstract Nonlinear rheological features were investigated for an aqueous solution of tetraethylammonium perfluorooctyl sulfonate ($ C_{8} $$ F_{17} $$ SO_{3} $–$ N^{+} $($ C_{2} $$ H_{5} $)4; abbreviated as FOSTEA). In the solution (c=0.045 mol/l; 28.3 g/l), spherical micelles of FOSTEA were connected with each other to form threads of pearl-necklace shape. These threads were further organized into a transient network to exhibit linear relaxation characteristic of living polymers, single-mode terminal relaxation widely separated from faster relaxation processes. Nonlinear relaxation experiments against large step-strains γ(≤8) revealed that the terminal relaxation mode had a γ-insensitive relaxation time but its relaxation intensity exhibited significant damping (much stronger than that for entangled polymers). In contrast, the relaxation time and intensity for the fast relaxation modes first increased and then decreased with increasing γ. Under shear flow, the FOSTEA threads exhibited strong thinning of the viscosity. These nonlinear features of the FOSTEA threads were compared with those of other threadlike micelles, analyzed on the basis of an empirically introduced constitutive equation, and discussed in relation to strain/low-induced scission of the living threads. Osaki, Kunihiro aut Matsumoto, Mutsuo aut Bossev, Dobrin P. aut McNamee, Cathy E. aut Nakahara, Masaru aut Yao, Ming-Long aut Enthalten in Rheologica acta Steinkopff Verlag, 1961 37(1998), 5 vom: Nov., Seite 470-485 (DE-627)129512052 (DE-600)210407-6 (DE-576)014919613 0035-4511 nnns volume:37 year:1998 number:5 month:11 pages:470-485 https://doi.org/10.1007/s003970050134 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY SSG-OPC-GEO SSG-OPC-GGO GBV_ILN_11 GBV_ILN_21 GBV_ILN_30 GBV_ILN_40 GBV_ILN_65 GBV_ILN_70 GBV_ILN_95 GBV_ILN_170 GBV_ILN_2016 GBV_ILN_2020 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4307 GBV_ILN_4323 AR 37 1998 5 11 470-485
allfieldsSound	10.1007/s003970050134 doi (DE-627)OLC205600433X (DE-He213)s003970050134-p DE-627 ger DE-627 rakwb eng 540 660 VZ 530 VZ Watanabe, H. verfasserin aut Nonlinear rheology for threadlike micelles of tetraethylammonium perfluorooctyl sulfonate 1998 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Steinkopff Verlag 1998 Abstract Nonlinear rheological features were investigated for an aqueous solution of tetraethylammonium perfluorooctyl sulfonate ($ C_{8} $$ F_{17} $$ SO_{3} $–$ N^{+} $($ C_{2} $$ H_{5} $)4; abbreviated as FOSTEA). In the solution (c=0.045 mol/l; 28.3 g/l), spherical micelles of FOSTEA were connected with each other to form threads of pearl-necklace shape. These threads were further organized into a transient network to exhibit linear relaxation characteristic of living polymers, single-mode terminal relaxation widely separated from faster relaxation processes. Nonlinear relaxation experiments against large step-strains γ(≤8) revealed that the terminal relaxation mode had a γ-insensitive relaxation time but its relaxation intensity exhibited significant damping (much stronger than that for entangled polymers). In contrast, the relaxation time and intensity for the fast relaxation modes first increased and then decreased with increasing γ. Under shear flow, the FOSTEA threads exhibited strong thinning of the viscosity. These nonlinear features of the FOSTEA threads were compared with those of other threadlike micelles, analyzed on the basis of an empirically introduced constitutive equation, and discussed in relation to strain/low-induced scission of the living threads. Osaki, Kunihiro aut Matsumoto, Mutsuo aut Bossev, Dobrin P. aut McNamee, Cathy E. aut Nakahara, Masaru aut Yao, Ming-Long aut Enthalten in Rheologica acta Steinkopff Verlag, 1961 37(1998), 5 vom: Nov., Seite 470-485 (DE-627)129512052 (DE-600)210407-6 (DE-576)014919613 0035-4511 nnns volume:37 year:1998 number:5 month:11 pages:470-485 https://doi.org/10.1007/s003970050134 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY SSG-OPC-GEO SSG-OPC-GGO GBV_ILN_11 GBV_ILN_21 GBV_ILN_30 GBV_ILN_40 GBV_ILN_65 GBV_ILN_70 GBV_ILN_95 GBV_ILN_170 GBV_ILN_2016 GBV_ILN_2020 GBV_ILN_4012 GBV_ILN_4046 GBV_ILN_4307 GBV_ILN_4323 AR 37 1998 5 11 470-485
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author	Watanabe, H.
spellingShingle	Watanabe, H. ddc 540 ddc 530 Nonlinear rheology for threadlike micelles of tetraethylammonium perfluorooctyl sulfonate
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topic_title	540 660 VZ 530 VZ Nonlinear rheology for threadlike micelles of tetraethylammonium perfluorooctyl sulfonate
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title	Nonlinear rheology for threadlike micelles of tetraethylammonium perfluorooctyl sulfonate
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title_full	Nonlinear rheology for threadlike micelles of tetraethylammonium perfluorooctyl sulfonate
author_sort	Watanabe, H.
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author_browse	Watanabe, H. Osaki, Kunihiro Matsumoto, Mutsuo Bossev, Dobrin P. McNamee, Cathy E. Nakahara, Masaru Yao, Ming-Long
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title_sort	nonlinear rheology for threadlike micelles of tetraethylammonium perfluorooctyl sulfonate
title_auth	Nonlinear rheology for threadlike micelles of tetraethylammonium perfluorooctyl sulfonate
abstract	Abstract Nonlinear rheological features were investigated for an aqueous solution of tetraethylammonium perfluorooctyl sulfonate ($ C_{8} $$ F_{17} $$ SO_{3} $–$ N^{+} $($ C_{2} $$ H_{5} $)4; abbreviated as FOSTEA). In the solution (c=0.045 mol/l; 28.3 g/l), spherical micelles of FOSTEA were connected with each other to form threads of pearl-necklace shape. These threads were further organized into a transient network to exhibit linear relaxation characteristic of living polymers, single-mode terminal relaxation widely separated from faster relaxation processes. Nonlinear relaxation experiments against large step-strains γ(≤8) revealed that the terminal relaxation mode had a γ-insensitive relaxation time but its relaxation intensity exhibited significant damping (much stronger than that for entangled polymers). In contrast, the relaxation time and intensity for the fast relaxation modes first increased and then decreased with increasing γ. Under shear flow, the FOSTEA threads exhibited strong thinning of the viscosity. These nonlinear features of the FOSTEA threads were compared with those of other threadlike micelles, analyzed on the basis of an empirically introduced constitutive equation, and discussed in relation to strain/low-induced scission of the living threads. © Steinkopff Verlag 1998
abstractGer	Abstract Nonlinear rheological features were investigated for an aqueous solution of tetraethylammonium perfluorooctyl sulfonate ($ C_{8} $$ F_{17} $$ SO_{3} $–$ N^{+} $($ C_{2} $$ H_{5} $)4; abbreviated as FOSTEA). In the solution (c=0.045 mol/l; 28.3 g/l), spherical micelles of FOSTEA were connected with each other to form threads of pearl-necklace shape. These threads were further organized into a transient network to exhibit linear relaxation characteristic of living polymers, single-mode terminal relaxation widely separated from faster relaxation processes. Nonlinear relaxation experiments against large step-strains γ(≤8) revealed that the terminal relaxation mode had a γ-insensitive relaxation time but its relaxation intensity exhibited significant damping (much stronger than that for entangled polymers). In contrast, the relaxation time and intensity for the fast relaxation modes first increased and then decreased with increasing γ. Under shear flow, the FOSTEA threads exhibited strong thinning of the viscosity. These nonlinear features of the FOSTEA threads were compared with those of other threadlike micelles, analyzed on the basis of an empirically introduced constitutive equation, and discussed in relation to strain/low-induced scission of the living threads. © Steinkopff Verlag 1998
abstract_unstemmed	Abstract Nonlinear rheological features were investigated for an aqueous solution of tetraethylammonium perfluorooctyl sulfonate ($ C_{8} $$ F_{17} $$ SO_{3} $–$ N^{+} $($ C_{2} $$ H_{5} $)4; abbreviated as FOSTEA). In the solution (c=0.045 mol/l; 28.3 g/l), spherical micelles of FOSTEA were connected with each other to form threads of pearl-necklace shape. These threads were further organized into a transient network to exhibit linear relaxation characteristic of living polymers, single-mode terminal relaxation widely separated from faster relaxation processes. Nonlinear relaxation experiments against large step-strains γ(≤8) revealed that the terminal relaxation mode had a γ-insensitive relaxation time but its relaxation intensity exhibited significant damping (much stronger than that for entangled polymers). In contrast, the relaxation time and intensity for the fast relaxation modes first increased and then decreased with increasing γ. Under shear flow, the FOSTEA threads exhibited strong thinning of the viscosity. These nonlinear features of the FOSTEA threads were compared with those of other threadlike micelles, analyzed on the basis of an empirically introduced constitutive equation, and discussed in relation to strain/low-induced scission of the living threads. © Steinkopff Verlag 1998
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title_short	Nonlinear rheology for threadlike micelles of tetraethylammonium perfluorooctyl sulfonate
url	https://doi.org/10.1007/s003970050134
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author2	Osaki, Kunihiro Matsumoto, Mutsuo Bossev, Dobrin P. McNamee, Cathy E. Nakahara, Masaru Yao, Ming-Long
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up_date	2024-07-04T03:29:17.338Z
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