Sulfide and sulfate solid solubility in lime, magnesia, and calcined dolomite: Part I. CaS and $ CaSO_{4} $ solubility in CaO
Abstract In the present work the solid solubilities of CaS and CaSQ, in burnt lime were investigated by equilibrating lime with CO-$ CO_{2} $-$ SO_{2} $ mixtures at temperatures from 950 to 1300°C. Also, the equilibrium constants for the formation of CaS and $ CaSO_{4} $ were determined. At high oxy...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Turkdogan, E. T. [verfasserIn] |
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| Format: |
Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
1974 |
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| Schlagwörter: |
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| Anmerkung: |
© American Society for Metals, The Melallurgical Society of AIME 1974 |
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| Übergeordnetes Werk: |
Enthalten in: Metallurgical and materials transactions / B - Springer New York, 1994, 5(1974), 7 vom: 01. Juli, Seite 1527-1535 |
|---|---|
| Übergeordnetes Werk: |
volume:5 ; year:1974 ; number:7 ; day:01 ; month:07 ; pages:1527-1535 |
| Links: |
|---|
| DOI / URN: |
10.1007/BF02646322 |
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OLC2059731429 |
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| 245 | 1 | 0 | |a Sulfide and sulfate solid solubility in lime, magnesia, and calcined dolomite: Part I. CaS and $ CaSO_{4} $ solubility in CaO |
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| 520 | |a Abstract In the present work the solid solubilities of CaS and CaSQ, in burnt lime were investigated by equilibrating lime with CO-$ CO_{2} $-$ SO_{2} $ mixtures at temperatures from 950 to 1300°C. Also, the equilibrium constants for the formation of CaS and $ CaSO_{4} $ were determined. At high oxy-gen activities, corresponding to a $ CO_{2} $/CO ratio >100 in the gas, the sulfur dissolves in lime primarily as sulfate ions. At lower oxygen activities ($ CO_{2} $/CO <30), the sulfur goes into so-lution in lime essentially as sulfide ions. Over the temperature range investigated the limit-ing sulfide solubility is within 0.01 to 0.03 pct S, whereas the sulfate solubility is within 0.03 to 0.1 pct S, increasing with increasing temperature. | ||
| 650 | 4 | |a Lime | |
| 650 | 4 | |a Calcium Sulfate | |
| 650 | 4 | |a Sulfate Solubility | |
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| 700 | 1 | |a Rice, B. B. |4 aut | |
| 700 | 1 | |a Vinters, J. V. |4 aut | |
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10.1007/BF02646322 doi (DE-627)OLC2059731429 (DE-He213)BF02646322-p DE-627 ger DE-627 rakwb eng 620 660 VZ Turkdogan, E. T. verfasserin aut Sulfide and sulfate solid solubility in lime, magnesia, and calcined dolomite: Part I. CaS and $ CaSO_{4} $ solubility in CaO 1974 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © American Society for Metals, The Melallurgical Society of AIME 1974 Abstract In the present work the solid solubilities of CaS and CaSQ, in burnt lime were investigated by equilibrating lime with CO-$ CO_{2} $-$ SO_{2} $ mixtures at temperatures from 950 to 1300°C. Also, the equilibrium constants for the formation of CaS and $ CaSO_{4} $ were determined. At high oxy-gen activities, corresponding to a $ CO_{2} $/CO ratio >100 in the gas, the sulfur dissolves in lime primarily as sulfate ions. At lower oxygen activities ($ CO_{2} $/CO <30), the sulfur goes into so-lution in lime essentially as sulfide ions. Over the temperature range investigated the limit-ing sulfide solubility is within 0.01 to 0.03 pct S, whereas the sulfate solubility is within 0.03 to 0.1 pct S, increasing with increasing temperature. Lime Calcium Sulfate Sulfate Solubility Calcium Sulfide Sulfide Reaction Rice, B. B. aut Vinters, J. V. aut Enthalten in Metallurgical and materials transactions / B Springer New York, 1994 5(1974), 7 vom: 01. Juli, Seite 1527-1535 (DE-627)182203832 (DE-600)1186125-3 (DE-576)038889196 1073-5615 nnns volume:5 year:1974 number:7 day:01 month:07 pages:1527-1535 https://doi.org/10.1007/BF02646322 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 AR 5 1974 7 01 07 1527-1535 |
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10.1007/BF02646322 doi (DE-627)OLC2059731429 (DE-He213)BF02646322-p DE-627 ger DE-627 rakwb eng 620 660 VZ Turkdogan, E. T. verfasserin aut Sulfide and sulfate solid solubility in lime, magnesia, and calcined dolomite: Part I. CaS and $ CaSO_{4} $ solubility in CaO 1974 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © American Society for Metals, The Melallurgical Society of AIME 1974 Abstract In the present work the solid solubilities of CaS and CaSQ, in burnt lime were investigated by equilibrating lime with CO-$ CO_{2} $-$ SO_{2} $ mixtures at temperatures from 950 to 1300°C. Also, the equilibrium constants for the formation of CaS and $ CaSO_{4} $ were determined. At high oxy-gen activities, corresponding to a $ CO_{2} $/CO ratio >100 in the gas, the sulfur dissolves in lime primarily as sulfate ions. At lower oxygen activities ($ CO_{2} $/CO <30), the sulfur goes into so-lution in lime essentially as sulfide ions. Over the temperature range investigated the limit-ing sulfide solubility is within 0.01 to 0.03 pct S, whereas the sulfate solubility is within 0.03 to 0.1 pct S, increasing with increasing temperature. Lime Calcium Sulfate Sulfate Solubility Calcium Sulfide Sulfide Reaction Rice, B. B. aut Vinters, J. V. aut Enthalten in Metallurgical and materials transactions / B Springer New York, 1994 5(1974), 7 vom: 01. Juli, Seite 1527-1535 (DE-627)182203832 (DE-600)1186125-3 (DE-576)038889196 1073-5615 nnns volume:5 year:1974 number:7 day:01 month:07 pages:1527-1535 https://doi.org/10.1007/BF02646322 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 AR 5 1974 7 01 07 1527-1535 |
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10.1007/BF02646322 doi (DE-627)OLC2059731429 (DE-He213)BF02646322-p DE-627 ger DE-627 rakwb eng 620 660 VZ Turkdogan, E. T. verfasserin aut Sulfide and sulfate solid solubility in lime, magnesia, and calcined dolomite: Part I. CaS and $ CaSO_{4} $ solubility in CaO 1974 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © American Society for Metals, The Melallurgical Society of AIME 1974 Abstract In the present work the solid solubilities of CaS and CaSQ, in burnt lime were investigated by equilibrating lime with CO-$ CO_{2} $-$ SO_{2} $ mixtures at temperatures from 950 to 1300°C. Also, the equilibrium constants for the formation of CaS and $ CaSO_{4} $ were determined. At high oxy-gen activities, corresponding to a $ CO_{2} $/CO ratio >100 in the gas, the sulfur dissolves in lime primarily as sulfate ions. At lower oxygen activities ($ CO_{2} $/CO <30), the sulfur goes into so-lution in lime essentially as sulfide ions. Over the temperature range investigated the limit-ing sulfide solubility is within 0.01 to 0.03 pct S, whereas the sulfate solubility is within 0.03 to 0.1 pct S, increasing with increasing temperature. Lime Calcium Sulfate Sulfate Solubility Calcium Sulfide Sulfide Reaction Rice, B. B. aut Vinters, J. V. aut Enthalten in Metallurgical and materials transactions / B Springer New York, 1994 5(1974), 7 vom: 01. Juli, Seite 1527-1535 (DE-627)182203832 (DE-600)1186125-3 (DE-576)038889196 1073-5615 nnns volume:5 year:1974 number:7 day:01 month:07 pages:1527-1535 https://doi.org/10.1007/BF02646322 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 AR 5 1974 7 01 07 1527-1535 |
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10.1007/BF02646322 doi (DE-627)OLC2059731429 (DE-He213)BF02646322-p DE-627 ger DE-627 rakwb eng 620 660 VZ Turkdogan, E. T. verfasserin aut Sulfide and sulfate solid solubility in lime, magnesia, and calcined dolomite: Part I. CaS and $ CaSO_{4} $ solubility in CaO 1974 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © American Society for Metals, The Melallurgical Society of AIME 1974 Abstract In the present work the solid solubilities of CaS and CaSQ, in burnt lime were investigated by equilibrating lime with CO-$ CO_{2} $-$ SO_{2} $ mixtures at temperatures from 950 to 1300°C. Also, the equilibrium constants for the formation of CaS and $ CaSO_{4} $ were determined. At high oxy-gen activities, corresponding to a $ CO_{2} $/CO ratio >100 in the gas, the sulfur dissolves in lime primarily as sulfate ions. At lower oxygen activities ($ CO_{2} $/CO <30), the sulfur goes into so-lution in lime essentially as sulfide ions. Over the temperature range investigated the limit-ing sulfide solubility is within 0.01 to 0.03 pct S, whereas the sulfate solubility is within 0.03 to 0.1 pct S, increasing with increasing temperature. Lime Calcium Sulfate Sulfate Solubility Calcium Sulfide Sulfide Reaction Rice, B. B. aut Vinters, J. V. aut Enthalten in Metallurgical and materials transactions / B Springer New York, 1994 5(1974), 7 vom: 01. Juli, Seite 1527-1535 (DE-627)182203832 (DE-600)1186125-3 (DE-576)038889196 1073-5615 nnns volume:5 year:1974 number:7 day:01 month:07 pages:1527-1535 https://doi.org/10.1007/BF02646322 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 AR 5 1974 7 01 07 1527-1535 |
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10.1007/BF02646322 doi (DE-627)OLC2059731429 (DE-He213)BF02646322-p DE-627 ger DE-627 rakwb eng 620 660 VZ Turkdogan, E. T. verfasserin aut Sulfide and sulfate solid solubility in lime, magnesia, and calcined dolomite: Part I. CaS and $ CaSO_{4} $ solubility in CaO 1974 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © American Society for Metals, The Melallurgical Society of AIME 1974 Abstract In the present work the solid solubilities of CaS and CaSQ, in burnt lime were investigated by equilibrating lime with CO-$ CO_{2} $-$ SO_{2} $ mixtures at temperatures from 950 to 1300°C. Also, the equilibrium constants for the formation of CaS and $ CaSO_{4} $ were determined. At high oxy-gen activities, corresponding to a $ CO_{2} $/CO ratio >100 in the gas, the sulfur dissolves in lime primarily as sulfate ions. At lower oxygen activities ($ CO_{2} $/CO <30), the sulfur goes into so-lution in lime essentially as sulfide ions. Over the temperature range investigated the limit-ing sulfide solubility is within 0.01 to 0.03 pct S, whereas the sulfate solubility is within 0.03 to 0.1 pct S, increasing with increasing temperature. Lime Calcium Sulfate Sulfate Solubility Calcium Sulfide Sulfide Reaction Rice, B. B. aut Vinters, J. V. aut Enthalten in Metallurgical and materials transactions / B Springer New York, 1994 5(1974), 7 vom: 01. Juli, Seite 1527-1535 (DE-627)182203832 (DE-600)1186125-3 (DE-576)038889196 1073-5615 nnns volume:5 year:1974 number:7 day:01 month:07 pages:1527-1535 https://doi.org/10.1007/BF02646322 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 AR 5 1974 7 01 07 1527-1535 |
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Sulfide and sulfate solid solubility in lime, magnesia, and calcined dolomite: Part I. CaS and $ CaSO_{4} $ solubility in CaO |
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sulfide and sulfate solid solubility in lime, magnesia, and calcined dolomite: part i. cas and $ caso_{4} $ solubility in cao |
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Sulfide and sulfate solid solubility in lime, magnesia, and calcined dolomite: Part I. CaS and $ CaSO_{4} $ solubility in CaO |
| abstract |
Abstract In the present work the solid solubilities of CaS and CaSQ, in burnt lime were investigated by equilibrating lime with CO-$ CO_{2} $-$ SO_{2} $ mixtures at temperatures from 950 to 1300°C. Also, the equilibrium constants for the formation of CaS and $ CaSO_{4} $ were determined. At high oxy-gen activities, corresponding to a $ CO_{2} $/CO ratio >100 in the gas, the sulfur dissolves in lime primarily as sulfate ions. At lower oxygen activities ($ CO_{2} $/CO <30), the sulfur goes into so-lution in lime essentially as sulfide ions. Over the temperature range investigated the limit-ing sulfide solubility is within 0.01 to 0.03 pct S, whereas the sulfate solubility is within 0.03 to 0.1 pct S, increasing with increasing temperature. © American Society for Metals, The Melallurgical Society of AIME 1974 |
| abstractGer |
Abstract In the present work the solid solubilities of CaS and CaSQ, in burnt lime were investigated by equilibrating lime with CO-$ CO_{2} $-$ SO_{2} $ mixtures at temperatures from 950 to 1300°C. Also, the equilibrium constants for the formation of CaS and $ CaSO_{4} $ were determined. At high oxy-gen activities, corresponding to a $ CO_{2} $/CO ratio >100 in the gas, the sulfur dissolves in lime primarily as sulfate ions. At lower oxygen activities ($ CO_{2} $/CO <30), the sulfur goes into so-lution in lime essentially as sulfide ions. Over the temperature range investigated the limit-ing sulfide solubility is within 0.01 to 0.03 pct S, whereas the sulfate solubility is within 0.03 to 0.1 pct S, increasing with increasing temperature. © American Society for Metals, The Melallurgical Society of AIME 1974 |
| abstract_unstemmed |
Abstract In the present work the solid solubilities of CaS and CaSQ, in burnt lime were investigated by equilibrating lime with CO-$ CO_{2} $-$ SO_{2} $ mixtures at temperatures from 950 to 1300°C. Also, the equilibrium constants for the formation of CaS and $ CaSO_{4} $ were determined. At high oxy-gen activities, corresponding to a $ CO_{2} $/CO ratio >100 in the gas, the sulfur dissolves in lime primarily as sulfate ions. At lower oxygen activities ($ CO_{2} $/CO <30), the sulfur goes into so-lution in lime essentially as sulfide ions. Over the temperature range investigated the limit-ing sulfide solubility is within 0.01 to 0.03 pct S, whereas the sulfate solubility is within 0.03 to 0.1 pct S, increasing with increasing temperature. © American Society for Metals, The Melallurgical Society of AIME 1974 |
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| title_short |
Sulfide and sulfate solid solubility in lime, magnesia, and calcined dolomite: Part I. CaS and $ CaSO_{4} $ solubility in CaO |
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Rice, B. B. Vinters, J. V. |
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2024-07-03T23:11:32.752Z |
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