The solubility of the liquid oxysulfide phase in liquid Fe-O-S alloys

Abstract The solubility of the liquid oxide phase in liquid Fe-O alloys has been measured for the temperature range of 1378 to 1740 °C. Also the solubility of the liquid oxysulfide phase in liquid Fe-O-S alloys has been determined for the composition range of 0.08 to 0.30 wt pct oxygen and 0 to 0.5...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Nduaguba, M. [verfasserIn] Elliott, J. F.

Format:	Artikel
Sprache:	Englisch

Erschienen:	1983

Schlagwörter:	Metallurgical Transaction Liquid Iron Standard Free Energy Liquid Oxide Phase Oxysulfide

Anmerkung:	© The Metallurgical of Society of AIME 1983

Übergeordnetes Werk:	Enthalten in: Metallurgical transactions / B - Springer-Verlag, 1975, 14(1983), 4 vom: Dez., Seite 679-683
Übergeordnetes Werk:	volume:14 ; year:1983 ; number:4 ; month:12 ; pages:679-683

Links:	Volltext

DOI / URN:	10.1007/BF02653954

Katalog-ID:	OLC2059741432

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520			\|a Abstract The solubility of the liquid oxide phase in liquid Fe-O alloys has been measured for the temperature range of 1378 to 1740 °C. Also the solubility of the liquid oxysulfide phase in liquid Fe-O-S alloys has been determined for the composition range of 0.08 to 0.30 wt pct oxygen and 0 to 0.5 wt pct sulfur. The oxygen content of liquid iron saturated with the liquid oxide phase is log O = −6358/T + 2.76. The standard free energy for the formation of the oxide phase is: xFe(l) + O(pct) = $ Fe_{x} $O(l); ΔG° = 242.4 − 0.0829T + 166,990/T(kJ). The equation for the standard free energy in the temperature range of 1550 to 1650 °C may be written as: −117.5 + 0.0496T (kJ). The effect of composition on temperature of saturation of liquid Fe-O-S alloys with the oxysulfide phase is:T(K) = −6358/(log pct O − 2.76) - (pct S)x [554 + 135.0(log O − 2.77)]. The relationship applies for the composition range of 0.15 to 0.30 wt pct oxygen and 0.0 to 0.5 wt pct sulfur and temperatures from 1480 to 1680 °C.
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allfields	10.1007/BF02653954 doi (DE-627)OLC2059741432 (DE-He213)BF02653954-p DE-627 ger DE-627 rakwb eng 620 660 VZ Nduaguba, M. verfasserin aut The solubility of the liquid oxysulfide phase in liquid Fe-O-S alloys 1983 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Metallurgical of Society of AIME 1983 Abstract The solubility of the liquid oxide phase in liquid Fe-O alloys has been measured for the temperature range of 1378 to 1740 °C. Also the solubility of the liquid oxysulfide phase in liquid Fe-O-S alloys has been determined for the composition range of 0.08 to 0.30 wt pct oxygen and 0 to 0.5 wt pct sulfur. The oxygen content of liquid iron saturated with the liquid oxide phase is log O = −6358/T + 2.76. The standard free energy for the formation of the oxide phase is: xFe(l) + O(pct) = $ Fe_{x} $O(l); ΔG° = 242.4 − 0.0829T + 166,990/T(kJ). The equation for the standard free energy in the temperature range of 1550 to 1650 °C may be written as: −117.5 + 0.0496T (kJ). The effect of composition on temperature of saturation of liquid Fe-O-S alloys with the oxysulfide phase is:T(K) = −6358/(log pct O − 2.76) - (pct S)x [554 + 135.0(log O − 2.77)]. The relationship applies for the composition range of 0.15 to 0.30 wt pct oxygen and 0.0 to 0.5 wt pct sulfur and temperatures from 1480 to 1680 °C. Metallurgical Transaction Liquid Iron Standard Free Energy Liquid Oxide Phase Oxysulfide Elliott, J. F. aut Enthalten in Metallurgical transactions / B Springer-Verlag, 1975 14(1983), 4 vom: Dez., Seite 679-683 (DE-627)12943163X (DE-600)192803-X (DE-576)014803984 0360-2141 nnns volume:14 year:1983 number:4 month:12 pages:679-683 https://doi.org/10.1007/BF02653954 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_20 GBV_ILN_30 GBV_ILN_70 GBV_ILN_2015 GBV_ILN_2027 GBV_ILN_4046 GBV_ILN_4319 GBV_ILN_4323 AR 14 1983 4 12 679-683
spelling	10.1007/BF02653954 doi (DE-627)OLC2059741432 (DE-He213)BF02653954-p DE-627 ger DE-627 rakwb eng 620 660 VZ Nduaguba, M. verfasserin aut The solubility of the liquid oxysulfide phase in liquid Fe-O-S alloys 1983 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Metallurgical of Society of AIME 1983 Abstract The solubility of the liquid oxide phase in liquid Fe-O alloys has been measured for the temperature range of 1378 to 1740 °C. Also the solubility of the liquid oxysulfide phase in liquid Fe-O-S alloys has been determined for the composition range of 0.08 to 0.30 wt pct oxygen and 0 to 0.5 wt pct sulfur. The oxygen content of liquid iron saturated with the liquid oxide phase is log O = −6358/T + 2.76. The standard free energy for the formation of the oxide phase is: xFe(l) + O(pct) = $ Fe_{x} $O(l); ΔG° = 242.4 − 0.0829T + 166,990/T(kJ). The equation for the standard free energy in the temperature range of 1550 to 1650 °C may be written as: −117.5 + 0.0496T (kJ). The effect of composition on temperature of saturation of liquid Fe-O-S alloys with the oxysulfide phase is:T(K) = −6358/(log pct O − 2.76) - (pct S)x [554 + 135.0(log O − 2.77)]. The relationship applies for the composition range of 0.15 to 0.30 wt pct oxygen and 0.0 to 0.5 wt pct sulfur and temperatures from 1480 to 1680 °C. Metallurgical Transaction Liquid Iron Standard Free Energy Liquid Oxide Phase Oxysulfide Elliott, J. F. aut Enthalten in Metallurgical transactions / B Springer-Verlag, 1975 14(1983), 4 vom: Dez., Seite 679-683 (DE-627)12943163X (DE-600)192803-X (DE-576)014803984 0360-2141 nnns volume:14 year:1983 number:4 month:12 pages:679-683 https://doi.org/10.1007/BF02653954 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_20 GBV_ILN_30 GBV_ILN_70 GBV_ILN_2015 GBV_ILN_2027 GBV_ILN_4046 GBV_ILN_4319 GBV_ILN_4323 AR 14 1983 4 12 679-683
allfields_unstemmed	10.1007/BF02653954 doi (DE-627)OLC2059741432 (DE-He213)BF02653954-p DE-627 ger DE-627 rakwb eng 620 660 VZ Nduaguba, M. verfasserin aut The solubility of the liquid oxysulfide phase in liquid Fe-O-S alloys 1983 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Metallurgical of Society of AIME 1983 Abstract The solubility of the liquid oxide phase in liquid Fe-O alloys has been measured for the temperature range of 1378 to 1740 °C. Also the solubility of the liquid oxysulfide phase in liquid Fe-O-S alloys has been determined for the composition range of 0.08 to 0.30 wt pct oxygen and 0 to 0.5 wt pct sulfur. The oxygen content of liquid iron saturated with the liquid oxide phase is log O = −6358/T + 2.76. The standard free energy for the formation of the oxide phase is: xFe(l) + O(pct) = $ Fe_{x} $O(l); ΔG° = 242.4 − 0.0829T + 166,990/T(kJ). The equation for the standard free energy in the temperature range of 1550 to 1650 °C may be written as: −117.5 + 0.0496T (kJ). The effect of composition on temperature of saturation of liquid Fe-O-S alloys with the oxysulfide phase is:T(K) = −6358/(log pct O − 2.76) - (pct S)x [554 + 135.0(log O − 2.77)]. The relationship applies for the composition range of 0.15 to 0.30 wt pct oxygen and 0.0 to 0.5 wt pct sulfur and temperatures from 1480 to 1680 °C. Metallurgical Transaction Liquid Iron Standard Free Energy Liquid Oxide Phase Oxysulfide Elliott, J. F. aut Enthalten in Metallurgical transactions / B Springer-Verlag, 1975 14(1983), 4 vom: Dez., Seite 679-683 (DE-627)12943163X (DE-600)192803-X (DE-576)014803984 0360-2141 nnns volume:14 year:1983 number:4 month:12 pages:679-683 https://doi.org/10.1007/BF02653954 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_20 GBV_ILN_30 GBV_ILN_70 GBV_ILN_2015 GBV_ILN_2027 GBV_ILN_4046 GBV_ILN_4319 GBV_ILN_4323 AR 14 1983 4 12 679-683
allfieldsGer	10.1007/BF02653954 doi (DE-627)OLC2059741432 (DE-He213)BF02653954-p DE-627 ger DE-627 rakwb eng 620 660 VZ Nduaguba, M. verfasserin aut The solubility of the liquid oxysulfide phase in liquid Fe-O-S alloys 1983 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Metallurgical of Society of AIME 1983 Abstract The solubility of the liquid oxide phase in liquid Fe-O alloys has been measured for the temperature range of 1378 to 1740 °C. Also the solubility of the liquid oxysulfide phase in liquid Fe-O-S alloys has been determined for the composition range of 0.08 to 0.30 wt pct oxygen and 0 to 0.5 wt pct sulfur. The oxygen content of liquid iron saturated with the liquid oxide phase is log O = −6358/T + 2.76. The standard free energy for the formation of the oxide phase is: xFe(l) + O(pct) = $ Fe_{x} $O(l); ΔG° = 242.4 − 0.0829T + 166,990/T(kJ). The equation for the standard free energy in the temperature range of 1550 to 1650 °C may be written as: −117.5 + 0.0496T (kJ). The effect of composition on temperature of saturation of liquid Fe-O-S alloys with the oxysulfide phase is:T(K) = −6358/(log pct O − 2.76) - (pct S)x [554 + 135.0(log O − 2.77)]. The relationship applies for the composition range of 0.15 to 0.30 wt pct oxygen and 0.0 to 0.5 wt pct sulfur and temperatures from 1480 to 1680 °C. Metallurgical Transaction Liquid Iron Standard Free Energy Liquid Oxide Phase Oxysulfide Elliott, J. F. aut Enthalten in Metallurgical transactions / B Springer-Verlag, 1975 14(1983), 4 vom: Dez., Seite 679-683 (DE-627)12943163X (DE-600)192803-X (DE-576)014803984 0360-2141 nnns volume:14 year:1983 number:4 month:12 pages:679-683 https://doi.org/10.1007/BF02653954 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_20 GBV_ILN_30 GBV_ILN_70 GBV_ILN_2015 GBV_ILN_2027 GBV_ILN_4046 GBV_ILN_4319 GBV_ILN_4323 AR 14 1983 4 12 679-683
allfieldsSound	10.1007/BF02653954 doi (DE-627)OLC2059741432 (DE-He213)BF02653954-p DE-627 ger DE-627 rakwb eng 620 660 VZ Nduaguba, M. verfasserin aut The solubility of the liquid oxysulfide phase in liquid Fe-O-S alloys 1983 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © The Metallurgical of Society of AIME 1983 Abstract The solubility of the liquid oxide phase in liquid Fe-O alloys has been measured for the temperature range of 1378 to 1740 °C. Also the solubility of the liquid oxysulfide phase in liquid Fe-O-S alloys has been determined for the composition range of 0.08 to 0.30 wt pct oxygen and 0 to 0.5 wt pct sulfur. The oxygen content of liquid iron saturated with the liquid oxide phase is log O = −6358/T + 2.76. The standard free energy for the formation of the oxide phase is: xFe(l) + O(pct) = $ Fe_{x} $O(l); ΔG° = 242.4 − 0.0829T + 166,990/T(kJ). The equation for the standard free energy in the temperature range of 1550 to 1650 °C may be written as: −117.5 + 0.0496T (kJ). The effect of composition on temperature of saturation of liquid Fe-O-S alloys with the oxysulfide phase is:T(K) = −6358/(log pct O − 2.76) - (pct S)x [554 + 135.0(log O − 2.77)]. The relationship applies for the composition range of 0.15 to 0.30 wt pct oxygen and 0.0 to 0.5 wt pct sulfur and temperatures from 1480 to 1680 °C. Metallurgical Transaction Liquid Iron Standard Free Energy Liquid Oxide Phase Oxysulfide Elliott, J. F. aut Enthalten in Metallurgical transactions / B Springer-Verlag, 1975 14(1983), 4 vom: Dez., Seite 679-683 (DE-627)12943163X (DE-600)192803-X (DE-576)014803984 0360-2141 nnns volume:14 year:1983 number:4 month:12 pages:679-683 https://doi.org/10.1007/BF02653954 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_20 GBV_ILN_30 GBV_ILN_70 GBV_ILN_2015 GBV_ILN_2027 GBV_ILN_4046 GBV_ILN_4319 GBV_ILN_4323 AR 14 1983 4 12 679-683
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author	Nduaguba, M.
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title_sort	the solubility of the liquid oxysulfide phase in liquid fe-o-s alloys
title_auth	The solubility of the liquid oxysulfide phase in liquid Fe-O-S alloys
abstract	Abstract The solubility of the liquid oxide phase in liquid Fe-O alloys has been measured for the temperature range of 1378 to 1740 °C. Also the solubility of the liquid oxysulfide phase in liquid Fe-O-S alloys has been determined for the composition range of 0.08 to 0.30 wt pct oxygen and 0 to 0.5 wt pct sulfur. The oxygen content of liquid iron saturated with the liquid oxide phase is log O = −6358/T + 2.76. The standard free energy for the formation of the oxide phase is: xFe(l) + O(pct) = $ Fe_{x} $O(l); ΔG° = 242.4 − 0.0829T + 166,990/T(kJ). The equation for the standard free energy in the temperature range of 1550 to 1650 °C may be written as: −117.5 + 0.0496T (kJ). The effect of composition on temperature of saturation of liquid Fe-O-S alloys with the oxysulfide phase is:T(K) = −6358/(log pct O − 2.76) - (pct S)x [554 + 135.0(log O − 2.77)]. The relationship applies for the composition range of 0.15 to 0.30 wt pct oxygen and 0.0 to 0.5 wt pct sulfur and temperatures from 1480 to 1680 °C. © The Metallurgical of Society of AIME 1983
abstractGer	Abstract The solubility of the liquid oxide phase in liquid Fe-O alloys has been measured for the temperature range of 1378 to 1740 °C. Also the solubility of the liquid oxysulfide phase in liquid Fe-O-S alloys has been determined for the composition range of 0.08 to 0.30 wt pct oxygen and 0 to 0.5 wt pct sulfur. The oxygen content of liquid iron saturated with the liquid oxide phase is log O = −6358/T + 2.76. The standard free energy for the formation of the oxide phase is: xFe(l) + O(pct) = $ Fe_{x} $O(l); ΔG° = 242.4 − 0.0829T + 166,990/T(kJ). The equation for the standard free energy in the temperature range of 1550 to 1650 °C may be written as: −117.5 + 0.0496T (kJ). The effect of composition on temperature of saturation of liquid Fe-O-S alloys with the oxysulfide phase is:T(K) = −6358/(log pct O − 2.76) - (pct S)x [554 + 135.0(log O − 2.77)]. The relationship applies for the composition range of 0.15 to 0.30 wt pct oxygen and 0.0 to 0.5 wt pct sulfur and temperatures from 1480 to 1680 °C. © The Metallurgical of Society of AIME 1983
abstract_unstemmed	Abstract The solubility of the liquid oxide phase in liquid Fe-O alloys has been measured for the temperature range of 1378 to 1740 °C. Also the solubility of the liquid oxysulfide phase in liquid Fe-O-S alloys has been determined for the composition range of 0.08 to 0.30 wt pct oxygen and 0 to 0.5 wt pct sulfur. The oxygen content of liquid iron saturated with the liquid oxide phase is log O = −6358/T + 2.76. The standard free energy for the formation of the oxide phase is: xFe(l) + O(pct) = $ Fe_{x} $O(l); ΔG° = 242.4 − 0.0829T + 166,990/T(kJ). The equation for the standard free energy in the temperature range of 1550 to 1650 °C may be written as: −117.5 + 0.0496T (kJ). The effect of composition on temperature of saturation of liquid Fe-O-S alloys with the oxysulfide phase is:T(K) = −6358/(log pct O − 2.76) - (pct S)x [554 + 135.0(log O − 2.77)]. The relationship applies for the composition range of 0.15 to 0.30 wt pct oxygen and 0.0 to 0.5 wt pct sulfur and temperatures from 1480 to 1680 °C. © The Metallurgical of Society of AIME 1983
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title_short	The solubility of the liquid oxysulfide phase in liquid Fe-O-S alloys
url	https://doi.org/10.1007/BF02653954
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author2	Elliott, J. F.
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up_date	2024-07-03T23:13:32.478Z
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The solubility of the liquid oxysulfide phase in liquid Fe-O-S alloys

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