The effect of iron oxide as an inhibition layer on iron-zinc reactions during Hot-Dip galvanizing
Abstract A study was conducted on the effect of a uniform oxide layer on the galvanizing reaction in 0.20 wt pct Al-Zn and pure Zn baths at 450 °C. In the 0.20 wt pct Al-Zn bath, poor wettability of the oxide layer was observed. No significant liquid Zn penetration of the oxide occurred and, therefo...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Jordan, C. E. [verfasserIn] |
|---|
| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1998 |
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| Schlagwörter: |
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| Anmerkung: |
© ASM International & TMS-The Minerals, Metals and Materials Society 1998 |
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| Übergeordnetes Werk: |
Enthalten in: Metallurgical and materials transactions / B - Springer-Verlag, 1994, 29(1998), 2 vom: Apr., Seite 479-484 |
|---|---|
| Übergeordnetes Werk: |
volume:29 ; year:1998 ; number:2 ; month:04 ; pages:479-484 |
| Links: |
|---|
| DOI / URN: |
10.1007/s11663-998-0127-6 |
|---|
| Katalog-ID: |
OLC2059757134 |
|---|
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| 520 | |a Abstract A study was conducted on the effect of a uniform oxide layer on the galvanizing reaction in 0.20 wt pct Al-Zn and pure Zn baths at 450 °C. In the 0.20 wt pct Al-Zn bath, poor wettability of the oxide layer was observed. No significant liquid Zn penetration of the oxide occurred and, therefore, attack of the steel substrate to form localized Fe-Zn growth did not occur. It was found that the iron oxide acted as a physical barrier or inhibition layer in the pure Zn bath, similar to the $ Fe_{2} $$ Al_{5} $ inhibition layer that forms at the steel interface in Al-Zn baths. The inhibition effect of the oxide in the pure Zn bath was temporary, since cracks and other macrodefects in the oxide acted as fast diffusion paths for Zn. Localized Fe-Zn growth (outbursts) formed at the steel/coating interface, and the number of outbursts was generally inversely proportional to the oxide layer thickness at constant immersion times. Increased immersion time for a constant oxide layer thickness led to an increase in the number of outbursts. These results simulate the diffusion short circuit mechanisms for $ Fe_{2} $$ Al_{5} $ inhibition layer breakdown in Al-containing Zn baths. | ||
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10.1007/s11663-998-0127-6 doi (DE-627)OLC2059757134 (DE-He213)s11663-998-0127-6-p DE-627 ger DE-627 rakwb eng 620 660 VZ Jordan, C. E. verfasserin aut The effect of iron oxide as an inhibition layer on iron-zinc reactions during Hot-Dip galvanizing 1998 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © ASM International & TMS-The Minerals, Metals and Materials Society 1998 Abstract A study was conducted on the effect of a uniform oxide layer on the galvanizing reaction in 0.20 wt pct Al-Zn and pure Zn baths at 450 °C. In the 0.20 wt pct Al-Zn bath, poor wettability of the oxide layer was observed. No significant liquid Zn penetration of the oxide occurred and, therefore, attack of the steel substrate to form localized Fe-Zn growth did not occur. It was found that the iron oxide acted as a physical barrier or inhibition layer in the pure Zn bath, similar to the $ Fe_{2} $$ Al_{5} $ inhibition layer that forms at the steel interface in Al-Zn baths. The inhibition effect of the oxide in the pure Zn bath was temporary, since cracks and other macrodefects in the oxide acted as fast diffusion paths for Zn. Localized Fe-Zn growth (outbursts) formed at the steel/coating interface, and the number of outbursts was generally inversely proportional to the oxide layer thickness at constant immersion times. Increased immersion time for a constant oxide layer thickness led to an increase in the number of outbursts. These results simulate the diffusion short circuit mechanisms for $ Fe_{2} $$ Al_{5} $ inhibition layer breakdown in Al-containing Zn baths. Material Transaction Oxide Layer Immersion Time Oxide Layer Thickness Inhibition Layer Marder, A. R. aut Enthalten in Metallurgical and materials transactions / B Springer-Verlag, 1994 29(1998), 2 vom: Apr., Seite 479-484 (DE-627)182203832 (DE-600)1186125-3 (DE-576)038889196 1073-5615 nnns volume:29 year:1998 number:2 month:04 pages:479-484 https://doi.org/10.1007/s11663-998-0127-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_20 GBV_ILN_30 GBV_ILN_62 GBV_ILN_70 GBV_ILN_2027 GBV_ILN_4046 GBV_ILN_4307 GBV_ILN_4319 GBV_ILN_4323 AR 29 1998 2 04 479-484 |
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10.1007/s11663-998-0127-6 doi (DE-627)OLC2059757134 (DE-He213)s11663-998-0127-6-p DE-627 ger DE-627 rakwb eng 620 660 VZ Jordan, C. E. verfasserin aut The effect of iron oxide as an inhibition layer on iron-zinc reactions during Hot-Dip galvanizing 1998 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © ASM International & TMS-The Minerals, Metals and Materials Society 1998 Abstract A study was conducted on the effect of a uniform oxide layer on the galvanizing reaction in 0.20 wt pct Al-Zn and pure Zn baths at 450 °C. In the 0.20 wt pct Al-Zn bath, poor wettability of the oxide layer was observed. No significant liquid Zn penetration of the oxide occurred and, therefore, attack of the steel substrate to form localized Fe-Zn growth did not occur. It was found that the iron oxide acted as a physical barrier or inhibition layer in the pure Zn bath, similar to the $ Fe_{2} $$ Al_{5} $ inhibition layer that forms at the steel interface in Al-Zn baths. The inhibition effect of the oxide in the pure Zn bath was temporary, since cracks and other macrodefects in the oxide acted as fast diffusion paths for Zn. Localized Fe-Zn growth (outbursts) formed at the steel/coating interface, and the number of outbursts was generally inversely proportional to the oxide layer thickness at constant immersion times. Increased immersion time for a constant oxide layer thickness led to an increase in the number of outbursts. These results simulate the diffusion short circuit mechanisms for $ Fe_{2} $$ Al_{5} $ inhibition layer breakdown in Al-containing Zn baths. Material Transaction Oxide Layer Immersion Time Oxide Layer Thickness Inhibition Layer Marder, A. R. aut Enthalten in Metallurgical and materials transactions / B Springer-Verlag, 1994 29(1998), 2 vom: Apr., Seite 479-484 (DE-627)182203832 (DE-600)1186125-3 (DE-576)038889196 1073-5615 nnns volume:29 year:1998 number:2 month:04 pages:479-484 https://doi.org/10.1007/s11663-998-0127-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_20 GBV_ILN_30 GBV_ILN_62 GBV_ILN_70 GBV_ILN_2027 GBV_ILN_4046 GBV_ILN_4307 GBV_ILN_4319 GBV_ILN_4323 AR 29 1998 2 04 479-484 |
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10.1007/s11663-998-0127-6 doi (DE-627)OLC2059757134 (DE-He213)s11663-998-0127-6-p DE-627 ger DE-627 rakwb eng 620 660 VZ Jordan, C. E. verfasserin aut The effect of iron oxide as an inhibition layer on iron-zinc reactions during Hot-Dip galvanizing 1998 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © ASM International & TMS-The Minerals, Metals and Materials Society 1998 Abstract A study was conducted on the effect of a uniform oxide layer on the galvanizing reaction in 0.20 wt pct Al-Zn and pure Zn baths at 450 °C. In the 0.20 wt pct Al-Zn bath, poor wettability of the oxide layer was observed. No significant liquid Zn penetration of the oxide occurred and, therefore, attack of the steel substrate to form localized Fe-Zn growth did not occur. It was found that the iron oxide acted as a physical barrier or inhibition layer in the pure Zn bath, similar to the $ Fe_{2} $$ Al_{5} $ inhibition layer that forms at the steel interface in Al-Zn baths. The inhibition effect of the oxide in the pure Zn bath was temporary, since cracks and other macrodefects in the oxide acted as fast diffusion paths for Zn. Localized Fe-Zn growth (outbursts) formed at the steel/coating interface, and the number of outbursts was generally inversely proportional to the oxide layer thickness at constant immersion times. Increased immersion time for a constant oxide layer thickness led to an increase in the number of outbursts. These results simulate the diffusion short circuit mechanisms for $ Fe_{2} $$ Al_{5} $ inhibition layer breakdown in Al-containing Zn baths. Material Transaction Oxide Layer Immersion Time Oxide Layer Thickness Inhibition Layer Marder, A. R. aut Enthalten in Metallurgical and materials transactions / B Springer-Verlag, 1994 29(1998), 2 vom: Apr., Seite 479-484 (DE-627)182203832 (DE-600)1186125-3 (DE-576)038889196 1073-5615 nnns volume:29 year:1998 number:2 month:04 pages:479-484 https://doi.org/10.1007/s11663-998-0127-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_20 GBV_ILN_30 GBV_ILN_62 GBV_ILN_70 GBV_ILN_2027 GBV_ILN_4046 GBV_ILN_4307 GBV_ILN_4319 GBV_ILN_4323 AR 29 1998 2 04 479-484 |
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10.1007/s11663-998-0127-6 doi (DE-627)OLC2059757134 (DE-He213)s11663-998-0127-6-p DE-627 ger DE-627 rakwb eng 620 660 VZ Jordan, C. E. verfasserin aut The effect of iron oxide as an inhibition layer on iron-zinc reactions during Hot-Dip galvanizing 1998 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © ASM International & TMS-The Minerals, Metals and Materials Society 1998 Abstract A study was conducted on the effect of a uniform oxide layer on the galvanizing reaction in 0.20 wt pct Al-Zn and pure Zn baths at 450 °C. In the 0.20 wt pct Al-Zn bath, poor wettability of the oxide layer was observed. No significant liquid Zn penetration of the oxide occurred and, therefore, attack of the steel substrate to form localized Fe-Zn growth did not occur. It was found that the iron oxide acted as a physical barrier or inhibition layer in the pure Zn bath, similar to the $ Fe_{2} $$ Al_{5} $ inhibition layer that forms at the steel interface in Al-Zn baths. The inhibition effect of the oxide in the pure Zn bath was temporary, since cracks and other macrodefects in the oxide acted as fast diffusion paths for Zn. Localized Fe-Zn growth (outbursts) formed at the steel/coating interface, and the number of outbursts was generally inversely proportional to the oxide layer thickness at constant immersion times. Increased immersion time for a constant oxide layer thickness led to an increase in the number of outbursts. These results simulate the diffusion short circuit mechanisms for $ Fe_{2} $$ Al_{5} $ inhibition layer breakdown in Al-containing Zn baths. Material Transaction Oxide Layer Immersion Time Oxide Layer Thickness Inhibition Layer Marder, A. R. aut Enthalten in Metallurgical and materials transactions / B Springer-Verlag, 1994 29(1998), 2 vom: Apr., Seite 479-484 (DE-627)182203832 (DE-600)1186125-3 (DE-576)038889196 1073-5615 nnns volume:29 year:1998 number:2 month:04 pages:479-484 https://doi.org/10.1007/s11663-998-0127-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_20 GBV_ILN_30 GBV_ILN_62 GBV_ILN_70 GBV_ILN_2027 GBV_ILN_4046 GBV_ILN_4307 GBV_ILN_4319 GBV_ILN_4323 AR 29 1998 2 04 479-484 |
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10.1007/s11663-998-0127-6 doi (DE-627)OLC2059757134 (DE-He213)s11663-998-0127-6-p DE-627 ger DE-627 rakwb eng 620 660 VZ Jordan, C. E. verfasserin aut The effect of iron oxide as an inhibition layer on iron-zinc reactions during Hot-Dip galvanizing 1998 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © ASM International & TMS-The Minerals, Metals and Materials Society 1998 Abstract A study was conducted on the effect of a uniform oxide layer on the galvanizing reaction in 0.20 wt pct Al-Zn and pure Zn baths at 450 °C. In the 0.20 wt pct Al-Zn bath, poor wettability of the oxide layer was observed. No significant liquid Zn penetration of the oxide occurred and, therefore, attack of the steel substrate to form localized Fe-Zn growth did not occur. It was found that the iron oxide acted as a physical barrier or inhibition layer in the pure Zn bath, similar to the $ Fe_{2} $$ Al_{5} $ inhibition layer that forms at the steel interface in Al-Zn baths. The inhibition effect of the oxide in the pure Zn bath was temporary, since cracks and other macrodefects in the oxide acted as fast diffusion paths for Zn. Localized Fe-Zn growth (outbursts) formed at the steel/coating interface, and the number of outbursts was generally inversely proportional to the oxide layer thickness at constant immersion times. Increased immersion time for a constant oxide layer thickness led to an increase in the number of outbursts. These results simulate the diffusion short circuit mechanisms for $ Fe_{2} $$ Al_{5} $ inhibition layer breakdown in Al-containing Zn baths. Material Transaction Oxide Layer Immersion Time Oxide Layer Thickness Inhibition Layer Marder, A. R. aut Enthalten in Metallurgical and materials transactions / B Springer-Verlag, 1994 29(1998), 2 vom: Apr., Seite 479-484 (DE-627)182203832 (DE-600)1186125-3 (DE-576)038889196 1073-5615 nnns volume:29 year:1998 number:2 month:04 pages:479-484 https://doi.org/10.1007/s11663-998-0127-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_20 GBV_ILN_30 GBV_ILN_62 GBV_ILN_70 GBV_ILN_2027 GBV_ILN_4046 GBV_ILN_4307 GBV_ILN_4319 GBV_ILN_4323 AR 29 1998 2 04 479-484 |
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The effect of iron oxide as an inhibition layer on iron-zinc reactions during Hot-Dip galvanizing |
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The effect of iron oxide as an inhibition layer on iron-zinc reactions during Hot-Dip galvanizing |
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Jordan, C. E. |
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Metallurgical and materials transactions / B |
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1998 |
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Jordan, C. E. Marder, A. R. |
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10.1007/s11663-998-0127-6 |
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620 660 |
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the effect of iron oxide as an inhibition layer on iron-zinc reactions during hot-dip galvanizing |
| title_auth |
The effect of iron oxide as an inhibition layer on iron-zinc reactions during Hot-Dip galvanizing |
| abstract |
Abstract A study was conducted on the effect of a uniform oxide layer on the galvanizing reaction in 0.20 wt pct Al-Zn and pure Zn baths at 450 °C. In the 0.20 wt pct Al-Zn bath, poor wettability of the oxide layer was observed. No significant liquid Zn penetration of the oxide occurred and, therefore, attack of the steel substrate to form localized Fe-Zn growth did not occur. It was found that the iron oxide acted as a physical barrier or inhibition layer in the pure Zn bath, similar to the $ Fe_{2} $$ Al_{5} $ inhibition layer that forms at the steel interface in Al-Zn baths. The inhibition effect of the oxide in the pure Zn bath was temporary, since cracks and other macrodefects in the oxide acted as fast diffusion paths for Zn. Localized Fe-Zn growth (outbursts) formed at the steel/coating interface, and the number of outbursts was generally inversely proportional to the oxide layer thickness at constant immersion times. Increased immersion time for a constant oxide layer thickness led to an increase in the number of outbursts. These results simulate the diffusion short circuit mechanisms for $ Fe_{2} $$ Al_{5} $ inhibition layer breakdown in Al-containing Zn baths. © ASM International & TMS-The Minerals, Metals and Materials Society 1998 |
| abstractGer |
Abstract A study was conducted on the effect of a uniform oxide layer on the galvanizing reaction in 0.20 wt pct Al-Zn and pure Zn baths at 450 °C. In the 0.20 wt pct Al-Zn bath, poor wettability of the oxide layer was observed. No significant liquid Zn penetration of the oxide occurred and, therefore, attack of the steel substrate to form localized Fe-Zn growth did not occur. It was found that the iron oxide acted as a physical barrier or inhibition layer in the pure Zn bath, similar to the $ Fe_{2} $$ Al_{5} $ inhibition layer that forms at the steel interface in Al-Zn baths. The inhibition effect of the oxide in the pure Zn bath was temporary, since cracks and other macrodefects in the oxide acted as fast diffusion paths for Zn. Localized Fe-Zn growth (outbursts) formed at the steel/coating interface, and the number of outbursts was generally inversely proportional to the oxide layer thickness at constant immersion times. Increased immersion time for a constant oxide layer thickness led to an increase in the number of outbursts. These results simulate the diffusion short circuit mechanisms for $ Fe_{2} $$ Al_{5} $ inhibition layer breakdown in Al-containing Zn baths. © ASM International & TMS-The Minerals, Metals and Materials Society 1998 |
| abstract_unstemmed |
Abstract A study was conducted on the effect of a uniform oxide layer on the galvanizing reaction in 0.20 wt pct Al-Zn and pure Zn baths at 450 °C. In the 0.20 wt pct Al-Zn bath, poor wettability of the oxide layer was observed. No significant liquid Zn penetration of the oxide occurred and, therefore, attack of the steel substrate to form localized Fe-Zn growth did not occur. It was found that the iron oxide acted as a physical barrier or inhibition layer in the pure Zn bath, similar to the $ Fe_{2} $$ Al_{5} $ inhibition layer that forms at the steel interface in Al-Zn baths. The inhibition effect of the oxide in the pure Zn bath was temporary, since cracks and other macrodefects in the oxide acted as fast diffusion paths for Zn. Localized Fe-Zn growth (outbursts) formed at the steel/coating interface, and the number of outbursts was generally inversely proportional to the oxide layer thickness at constant immersion times. Increased immersion time for a constant oxide layer thickness led to an increase in the number of outbursts. These results simulate the diffusion short circuit mechanisms for $ Fe_{2} $$ Al_{5} $ inhibition layer breakdown in Al-containing Zn baths. © ASM International & TMS-The Minerals, Metals and Materials Society 1998 |
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The effect of iron oxide as an inhibition layer on iron-zinc reactions during Hot-Dip galvanizing |
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