Measurement of oxygen potentials in Ag-Pb system employing oxygen sensor
Abstract Accurate and instantaneous analysis of dissolved nonmetallic or metallic species in molten metals at elevated temperatures using an online electrochemical sensor is important for continuous process control during metal refining and alloying operations in metallurgical industries. In this ar...
Ausführliche Beschreibung
Autor*in: |
Kurchania, Rajnish [verfasserIn] |
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Format: |
Artikel |
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Sprache: |
Englisch |
Erschienen: |
2001 |
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Schlagwörter: |
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Anmerkung: |
© ASM International & TMS-The Minerals, Metals and Materials Society 2001 |
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Übergeordnetes Werk: |
Enthalten in: Metallurgical and materials transactions / B - Springer-Verlag, 1994, 32(2001), 3 vom: Juni, Seite 417-421 |
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Übergeordnetes Werk: |
volume:32 ; year:2001 ; number:3 ; month:06 ; pages:417-421 |
Links: |
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DOI / URN: |
10.1007/s11663-001-0026-6 |
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Katalog-ID: |
OLC2059761565 |
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10.1007/s11663-001-0026-6 doi (DE-627)OLC2059761565 (DE-He213)s11663-001-0026-6-p DE-627 ger DE-627 rakwb eng 620 660 VZ Kurchania, Rajnish verfasserin aut Measurement of oxygen potentials in Ag-Pb system employing oxygen sensor 2001 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © ASM International & TMS-The Minerals, Metals and Materials Society 2001 Abstract Accurate and instantaneous analysis of dissolved nonmetallic or metallic species in molten metals at elevated temperatures using an online electrochemical sensor is important for continuous process control during metal refining and alloying operations in metallurgical industries. In this article, the application of long-life, solid-state electrochemical sensors for oxygen has been demonstrated to measure the oxygen potential as a function of the lead concentration in a molten Ag-Pb system at 1323 K. Yttria-stabilized zirconia (YSZ) in the form of one end-closed tube 20 mm long, 3 mm inner diameter, and 1 mm wall thickness has been used as a solid electrolyte in the oxygen sensor. Electromotive force (EMF) of the solid-state electrochemical cell (−)Pt, Ni-NiO//YSZ//OAg-Pb, Mo(+) has been measured at 1323 K. The reference electrode consisted of Ni + NiO biphasic mixture; the working electrode was composed of a molten Ag-Pb alloy of varying concentrations of lead. The concentrations of lead in silver ranged from 0.02 to 10.20 wt pct. Samples of the molten alloy were drawn after each addition of Pb to Ag and analyzed by induction coupled plasma (ICP). Material Transaction Oxygen Sensor Oxygen Potential Lead Shot Lead Addition Kale, Girish M. aut Enthalten in Metallurgical and materials transactions / B Springer-Verlag, 1994 32(2001), 3 vom: Juni, Seite 417-421 (DE-627)182203832 (DE-600)1186125-3 (DE-576)038889196 1073-5615 nnns volume:32 year:2001 number:3 month:06 pages:417-421 https://doi.org/10.1007/s11663-001-0026-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_20 GBV_ILN_30 GBV_ILN_62 GBV_ILN_70 GBV_ILN_2027 GBV_ILN_4046 GBV_ILN_4307 GBV_ILN_4319 GBV_ILN_4323 AR 32 2001 3 06 417-421 |
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10.1007/s11663-001-0026-6 doi (DE-627)OLC2059761565 (DE-He213)s11663-001-0026-6-p DE-627 ger DE-627 rakwb eng 620 660 VZ Kurchania, Rajnish verfasserin aut Measurement of oxygen potentials in Ag-Pb system employing oxygen sensor 2001 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © ASM International & TMS-The Minerals, Metals and Materials Society 2001 Abstract Accurate and instantaneous analysis of dissolved nonmetallic or metallic species in molten metals at elevated temperatures using an online electrochemical sensor is important for continuous process control during metal refining and alloying operations in metallurgical industries. In this article, the application of long-life, solid-state electrochemical sensors for oxygen has been demonstrated to measure the oxygen potential as a function of the lead concentration in a molten Ag-Pb system at 1323 K. Yttria-stabilized zirconia (YSZ) in the form of one end-closed tube 20 mm long, 3 mm inner diameter, and 1 mm wall thickness has been used as a solid electrolyte in the oxygen sensor. Electromotive force (EMF) of the solid-state electrochemical cell (−)Pt, Ni-NiO//YSZ//OAg-Pb, Mo(+) has been measured at 1323 K. The reference electrode consisted of Ni + NiO biphasic mixture; the working electrode was composed of a molten Ag-Pb alloy of varying concentrations of lead. The concentrations of lead in silver ranged from 0.02 to 10.20 wt pct. Samples of the molten alloy were drawn after each addition of Pb to Ag and analyzed by induction coupled plasma (ICP). Material Transaction Oxygen Sensor Oxygen Potential Lead Shot Lead Addition Kale, Girish M. aut Enthalten in Metallurgical and materials transactions / B Springer-Verlag, 1994 32(2001), 3 vom: Juni, Seite 417-421 (DE-627)182203832 (DE-600)1186125-3 (DE-576)038889196 1073-5615 nnns volume:32 year:2001 number:3 month:06 pages:417-421 https://doi.org/10.1007/s11663-001-0026-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_20 GBV_ILN_30 GBV_ILN_62 GBV_ILN_70 GBV_ILN_2027 GBV_ILN_4046 GBV_ILN_4307 GBV_ILN_4319 GBV_ILN_4323 AR 32 2001 3 06 417-421 |
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10.1007/s11663-001-0026-6 doi (DE-627)OLC2059761565 (DE-He213)s11663-001-0026-6-p DE-627 ger DE-627 rakwb eng 620 660 VZ Kurchania, Rajnish verfasserin aut Measurement of oxygen potentials in Ag-Pb system employing oxygen sensor 2001 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © ASM International & TMS-The Minerals, Metals and Materials Society 2001 Abstract Accurate and instantaneous analysis of dissolved nonmetallic or metallic species in molten metals at elevated temperatures using an online electrochemical sensor is important for continuous process control during metal refining and alloying operations in metallurgical industries. In this article, the application of long-life, solid-state electrochemical sensors for oxygen has been demonstrated to measure the oxygen potential as a function of the lead concentration in a molten Ag-Pb system at 1323 K. Yttria-stabilized zirconia (YSZ) in the form of one end-closed tube 20 mm long, 3 mm inner diameter, and 1 mm wall thickness has been used as a solid electrolyte in the oxygen sensor. Electromotive force (EMF) of the solid-state electrochemical cell (−)Pt, Ni-NiO//YSZ//OAg-Pb, Mo(+) has been measured at 1323 K. The reference electrode consisted of Ni + NiO biphasic mixture; the working electrode was composed of a molten Ag-Pb alloy of varying concentrations of lead. The concentrations of lead in silver ranged from 0.02 to 10.20 wt pct. Samples of the molten alloy were drawn after each addition of Pb to Ag and analyzed by induction coupled plasma (ICP). Material Transaction Oxygen Sensor Oxygen Potential Lead Shot Lead Addition Kale, Girish M. aut Enthalten in Metallurgical and materials transactions / B Springer-Verlag, 1994 32(2001), 3 vom: Juni, Seite 417-421 (DE-627)182203832 (DE-600)1186125-3 (DE-576)038889196 1073-5615 nnns volume:32 year:2001 number:3 month:06 pages:417-421 https://doi.org/10.1007/s11663-001-0026-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_20 GBV_ILN_30 GBV_ILN_62 GBV_ILN_70 GBV_ILN_2027 GBV_ILN_4046 GBV_ILN_4307 GBV_ILN_4319 GBV_ILN_4323 AR 32 2001 3 06 417-421 |
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10.1007/s11663-001-0026-6 doi (DE-627)OLC2059761565 (DE-He213)s11663-001-0026-6-p DE-627 ger DE-627 rakwb eng 620 660 VZ Kurchania, Rajnish verfasserin aut Measurement of oxygen potentials in Ag-Pb system employing oxygen sensor 2001 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © ASM International & TMS-The Minerals, Metals and Materials Society 2001 Abstract Accurate and instantaneous analysis of dissolved nonmetallic or metallic species in molten metals at elevated temperatures using an online electrochemical sensor is important for continuous process control during metal refining and alloying operations in metallurgical industries. In this article, the application of long-life, solid-state electrochemical sensors for oxygen has been demonstrated to measure the oxygen potential as a function of the lead concentration in a molten Ag-Pb system at 1323 K. Yttria-stabilized zirconia (YSZ) in the form of one end-closed tube 20 mm long, 3 mm inner diameter, and 1 mm wall thickness has been used as a solid electrolyte in the oxygen sensor. Electromotive force (EMF) of the solid-state electrochemical cell (−)Pt, Ni-NiO//YSZ//OAg-Pb, Mo(+) has been measured at 1323 K. The reference electrode consisted of Ni + NiO biphasic mixture; the working electrode was composed of a molten Ag-Pb alloy of varying concentrations of lead. The concentrations of lead in silver ranged from 0.02 to 10.20 wt pct. Samples of the molten alloy were drawn after each addition of Pb to Ag and analyzed by induction coupled plasma (ICP). Material Transaction Oxygen Sensor Oxygen Potential Lead Shot Lead Addition Kale, Girish M. aut Enthalten in Metallurgical and materials transactions / B Springer-Verlag, 1994 32(2001), 3 vom: Juni, Seite 417-421 (DE-627)182203832 (DE-600)1186125-3 (DE-576)038889196 1073-5615 nnns volume:32 year:2001 number:3 month:06 pages:417-421 https://doi.org/10.1007/s11663-001-0026-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_20 GBV_ILN_30 GBV_ILN_62 GBV_ILN_70 GBV_ILN_2027 GBV_ILN_4046 GBV_ILN_4307 GBV_ILN_4319 GBV_ILN_4323 AR 32 2001 3 06 417-421 |
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10.1007/s11663-001-0026-6 doi (DE-627)OLC2059761565 (DE-He213)s11663-001-0026-6-p DE-627 ger DE-627 rakwb eng 620 660 VZ Kurchania, Rajnish verfasserin aut Measurement of oxygen potentials in Ag-Pb system employing oxygen sensor 2001 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © ASM International & TMS-The Minerals, Metals and Materials Society 2001 Abstract Accurate and instantaneous analysis of dissolved nonmetallic or metallic species in molten metals at elevated temperatures using an online electrochemical sensor is important for continuous process control during metal refining and alloying operations in metallurgical industries. In this article, the application of long-life, solid-state electrochemical sensors for oxygen has been demonstrated to measure the oxygen potential as a function of the lead concentration in a molten Ag-Pb system at 1323 K. Yttria-stabilized zirconia (YSZ) in the form of one end-closed tube 20 mm long, 3 mm inner diameter, and 1 mm wall thickness has been used as a solid electrolyte in the oxygen sensor. Electromotive force (EMF) of the solid-state electrochemical cell (−)Pt, Ni-NiO//YSZ//OAg-Pb, Mo(+) has been measured at 1323 K. The reference electrode consisted of Ni + NiO biphasic mixture; the working electrode was composed of a molten Ag-Pb alloy of varying concentrations of lead. The concentrations of lead in silver ranged from 0.02 to 10.20 wt pct. Samples of the molten alloy were drawn after each addition of Pb to Ag and analyzed by induction coupled plasma (ICP). Material Transaction Oxygen Sensor Oxygen Potential Lead Shot Lead Addition Kale, Girish M. aut Enthalten in Metallurgical and materials transactions / B Springer-Verlag, 1994 32(2001), 3 vom: Juni, Seite 417-421 (DE-627)182203832 (DE-600)1186125-3 (DE-576)038889196 1073-5615 nnns volume:32 year:2001 number:3 month:06 pages:417-421 https://doi.org/10.1007/s11663-001-0026-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_11 GBV_ILN_20 GBV_ILN_30 GBV_ILN_62 GBV_ILN_70 GBV_ILN_2027 GBV_ILN_4046 GBV_ILN_4307 GBV_ILN_4319 GBV_ILN_4323 AR 32 2001 3 06 417-421 |
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Kurchania, Rajnish Kale, Girish M. |
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title_sort |
measurement of oxygen potentials in ag-pb system employing oxygen sensor |
title_auth |
Measurement of oxygen potentials in Ag-Pb system employing oxygen sensor |
abstract |
Abstract Accurate and instantaneous analysis of dissolved nonmetallic or metallic species in molten metals at elevated temperatures using an online electrochemical sensor is important for continuous process control during metal refining and alloying operations in metallurgical industries. In this article, the application of long-life, solid-state electrochemical sensors for oxygen has been demonstrated to measure the oxygen potential as a function of the lead concentration in a molten Ag-Pb system at 1323 K. Yttria-stabilized zirconia (YSZ) in the form of one end-closed tube 20 mm long, 3 mm inner diameter, and 1 mm wall thickness has been used as a solid electrolyte in the oxygen sensor. Electromotive force (EMF) of the solid-state electrochemical cell (−)Pt, Ni-NiO//YSZ//OAg-Pb, Mo(+) has been measured at 1323 K. The reference electrode consisted of Ni + NiO biphasic mixture; the working electrode was composed of a molten Ag-Pb alloy of varying concentrations of lead. The concentrations of lead in silver ranged from 0.02 to 10.20 wt pct. Samples of the molten alloy were drawn after each addition of Pb to Ag and analyzed by induction coupled plasma (ICP). © ASM International & TMS-The Minerals, Metals and Materials Society 2001 |
abstractGer |
Abstract Accurate and instantaneous analysis of dissolved nonmetallic or metallic species in molten metals at elevated temperatures using an online electrochemical sensor is important for continuous process control during metal refining and alloying operations in metallurgical industries. In this article, the application of long-life, solid-state electrochemical sensors for oxygen has been demonstrated to measure the oxygen potential as a function of the lead concentration in a molten Ag-Pb system at 1323 K. Yttria-stabilized zirconia (YSZ) in the form of one end-closed tube 20 mm long, 3 mm inner diameter, and 1 mm wall thickness has been used as a solid electrolyte in the oxygen sensor. Electromotive force (EMF) of the solid-state electrochemical cell (−)Pt, Ni-NiO//YSZ//OAg-Pb, Mo(+) has been measured at 1323 K. The reference electrode consisted of Ni + NiO biphasic mixture; the working electrode was composed of a molten Ag-Pb alloy of varying concentrations of lead. The concentrations of lead in silver ranged from 0.02 to 10.20 wt pct. Samples of the molten alloy were drawn after each addition of Pb to Ag and analyzed by induction coupled plasma (ICP). © ASM International & TMS-The Minerals, Metals and Materials Society 2001 |
abstract_unstemmed |
Abstract Accurate and instantaneous analysis of dissolved nonmetallic or metallic species in molten metals at elevated temperatures using an online electrochemical sensor is important for continuous process control during metal refining and alloying operations in metallurgical industries. In this article, the application of long-life, solid-state electrochemical sensors for oxygen has been demonstrated to measure the oxygen potential as a function of the lead concentration in a molten Ag-Pb system at 1323 K. Yttria-stabilized zirconia (YSZ) in the form of one end-closed tube 20 mm long, 3 mm inner diameter, and 1 mm wall thickness has been used as a solid electrolyte in the oxygen sensor. Electromotive force (EMF) of the solid-state electrochemical cell (−)Pt, Ni-NiO//YSZ//OAg-Pb, Mo(+) has been measured at 1323 K. The reference electrode consisted of Ni + NiO biphasic mixture; the working electrode was composed of a molten Ag-Pb alloy of varying concentrations of lead. The concentrations of lead in silver ranged from 0.02 to 10.20 wt pct. Samples of the molten alloy were drawn after each addition of Pb to Ag and analyzed by induction coupled plasma (ICP). © ASM International & TMS-The Minerals, Metals and Materials Society 2001 |
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container_issue |
3 |
title_short |
Measurement of oxygen potentials in Ag-Pb system employing oxygen sensor |
url |
https://doi.org/10.1007/s11663-001-0026-6 |
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up_date |
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