A polymeric approach to the sulfide capacity of silicate slags and melts
Abstract A thermochemical model for calculating the sulfide capacity of simple and complex silicate melts in the framework of the Toop-Samis polymeric model combined with a Flood-Grjotheim treatment of partial reactions is proposed. “Electrically equivalent ion fractions” are computed, in a fused sa...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Moretti, Roberto [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2003 |
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| Schlagwörter: |
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| Anmerkung: |
© ASM International & TMS-The Minerals, Metals and Materials Society 2003 |
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| Übergeordnetes Werk: |
Enthalten in: Metallurgical and materials transactions / B - Springer-Verlag, 1994, 34(2003), 4 vom: Aug., Seite 399-410 |
|---|---|
| Übergeordnetes Werk: |
volume:34 ; year:2003 ; number:4 ; month:08 ; pages:399-410 |
| Links: |
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| DOI / URN: |
10.1007/s11663-003-0066-1 |
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OLC2059763665 |
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| 520 | |a Abstract A thermochemical model for calculating the sulfide capacity of simple and complex silicate melts in the framework of the Toop-Samis polymeric model combined with a Flood-Grjotheim treatment of partial reactions is proposed. “Electrically equivalent ion fractions” are computed, in a fused salt Temkin notation, over the appropriate matrixes, whose relative extensions are assigned by solving the mass balances of the Toop-Samis model. The polymerization constant between quasi-chemical species of oxygen is related to the contrast of acid-base properties of the slag-constituent oxides, depending on their role of either network former or modifier and on their optical basicity value. Model activities follow the Raoultian behavior implicit in the ion matrix solution of the Temkin notation and the adopted parameters bring a clear energetic significance. The model displays a high heuristic capability with virtually no compositional limits as long as the structural role assigned to each oxide holds. | ||
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10.1007/s11663-003-0066-1 doi (DE-627)OLC2059763665 (DE-He213)s11663-003-0066-1-p DE-627 ger DE-627 rakwb eng 620 660 VZ Moretti, Roberto verfasserin aut A polymeric approach to the sulfide capacity of silicate slags and melts 2003 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © ASM International & TMS-The Minerals, Metals and Materials Society 2003 Abstract A thermochemical model for calculating the sulfide capacity of simple and complex silicate melts in the framework of the Toop-Samis polymeric model combined with a Flood-Grjotheim treatment of partial reactions is proposed. “Electrically equivalent ion fractions” are computed, in a fused salt Temkin notation, over the appropriate matrixes, whose relative extensions are assigned by solving the mass balances of the Toop-Samis model. The polymerization constant between quasi-chemical species of oxygen is related to the contrast of acid-base properties of the slag-constituent oxides, depending on their role of either network former or modifier and on their optical basicity value. Model activities follow the Raoultian behavior implicit in the ion matrix solution of the Temkin notation and the adopted parameters bring a clear energetic significance. The model displays a high heuristic capability with virtually no compositional limits as long as the structural role assigned to each oxide holds. Material Transaction Sulfide Capacity Optical Basicity Maximum Bias Sulfide Solubility Ottonello, Giulio aut Enthalten in Metallurgical and materials transactions / B Springer-Verlag, 1994 34(2003), 4 vom: Aug., Seite 399-410 (DE-627)182203832 (DE-600)1186125-3 (DE-576)038889196 1073-5615 nnns volume:34 year:2003 number:4 month:08 pages:399-410 https://doi.org/10.1007/s11663-003-0066-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_20 GBV_ILN_30 GBV_ILN_62 GBV_ILN_70 GBV_ILN_602 GBV_ILN_2027 GBV_ILN_4046 GBV_ILN_4319 GBV_ILN_4323 AR 34 2003 4 08 399-410 |
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10.1007/s11663-003-0066-1 doi (DE-627)OLC2059763665 (DE-He213)s11663-003-0066-1-p DE-627 ger DE-627 rakwb eng 620 660 VZ Moretti, Roberto verfasserin aut A polymeric approach to the sulfide capacity of silicate slags and melts 2003 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © ASM International & TMS-The Minerals, Metals and Materials Society 2003 Abstract A thermochemical model for calculating the sulfide capacity of simple and complex silicate melts in the framework of the Toop-Samis polymeric model combined with a Flood-Grjotheim treatment of partial reactions is proposed. “Electrically equivalent ion fractions” are computed, in a fused salt Temkin notation, over the appropriate matrixes, whose relative extensions are assigned by solving the mass balances of the Toop-Samis model. The polymerization constant between quasi-chemical species of oxygen is related to the contrast of acid-base properties of the slag-constituent oxides, depending on their role of either network former or modifier and on their optical basicity value. Model activities follow the Raoultian behavior implicit in the ion matrix solution of the Temkin notation and the adopted parameters bring a clear energetic significance. The model displays a high heuristic capability with virtually no compositional limits as long as the structural role assigned to each oxide holds. Material Transaction Sulfide Capacity Optical Basicity Maximum Bias Sulfide Solubility Ottonello, Giulio aut Enthalten in Metallurgical and materials transactions / B Springer-Verlag, 1994 34(2003), 4 vom: Aug., Seite 399-410 (DE-627)182203832 (DE-600)1186125-3 (DE-576)038889196 1073-5615 nnns volume:34 year:2003 number:4 month:08 pages:399-410 https://doi.org/10.1007/s11663-003-0066-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_20 GBV_ILN_30 GBV_ILN_62 GBV_ILN_70 GBV_ILN_602 GBV_ILN_2027 GBV_ILN_4046 GBV_ILN_4319 GBV_ILN_4323 AR 34 2003 4 08 399-410 |
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10.1007/s11663-003-0066-1 doi (DE-627)OLC2059763665 (DE-He213)s11663-003-0066-1-p DE-627 ger DE-627 rakwb eng 620 660 VZ Moretti, Roberto verfasserin aut A polymeric approach to the sulfide capacity of silicate slags and melts 2003 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © ASM International & TMS-The Minerals, Metals and Materials Society 2003 Abstract A thermochemical model for calculating the sulfide capacity of simple and complex silicate melts in the framework of the Toop-Samis polymeric model combined with a Flood-Grjotheim treatment of partial reactions is proposed. “Electrically equivalent ion fractions” are computed, in a fused salt Temkin notation, over the appropriate matrixes, whose relative extensions are assigned by solving the mass balances of the Toop-Samis model. The polymerization constant between quasi-chemical species of oxygen is related to the contrast of acid-base properties of the slag-constituent oxides, depending on their role of either network former or modifier and on their optical basicity value. Model activities follow the Raoultian behavior implicit in the ion matrix solution of the Temkin notation and the adopted parameters bring a clear energetic significance. The model displays a high heuristic capability with virtually no compositional limits as long as the structural role assigned to each oxide holds. Material Transaction Sulfide Capacity Optical Basicity Maximum Bias Sulfide Solubility Ottonello, Giulio aut Enthalten in Metallurgical and materials transactions / B Springer-Verlag, 1994 34(2003), 4 vom: Aug., Seite 399-410 (DE-627)182203832 (DE-600)1186125-3 (DE-576)038889196 1073-5615 nnns volume:34 year:2003 number:4 month:08 pages:399-410 https://doi.org/10.1007/s11663-003-0066-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_20 GBV_ILN_30 GBV_ILN_62 GBV_ILN_70 GBV_ILN_602 GBV_ILN_2027 GBV_ILN_4046 GBV_ILN_4319 GBV_ILN_4323 AR 34 2003 4 08 399-410 |
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10.1007/s11663-003-0066-1 doi (DE-627)OLC2059763665 (DE-He213)s11663-003-0066-1-p DE-627 ger DE-627 rakwb eng 620 660 VZ Moretti, Roberto verfasserin aut A polymeric approach to the sulfide capacity of silicate slags and melts 2003 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © ASM International & TMS-The Minerals, Metals and Materials Society 2003 Abstract A thermochemical model for calculating the sulfide capacity of simple and complex silicate melts in the framework of the Toop-Samis polymeric model combined with a Flood-Grjotheim treatment of partial reactions is proposed. “Electrically equivalent ion fractions” are computed, in a fused salt Temkin notation, over the appropriate matrixes, whose relative extensions are assigned by solving the mass balances of the Toop-Samis model. The polymerization constant between quasi-chemical species of oxygen is related to the contrast of acid-base properties of the slag-constituent oxides, depending on their role of either network former or modifier and on their optical basicity value. Model activities follow the Raoultian behavior implicit in the ion matrix solution of the Temkin notation and the adopted parameters bring a clear energetic significance. The model displays a high heuristic capability with virtually no compositional limits as long as the structural role assigned to each oxide holds. Material Transaction Sulfide Capacity Optical Basicity Maximum Bias Sulfide Solubility Ottonello, Giulio aut Enthalten in Metallurgical and materials transactions / B Springer-Verlag, 1994 34(2003), 4 vom: Aug., Seite 399-410 (DE-627)182203832 (DE-600)1186125-3 (DE-576)038889196 1073-5615 nnns volume:34 year:2003 number:4 month:08 pages:399-410 https://doi.org/10.1007/s11663-003-0066-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_20 GBV_ILN_30 GBV_ILN_62 GBV_ILN_70 GBV_ILN_602 GBV_ILN_2027 GBV_ILN_4046 GBV_ILN_4319 GBV_ILN_4323 AR 34 2003 4 08 399-410 |
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10.1007/s11663-003-0066-1 doi (DE-627)OLC2059763665 (DE-He213)s11663-003-0066-1-p DE-627 ger DE-627 rakwb eng 620 660 VZ Moretti, Roberto verfasserin aut A polymeric approach to the sulfide capacity of silicate slags and melts 2003 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © ASM International & TMS-The Minerals, Metals and Materials Society 2003 Abstract A thermochemical model for calculating the sulfide capacity of simple and complex silicate melts in the framework of the Toop-Samis polymeric model combined with a Flood-Grjotheim treatment of partial reactions is proposed. “Electrically equivalent ion fractions” are computed, in a fused salt Temkin notation, over the appropriate matrixes, whose relative extensions are assigned by solving the mass balances of the Toop-Samis model. The polymerization constant between quasi-chemical species of oxygen is related to the contrast of acid-base properties of the slag-constituent oxides, depending on their role of either network former or modifier and on their optical basicity value. Model activities follow the Raoultian behavior implicit in the ion matrix solution of the Temkin notation and the adopted parameters bring a clear energetic significance. The model displays a high heuristic capability with virtually no compositional limits as long as the structural role assigned to each oxide holds. Material Transaction Sulfide Capacity Optical Basicity Maximum Bias Sulfide Solubility Ottonello, Giulio aut Enthalten in Metallurgical and materials transactions / B Springer-Verlag, 1994 34(2003), 4 vom: Aug., Seite 399-410 (DE-627)182203832 (DE-600)1186125-3 (DE-576)038889196 1073-5615 nnns volume:34 year:2003 number:4 month:08 pages:399-410 https://doi.org/10.1007/s11663-003-0066-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_20 GBV_ILN_30 GBV_ILN_62 GBV_ILN_70 GBV_ILN_602 GBV_ILN_2027 GBV_ILN_4046 GBV_ILN_4319 GBV_ILN_4323 AR 34 2003 4 08 399-410 |
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A polymeric approach to the sulfide capacity of silicate slags and melts |
| abstract |
Abstract A thermochemical model for calculating the sulfide capacity of simple and complex silicate melts in the framework of the Toop-Samis polymeric model combined with a Flood-Grjotheim treatment of partial reactions is proposed. “Electrically equivalent ion fractions” are computed, in a fused salt Temkin notation, over the appropriate matrixes, whose relative extensions are assigned by solving the mass balances of the Toop-Samis model. The polymerization constant between quasi-chemical species of oxygen is related to the contrast of acid-base properties of the slag-constituent oxides, depending on their role of either network former or modifier and on their optical basicity value. Model activities follow the Raoultian behavior implicit in the ion matrix solution of the Temkin notation and the adopted parameters bring a clear energetic significance. The model displays a high heuristic capability with virtually no compositional limits as long as the structural role assigned to each oxide holds. © ASM International & TMS-The Minerals, Metals and Materials Society 2003 |
| abstractGer |
Abstract A thermochemical model for calculating the sulfide capacity of simple and complex silicate melts in the framework of the Toop-Samis polymeric model combined with a Flood-Grjotheim treatment of partial reactions is proposed. “Electrically equivalent ion fractions” are computed, in a fused salt Temkin notation, over the appropriate matrixes, whose relative extensions are assigned by solving the mass balances of the Toop-Samis model. The polymerization constant between quasi-chemical species of oxygen is related to the contrast of acid-base properties of the slag-constituent oxides, depending on their role of either network former or modifier and on their optical basicity value. Model activities follow the Raoultian behavior implicit in the ion matrix solution of the Temkin notation and the adopted parameters bring a clear energetic significance. The model displays a high heuristic capability with virtually no compositional limits as long as the structural role assigned to each oxide holds. © ASM International & TMS-The Minerals, Metals and Materials Society 2003 |
| abstract_unstemmed |
Abstract A thermochemical model for calculating the sulfide capacity of simple and complex silicate melts in the framework of the Toop-Samis polymeric model combined with a Flood-Grjotheim treatment of partial reactions is proposed. “Electrically equivalent ion fractions” are computed, in a fused salt Temkin notation, over the appropriate matrixes, whose relative extensions are assigned by solving the mass balances of the Toop-Samis model. The polymerization constant between quasi-chemical species of oxygen is related to the contrast of acid-base properties of the slag-constituent oxides, depending on their role of either network former or modifier and on their optical basicity value. Model activities follow the Raoultian behavior implicit in the ion matrix solution of the Temkin notation and the adopted parameters bring a clear energetic significance. The model displays a high heuristic capability with virtually no compositional limits as long as the structural role assigned to each oxide holds. © ASM International & TMS-The Minerals, Metals and Materials Society 2003 |
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| container_issue |
4 |
| title_short |
A polymeric approach to the sulfide capacity of silicate slags and melts |
| url |
https://doi.org/10.1007/s11663-003-0066-1 |
| remote_bool |
false |
| author2 |
Ottonello, Giulio |
| author2Str |
Ottonello, Giulio |
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182203832 |
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| doi_str |
10.1007/s11663-003-0066-1 |
| up_date |
2024-07-03T23:18:19.345Z |
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1803601784966479872 |
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